The invention provides a high-efficiency compound regenerative electrical energy device. The device comprises a reactor, an anode chamber, an anode plate, a cathode chamber, a cathode plate, a proton exchange membrane module, a liquid distributor, a gas distributor, a purge distributor, a battery load, an output pump, a circulating pump, a heating/cooling device, a slurry pump, an air blower, a purge gas stop valve, a flow control valve, a magnetic flap liquidometer, a self-operated pressure-regulating valve, and an immersed pump. The gas distributor is disposed at the bottom of the cathode chamber, and the circulating pump is disposed in the middle of the reactor barrel. The air blower communicates with the gas distributor by the self-operated pressure-regulating valve, and the immersed pump is disposed at the bottom of the cathode chamber. The device uses the coupling mode of fuel cell and catalyst reactivation by means of the arrangement of air cathode fuel cell, is beneficial to improve the oxidation regeneration rate of the catalyst, and realizes the rapid regeneration of the complex catalyst.