The invention relates to a production process of a high-purity graphite section and a sectorial columnar graphite section prepared by the process. The process comprises the following steps: milling, mixing kneading, rolling, re-milling, compression molding, roasting, dipping, re-roasting and dipping to the selected materials; placing the roasted carbon products in a closed graphite purification furnace; sequentially inletting inert gas, chlorine, Freon and tetrafluoroethane inert gas under corresponding temperature for graphitization purification. The process has the advantages of short roasting and graphitization time, high production efficiency and low energy consumption. The graphite section prepared by the process is characterized by high purity, high density, high intensity, good thermal shock resistance, easy precision finishing and extremely wide application. Moreover, the prepared sectorial columnar graphite section, which is easy to be spliced into cylindrical graphite, can avoid the generation of cracks owing to excessive temperature differentials between the exterior and the core of large-scaled sections, prolongs the service life of the products and meets the needs of the market on large-size and high-standard cylindrical graphite section.