2694results about "Regenerative fuel cells" patented technology

The invention discloses an intelligent energy scheduling method and system for a flow battery, and relates to the technical field of flow batteries, and the method comprises the following steps: collecting energy operation parameters of the flow battery in real time, and dynamically estimating an electrolyte state to obtain multiple pieces of energy state information; a target to be dispatched is set, and a fuzzy control strategy is formulated through retrograde multi-target optimization; executing a fuzzy control strategy to generate a regulation and control signal set and scheduling; and finally, according to a scheduling result, performing reverse tracing to optimize a fuzzy control strategy, and updating a regulation signal set to obtain a multi-stage regulation instruction to perform intelligent scheduling on the energy of the flow battery. The method solves the technical problems of low matching degree between a scheduling strategy and an actual demand, large power loss and fast battery life attenuation caused by difficulty in accurately capturing an energy state in real time in a traditional flow battery scheduling method, and achieves the purposes of intelligent flow battery energy scheduling, power loss reduction, battery life prolonging and energy conservation. And the matching degree between the scheduling and the actual demand is improved.

The invention discloses a positive electrode material for a zinc-bromine flow battery and a preparation method and application thereof, and belongs to the technical field of zinc-bromine flow batteries, the preparation method comprises the following steps: crushing and sieving an active carbon source, adding the active carbon source into a graphene oxide aqueous dispersion, stirring, centrifuging, removing supernate, drying, mixing with an activating agent, and activating in an inert atmosphere; washing to be neutral, drying and sieving to obtain a graphene / activated carbon composite material; and attaching the graphene / activated carbon composite material to a carbon-plastic bipolar plate to obtain the positive electrode material for the zinc-bromine flow battery. A graphene / activated carbon composite system is combined with a high-conductivity network, graded holes and surface functional groups, so that the reaction kinetics bottleneck of a traditional carbon material Br2 is broken through.

The invention discloses preparation and application of a diatomic catalyst modified carbon felt electrode. The preparation method of the modified carbon felt electrode comprises the following steps: dissolving bismuth salt, cobalt salt and urea in water to obtain a complexing solution; immersing the carbon felt substrate subjected to acid activation into a complexing solution for soaking treatment, then taking out the carbon felt substrate, and drying to obtain a precursor-loaded carbon felt; and sequentially carrying out primary heating, cold shock and secondary heating treatment on the precursor-loaded carbon felt, and cooling to obtain the Bi-Co diatom modified carbon felt electrode. The carbon felt electrode can be applied to an all-vanadium redox flow battery. The innovation point of the invention lies in that through the synergistic effect of double atoms and the mutual cooperation of the nitrogen-doped carbon substrate, the intrinsic activity bottleneck of the traditional catalyst is broken through, the comprehensive advantages of high catalytic activity, excellent stability and low cost are achieved, and a new technical solution is provided for the high performance and large-scale application of the flow battery.

The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.

The invention provides a flow battery composite electrode, a preparation method thereof and a flow battery. The preparation method comprises the following steps: placing a pretreated carbonaceous substrate in a mixed solution of a surfactant, an electrolyte and a transition metal salt, growing a metal oxide nanosheet array on the surface of the pretreated carbonaceous substrate by using an electrochemical deposition process, washing, drying and roasting to obtain the flow battery composite electrode, wherein the feeding ratio of the surfactant to the transition metal salt is (1-2) g: (0.02-0.2) mol. The invention also provides the flow battery composite electrode prepared by the preparation method and a flow battery prepared from the electrode. According to the preparation method, the electrochemical reaction activity of the electrode in the all-vanadium redox flow battery can be optimized by regulating and controlling the chemical composition and the microstructure of the catalyst loaded on the surface of the carbon fiber.

The invention discloses a zinc-bromine flow battery multifunctional negative electrode electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: uniformly stirring and mixing a solvent, deionized water and a cosolvent, adding an electrolyte, stirring until the electrolyte is completely dissolved, then adding a supporting electrolyte and a negative electrode additive, stirring until the supporting electrolyte and the negative electrode additive are completely dissolved, and obtaining the zinc-bromine flow battery multifunctional negative electrode electrolyte. The multifunctional negative electrode electrolyte of the zinc-bromine flow battery is obtained; the negative electrode cosolvent is dimethylformamide; and the negative electrode additive is at least one of saponin and cinnamyl aldehyde. Saponin molecules are adsorbed on the surface of the zinc electrode, and electronegative carboxyl groups of the saponin molecules form an electrostatic repulsion net in an electric double layer, so that zinc ions are forced to be uniformly dispersed, local ion concentration hot spots are eliminated, and dendritic crystal nucleation is inhibited from the source. In cinnamyl aldehyde, the strong electronegativity of oxygen atoms and the electronegativity of aldehyde oxygen are far higher than those of hydrogen, so that electrons are strongly attracted, adjacent carbon atoms are positively charged, polar adsorption sites are formed, the hydrogen evolution reaction is effectively inhibited, and the stability and the cycle life of the battery are greatly improved.

To provide an electrolyte for a redox flow battery that can reduce deposition of a metal forming an organometallic complex.SOLUTION: There is provided the electrolyte for a redox flow battery, including: an organometallic complex; and an auxiliary complexing agent including at least one type selected from the group consisting of a polycarboxylic acid, a polyol, and an aminocarboxylic acid.SELECTED DRAWING: Figure 1

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: dissolving aniline and a dithio compound in an acidic ice bath, dropwise adding a peroxy strong oxidant to generate a polyaniline-disulfide bond copolymer, dialyzing, and freeze-drying to obtain powder; then heating soluble silver salt, a reducing agent, a hydrophilic dispersing agent and an organic sulfydryl silane coupling agent to prepare functionalized nano-silver particles; the powder and nano-silver particles are dispersed in N-methyl pyrrolidone for ultrasonic treatment, and dynamic self-repairing coating slurry is prepared; and performing acid pretreatment on the carbon fiber paper, and performing electrochemical deposition on the slurry to prepare the zinc-bromine battery positive electrode material. According to the zinc-bromine battery positive electrode material, the coulombic efficiency and the voltage efficiency of a zinc-bromine flow battery are remarkably improved and the cycle life of the zinc-bromine flow battery is remarkably prolonged through methods of dynamic covalent bonds, nano-silver catalysis, a hierarchical pore structure, carbon fiber pretreatment and the like, and the zinc-bromine flow battery positive electrode material has chemical stability, efficient bromine adsorption capacity and excellent catalytic activity.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention belongs to the technical field of electrochemical energy storage, and discloses a composite bipolar plate for a zinc-bromine flow battery and a preparation method thereof.The preparation method comprises the steps that carbon fibers, ketjen black and graphene dispersion liquid are stirred to be uniform, and a conductive carbon composite material is obtained; a binder, a dispersing agent and the conductive carbon composite material are subjected to ball milling, and a bipolar plate prefabricated material is obtained; carrying out melt blending on the bipolar plate prefabricated material, and extruding to obtain a substrate; and spraying the nitrogen-doped porous carbon material on the surface of a substrate, and performing hot pressing. The graphene, the carbon fibers and the ketjen black are stirred and compounded, the carbon fibers and the ketjen black enter the space between graphene sheet layers, and the ketjen black is attached to the surfaces of the carbon fibers and the graphene, so that the structure not only can prevent the graphene from generating a re-stacking effect in the mixing process, but also can form a'point-line-surface 'ternary interpenetrating high-conductivity network, so that the conductivity of the graphene is improved. According to the preparation method disclosed by the invention, the deposition uniformity of zinc is improved, so that the voltage efficiency and the cycling stability of the battery are improved.

The invention relates to the technical field of preparation of an electrolyte for a vanadium redox flow battery, in particular to a reduction method of an alkaline vanadium-containing solution during short-process preparation of a vanadium electrolyte. The reduction method comprises the following steps: (1) adding a reducing agent sodium sulfite into an alkaline vanadium-containing solution and dissolving; and (2) acid is added into the solution obtained after dissolving in the step (1), the pH is adjusted, a reduction reaction is conducted, and vanadium is reduced to be tetravalent. The method provided by the invention effectively solves the problem of vanadium loss caused by precipitation generated in the sequential operation process of acidification and reduction of the alkaline vanadium-containing solution in the prior art, and meanwhile, the method provided by the invention is easy for engineering implementation.

The invention discloses an aqueous flow battery negative electrode electrolyte based on water-soluble organic disulfide, an application of the aqueous flow battery negative electrode electrolyte and an aqueous flow battery, and belongs to the field of flow batteries. The negative electrode electrolyte comprises a water-soluble aliphatic organic disulfide, a catalyst, a supporting electrolyte and water, wherein the general formula of the water-soluble aliphatic organic disulphide is R-S-S-R, wherein R is alkyl of which the end part contains a hydrophilic group; the catalyst is one or a combination of two of selenium, sulfur and tellurium. The obtained negative electrode electrolyte is used in the flow battery, the flow battery has high energy density, excellent rate capability and excellent long cycle stability, and the cycle capacity retention rate of 2000 cycles is still greater than 95%; meanwhile, the cost is low, and the application prospect is wide.

The utility model provides a tubular flow battery liquid storage tank which comprises an electrolyte liquid storage tank body, a turbulent flow mixing part is arranged at the bottom of the electrolyte liquid storage tank body, the liquid outlet end of the turbulent flow mixing part is connected to a liquid outlet pipe, the electrolyte liquid storage tank body is filled with electrolyte, and the electrolyte flows to the liquid outlet pipe through the turbulent flow mixing part. And a plurality of inlet ends are arranged on the turbulent flow mixing part, and the multiple inlet ends are used for carrying out turbulent flow mixing on the electrolyte filled in the electrolyte storage tank body. According to the tubular liquid storage tank for the flow battery disclosed by the utility model, a plurality of inlet ends are arranged aiming at a square groove liquid storage tank which is most commonly used by a prefabricated cabin type flow battery, so that an electrolyte can form vortexes in a plurality of areas in a flowing process in the tank, and the electrolyte can be fully mixed to reduce flowing dead zones; the mixing degree and turbulence degree of liquid in the tank are improved, a flowing dead zone is avoided, and the utilization rate of electrolyte is improved.

The invention discloses an all-vanadium redox flow battery positive and negative electrode storage tank liquid level automatic balance control device which comprises a positive electrode electrolyte storage tank, a negative electrode electrolyte storage tank and a galvanic pile, a first circulation loop is formed between the positive electrode electrolyte storage tank and the galvanic pile, and a second circulation loop is formed between the negative electrode electrolyte storage tank and the galvanic pile. Venturi tubes are arranged on the positive electrode electrolyte return pipeline and the negative electrode electrolyte return pipeline, liquid pumping holes of the Venturi tubes are communicated with the negative electrode electrolyte storage tank and the positive electrode electrolyte storage tank through an electrolyte pumping pipeline, and a liquid level monitoring device is arranged on the electrolyte pumping pipeline. The venturi tube is communicated with the electrolyte suction pipeline, and redundant electrolyte in one electrolyte storage tank is sucked into the other electrolyte storage tank by means of pressure difference generated by the venturi tube, so that the design of the positive and negative electrolyte storage tanks is not limited by the relative height of the electrolyte level, and the space of the storage tanks can be fully utilized; the integration level of the battery system is improved, and the occupied area is reduced.

The invention discloses a zinc-nickel flow battery purging system and method. The purging system comprises a purging gas supply module, a flow control module, a purging pipeline network, a pressure monitoring module, a gas collection module and an intelligent control system, the purge gas supply module is connected with the flow control module, the flow control module is connected with the purge pipeline network, the purge pipeline network is connected with the zinc-nickel flow battery stack, and the zinc-nickel flow battery stack is connected with the gas collection module. The purging gas supply module, the flow control module, the pressure monitoring module and the gas collection module are all connected with the intelligent control system; and a pressure monitoring module is arranged on the purging pipeline network. The purging system disclosed by the invention can effectively control the content of oxygen and hydrogen in the battery, reduce impurity deposition and gas accumulation on the surface of an electrode, prevent potential safety hazards caused by gas accumulation, reduce explosion risk and internal resistance of the battery, improve charge-discharge efficiency of the battery, improve safety and prolong the service life of an electrolyte and the electrode.

The invention relates to a composite additive for an all-vanadium redox flow battery electrolyte and a preparation method and application thereof, the composite additive comprises an organic ligand, organic sulfonate, phosphate and halide, and the molar ratio of the organic ligand to the organic sulfonate to the phosphate to the halide is 1: (1-2): (1-2): (1-10). Through the synergistic effect of the four added components, the precipitation problem of divalent vanadium ions under a low-temperature condition and pentavalent vanadium ions under a high-temperature condition is remarkably improved, the high-temperature stability of the positive electrode electrolyte and the low-temperature stability of the negative electrode electrolyte of the all-vanadium redox flow battery are effectively improved, the service life of the battery is prolonged, and the service life of the battery is prolonged. Meanwhile, through the synergistic effect of the four effective components, the use amount of the additive is reduced, and the use cost of the additive is reduced.

The invention discloses a preparation method of a modified zinc-bromine flow battery carbon felt negative electrode and the carbon felt negative electrode prepared by the method, and belongs to the field of zinc-bromine flow batteries. According to the method, after the carbon felt is soaked in a mixed solution of cuprous sulfate, water and acetonitrile, the acetonitrile is gradually evaporated from the solution through heating, the cuprous sulfate is gradually subjected to disproportionation reaction, and the copper elementary substance generated by the disproportionation reaction of the cuprous sulfate is deposited on the surface of the carbon felt, so that the purpose of loading the modified carbon felt with the copper elementary substance is achieved. The copper elementary substance is relatively stable in chemical property and has good zinc affinity, and the copper elementary substance is loaded on the surface of the carbon felt, so that the overpotential of zinc nucleation can be reduced, and reaction active sites on the surface of the carbon felt are increased. Besides, relatively strong acting force exists between copper and zinc, so that uniform deposition / stripping of zinc in the charging and discharging process is facilitated, a more uniform zinc deposition layer is formed on the surface of the carbon felt, formation of zinc dendrites is reduced, and the electrochemical performance of the zinc-bromine flow battery is improved.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: firstly, cleaning and activating a carbon-based three-dimensional conductive network substrate by adopting plasmas, performing oxygen / argon plasma etching, and performing chemical vapor deposition on carbon to prepare three-dimensional porous carbon; then growing a metal oxide nanocrystalline array on the three-dimensional porous carbon by a hydrothermal method, and carrying out ammonia gas calcination to convert the metal oxide nanocrystalline array into a metal nitride nanocrystalline array; then preparing an electro-deposition solution containing tin bismuth salt and an aniline-bromine source polymerization solution, and constructing Sn-Bi bimetallic nanoparticles and a polyaniline-bromine complex layer on the metal nitride nanocrystalline array / three-dimensional porous carbon precursor through electro-deposition and electro-polymerization in sequence to finally prepare the high-performance zinc-bromine battery positive electrode material. The positive electrode material has high conductivity, excellent Br2 / Br <-> catalytic activity and structural stability, and the coulombic efficiency, the voltage efficiency and the energy efficiency of the battery are remarkably improved.

The invention relates to a modified graphite felt, a preparation method thereof and application of the modified graphite felt in a vanadium redox flow battery, and belongs to the technical field of redox flow battery electrodes. The method comprises the following steps: mixing a graphite felt with a mixed solution, and carrying out thermal reaction to obtain a metal organic framework two-dimensional nanosheet loaded graphite felt; sintering the graphite felt loaded by the metal organic framework two-dimensional nanosheet to obtain a modified graphite felt; wherein the mixed solution comprises a nitrogen-containing organic ligand and a metal salt. According to the modified graphite felt, the surface of the modified graphite felt is coated with a layer of metal nitrogen-carbon two-dimensional nanosheets, the metal organic framework two-dimensional nanosheets are formed by the coordination reaction of the nitrogen-containing organic ligands and the metal salts, metal is uniformly dispersed in the organic framework two-dimensional nanosheets, and then the metal is uniformly dispersed in the metal nitrogen-carbon two-dimensional nanosheets; therefore, numerous metal active sites are uniformly distributed on the surface of the obtained modified graphite felt, nitrogen element doping is formed at the same time, and the electrochemical performance of the modified graphite felt electrode is improved.

The invention discloses an aqueous all-iron flow battery negative electrode electrolyte and an aqueous all-iron flow battery, and belongs to the fields of an electrochemical energy storage technology and a flow battery. The aqueous total iron flow battery negative electrode electrolyte comprises an iron ion-containing active substance, a first complexing agent, a second complexing agent and hydrogen evolution inhibitor, a supporting electrolyte and water, and the first complexing agent and the second complexing agent and hydrogen evolution inhibitor are simultaneously combined to iron ions to form a stable chelate with a saturated six-coordinate structure. The first complexing agent is selected from triethanolamine or analogues thereof, and the second complexing agent and hydrogen evolution inhibitor is selected from organic acids having a chelation effect and salts thereof. According to the invention, two complexing agents are combined with the same iron ion at the same time to form a stable six-coordinate structure, so that the problems of capacity fading, low energy efficiency and poor cycling stability caused by iron separation and hydrogen separation due to dissociation of organic matters and ferrous ions in the operation process of the battery are effectively relieved.

The invention discloses a zinc-bromine flow battery electrolyte, a negative electrode cosolvent and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, the negative electrode cosolvent of the zinc-bromine flow battery electrolyte is a carboxyl-containing butenoic acid substance, the butenoic acid substance is used as the cosolvent, and zinc is induced to preferentially deposit on a (002) plane by modifying a solid-liquid interface, so that the zinc-bromine flow battery electrolyte is obtained. And the deposition process of zinc is converted from an irregular form which tends to form a dendritic crystal shape and a moss shape into a deposition layer which tends to form a flat and compact deposition layer which is parallel to the substrate. The highly uniform zinc deposition fundamentally and effectively inhibits the formation and growth of zinc dendrites, and greatly improves the stability of the negative electrode and the cycle life of the battery. Chlorides improve ionic conductivity to reduce internal resistance, and sodium acetate buffer inhibits hydrogen evolution on stable pH; and synergistic optimization of positive and negative components ensures efficient reaction. And moreover, the raw materials are easy to obtain, the preparation is simple and convenient, the industrialization threshold is reduced, and the large-scale energy storage requirement is met.

The present invention belongs to the field of liquid flow energy storage battery materials, and particularly relates to a multi-dimensional conductive material, a preparation method thereof, and an application thereof in a vanadium redox flow battery. The present invention uses a biomass precursor to bond graphite and multi-walled carbon nanotubes, and through stepwise pyrolysis, converts the carbon-based biomass into graphitized carbon nanotubes. The amorphous carbon in the graphite and the original carbon nanotubes is also further graphitized, and finally a multi-dimensional conductive material with carbon nanotubes inserted into a graphite matrix is formed. The multi-dimensional characteristics on the surface of the multi-dimensional conductive material are beneficial to forming a longitudinal conductive path on the bipolar plate, reducing the vertical bulk resistance of the bipolar plate, and also facilitating the wetting of epoxy resin between conductive particles and the mechanical interlocking of its molecular chains, improving the mechanical strength of the bipolar plate, effectively enhancing the service performance of the bipolar plate, meeting the requirements of long-term operation of the flow battery, relatively reducing the material cost of the flow battery, strongly promoting the industrialization of the bipolar plate, and having good application value.

The invention relates to an electrolyte precursor of an iron-chromium flow battery, an electrolyte, a preparation method and an application. The electrolyte precursor comprises a basic electrolyte and a stabilizer; the stabilizer comprises an indium-containing compound and amino acid. According to the electrolyte precursor of the iron-chromium flow battery, provided by the invention, the combination of the indium-containing compound and the amino acid is used as a stabilizer of the electrolyte, and under the synergistic matching condition of the indium-containing compound, the amino acid and chromium ions can be subjected to complex reaction, so that the inactivated hydrated chromium ions are converted into active chromium ions, and the chromium ions are converted into active chromium ions. Therefore, the reaction activity of the electrolyte is improved, and the cycling stability of the electrolyte is improved.

The invention belongs to the technical field of redox flow batteries, and particularly discloses a high-performance hierarchical pore carbon felt electrode for a flow battery and a preparation method of the high-performance hierarchical pore carbon felt electrode for the flow battery. Zinc salt or bismuth salt is dissolved in a solvent, and a precursor solution is obtained through stirring and ultrasonic treatment; dipping the pre-oxidized felt into the precursor solution, performing ultrasonic treatment, taking out and drying; and carbonizing the dried carbon felt at a high temperature in a protective atmosphere, treating with nitric acid, cleaning with deionized water, and drying to obtain the hierarchical porous carbon felt electrode with high activity and high specific surface area. The prepared high-performance hierarchical pore carbon felt electrode has a multi-scale pore structure and rich active sites, the specific surface area, the conductivity and the catalytic activity are remarkably improved, meanwhile, the hydrophilicity is optimized, and the electrolyte wettability is enhanced. The method is short in technological process, high in efficiency, low in cost and suitable for large-scale production and industrial application of the high-performance carbon felt electrode.

The invention belongs to the technical field of flow batteries, and discloses a flexible graphite bipolar plate with a self-repairing function and a preparation method and application thereof. The flexible graphite bipolar plate comprises a flexible graphite-polymer composite matrix, microcapsules and a graphene conductive layer, wherein the graphene conductive layer is arranged on the surface of the flexible graphite-polymer composite matrix; the microcapsule is dispersed in the flexible graphite-polymer composite matrix, the core of the microcapsule is a liquid metal alloy, the liquid metal alloy contains Ga, and the shell of the microcapsule is polyurethane. The microcapsules containing the liquid metal alloy are introduced into the flexible graphite bipolar plate in situ, and when the flexible graphite bipolar plate generates microcracks due to mechanical stress, thermal cycle and the like, the internal microcapsules are broken at the first time to release the liquid metal and fill the cracks, so that the graphite bipolar plate still keeps relatively high mechanical strength and air tightness, and the service life of the flexible graphite bipolar plate is prolonged. Therefore, the conductive stability and the use durability of the flow battery are improved.

The invention discloses a mixed ferrovanadium flow battery based on a redox targeting reaction, and belongs to the technical field of flow batteries. The problems that an existing vanadium-based flow battery is high in cost and limited in energy density are solved. According to the invention, the iron salt with low price is used for partially replacing the vanadium salt with high price, and the cost of the electrolyte is effectively reduced and the capacity and the energy density of the battery are effectively improved through the redox targeting reaction between the ferrovanadium electrolyte double-medium and the solid active substance; the battery keeps stable circulation and coulombic efficiency under relatively high current density, so that large-scale application of the vanadium-based flow battery becomes possible.

The embodiment of the invention discloses a flow battery stack and a flow battery system, the flow battery stack is formed by connecting a plurality of flow battery monomers in series, and each flow battery monomer comprises a bipolar plate and electrode plate integrated structure, a battery diaphragm and membrane frame integrated structure and a bead string curtain type nozzle array; the bead string curtain type nozzle array is arranged in a positive reaction chamber and / or a negative reaction chamber of the flow battery monomer, and the bead string curtain type nozzle array is arranged in a cavity in the middle of a membrane frame and a membrane reaction area at the central position of a battery diaphragm; and the bead string curtain type nozzle array comprises a plurality of nozzle units which are arranged into an array at a preset distance, and is used for spraying the electrolyte to the corresponding electrode plate and / or the diaphragm of the corresponding reaction chamber for reaction. According to the invention, the bead string curtain type nozzle array is arranged to uniformly spray the electrolyte out of the reaction chamber for reaction, so that the technical problems of low interface mass transfer efficiency and non-uniformity caused by non-uniform flow velocity distribution of the electrolyte of the flow battery are solved.

A hydrogen storage assembly includes an enclosure substantially encompassing an electrolyzer, a hydrogen storage system, a hydrogen fuel cell, an electrochemical energy storage module, a power conversion system, and a control system. The electrolyzer is configured to separate, via electrolysis, water into hydrogen gas that is stored in the hydrogen storage system; the hydrogen fuel cell is configured to convert the stored hydrogen gas into electrical energy and water. The electrochemical energy storage module is configured to function as an energy buffer; the power conversion system is configured to convert the produced electrical energy to a desired form. The control system is configured to control the storage and distribution of the stored hydrogen and electrical energy in an optimized manner to achieve predefined financial and energy-use objectives.

The invention discloses an MPC-SP-based all-vanadium redox flow battery constant-power charging and discharging control method, which is applied to an energy storage control system composed of an MPC-SP controller, a PCS and an all-vanadium redox flow battery, and is characterized in that the controller dynamically and accurately adjusts the power output to the battery based on preset SOC interval division, and the power output to the battery is increased along with the increase of the actual SOC value of the battery. The power is increased in stages. Meanwhile, the controller pays attention to the voltage Ud of the battery end all the time, and when the Ud reaches a voltage limiting value, the constant voltage mode is switched, so that the battery is effectively prevented from being damaged due to overhigh voltage. The state-based dynamic power management is much safer, more flexible and more intelligent than traditional fixed constant power control. According to the invention, the change rate of current in the charge-discharge process of the all-vanadium redox flow battery can be reduced, the service life of the battery is prolonged, and the safety is guaranteed.

The invention belongs to the technical field of electrochemical energy storage, and discloses a flow battery composite membrane material and a preparation method thereof, and the preparation method comprises the following steps: spraying a ZIF-8 metal organic framework solution to the positive electrode side of a microporous diaphragm, and drying to obtain the flow battery composite membrane material. According to the zinc-bromine flow battery and the preparation method thereof, ZIF-8 acts on the positive electrode side of the microporous diaphragm, ZIF-8 shows good chemical stability in an acidic electrolyte environment of the zinc-bromine flow battery and is not easily oxidized and degraded by bromine, and a stable framework ensures that a screening pore channel is kept complete in long-term operation and continuously plays a role in resisting bromine, so that the corrosion of a zinc negative electrode and the loss of bromine active substances are reduced, and the service life of the zinc-bromine flow battery is prolonged. The problems of low bromine permeation and bromine reaction rate on the positive electrode side of the zinc-bromine flow battery and the like can be effectively solved, and the coulombic efficiency and the voltage efficiency can be remarkably improved, so that the microporous diaphragm with excellent comprehensive performance is obtained.