1384 results about "Acid water" patented technology

The invention provides a self-leveling rapid repair mortar based on a steel slag solid waste cementing material and a preparation method thereof, the self-leveling rapid repair mortar comprises the following components in parts by mass: 100 parts of a self-leveling rapid repair mortar cementing material: 20-32 parts of steel slag powder, 20-30 parts of slag powder, 10-23 parts of raw ash, 10-15 parts of desulfurized gypsum, 5-8 parts of silica fume, and 8-25 parts of rapid hardening sulphoaluminate cement; the fine aggregate comprises 50 parts of quartz sand and 50 parts of steel slag aggregate; 0.3 to 0.7 part of a polyether defoaming agent, 0.05 to 0.25 part of lithium carbonate and 6 to 12 parts of a polycarboxylic acid water reducing agent; and 25-28 parts of water. According to the self-leveling rapid repair mortar based on the steel slag solid waste cementing material, on the basis of an alkali excitation synergistic sulfate excitation mechanism, the solid waste materials such as the steel slag powder, the slag powder, the raw ash and the desulfurized gypsum are utilized, and through proportioning optimization, the self-leveling rapid repair mortar which can open traffic within 2 hours and has the compressive strength gt within 28 days is prepared; the bonding strength is gt; the self-leveling mortar for rapidly repairing the cement concrete pavement has the advantages of self-leveling, no shrinkage of later strength and excellent durability.

The invention discloses ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete comprises the following components in percentage by mass: 15%-25% of cement, 3%-6% of nano SiO2, 30%-35% of fly ash or steel slag powder, 35%-40% of recycled aggregate, 1%-4% of fiber, 0.5% of a microbial remediation agent and 1%-3% of nano TiO2. The preparation method comprises the following steps: S1, pretreating the recycled aggregate; and S2, packaging the microbial remediation agent: mixing the bacillus pasteurii spores with calcium lactate, and wrapping the mixture in calcium phosphate microspheres. S3, step-by-step stirring; S3.1, dry mixing: uniformly stirring the cement, the fly ash, the nano SiO2, the nano TiO2 and the recycled aggregate; s3.2, wet mixing is carried out, water solution fibers containing the polycarboxylic acid water reducing agent are added, uniform stirring is carried out, and the water-binder ratio of the water solution containing the polycarboxylic acid water reducing agent is 0.18; s3.3, final mixing: adding the packaged microbial remediation agent, and uniformly stirring; and S4, directional curing: performing steam curing at 80 DEG C for 48 hours, performing ultraviolet irradiation, and performing constant-temperature and constant-humidity curing for 7 days. The ultra-high performance concrete has the effects of low cost, low carbon emission, multi-function integration and repeatable crack self-repairing.

The invention provides a modified coal gangue-based large-flow-state grouting and water plugging material and a preparation method thereof. Comprising 80-90 parts of a coal gangue sample, 1-5 parts of Portland cement, 1-5 parts of sulphoaluminate cement, 0.51-3 parts of a polycarboxylic acid water reducing agent, 1-4 parts of cellulose ether with the viscosity of 200w, 0.1-5 parts of a calcium oxide expanding agent, 0.5-5 parts of a plastic expanding agent, 0.5-1 part of redispersible latex powder, 0.5-5 parts of polyacrylamide with the molecular weight of 1000 and water, and the water-material ratio is 0.4. According to the modified coal gangue-based large-flow-state grouting and water plugging material and the preparation method thereof, the cement consumption can be remarkably reduced, the cost is reduced, the utilization rate of solid wastes (such as coal gangue) is increased, and the material has good flow-state performance and adjustable setting time; the method is suitable for deep and large shaft surrounding rock water seepage treatment in coal mining and other mine engineering.

A method for efficiently and safely cleaning an apparatus for a tin compound and a highly purified apparatus for a tin compound are provided. A method of cleaning an apparatus that has been in contact with a tin compound having formula (1) includes at least steps (A) to (C) in this order:(A) a step of cleaning the apparatus with a non-protonic solvent,(B) a step of cleaning the apparatus with an acidic aqueous solution and / or alkaline aqueous solution, and(C) a step of cleaning the apparatus with ultrapure water having a resistivity of 17 MΩ·cm at 25° C.RpSnXm  (1)R is a hydrocarbon group, p is an integer of 0 to 3, X is a hydrolyzable substituent, and m=4-p.

The invention relates to the technical field of water treatment, and discloses a direct spraying type waste heat recovery acidic water treatment method. The method comprises the following steps: arranging a pH value difference sensor group and a conductivity sensor at a joint of a buried pipe cold storage system and a direct-spraying type waste heat recovery device, and monitoring the whole process of acid water treatment in real time to obtain water quality change data of the acid water; performing filtering treatment and working condition matching analysis on the acid water quality change data and the system operation parameters to obtain a cold storage-acid water treatment cooperation mode; performing thermochemical coupling analysis through the hyperboloid mapping network to obtain a corrosion risk assessment result; and executing the heat exchange efficiency and pH value adjustment dual-constraint optimization model according to a corrosion risk assessment result, and outputting an anti-corrosion control strategy. According to the method, the complex nonlinear relation between the pH value change and the temperature gradient can be accurately captured, the accuracy of corrosion risk prediction is greatly improved, and damage to equipment caused by corrosion is effectively avoided.

The invention discloses high-performance fluid-state solidified soil for backfill based on composite ardealite of building residue soil, which is prepared by taking the building residue soil as a core raw material, taking a compound of a polycarboxylic acid water reducer and hydroxypropyl methyl cellulose as a fluidization regulator, and mixing the fluidization regulator and the building residue soil to prepare the high-performance fluid-state solidified soil for backfill. Superfine slag powder, fly ash, nano silicon dioxide, metakaolin and ardealite are used as curing agents, so that the fluid-state solidified soil with strong performance is obtained. Through the synergistic effect of all the components and innovative processes such as liquid nitrogen low-temperature grinding, nano material compounding and a segmented vacuum stirring process, the effect that the ultrahigh strength of the construction waste soil reaches 7.5 MPa within 14 days is achieved for the first time and is improved by 40% or above compared with that of conventional solidified soil, and the industrial problem that traditional waste soil is insufficient in solidification strength is solved; and collaborative optimization of strength and fluidity is realized. Meanwhile, efficient resource utilization of the construction waste is achieved, land occupation and environmental pollution caused by muck landfill are greatly reduced, and the requirement for green and sustainable development is met.

The utility model discloses an imazethapyr water agent synthesis reaction kettle, and relates to the technical field of pesticide preparation production. The reaction kettle comprises a reaction kettle body and a cover body, a stirring mechanism is arranged at the bottom end of the cover body, and the stirring mechanism is used for stirring and mixing liquid in the reaction kettle body. During use, the driving motor is started to drive the rotating shaft to rotate, when the rotating shaft rotates, a plurality of transverse stirring blades are driven to stir materials at the horizontal position, meanwhile, the rotating shaft drives the circular plate and the two L-shaped rods to synchronously rotate, and through the action of the two L-shaped rods, the materials are prevented from being stacked at the bottom end of the reaction kettle body, and the stirring effect is improved; when the rotating rod rotates, the rotating rod in the rotating rod is driven to synchronously revolve, so that the rotating rod is driven to achieve the autorotation function through the meshing effect of the gear and the annular inner rack, and when the rotating rod rotates, the cleaning brush is driven to comprehensively clean the inner wall of the peripheral side of the reaction kettle body through the thread effect of the reciprocating thread groove and the lifting block.

The invention discloses an early-strength high-fluidity cement-based grouting material and a preparation method thereof, and belongs to the technical field of grouting materials. The grouting material is prepared from the following raw materials in percentage by mass: 40-50% of cement, 3-5% of an early strength agent, 0.5-1.5% of a water reducing agent, 3-20% of a mineral admixture, 0.2-1% of a defoaming agent and 35-50% of aggregate, the early strength agent is a composition of a ground nano seed crystal early strength agent based on hydrated calcium silicate and lithium sulfate, and the water reducing agent is an asparaginic acid ester modified polycarboxylic acid water reducing agent. According to the invention, high fluidity and high stability of the cement-based grouting material are realized, the problem of insufficient early strength of the traditional grouting material is solved, and sufficient grouting in a complex and narrow construction environment can be met.

The invention discloses a chlorobenzene wastewater continuous stripping purification recovery device and an implementation method, the chlorobenzene wastewater continuous stripping purification recovery device comprises an aeration tank, an alkali water washing system, an acid water washing system, an acid-base neutralization system and a ferric hydroxide separation system, the aeration tank is connected with the alkali water washing system, the acid water washing system is connected with the alkali water washing system, and the acid water washing system is connected with the ferric hydroxide separation system. The acid-base neutralization system is connected with the alkali-water washing system, the acid-water washing system and the ferric hydroxide separation system, and the alkali-water washing system and the acid-water washing system are both in two-stage steam stripping, and have the following advantages: alkali washing water and acid washing water generated in the chlorobenzene production process are subjected to two-stage nitrogen steam stripping, so that the content of organic matters is greatly reduced; ferric hydroxide is generated through neutralization of acid-alkali wastewater, the total amount of the wastewater is reduced, then the ferric hydroxide reacts with hydrochloric acid in the pickling water to generate ferric trichloride, hydrochloric acid is neutralized, the neutralization product ferric hydroxide is consumed, the wastewater amount is reduced, and recycling of wastewater resources is achieved.

Described herein are methods for making alkenyl disiloxanes, comprising combining an alkenyl halosilane with a bis-hydrido terminated alkyl disiloxane and adding the mixture to water, an acidic aqueous solution, or a basic aqueous solution. The ratio of the alkenyl halosilane to the bis-hydrido terminated alkyl disiloxane is about 1:10 to about 10:1. The alkenyl halosilane and bis-hydrido terminated alkyl disiloxane are mixed at about 20° C. to about 45° C. In an example, no organic solvent is present. The reaction product is separated and washed with saturated NaHCO3 solution (e.g., sodium bicarbonate).

The invention discloses multi-scale toughened full-solid-waste ultrahigh-ductility concrete, which is prepared from the following raw materials in parts by weight: 500 to 650 parts of full-solid-waste cementing materials, 110 to 150 parts of calcined coal gasification slag, 190 to 250 parts of calcined fly ash, 20 to 40 parts of silica fume, 10 to 30 parts of metakaolin, 780 to 930 parts of washed sand, 10 to 25 parts of fly ash fibers, 0.6 to 0.9 part of hydroxypropyl methyl cellulose, 20 to 30 parts of polycarboxylic acid water reducing agents and 300 to 400 parts of water. The calcined coal gasification slag is subjected to gradient heating to 800-960 DEG C, heat preservation is conducted for 30-60 min, then the calcined coal gasification slag is cooled to the room temperature at the cooling rate of 10-15 DEG C / min, and the calcined coal gasification slag is obtained after powder grinding. According to the multi-scale toughened full-solid-waste ultrahigh-ductility concrete provided by the invention, the toughness and the mechanical property of the concrete can be enhanced, the performance of the concrete in an extreme environment is improved, meanwhile, the solid waste utilization rate is increased, and the production cost of the concrete is reduced.

The invention discloses a delayed coagulation type polycarboxylate superplasticizer and a preparation method thereof, and relates to the field of concrete admixtures. The retarding type polycarboxylic acid water reducing agent is prepared from 45 to 55 parts of unsaturated polyether monomer, 15 to 20 parts of quaternary ammonium salt cationic monomer, 10 to 15 parts of unsaturated sulfonic acid or unsaturated sulfonate monomer, 5.5 to 7.5 parts of unsaturated phosphate monomer, 4.8 to 6.2 parts of unsaturated hydroxy fatty acid ester monomer, 100 to 120 parts of acrylic acid, 1 to 2 parts of chain transfer agent, 1.5 to 2 parts of oxidizing agent, 0.75 to 1 part of reducing agent and 500 parts of water. The structural general formula of the unsaturated polyether monomer is R1CH2O (CH2CH2O) nR2, R1 is an alkenyl group, and R2 is any one of a phenyl group and a phenylalanine alkyl ester group. The delayed coagulation type polycarboxylate superplasticizer can effectively improve the delayed coagulation effect of a concrete mixture with the fine aggregate mud content larger than 1.5% in a high-temperature environment, and constructability is ensured.

The utility model relates to a system for reducing the acid value of hydrolysate in the separation and washing process of dimethyl dichlorosilane hydrolysate. Comprising three stages of coalescers, dimethyl dichlorosilane acidic hydrolysate enters the system from the first stage of coalescer, process water enters the system from the third stage of coalescer, the acidic hydrolysate and diluted hydrochloric acid or process water are mixed in each stage of coalescer, oil-water two-phase separation is completed through multiple times of washing and coalescence, and meanwhile the acid value of the hydrolysate is reduced; each stage of coalescer comprises two static mixers connected in series, a group of prefilters and a large coalescer, the coalescer is Z-shaped, and four stages of filter elements are arranged in each stage of coalescer. Through repeated tests, a modified polyvinylidene fluoride filter element of Pall Company is finally selected, and after continuous three-stage coalescer treatment, the acid value of dimethyldichlorosilane hydrolysate can be reduced to 10 PPM or below.

A method and system treat contaminated water. In one embodiment, the method comprises treating contaminated water by introducing a methylmorpholine-N-oxide solution to a vessel. The vessel contains the contaminated water and iron oxide. The contaminated water comprises contaminants. In addition, the methylmorpholine-N-oxide solution comprises methylmorpholine-N-oxide and water. The method further comprises contacting the methylmorpholine-N-oxide solution with the contaminated water. In addition, the method comprises treating the contaminated water by allowing the methylmorpholine-N-oxide to react with the contaminants in the presence of the iron oxide.

The invention provides novel waterproof phase change thermal insulation mortar and a preparation method thereof, and relates to the technical field of mortar building materials, the novel waterproof phase change thermal insulation mortar is prepared from the following raw materials by weight: 500 parts of ordinary Portland cement, 150 parts of water, 250-450 parts of fine sand, 50-200 parts of a shape-stabilized phase change material, 5-15 parts of a polycarboxylic acid water reducer, and 1-5 parts of polysorbate. The diatomite is treated by adopting a three-step method of calcination, acid pickling and hydrophobic modification, so that on the basis of reducing impurities and increasing the pore volume, the diatomite is modified from hydrophilicity to hydrophobicity and lipophilicity, the adsorption capacity of the diatomite to n-hexadecane is further enhanced, and the enthalpy and volume stability of the shape-stabilized phase change material can be remarkably improved.

The invention relates to the field of concrete admixtures, and particularly discloses an air-entraining type polycarboxylic acid water reducer and a preparation method thereof. The air-entraining type polycarboxylate superplasticizer is prepared from the following raw materials in parts by weight: 320 to 380 parts of unsaturated polyether macromonomer, 10 to 30 parts of air-entraining type functional monomer, 26 to 50 parts of unsaturated carboxylic acid or unsaturated carboxylic acid derivative, 1 to 4 parts of oxidizing agent, 0.5 to 2 parts of reducing agent, 0.6 to 2.8 parts of chain transfer agent, 18 to 30 parts of neutralizing agent and 500 to 600 parts of water, the preparation method of the air-entraining type functional monomer comprises the following steps: crushing maleated rosin, mixing the crushed maleated rosin with 48% liquid caustic soda, heating to 100-125 DEG C, carrying out heat preservation reaction for 1-2 hours, and adding water for dilution after the reaction is finished. According to the polycarboxylate superplasticizer, the air-entraining type functional monomer is added, so that the dispersity of the superplasticizer is not influenced, the polycarboxylate superplasticizer has relatively low air-entraining property, and the polycarboxylate superplasticizer has the advantages of improving the workability of concrete and increasing the freezing resistance and durability of the concrete at the same time.

The invention relates to the technical field of precious metal recovery, in particular to a precious metal recovery method. Comprising the following steps: filtering wastewater containing precious metals by using a precious metal recovery composite membrane, and drying the precious metal recovery composite membrane after filtering; then filtering an acidic aqueous solution by using the dried precious metal recovery composite membrane, and then continuously filtering and cleaning by using clear water; the cleaned precious metal recovery composite membrane is put into an N, N-dimethylformamide soaking solution, then ultrasonic oscillation treatment is conducted, the composite membrane is taken out of the soaking solution, then centrifugal treatment is conducted on the soaking solution, precipitates are collected, and the precious metal particles are obtained. The precious metal is recovered by adopting a membrane filtration method, and compared with an impregnation method, a large amount of membrane cost is saved, so that the precious metal recovery cost is reduced, and the method is suitable for industrial metal recovery.

The invention discloses a nano composite cement-based material and a preparation method, and belongs to the technical field of cement-based rapid repairing materials, the material comprises the following components by weight: 1000-1200 parts of high belite sulphoaluminate cement, 525-700 parts of nano activated fly ash, 465-600 parts of superfine slag, 45-78 parts of steel fiber, 28-63 parts of an expanding agent, 15-30 parts of a temperature-sensitive polycarboxylic acid water reducer, 78-95 parts of self-repairing microcapsules, and 284-325 parts of water. Wherein the self-repairing microcapsule is of a double-capsule-core and double-capsule-wall structure. The preparation method comprises the following steps: preparing the self-repairing microcapsule, mixing the cementing material, adding the water reducing agent and water, stirring, adding the microcapsule and the expanding agent, stirring, curing and the like. According to the invention, through a synergistic enhancement technology of a composite gel system, a multi-dimensional enhanced network and an environmental response technology, the material has the characteristics of rapid hardening and early strength, can be demolded within 2 hours, and solves the problems of long initial setting time, poor crack resistance, lack of self-repairing capability, high maintenance frequency and the like in repairing of the airfield pavement in the arid region.

The invention relates to the technical field of concrete admixtures, in particular to a high-performance polycarboxylate superplasticizer and a preparation method thereof. The high-performance polycarboxylate superplasticizer comprises the following components: a polycarboxylate superplasticizer and modified cellulose ether, the polycarboxylate superplasticizer is prepared by polymerization reaction of vinyl polyether macromonomer, unsaturated carboxylic acid and functional monomer under the action of initiator and chain transfer agent. According to the high-performance polycarboxylic acid water reducing agent provided by the invention, the polycarboxylic acid water reducing agent and the modified cellulose ether are compounded and applied to concrete, the initial fluidity of the concrete is good, the slump retaining property is good, the water-retaining property, the wrapping property and the cohesiveness of the concrete are good, and the segregation and bleeding phenomena are avoided when the concrete is mixed with the high-performance polycarboxylic acid water reducing agent.

The invention relates to the technical field of chemical additives of building materials, in particular to an anti-corrosion concrete additive and a preparation method thereof. The concrete additive comprises the following components in parts by weight: 40-80 parts of fly ash, 10-20 parts of modified plant fibers, 5-8 parts of a water reducing agent, 3-6 parts of inorganic salt and 10-30 parts of water, and the modified plant fibers are obtained by grafting and modifying semi-carbonized plant fibers and fluorosilane; the water reducing agent is an amphoteric polycarboxylic acid water reducing agent. In the anticorrosive concrete additive provided by the invention, concrete pores are filled with the fly ash, so that the microstructure is improved; the modified plant fiber enhances the mechanical property and crack resistance of the concrete; the amphoteric polycarboxylate superplasticizer not only improves the workability of the concrete, but also forms a protective film on the surface of the steel bar; the inorganic salt further enhances the impermeability of the concrete, and the additive can comprehensively improve the comprehensive performance of the concrete, especially the corrosion resistance and the service life of the concrete in a severe environment through multi-component compounding.

The invention belongs to the technical field of building materials, and particularly relates to a micro-expansion anti-cracking waterproof composite deep groove filler and a preparation method thereof. The micro-bulking anti-cracking waterproof composite deep groove filler provided by the invention comprises cement, gypsum, mineral powder, nano silicon oxide, coarse aggregate, fine aggregate, modified fibers, an expanding agent, a polycarboxylate superplasticizer and water. According to the invention, polyacrylamide, calcium sulphoaluminate and magnesium oxide are adopted to jointly form an expanding agent, and early-stage-late-stage full-period shrinkage compensation is jointly formed in a concrete hydration process, so that the density of the concrete is effectively improved, and the waterproof performance of the concrete is further improved; according to the invention, sodium dodecyl benzene sulfonate and propylene glycol block polyether are adopted to carry out compound modification on graphene oxide, and gamma-aminopropyltriethoxysilane is connected to the surface of basalt fiber, so that the bonding strength of basalt fiber and a cement matrix and the compactness of the cement matrix are improved, and the waterproof and anti-cracking properties of concrete are further improved.

The invention discloses concrete with high salt corrosion resistance and a preparation method of the concrete. The concrete is prepared from 300-400 kg / m < 3 > of cement, 50-150 kg / m < 3 > of slag powder, 1000-1200 kg / m < 3 > of gravel, 650-800 kg / m < 3 > of machine-made sand, 0.5-2 kg / m < 3 > of a modified polycarboxylic acid water reducing agent, 0.005-0.01 kg / m < 3 > of an air entraining agent, 0.05-0.1 kg / m < 3 > of an ion chelating agent, 0.05-0.1 kg / m < 3 > of polyacrylamide, 0.01-0.05 kg / m < 3 > of sodium methyl silicate, 0.1-0.5 kg / m < 3 > of multiwalled carbon nanotube dispersion liquid and 140-160 kg / m < 3 > of water. The preparation method comprises the following steps: stirring and mixing the modified polycarboxylate superplasticizer, the air entraining agent, the ion chelating agent, the polyacrylamide, the sodium methyl silicate and part of the water for mixing to obtain an admixture mixed solution; sequentially putting broken stones, cement, machine-made sand, the admixture mixed solution, the multi-walled carbon nanotube dispersion liquid and the rest of mixing water into a stirrer, and stirring for 2-3 minutes, so as to obtain the concrete with high salt corrosion resistance. The concrete has high salt corrosion resistance in a complex service environment, the service life of a concrete structure is effectively prolonged, and a reliable guarantee is provided for infrastructure construction.

The invention discloses anti-cracking concrete and a preparation method thereof, and the anti-cracking concrete is prepared from the following raw materials in parts by weight: 400-450 parts of cement, 600-700 parts of fine aggregate, 900-1000 parts of gravel, 70-80 parts of a composite additive, 30-40 parts of modified fiber, 4-5 parts of a water reducing agent and 160-180 parts of water, the composite additive is prepared from fly ash, modified sepiolite, calcium sulphoaluminate and an air entraining agent; the modified sepiolite is obtained by taking sepiolite as a raw material, pretreating the sepiolite through a silane coupling agent and then sequentially reacting the pretreated sepiolite with sulfanilamide and dodecyl chloride. According to the invention, through the synergistic effect of the composite additive and the modified fiber, the comprehensive improvement of the crack resistance and mechanical strength of the concrete is realized, in the composite additive, the moderate expansion of calcium sulphoaluminate compensates the early shrinkage stress, the microbubble system formed by the air entraining agent relieves the stress concentration, and the dispersion effect of the polycarboxylate superplasticizer is matched, so that the crack resistance and mechanical strength of the concrete are improved. The hardened body forms a compact and uniform microstructure, and the tensile strength of the concrete is improved.

The invention discloses a method for preparing a mine filling cementitious material by using cyanide tailings, comprising the following steps: weighing dried cyanide tailings, secondary aluminum ash, barium slag and phosphogypsum in proportion, and putting them into a tank mixer for mixing; after uniform mixing, adding sodium hydroxide solution for wetting, and using a tablet press to press the powder into a cubic green body, and placing the green body in an oven for drying without overlapping; putting the dried green body into a high-temperature box-type muffle furnace for calcining; adding phosphogypsum into the calcined clinker phase, crushing the green body, and sending the green body into a ball mill for ball milling treatment to obtain a cementitious material, and using tailings as aggregates, and supplemented with a polycarboxylic acid water reducer, and adding water to prepare a cementitious material for mine filling; the invention uses cyanide tailings as raw materials, and combines industrial solid wastes such as barium slag, secondary aluminum ash and phosphogypsum, and adopts a one-step activation method to prepare a cementitious material, which can simultaneously complete the decyanation and detoxification of the tailings and the activation of the tailings, has a simple process flow, and the prepared filling material has a fast hydration and hardening rate, good fluidity and high mechanical strength.

The invention discloses a viscosity-reducing fast-dispersing polycarboxylate superplasticizer for high-strength concrete and a preparation method thereof, and relates to the technical field of polycarboxylate superplasticizers. The viscosity-reducing fast-dispersing polycarboxylic acid water reducer for the high-strength concrete comprises the following components in parts by weight: 400 parts of unsaturated polyether macromonomer, 20-40 parts of unsaturated acid monomer and 10-20 parts of unsaturated functional monomer. The invention also provides a preparation method of the polycarboxylate superplasticizer. The water reducer can reduce the viscosity of high-strength concrete, improve the dispersing performance of the concrete and shorten the mixing time, so that the problems of high plastic viscosity and the like of the concrete are solved under the condition of not reducing other performances such as the strength of the concrete.

A dehydrogenation reaction device includes a chemical hydride storage unit including a chemical hydride storage tank, a reaction unit including an acid aqueous solution storage tank, and a dehydrogenation reactor configured to generate hydrogen by reacting a chemical hydride with an acid aqueous solution, and a hydrogen storage unit including a hydrogen storage tank configured to store the hydrogen produced in the dehydrogenation reactor. The dehydrogenation reactor includes a body portion made of a metal and a reinforcement portion surrounding the outer surface of the body portion and including fiber reinforced plastic (FRP).

The invention discloses a super-early-strength shrinkage-free high-crack-resistance tunnel spraying repair material in the technical field of civil engineering materials, which comprises the following raw materials in percentage by mass: 35-45% of sulphoaluminate cement; 8%-12% of a superfine early strength admixture; 2%-3% of a calcium sulphoaluminate expanding agent; 1%-2% of a magnesium oxide-based expanding agent; 1-2% of a calcium-magnesium composite expanding agent; 10%-15% of hollow glass beads; 1.5%-2.5% of copper plated steel fiber; 0.1%-0.3% of polypropylene fiber; 25%-30% of graded quartz sand; 0.5%-1.0% of a polycarboxylic acid water reducing agent; 3%-5% of an alkali-free liquid accelerator; 0.3%-0.8% of a thixotropic agent; and 0.1%-0.3% of a thickening time control agent. According to the method, a multi-scale performance cooperative regulation system is innovatively constructed. Through accurate control of the hydration process of a gel system, a shrinkage stress multi-stage compensation mechanism and systematic integration of a fiber-matrix interface strengthening technology, the mutual restriction relationship among early strength development, volume stability and crack resistance of a traditional material is broken through.

The invention discloses an anti-cracking cement mortar containing slag and a preparation method thereof, and relates to the technical field of slag cement mortars.The anti-cracking cement mortar is prepared from, by mass, 100 parts of a slag cement raw material, 39-44.5 parts of water, 0.6-1 part of a polycarboxylic acid water reducing agent, 0.3-0.5 part of a super absorbent polymer, 4-5 parts of an exciting agent and 0.03-0.05 part of multi-walled carbon nanotubes; the preparation method of the anti-cracking cement mortar comprises the following steps: premixing the slag cement raw material, the super absorbent polymer and the multi-walled carbon nanotubes for 1-2 minutes, sequentially adding the water, the polycarboxylic acid water reducing agent and the exciting agent, mixing at a low speed for 1-2 minutes, and mixing at a high speed for 3-5 minutes to obtain the anti-cracking cement mortar.

The invention relates to the technical field of building materials, in particular to light water-resistant phosphogypsum-based cement concrete mortar and a preparation process thereof. The phosphogypsum-based cement concrete mortar comprises the following components: activated phosphogypsum, sulphoaluminate cement, magnesium phosphate cement, modified zeolite powder, lightweight aggregate, modified nano silicon dioxide, a core-shell toughening agent, a polycarboxylate superplasticizer and water, and the preparation method comprises the following steps: respectively preparing the activated phosphogypsum, the modified zeolite powder, the modified nano silicon dioxide and the core-shell toughening agent; the water resistance of the ardealite is improved through activating treatment, the interface bonding force and the structural compactness are enhanced through multi-component synergism by means of selective adsorption of the modified zeolite powder, the mechanical property of the lightweight aggregate is optimized, the toughness is improved through the core-shell toughening agent, and lightweight, high water resistance, stable performance and durability improvement of the mortar are achieved; the requirements of complex building scenes are met, and environment-friendly and practical values are achieved.

The invention discloses a quick-setting high-strength expansive type leakage crack plugging material and method and application, and belongs to the technical field of cement-based material admixtures, the quick-setting high-strength expansive type leakage crack plugging material is prepared by adopting a mixing method, and the quick-setting high-strength expansive type leakage crack plugging material comprises a base material formed by compounding cement, desulfurized gypsum, calcium oxide, alkaline aluminum oxide, calcium formate, hydrated calcium silicate, carboxyl cellulose and a solid polycarboxylate superplasticizer; the active component is formed by compounding polyaluminum sulfate, magnesium sulfate, disodium ethylene diamine tetraacetate, borax and a defoaming agent; the superfine fly ash, the superfine silicon dioxide, the superfine hydroxyapatite, the superfine zinc sulfate, the nano titanium dioxide and the superfine boron nitride are compounded to form a structure regulating functional component. The three components are uniformly stirred by adding water, and then are mixed with an exciting agent to be used for plugging leakage cracks and filling gaps. The leakage plugging material provided by the invention has the advantages of scientific and reasonable composition, simple preparation and application methods, rapid curing, high strength, good durability, micro-expansion and the like, and has good plugging and filling effects on water bursting, water permeation and gas.