1032 results about "Electrodialysis" patented technology

The present invention relates to a system and a treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements. The system includes a bipolar membrane electrodialysis device, a phosphorus precipitator, and a membrane treatment device. Inside the bipolar membrane electrodialysis device, there are successively arranged a cathode, a first bipolar membrane, a main cation exchange membrane, a main anion exchange membrane, a second bipolar membrane, and an anode. Between the first bipolar membrane and the main cation exchange membrane is an alkali chamber, between the main cation exchange membrane and the main anion exchange membrane is a wastewater chamber, between the main anion exchange membrane and the second bipolar membrane is an acid chamber, the outside of the first bipolar membrane is a cathode chamber, and the outside of the second bipolar membrane is an anode chamber; the high-phosphorus wastewater is input into the wastewater chamber, the acid chamber is provided with a phosphoric acid recovery pipe, and the alkali chamber and the wastewater chamber are respectively connected to the phosphorus precipitator through an alkali liquid pipe and a first water production pipe; the phosphorus precipitator is provided with a precipitant inlet for inputting a calcium precipitant or a magnesium precipitant, the concentrated water outlet of the membrane treatment device is connected to the wastewater chamber, and the produced water of the membrane treatment device is reused as reclaimed water.

The invention discloses a method for efficiently separating and purifying plant exosomes and application, and belongs to the technical field of biological nanotechnology. The method comprises the following key steps: (1) performing sterile cleaning on plant raw materials, and then performing peeling or tissue slitting pretreatment; (2) carrying out mechanical crushing treatment by adopting a phosphate buffer solution (PBS), and filtering through a 200-mesh screen to obtain a primary extracting solution; (3) performing gradient centrifugal purification on the extracting solution, collecting supernate, and filtering the supernate through a 0.45 mu m microporous filter membrane; (4) adding 8-12% of polyethylene glycol for low-temperature phase separation and precipitation; (5) purifying by using an electrodialysis technology; and (6) carrying out final concentration by adopting a 100kDa ultrafiltration membrane to obtain the high-purity PELNs preparation. According to the method, the process, equipment and reagents are simple and easy to obtain, the final yield is high, the purity is high, particle size distribution is uniform, and an innovative solution is provided for large-scale industrial production of natural-source nano-drug carriers.

The invention relates to the technical field of coal bed gas development and gas extraction, in particular to an electrodialysis-liquid CO2 time sequence synergistic anti-reflection method and system. Comprising an electrodialysis pretreatment stage, a CO2 synergetic permeability increasing stage and a process regulation and energy recovery stage, a mixed solution is injected into a coal seam in a pulse injection mode, and energy recovery is conducted through pipeline fluid pressure in the injection stopping period. According to the technical scheme, through multi-stage cooperation of electrodialysis pretreatment, CO2 phase change fracturing and pulse consolidation and regulation, accurate transformation of the coal seam low-permeability area is achieved. According to the scheme, electrodialysis is utilized to drive an acidic working solution to target and migrate to a difficult-to-permeate area, mineral substances are dissolved, and pores are expanded; then, high-energy expansion stress is generated through liquid CO2 phase change, and a through fracture network is formed; and finally, a pulse injection and energy recovery mechanism is adopted, fracture closing is restrained, system energy consumption is reduced, and therefore the coal seam breathability and the gas extraction efficiency are integrally improved.

The utility model discloses an electrodialysis device with an automatic hydraulic station, and belongs to the field of electrodialysis devices. The hydraulic cylinder is connected with the electrodialysis assembly; an oil tank; one end of the pump body is communicated with the oil tank; the inlet end of the one-way valve is communicated with the other end of the pump body, and the outlet end of the one-way valve is communicated with the hydraulic cylinder; one end of the pressure sensor is communicated with the oil tank, and the other end of the pressure sensor is communicated between the outlet end of the one-way valve and the hydraulic cylinder; one end of the electromagnetic valve is communicated with the oil tank, and the other end of the electromagnetic valve is communicated between the outlet end of the one-way valve and the hydraulic cylinder; and the controller is electrically connected with the pressure sensor and the electromagnetic valve. The utility model has the technical effects that the pressure can be automatically controlled conveniently, and the pressure can be prevented from being too large or too small.

The invention relates to a novel composite bipolar membrane for preparing low-carbon alcohol alkali metal salt and an electrodialysis process of the novel composite bipolar membrane, and belongs to the technical field of membrane separation and electrochemical synthesis. The composite bipolar membrane comprises a cation exchange layer, a middle catalyst layer and an anion exchange layer which are sequentially laminated and compounded, the process comprises the following steps: introducing a salt solution containing alkali metal ions into an anode chamber of a bipolar membrane electrodialysis system, and introducing a low-carbon alcohol solution into a cathode chamber; applying a direct-current electric field to the two sides of the composite bipolar membrane, so that the low-carbon alcohol is dissociated at the membrane interface to generate alkoxy ions and hydrogen ions; the alkoxy ions migrate to an anode chamber to be combined with the alkali metal ions to generate low-carbon alcohol alkali metal salt; the membrane material is high in adaptability, the membrane structure is good in stability, technological parameters are mature, and the system integration degree is high.

The application discloses a bipolar membrane electrodialysis device, which comprises an outer box body and further comprises a liquid inlet mechanism, a plurality of electrodialysis mechanisms and a plurality of filtering mechanisms. The filtering mechanism comprises a filtering box, a driving filtering assembly and a liquid feeding assembly. The driving filtering assembly comprises a motor installed on the top of the filtering box, the output shaft of the motor is fixedly connected with a threaded rod, the outer periphery of the threaded rod is threadedly connected with a filtering plate slidingly connected to the inner wall of the filtering box, and the bottom inner wall of the filtering box is fixedly connected with a plurality of plug rods matched with filtering holes of the filtering plate. Raw water is delivered to the inside of the filtering box through the liquid inlet mechanism, is actively filtered without turbulence through the driving filtering assembly, is delivered to the corresponding electrodialysis mechanism through the liquid feeding assembly and is further subjected to electrodialysis treatment. The filtering plate and other components are arranged to filter out the solid impurities mixed in industrial glucose acid salt, so that the bipolar membrane electrodialysis process and the bipolar membrane body are not affected.

The invention belongs to the technical field of green processing of biomass materials, and particularly relates to a green preparation process of high-deacetylation-degree chitin. The preparation method aims at the problem of high energy consumption of existing high-deacetylation-degree chitin preparation. According to the method, raw materials are pretreated by utilizing a compound enzyme system under a low-temperature condition, chitin crystal lattices are preliminarily dissociated by combining a deep eutectic solvent at a medium temperature, high deacetylation conversion is realized through short-time dissolution of an ionic liquid, and meanwhile, a membrane separation-electrodialysis-gradient freezing crystallization three-stage recycling technology is matched, so that recycling of the solvent is realized; the method greatly reduces the reaction temperature and energy consumption, avoids the use of corrosive reagents, and has the advantages of environmental protection, low energy consumption, high deacetylation degree of the product, excellent quality and the like.

The invention relates to a method for simultaneously preparing lithium hydroxide and sulfuric acid. The invention provides a method for simultaneously preparing lithium hydroxide and sulfuric acid, which comprises the following steps: preparing a bipolar membrane electrodialysis device which comprises a first bipolar membrane, an anion exchange membrane, a cation exchange membrane and a second bipolar membrane, and forming an acid chamber between the first bipolar membrane and the anion exchange membrane, a salt chamber is formed between the anion exchange membrane and the cation exchange membrane, and an alkali chamber is formed between the cation exchange membrane and the second bipolar membrane; a lithium sulfate aqueous solution is added into a salt chamber of the bipolar membrane electrodialysis device, a sulfuric acid aqueous solution is added into an acid chamber, and a lithium hydroxide aqueous solution is added into an alkali chamber; and discharging the desalted solution formed in the salt chamber of the bipolar membrane electrodialysis device, discharging the sulfuric acid aqueous solution formed in the acid chamber, and discharging the lithium hydroxide aqueous solution formed in the alkali chamber.

The invention relates to the technical field of electrochemical water treatment, and discloses a high-salt waste liquid electric flocculation hardness removal and electrodialysis resourceful treatment method and a high-salt waste liquid electric flocculation hardness removal and electrodialysis resourceful treatment system. The method comprises the following steps: collecting water quality parameters of the high-salt waste liquid and initial electrochemical impedance spectroscopy parameters of a polar plate; calculating the initial current density according to the hardness and the conductivity, carrying out electric flocculation treatment, monitoring impedance spectrum change in real time, identifying the scaling type, and predicting the residual operation time of the polar plate; the current density is optimized according to the prediction time, and the residual hardness is calculated; and adjusting electrodialysis parameters by taking the residual hardness as a feedforward signal for concentration, and performing bipolar membrane electrodialysis on the concentrated solution to obtain acid-alkali liquor. The problems that in the electrochemical treatment process of the high-salt waste liquid, the state of a polar plate cannot be monitored in real time, consequently, operation parameters are adjusted blindly, and energy consumption is high and the recycling efficiency is low due to the fact that parameters of a pretreatment unit and parameters of a pretreatment unit are not linked are solved.

The present application relates to the field of functional nutritional condiment, and specifically discloses abalone umami peptide prepared by using abalone cooking waste liquid as raw material and a preparation method thereof, which comprises the following steps: (1) removing solid impurities from the abalone cooking waste liquid and removing heavy metals by electrodialysis; (2) adding specific protease to the material obtained in step (1) at a dosage of 0.1-1% of the weight of the solid content in the material obtained in step (1), and performing enzymatic reaction at a pH value of 6-7 and a reaction temperature of 40-60 DEG C for 0.5-2 h; (3) removing impurities by using nanofiltration membrane and performing spray drying to obtain abalone umami peptide. The abalone umami peptide prepared by the method solves the problem of environmental pollution caused by a large amount of abalone cooking waste liquid, and realizes a new way of resource utilization of abalone cooking waste liquid. The abalone umami peptide has a molecular weight of 1-2 KD and accounts for more than 70%, has high antioxidant bioactivity, low heavy metal content, and rich seafood flavor, and can be widely applied in the field of functional nutritional condiment.

Provided is a cation exchange membrane in which when a hydroxide aqueous solution showing strong alkalinity is produced by using an electrodialyzer, significant swelling in the cation exchange membrane in contact with the hydroxide aqueous solution is suppressed, destruction of a cation exchange resin due to polyvalent cations contained as impurities in a raw material inorganic salt is suppressed, and the capacity of the cation exchange membrane is hardly lowered.　This cation exchange membrane is characterized by having an electric resistance of 2.0-5.0 (Ω∙cm2), as measured at 25ºC in 0.5 mol / L of a NaCl aqueous solution, and a dimensional change rate of at most 1.2%.

The invention discloses a method for converting lithium hydroxide into lithium carbonate. The method comprises the following steps: S1, preparing or taking a lithium hydroxide solution and a carbonate solution; s2, putting the lithium hydroxide solution and the carbonate solution into electrodialysis equipment, and carrying out electrodialysis treatment; and S3, after electrodialysis is finished, collecting a lithium carbonate solution, and sequentially carrying out lithium precipitation and solid-liquid separation on the lithium carbonate solution to obtain the battery-grade lithium carbonate. According to the method for converting lithium hydroxide into lithium carbonate disclosed by the invention, CO2 is replaced by carbonate, so that the generation of lithium bicarbonate is avoided, the lithium carbonate and the byproduct alkali liquor are directly obtained, the raw material source is wide, the preparation condition is mild, the production cost is greatly reduced, and the method has huge potential economic benefits.

The invention belongs to the technical field of impurity separation, and particularly discloses a method for separating and purifying impurities in a process for preparing glyoxylic acid through oxalic acid electrolysis, a crystallization kettle is included, an isolation device is arranged in the crystallization kettle, and the isolation device comprises a conical top cover, a conveying pipe, an annular filter screen, a directional conveying assembly and a sealing assembly; the conical top cover is arranged at the axis of the crystallization kettle, an opening of the conical top cover faces downwards, and a plurality of fixing rods are fixedly connected between the top of the conical top cover and the inner wall of the side face of the crystallization kettle. According to the method, glyoxylic acid product solutions with different concentration specifications and the high-purity glyoxylic acid crystal can be obtained after the electrolyte is sequentially subjected to pre-evaporation, electrodialysis, secondary evaporation, cooling crystallization, solid-liquid separation, washing and drying and other procedures, so that the prepared high-purity glyoxylic acid crystal can be popularized and applied in the field of high-end medicine.

The utility model provides a vacuum concealed pipe circulating water salt elimination system which comprises a plurality of concealed pipes which are respectively connected with a water conveying pipe through a water collecting pipe; the concealed pipe comprises a pipe body, and a plurality of water collecting holes are formed in the pipe body; each water collecting pipe is provided with a vacuum negative-pressure drainage device, the water conveying pipe is connected with a salt washing water treatment device, and the water conveying pipe is provided with a water suction pump; a water outlet pipe is further connected to the salt washing water treatment device, and the water outlet pipe is connected with an irrigation leaching water distribution device used for leaching soil; the washing brine treatment device comprises an electrodialysis treatment unit, the front end of the electrodialysis treatment unit is connected with a reservoir, the rear end is connected with a fresh water tank, and a flowmeter is arranged on a pipeline for connecting the electrodialysis treatment unit and the reservoir; the fresh water pool is connected with the water outlet pipe, the reservoir is connected with the water pipe, the fresh water pool is further provided with an overflow pipe, and a drainage port end of the overflow pipe extends to the drainage ditch. According to the invention, the salt elimination efficiency is greatly improved, the investment cost of concealed pipe laying is reduced, the water is saved, and water pollution is prevented.

The invention discloses a method for preparing high-modulus sodium silicate and co-producing white carbon black from rice hull ash. The method comprises the following steps: crushing the rice hull ash, and acidizing to obtain purified rice hull ash powder; reacting the purified rice hull ash powder with 5wt%-15wt% of caustic soda generated by bipolar membrane electrolysis to prepare a sodium silicate solution; carrying out neutralization reaction on the sodium silicate solution and 1-15 wt% of sulfuric acid solution under the assistance of ultrasonic waves, and filtering to obtain silicon dioxide silica gel and filtrate; washing and drying the silicon dioxide silica gel to obtain a white carbon black product; and carrying out electrolytic treatment on the filtrate through a bipolar membrane electrodialysis system, and respectively recycling the recovered alkali liquor and acid liquor. According to the method, resource utilization of the rice hull ash and cyclic regeneration of the reaction medium are realized, and a green production process is formed.

The invention relates to a method for separating and purifying a liquid system, the liquid system comprises an ionic liquid with the concentration ranging from 0.05 mol / L to 6.0 mol / L and a metal salt with the concentration ratio of the ionic liquid to the metal salt ranging from 2: 1 to 1: 2, and the method comprises the following steps: carrying out first-stage electrodialysis on the liquid system at the first current density ranging from 0.1 mA / cm < 2 > to 50 mA / cm < 2 >, and carrying out second-stage electrodialysis on the liquid system at the second current density ranging from 0.1 mA / cm < 2 > to 50 mA / cm < 2 >; an ionic liquid primary product and a metal salt primary product are obtained; evaporating the ionic liquid primary product and the metal salt primary product to obtain an ionic liquid concentrated solution and a metal salt concentrated solution; and performing second-stage electrodialysis on the ionic liquid concentrated solution and the metal salt concentrated solution at a second current density of 0.1-50mA / cm < 2 > to obtain an ionic liquid product and a metal salt product. According to the method disclosed by the invention, all process links are properly joined and organically coupled, and the method is operated at normal temperature and normal pressure, has relatively high production efficiency, is easy for large-scale development, is an additive-free, basically secondary-waste-free and green method, and has industrial application value.

An electrochemical apparatus comprising: an anode; a bipolar membrane; an anion exchange membrane; a cation exchange membrane; and a cathode; wherein: the anode at least partially defines a first fluid flow path; the anode and / or the first fluid flow path is in contact with the anion exchange membrane of the bipolar membrane; a second fluid flow path is defined between the cation exchange membrane of the bipolar membrane and the anion exchange membrane; a third fluid flow path is defined between the anion exchange membrane and the cation exchange membrane; the cathode at least partially defines a fourth fluid flow path; and the cation exchange membrane is in contact with the cathode and / or the fourth fluid flow path.

The invention provides a method for recovering lithium phosphate from a lithium iron phosphate positive electrode material, which comprises the following steps: carrying out oxidation leaching on the lithium iron phosphate positive electrode material by using an acid solution and an oxidizing agent to obtain a first leaching solution and a first leaching residue; after water is added into the first leaching residues for size mixing, alkali leaching is conducted through sodium hydroxide, second leaching liquid and iron / carbon insoluble residues are obtained, and sodium phosphate crystals are obtained after the second leaching liquid is condensed; carrying out lithium precipitation reaction on the first leaching solution by using the sodium phosphate crystal to obtain lithium phosphate and lithium precipitation residual liquid; the lithium precipitation residual liquid is subjected to concentration and impurity removal, and then is subjected to a bipolar membrane electrodialysis process to obtain an acid solution and sodium hydroxide for reutilization. The invention aims to provide a method for mutually separating lithium, iron and phosphorus aiming at the waste lithium iron phosphate positive electrode material, the method can almost completely recover lithium, iron and phosphorus in the lithium iron phosphate positive electrode material, and the lithium is high in recovery rate and high in purity.

The invention provides a method for extracting lithium from sulfate subtype salt lake original brine and application, and belongs to the field of salt lake lithium extraction.The method for extracting lithium from sulfate subtype salt lake original brine comprises the following steps that the sulfate subtype salt lake original brine is subjected to pretreatment and nanofiltration treatment, and low-sulfate-radical brine and high-sulfate-radical brine are obtained; the low-sulfate-radical brine is subjected to desorption after being treated by an aluminum-series lithium adsorbent, and a first desorption solution is obtained; the high-sulfate-radical brine is desorbed after being treated by a titanium-series lithium adsorbent, and a second desorption solution is obtained; the first desorption solution and the second desorption solution are sequentially subjected to RO membrane concentration, multi-stage nanofiltration, electrodialysis concentration, evaporation concentration, resin impurity removal and lithium precipitation treatment, and the battery-grade lithium carbonate is obtained. The nanofiltration treatment is small in operation pressure and low in energy consumption; and the obtained low-sulfate-radical brine and high-sulfate-radical brine are respectively treated by adopting proper adsorbents according to different sulfate radical concentrations so as to efficiently recover lithium, so that the lithium yield is improved, the operation is simple, and the obtained battery-grade lithium carbonate is high in purity and excellent in performance.

The invention discloses a preparation and application method of a modified ion exchange membrane for electrodialysis, aiming at the problems of poor selectivity, low mechanical strength, high energy consumption and the like of the existing ion exchange membrane, the high-performance modified membrane is prepared by a base membrane pretreatment-functional grafting-gradient curing synergistic process. The preparation method specifically comprises the following steps: performing ultrasonic cleaning and acid-base activation on a polyethersulfone or sulfonated polystyrene-based membrane, soaking the polyethersulfone or sulfonated polystyrene-based membrane in a modification solution containing an amino / carboxyl / sulfo functional monomer, a cross-linking agent and an initiator, and performing gradient heating curing to form a stable cross-linked network; the grafting rate of the modified membrane is 15-35%, the ion exchange capacity is 1.8-2.5 mmol / g, the water content is 25-40%, and the membrane surface resistance is less than 3 omega.cm < 2 >. When the membrane is applied to an electrodialysis device, the membrane runs under the conditions of 10-30V direct-current voltage, 5-15cm / s flow velocity and 25-45 DEG C, the high-salinity wastewater desalination rate is greater than or equal to 95%, and the monovalent ion selectivity coefficient reaches 5.8-7.2; when the catalyst is used for acid-base recovery, the H < + > migration number is 0.92-0.96, and the energy consumption is reduced by 18-25%.

The invention provides a temperature control enhanced biological electrodialysis ammonia recovery system and a recovery method. The recovery system comprises a microbial electrodialysis cell and an ammonia recovery unit, the microbial electrodialysis pool comprises a pool body, a cation exchange membrane, an anode chamber, a cathode chamber, an anode, a cathode, a power supply and a temperature control piece; the anode chamber is provided with an anolyte inlet and an anolyte outlet, and the cathode chamber is provided with a catholyte inlet and a catholyte outlet; the anode chamber is filled with ammonia-nitrogen wastewater to be treated, and the cathode chamber is filled with catholyte; the temperature control piece can control the temperature in the anode chamber and the cathode chamber for heating; the ammonia recovery unit comprises an absorption tank and a membrane assembly; the absorption tank is filled with acidic absorption liquid; membrane filaments of the membrane assembly are soaked in the acid absorption liquid, the membrane assembly is provided with an inlet end and an outlet end which are communicated with the membrane filaments, the inlet end is connected with the catholyte outlet, and the outlet end is connected with the catholyte inlet. According to the ammonia recovery system disclosed by the invention, the removal and recovery efficiency of ammonia nitrogen can be remarkably improved through a reasonable regulation and control mode, and the ammonia nitrogen recovery efficiency is optimized.

The invention relates to the technical field of environmental protection, in particular to a resourceful treatment method for washing fly ash and application. The method provided by the invention overcomes the defects of low resource recovery rate and residual pollutants in the existing resourceful treatment of the washing fly ash. The method comprises the following steps: firstly mixing the fly ash with a chelating agent, then mixing with an acid washing solution, and carrying out primary washing to obtain a primary filter cake and a primary filtrate; performing second-stage washing on the first-stage filter cake by using deacidified wastewater to obtain a second-stage filter cake and second-stage filtrate; performing third-stage washing on the second-stage filter cake by using condensed water to obtain a third-stage filter cake and third-stage filtrate; the method comprises the following steps: firstly, carrying out pH regulation and flocculation treatment to generate a precipitate and a purified filtrate, and carrying out filtration, electrodialysis and evaporative crystallization on the purified filtrate to obtain sodium chloride and sodium sulfate; and mixing the third-stage filter cake with the precipitate, carrying out melting treatment, and cooling a vitrification product. The resourceful treatment method for the washing fly ash is high in resourceful efficiency and low in pollutant residue.

The invention provides a method for extracting and separating a general flavone crude extract from paeonia lactiflora stems and leaves, which comprises the following steps: adding a choline chloride-malic acid eutectic solvent into paeonia lactiflora stem and leaf powder, soaking, carrying out ultrasonic treatment, carrying out suction filtration to remove solid impurities to obtain a paeonia lactiflora stem and leaf extracting solution, diluting with ultrapure water, carrying out electrodialysis treatment, and drying to obtain the general flavone crude extract. A solid-liquid mixture containing solid residues is obtained in the middle chamber, precipitates are reserved after centrifugation, and the total flavone crude extract is obtained after blow-drying. The invention also provides application of the extracted and separated total flavone crude extract in preparation of medicines, cosmetics or functional foods for antioxidation, anti-inflammation, anti-tumor, cardiovascular protection or / and immunoregulation. The method is high in separation speed, high in separation rate and environment-friendly, flavone loss can be reduced to the maximum extent, and the yield of the total flavone crude extract is 0.27%-0.39%.

This invention belongs to the field of biomass subcritical fertilizer production, specifically relating to a mobile photovoltaic-powered subcritical fertilizer production system and its product application aimed at reducing nitrogen and phosphorus emissions, increasing efficiency, and resource-based disposal of high-moisture waste. It includes a solar preheating system, a photovoltaic power supply system, an auxiliary heating system, a hydrothermal reaction system, and a post-treatment system. The photovoltaic power supply system and auxiliary heating system are connected to the electrical load of the hydrothermal reaction system; the hydrothermal reaction system is connected to both the solar preheating system and the post-treatment system. This invention utilizes electrodialysis technology to desalinate the hydrothermal charcoal before returning it to the field. Through electrodialysis, the desalination rate of the charcoal reaches 45%-90%, and the conductivity of the desalinated charcoal is 1.40-6.75 mS / cm. The desalinated charcoal significantly increases crop yield; chlorophyll content increases by 25.5-67.5%, fresh weight increases by 18.5%-175%, and lettuce root length increases by 37.0%-98.2%. The high degree of desalination avoids the negative effects of salt stress on lettuce roots.

The invention discloses a method for separating lithium and boron in a solution with a high boron-lithium ratio. The separation method comprises the following steps: carrying out primary homogeneous electrodialysis concentration separation on a solution with a high boron-lithium ratio under an alkaline condition to prepare primary lithium-rich concentrated water; diluting the first-stage lithium-rich concentrated water to prepare first-stage diluted lithium-rich concentrated water; performing high-pressure RO concentration on the primary diluted lithium-rich concentrated water under an acidic condition to prepare lithium-rich RO concentrated water; performing first-stage homogeneous phase electrodialysis concentration separation on the lithium-rich RO concentrated water under an acidic condition to prepare first-stage lithium-rich concentrated water; carrying out adsorption boron removal and desorption treatment on the first-stage lithium-rich concentrated water by adopting boron removal adsorption resin under an alkaline condition to prepare mixed lithium-rich concentrated water and boron-containing desorption liquid; carrying out MVR (mechanical vapor recompression) evaporation on the mixed lithium-rich concentrated water for preparing battery-grade lithium carbonate; and mixing the secondary boron-rich fresh water with the boron-containing desorption solution, and carrying out MVR evaporation to obtain a boric acid product. According to the method, a reasonable boron removal process combination is adopted, and boron in the solution with the high boron-lithium ratio is removed.

A direct electrolysis technology for a natural mineral wet mineralization CO2 capture stock solution belongs to the field of carbon capture and resource utilization, and is characterized in that CO2 is captured through natural mineral wet mineralization to generate a bicarbonate solution, an electrolytic bath is constructed by using a bismuth-based catalyst and a cation exchange membrane to directly electrolyze to generate formate, and the formate is directly electrolyzed to generate the CO2 capture stock solution. Formate and regenerated trapping liquid are separated through a bipolar membrane electrodialysis technology, slag can be converted into a silicon-based building material, and integration of emission reduction, value addition and circulation is achieved. Compared with a traditional amine trapping technology, the method has the advantages that the energy consumption is reduced by 40%-50%, the trapping liquid raw material cost is reduced by 60%-70%, the problems of solvent volatilization and equipment corrosion are avoided, and the method is suitable for distributed carbon trapping and resource conversion in high-emission industries such as steel and chemical engineering.

The invention relates to the field of comprehensive utilization of biomass resources and preparation of high polymer materials, in particular to a green preparation method of high-deacetylation-degree chitin capable of recycling reaction waste liquid. The invention aims to solve the problems of serious environmental pollution, resource waste, low product purity and incomplete waste liquid recycling in chitin extraction. The method comprises the following steps: by taking crustacean biomass as a raw material, firstly carrying out high-voltage pulse electric field pretreatment to crush the tissue structure of the raw material and improve the reaction activity, and then heating and extracting in a choline chloride-lactic acid deep eutectic solvent system to realize efficient removal of proteins and inorganic salts in the raw material; according to the method, the chitin and the alkali liquor are subjected to a rapid deacetylation reaction by adopting microwave assistance and cooperating with the action of the phase transfer catalyst; according to the method, a waste liquid graded recycling system is adopted, hydrochloric acid in waste acid liquid generated by decalcification is recycled through electrodialysis, alkali liquid is recycled through ultrafiltration-nanofiltration double-membrane combination, deep eutectic solvent components are recycled through reduced pressure distillation, and recycling of acid, alkali and a solvent is achieved.

The invention discloses a preparation method of an ether-containing side chain modified cation selective separation membrane, which comprises the following steps: by taking an own microporous polymer as a precursor for preparing a membrane material, realizing an ion exchange function of the membrane material through grafting a sulfonated monomer; on the basis, the transmission difference of different ions in the membrane is further realized through grafting of ether-bond-containing micromolecular monomers, the ion selectivity is constructed, and the prepared membrane material has the ion separation performance superior to that of a current commercial cation selective separation membrane. The industrial production difficulty is remarkably reduced by the membrane synthesis preparation route of the solution grafting reaction, the large-scale production is easy to realize, and the prepared membrane material can reach the ion flux of industrial-grade electrodialysis and is expected to realize large-scale application.

The invention discloses a waste sulfuric acid treatment method and device, the device comprises a sintered filter element filter, a fine filtration coalescer, an adsorption tank and a membrane separator which are connected in sequence, and the fine filtration coalescer adopts a ceramic membrane tube or a polytetrafluoroethylene membrane tube or a silicon carbide lining membrane tube as a filter material; an adsorption material in the adsorption tank is one or a combined adsorption material of more than two of activated carbon, a modified molecular sieve, a metal organic framework material and a nano adsorption material; and the membrane separation system adopts one or a combined membrane of more than two of an ultrafiltration membrane, a reverse osmosis membrane and an electrodialysis membrane. The alkylation waste acid regeneration process can be simplified, the occupied area of the device is saved, the engineering investment is reduced, and the operation cost is greatly reduced compared with that of an existing process technology; according to the method, a physical separation means is adopted, organic polymeric oil, dissolved organic matters, dissolved salts and other impurities in the alkylated waste sulfuric acid can be effectively removed without decomposing and reconstructing the waste sulfuric acid, and the concentrated sulfuric acid after concentration completely meets the production requirements of an alkylation device.

The invention discloses a phosphoric acid production process which comprises the following steps: S1, mixing phosphoric acid and phosphorite in a reactor for reaction, and filtering and washing reaction liquid to obtain monocalcium phosphate filtrate; s2, the monocalcium phosphate filtrate enters a bipolar membrane electrodialyzer, the bipolar membrane electrodialyzer is formed by sequentially arranging a cation exchange membrane, an anion exchange membrane and a bipolar membrane, and an acid chamber, a salt chamber and an alkali chamber are formed respectively; the monocalcium phosphate is converted into phosphoric acid and calcium hydroxide under the action of the electrodialyzer. According to the method, phosphoric acid with relatively high purity can be directly prepared, and phosphogypsum is not generated. Compared with the traditional wet-process phosphoric acid, the produced solid waste amount is sharply reduced and is about one tenth to one twentieth of that of the traditional wet-process phosphoric acid, and the phosphoric acid is rich in silicon, magnesium, iron and the like and can be used as a fertilizer additive.