773 results about "Esterification reaction" patented technology

A boron-containing polyethylene glycol fatty acid ester surfactant belongs to the field of organic chemistry and functional materials. The boron-containing polyethylene glycol fatty acid ester surfactant is prepared as follows: polyethylene glycol (PEG), boric acid and fatty acid are used as raw materials, first esterification reaction of the PEG and the boric acid is performed, then esterification reaction of the PEG and the fatty acid is performed to obtain boron-containing poly ethylene glycol fatty acid ester; by changing the species of fatty acids and catalysts and molecular weight of the PEG, the esterification rate can be enhanced, the boron-containing poly ethylene glycol fatty acid ester product can be used as a surfactant, and the boron-containing poly ethylene glycol fatty acid ester can reduce water surface tension and has good emulsifying properties.

The invention provides a polyester polyol production method, a polyester polyol production device and application, according to the polyester polyol production method, single-stage gas-liquid separation in the prior art is improved, and at least two-stage series gas-liquid separation is carried out in the esterification reaction process, so that the total production time is shortened, the production efficiency is improved, and the production cost is reduced. By-products such as polyether can be effectively removed, and the product quality stability of the polyester polyol can be effectively improved.

The invention provides a glyceryl triacetate production parameter control method and system based on reinforcement learning, and relates to the technical field of optimization control methods, and the method comprises the steps: obtaining the production parameters of glyceryl triacetate; based on the kinetic model, constructing a kinetic equation of the esterification reaction of glycerol and acetic acid; constructing a digital twinborn simulation environment of the glyceryl triacetate production process; defining a reinforcement learning framework by taking a digital twin simulation environment as a scene; according to the reinforcement learning framework, taking the Elman neural network as a state predictor, and predicting the state of the glyceryl triacetate; solving the reinforcement learning framework through an MO-MPO algorithm, and determining an optimal control strategy and an optimal production parameter sequence corresponding to the optimal control strategy; judging whether the process capability index is smaller than a process capability index threshold value or not; if yes, continuing to solve the reinforcement learning framework; otherwise, outputting an optimal production parameter sequence; and controlling the optimal production parameter sequence through a PID (Proportion Integration Differentiation) control algorithm.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The synthesis method comprises the following steps: S1, adding furandicarboxylic acid into a reaction container, adding a certain amount of methanol, adding a double-acid-site strong acid solid catalyst, starting stirring, controlling the reaction temperature to carry out esterification reaction, and after the reaction is finished, filtering, washing and drying to obtain furandihydrazide; separating out the double-acid-site strong acid solid catalyst to obtain clear liquid, namely dimethyl furandicarboxylate; s2, transferring dimethyl furandicarboxylate serving as a raw material into another reaction container, adding a certain amount of sodium formate serving as a catalyst, then adding a proper amount of hydrazine hydrate, controlling the reaction temperature, keeping a reflux state, reacting for a period of time, cooling to room temperature after the reaction is finished, and performing centrifugal separation to obtain white solid furandihydrazide. The synthesis method has the advantages of simple reaction steps, no need of toxic and harmful catalysts, mild reaction conditions, high conversion rate and high yield, and can realize efficient, green and low-cost production of furandihydrazide.

The invention discloses a peracetylated polysaccharide derivative mixing accelerator as well as a preparation method and application thereof, and relates to the technical field of polysaccharide derivatives. Alkyl polyglucoside and glycidyl ether are subjected to etherification reaction to obtain polysaccharide derivatives; and adding acetic anhydride and an organic weak base catalyst into the polysaccharide derivative, and carrying out esterification reaction to obtain the peracetylated polysaccharide derivative. The obtained peracetylated polysaccharide derivative can be used for reducing the minimum miscible pressure of CO2 in an offshore oilfield. The polysaccharide derivative provided by the invention is simple in synthesis process, and the molecular activity of the polysaccharide derivative can be regulated and controlled by changing the number of carbon dioxide-philic groups and the length of oleophylic unsaturated hydrocarbon chains, so that the polysaccharide derivative can be used in the CO2 oil displacement process of oilfield exploitation, and the minimum miscible pressure in the CO2 oil displacement process is effectively reduced.

The invention relates to the technical field of rice bran processing, and discloses a rice bran degreasing and nutrition retention edible process synergistic treatment method which comprises the following steps: (a) in an NADES-aqueous solution medium, adding an immobilized catalyst A, and hydrolyzing ferulate bonds and phospholipids in rice bran at low temperature; (b) carrying out intermediate dehydration on the slurry obtained in the step (a) to reduce the water activity; (c) adding an immobilized catalyst B into the dehydrated slurry in the step (b), carrying out esterification reaction, and grafting free ferulic acid generated by hydrolysis to glyceride in situ; and (d) carrying out solid-liquid separation on the slurry obtained in the step (c) to obtain finished oil and finished powder. According to the method, an NADES medium is adopted to replace an organic solvent, the whole process is carried out at low temperature, degradation of heat-sensitive nutrient substances is avoided, and resource utilization of ferulic acid is achieved. The prepared functional rice bran oil is rich in feruloyl glyceride, total tocopherol and oryzanol, and is low in acid value and peroxide value.

The invention relates to a method for preparing high-molecular-weight polyethylene furandicarboxylate by a one-step method, and belongs to the technical field of bio-based polyester materials. The method comprises the following steps: weighing raw materials including 2, 5-furandicarboxylic acid, ethylene glycol, an end group regulator, a protective agent, a decarboxylation inhibitor and a catalyst, mixing and adding into a reaction container, introducing nitrogen, maintaining the pressure of the nitrogen in the reaction container to be 50-150 kPa, carrying out esterification reaction, heating and vacuumizing until the pressure is less than or equal to 50 Pa after the esterification reaction is completed, and carrying out polycondensation reaction to obtain the 2, 5-furandicarboxylic acid. And carrying out extrusion and drying so as to obtain the high-molecular-weight polyethylene furandicarboxylate, wherein the high-molecular-weight polyethylene furandicarboxylate is obtained. According to the method, the FDCA conversion rate is larger than or equal to 98%, the number-average molecular weight of the obtained product is larger than or equal to 32 kg / mol, no heavy metal residues exist, and the method is suitable for large-scale production of high-end bio-based packaging materials.

The invention belongs to the technical field of organic synthesis, and provides a preparation method of a cationic lipid compound, which comprises the following steps: (1) reacting 1, 5-dihalopentane, 2-tert-butyl glycolate and alkali to obtain a product G; (2) hydrolyzing the product G under an acidic condition to obtain a product H; (3) carrying out esterification reaction on the product H, the raw material C, 4-dimethylaminopyridine and a condensing agent in dichloromethane to obtain a product J; and (4) carrying out amination reaction on the product J, the raw material L and alkali in acetonitrile to obtain the cationic lipid compound. Compared with the prior art, the method has the relatively remarkable advantages that when the first part of halogenated long-chain alkyl ester H is synthesized by the method, 1, 5-dihalopentane and 2-tert-butyl glycolate are used as raw materials, the halogenated long-chain alkyl ester J is synthesized by a simple method, the product is obtained at a higher yield in synthesis, and the method is suitable for kilogram-level production. The route synthesis only comprises four steps of chemical reactions, and is suitable for industrial production.

The invention discloses a bio-based recoverable high-thermal-conductivity dynamic ordered network composite material and a preparation method thereof, and is characterized in that the material takes a bio-based multifunctional epoxy system and a carboxylic acid compound containing disulfide bonds as reaction monomers, and the reaction monomers are reacted under the conditions of high temperature and metal salt catalyzed epoxy-carboxylic acid esterification reaction to obtain the bio-based recoverable high-thermal-conductivity dynamic ordered network composite material. A dynamic ordered network structure simultaneously containing disulfide bonds and beta-hydroxyl ester bonds is constructed, and the dynamic ordered network can be used as a springboard for phonon transmission, serves as an efficient'thermal bridge ', and plays a role similar to an ordered'crystal domain', so that higher heat-conducting property is shown when heat-conducting filler is not introduced, high flexibility and intrinsic heat conduction are realized, and the service life of the material is prolonged. And the material is endowed with reprocessing and recycling characteristics. Due to the synergistic existence of carboxyl, hydroxyl generated by epoxy ring opening and metal coordination in the system, and in combination with electrostatic interaction, Van der Waals force and hydrophobic interaction, the material has the adhesion characteristic suitable for a thermal interface at the same time.

The invention discloses a conjugated polymer photocatalyst, a preparation method thereof and application of the conjugated polymer photocatalyst in photocatalytic synthesis of nitric acid, and belongs to the technical field of polymer materials and photocatalysis. The preparation method of the catalyst mainly comprises the following steps: synthesizing an intermediate 2CzTPN-Br through a nucleophilic substitution reaction, then synthesizing an intermediate TBBA through an esterification reaction, and finally copolymerizing the intermediate 2CzTPN-Br and the intermediate TBBA through a coupling polymerization reaction to obtain the target catalyst. The preparation method disclosed by the invention is controllable in process, and the obtained catalyst does not need to participate in noble metal and has wide light absorption, high specific surface area and excellent carrier separation efficiency; when being applied to photocatalytic synthesis of nitric acid, nitrogen in air can be directly and efficiently converted into nitric acid under the mild conditions of room temperature, air atmosphere and water serving as a solvent, excellent durability is shown, the yield of nitric acid can reach 4466.2 mol g <-1 > cat after 324-hour continuous illumination, and wide application prospects are achieved in the field of green synthesis.

The invention provides an environment-friendly water-based pressure-sensitive adhesive as well as a synthesis method and application thereof. The environment-friendly water-based pressure-sensitive adhesive comprises a dehydroabietic acid-based acrylate derivative grafted acrylate emulsion and a rosin emulsion, wherein the acrylate emulsion is prepared from an acrylate monomer, a dehydroabietic acid-based acrylate derivative monomer, an emulsifier, an initiator and water through an emulsion polymerization reaction. The dehydroabietic acid-based acrylate derivative monomer is prepared from a rosin derivative dehydroabietic acid and a hydroxyl acrylate monomer through an esterification reaction; according to the environment-friendly water-based pressure-sensitive adhesive, the synthesis method and the application thereof, the comprehensive performance of the acrylate pressure-sensitive adhesive is improved, the environment-friendly water-based acrylate pressure-sensitive adhesive is developed, the rosin derivative is added as a synthesis or compounding raw material, dependence on fossil raw materials is reduced, and meanwhile, the environment-friendly water-based acrylate pressure-sensitive adhesive is prepared. The comprehensive performance such as initial adhesion and peel strength of the pressure-sensitive adhesive is remarkably improved, and the whole production and use process is free of VOC emission and environmentally friendly.

The invention discloses a high-stability functional beverage based on citric acid and maltodextrin dynamic cross-linked microencapsulated spirulina and a preparation method of the high-stability functional beverage, and belongs to the technical field of functional food processing. Aiming at the problems of flavor defect, easy degradation of active ingredients, poor storage stability, narrow system adaptability and the like of the existing spirulina beverage, the invention initiates a citric acid and maltodextrin dynamic crosslinking wall material system, constructs a core-shell structure microcapsule, and combines a synergistic process of spray drying, gradient homogenization, staged sterilization and the like to prepare the spirulina beverage. The efficient embedding and function maintenance of the spirulina in various beverage substrates are realized. A dense ester bond network is formed on the basis of dynamic esterification reaction of maltodextrin hydroxyl and citric acid carboxyl, a cross-linking degree detection method is optimized, and nonlinear improvement of a synergistic technical effect is realized. The process is stable and controllable, the microcapsule embedding rate is high, the method is suitable for multiple systems such as yoghourt, fruit juice and vegetable protein beverages, and the method can be widely applied to the field of functional foods and has remarkable industrialization value.

The invention discloses a preparation method of high-temperature transformer oil, and belongs to the technical field of high-temperature transformer oil. Comprising the following steps: 1, carrying out hydrolysis reaction to obtain ricinoleic acid; step 2, carrying out first esterification reaction to obtain a ricinoleic acid esterification product; 3, performing epoxidation reaction to obtain an epoxidized ricinoleic acid esterification product; 4, carrying out ring-opening reaction to obtain ring-opened castor oil; 5, carrying out a second esterification reaction to obtain modified castor oil base oil; and 6, mixing the modified castor oil base oil, a viscosity index improver, an antioxidant, a demulsifying agent and an extreme pressure agent to obtain the high-temperature transformer oil. The invention provides modified castor oil and a preparation method thereof. The high-temperature antioxidant transformer oil prepared by using the modified castor oil as base oil has the characteristics of environmental protection, degradability, high flash point, high breakdown voltage and the like, and also has excellent oxidation stability.

The invention provides isosorbide-based copolyester as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. According to the preparation method, a step-by-step esterification method is adopted, firstly, isosorbide, excessive aromatic dicarboxylic acid and an acylating agent are subjected to a first esterification reaction, so that the acylating agent can efficiently and specifically activate secondary hydroxyl of isosorbide, and the initial esterification rate of isosorbide is greatly increased. Meanwhile, the excessive aromatic dicarboxylic acid ensures that the generated isosorbide prepolymer takes carboxyl as a terminal group, so that isosorbide molecules are'locked 'in the middle of a polymer chain segment. Due to the fact that the isosorbide is embedded in the middle of the chain segment in advance, the problem that the isosorbide falls off in the ester exchange reaction due to the fact that the isosorbide is located at the chain end and low in reaction activity in the subsequent polycondensation stage is effectively solved, and therefore the retention rate of the isosorbide in the final polymer is greatly increased, and the glass-transition temperature of the isosorbide is greatly increased.

The invention discloses a puncture-resistant packaging film and a preparation method thereof. The packaging film comprises a polyamide layer; the polyamide layer is prepared from the following raw materials in parts by mass: 70 to 90 parts of polyamide, 20 to 30 parts of modified polyamide and 5 to 10 parts of modified filler; the modified polyamide is prepared by the method comprising the following steps: carrying out condensation polymerization on a mixed monomer containing diamine, dibasic acid and polybasic acid to obtain a polyamide prepolymer; wherein the molar weight of the polybasic acid accounts for 5-10% of the total mole number of the dibasic acid and the polybasic acid; the preparation method comprises the following steps: carrying out melt esterification reaction on a polyamide prepolymer and polyester diol in a mass ratio of (10-25): (75-90) in the presence of a catalyst, and reacting a terminal hydroxyl group of the polyester diol with a carboxyl group of the polyamide prepolymer to obtain the modified polyamide. The problems that the polyamide material is high in rigidity and poor in puncture resistance can be effectively solved.

The invention relates to the technical field of high-molecular compounds, in particular to a novel rubber modifier and a monitoring preparation system thereof, the novel rubber modifier is composed of rosin polyol ester and petroleum resin through graft polymerization reaction, the rosin polyol ester is prepared from rosin substances and polyol through esterification reaction under the action of a composite catalyst; the monitoring preparation system comprises a reaction unit, a feeding unit, a detection unit and a graft polymerization control unit, and the graft polymerization control unit adjusts the operation parameters of the reaction unit and the addition amount of a catalyst according to the processes of the esterification reaction and the graft polymerization reaction; according to the invention, the rosin polyol ester modified petroleum resin is used as the tear-resistant modifier, and the esterification reaction and the dendritic reaction in the preparation process are detected and controlled in the whole process by monitoring the preparation system, so that the tear-resistant modifier product with excellent performance and controllable quality is obtained.

The invention discloses a medical pressure-sensitive adhesive patch based on citric acid, a preparation method and application, the medical pressure-sensitive adhesive patch is composed of an adhesion layer and an anti-adhesion layer, and the thickness ratio of the adhesion layer to the anti-adhesion layer is 1: 1-100: 1; the adhesion layer is obtained by polymerizing a citric acid unit and a polyhydroxy compound unit; the hydrophobic high-molecular polymer is selected from at least one of a polylactic acid-glycolic acid copolymer, polylactic acid, polyurethane and polyether urethane. According to the preparation method, three carboxyl groups in the citric acid not only can be used for esterification reaction with polyhydric alcohols to form a network, but also can provide excellent adhesive force for contact between the adhesive patch and the tissue surface through electrostatic interaction or hydrogen-bond interaction. The anti-sticking layer prepared from the hydrophobic high-molecular polymer can effectively resist invasion of external moisture and bacteria, so that the service time of the adhesive patch is prolonged; meanwhile, the anti-sticking layer can also play a supporting role, so that the mechanical strength of the adhesive tape is improved.

The invention relates to a composite catalyst as well as a preparation method and application thereof, and mainly solves the problems of high temperature, more byproducts, catalyst residues, equipment corrosion, low catalytic efficiency of a novel catalyst and the like when a traditional strong acid catalyst system is used in the prior art. The research method comprises the following steps: preparing a sulfonic acid alkyl imidazole compound catalyst by a two-step method; 1 wt% of the catalyst is used for carrying out esterification reaction on polyhydric alcohol and fatty acid; after the reaction is finished, a product is separated from the catalyst, and the ionic liquid is recycled; and carrying out weak base washing, filtering and water washing refining on the product. The catalytic efficiency of the catalyst reaches up to 99.5% or above, the product hydroxyl value is smaller than 5 mgKOH / g, the acid value is smaller than 0.5 mgKOH / g, and the esterification efficiency is still kept to be 99.0% or above after the catalyst is recycled 6 times. The method has the advantages of simple process, mild reaction conditions and recyclable catalyst, well solves the problems of high temperature, catalyst residue, many byproducts and equipment corrosion in the traditional catalytic esterification system, and can be used in the preparation process of various ester products.

This invention discloses a method for preparing high-quality bio-based 1,9-nonanediol, comprising the following steps: transesterification, precipitation, fatty acid methyl ester refining, ozone oxidation pyrolysis, solvent recovery, esterification, dimethyl azelaate refining, and hydrogenation to obtain high-quality bio-based 1,9-nonanediol. This invention achieves gradient and full-component utilization of vegetable oil raw materials: the oil-based portion of triglycerides is used to produce high-quality bio-based 1,9-nonanediol, while simultaneously producing byproducts such as methyl palmitate, methyl stearate, propionic acid, hexanoic acid, and nonanoic acid; the glycerol-based portion of triglycerides is used as a byproduct of glycerol production. This invention utilizes esterification to reconstruct the products of ozone oxidation pyrolysis, converting the high-boiling-point monomethyl azelaate into the low-boiling-point dimethyl azelaate, achieving efficient separation from saturated fatty acid methyl esters. The dimethyl azelaate, as a raw material, is then hydrogenated to obtain high-quality nonanediol, significantly reducing production costs.

The application discloses a preparation method of arbutin analogues with high transdermal absorption efficiency, and is characterized in that the method comprises the following steps: under the action of a solvent and a catalyst, compound I and compound II are subjected to esterification to obtain compound III, wherein the compound III is the arbutin analogue. The arbutin (compound I) is used as a raw material, the structure of the arbutin is modified through esterification, the transdermal performance of the arbutin is improved, the bioavailability is increased, and finally the whitening effect is improved.

The application provides a method for synthesizing an eplerenone intermediate N-1 by one-pot method, and belongs to the technical field of organic synthesis. The method is characterized in that: the eplerenone intermediate N-4 is dissolved in dichloromethane, a potassium carbonate aqueous solution and dibromohydantoin are added to perform an opening ring reaction; after the reaction is completed, hydrochloric acid is directly added to perform a rearrangement reaction; then water is separated and methanol is added in the organic layer to perform an ozonation reaction; then sodium sulfite is added to perform a reduction reaction; then hydrochloric acid is added to perform a methyl esterification reaction, so as to obtain the eplerenone intermediate N-1 crude product, and finally the eplerenone intermediate N-1 fine product is obtained through refining. The method realizes the one-pot synthesis of the eplerenone intermediate N-1 from the eplerenone intermediate N-4 through the continuous reactions of opening ring, rearrangement, ozonation, reduction and methyl esterification, and can avoid column chromatography purification, so that the method becomes a green chemical process route with greatly reduced organic solvent consumption and wastewater.

This invention relates to the field of oil and fat synthesis technology, specifically to a method for preparing nervonic acid monoglyceride. In this invention, nervonic acid and glycerol are used as raw materials, and an esterification reaction is carried out under microwave assistance to obtain a first mixture containing nervonic acid monoglyceride, nervonic acid diglyceride, nervonic acid triglyceride, unreacted nervonic acid and glycerol, and a catalyst. Glycerol and the catalyst are removed by ethyl acetate extraction to obtain a second mixture. Subsequently, taking advantage of the temperature-sensitive nature of nervonic acid monoglyceride in edible oils, it is separated and purified to obtain nervonic acid monoglyceride. The esterification reaction under microwave assistance not only avoids the corrosion and contamination problems caused by traditional acid catalysts, but also significantly shortens the esterification reaction time, improves synthesis efficiency, and effectively inhibits the isomerization of cis-nervonic acid during the reaction, ensuring the stability of the product configuration.

The invention discloses an esterification reaction lipase screening method based on covalent bond docking, and belongs to the technical field of protein docking simulation. According to the method, parameters of an acylase intermediate are constructed, and then covalent docking and energy screening are performed on the acylase intermediate, so that prediction of lipase reaction activity and substrate selectivity is realized, and the defects that carbonyl carbon cannot be automatically identified, Ser-C covalent bonds cannot be established, double bonds / bond angles cannot be managed, and the reaction efficiency is low in traditional docking are overcome. The problems that in a covalent system, simulation of a nucleophilic attack path lacks a unified distance, angle and dihedral angle constraint system, and automatic and high-throughput screening of multiple lipases and multiple substrates is difficult to achieve are solved.

The application discloses a multifunctional biological imbibition agent and a preparation method and application thereof. The preparation method of the multifunctional biological imbibition agent comprises the following steps: (S1), alkylization reaction to obtain alkyl naphthalene; (S2), chloromethylation reaction to obtain halomethyl alkyl naphthalene; (S3), halogen alkyl nucleophilic substitution reaction to obtain hydroxymethyl alkyl naphthalene; and (S4), esterification reaction to obtain the multifunctional biological imbibition agent. The application further discloses application of the multifunctional biological imbibition agent as an imbibition agent in shale oil reservoir oil extraction. The application has the following advantages: (1) the reservoir adsorption amount is small, but the good wetting reversal characteristic is still maintained, and the emulsification is weak; (2) the high-temperature resistance is strong, and the temperature resistance reaches above 200 DEG C; (3) the preparation process is simple, and the yield is high; (4) the dosage is small, the cost is low, and the economic benefit is remarkable.

The application belongs to the technical field of lubricating oil, and specifically provides a gas engine lubricating oil and a preparation method thereof.The gas engine lubricating oil comprises the following raw materials: ester base oil, anti-wear agent, dispersant, pour point depressant and antifoaming agent, wherein the ester base oil is prepared by esterification reaction of polyhydric alcohol and fatty acid; the preparation method of the anti-wear agent comprises the following steps: first, reacting acrylic acid with vinyl imidazole to prepare a modifier; then, polymeric phenol is obtained by polymerization of phenol under the action of a catalyst; finally, the polymeric phenol, boric acid and vegetable oil are reacted, the modifier is added after a certain time of reaction, and the reaction is continued to obtain the anti-wear agent.The preparation method of the gas engine lubricating oil of the application is that the raw material components are uniformly mixed according to the formula, and the gas engine lubricating oil of the application has good wear resistance, oxidation resistance, high-temperature detergency and thermal stability.

The invention relates to the technical field of photosensitive coatings, and particularly discloses high-flexibility photosensitive solder resist ink and a preparation method thereof. The high-flexibility photosensitive solder resist ink provided by the invention comprises a main agent and a curing agent, the main agent comprises a growth straight chain carboxyl-containing resin solution; the growth straight-chain carboxyl-containing resin solution is prepared by carrying out ring-opening reaction on epoxy resin, introducing beta-(acryloyloxy) acid and then carrying out esterification reaction with acid anhydride; the curing agent comprises thermosetting resin and a toughening agent; the thermosetting resin comprises biphenyl epoxy resin, and the flexibilizer is aliphatic epoxy resin. The composite effect of the straight-chain carboxyl-containing resin solution, the specific thermosetting resin and the flexibilizer is improved, the flexibility of a liquid photosensitive solder resist ink curing film can be obviously improved, and meanwhile, the liquid photosensitive solder resist ink has good chemical gold resistance and soldering resistance and is particularly suitable for a flexible circuit board.

The invention belongs to the technical field of polymer materials, and particularly relates to a polyaromatic-carbonic acid-aliphatic copolyester production method which comprises the following steps: mixing aromatic dibasic acid and aliphatic dihydric alcohol, feeding into a first esterification kettle, and adding an esterification catalyst for esterification reaction to obtain an esterification product; uniformly mixing aliphatic dihydric alcohol, feeding the mixture into a second esterification kettle, adding diester carbonate and a transesterification catalyst into the second esterification kettle, reacting to obtain a transesterification product, and feeding the transesterification product into a demonomerisation kettle to obtain a demonomerisation product; mixing the esterification product and the demonomerisation product with a polycondensation catalyst and a stabilizer, shearing and homogenizing, feeding into a pre-polycondensation kettle for reaction to obtain a pre-polycondensation product, feeding the pre-polycondensation product into a final polycondensation kettle for reaction to obtain a copolymer, and performing water-cooling granulation to obtain a copolyester product. According to the production method provided by the invention, the final polycondensation time can be shortened, and the weight-average molecular weight and the mechanical strength of the prepared copolyester are improved.

The invention discloses a high-thermal-conductivity self-adhesion thermal interface material and a preparation method thereof, and is characterized in that polylipoic acid (polyTA) formed by high-temperature ring opening polymerization of lipoic acid (LA) is used as a dynamic reversible polymer matrix, the dynamic reversible polymer matrix has the characteristics of recoverability, self-healing and adhesion due to the inherent dynamic property of disulfide bonds, a spherical thermal conductive filler is modified by a polyphenol compound, and the high-thermal-conductivity self-adhesion thermal interface material is prepared. Polyhydroxy functional groups are given, the surface energy is reduced, meanwhile, certain viscosity is achieved, polyethylene glycol diacrylate is added to serve as a stabilizer, ferric iron salt is evenly stirred and mixed, the reaction time is controlled, and a stable cross-linked network system is constructed. Hydroxyl groups on the surface of the polyphenol-decorated heat-conducting filler and carboxyl groups in polylipoic acid are subjected to esterification reaction, and meanwhile, Fe < 3 + > and the carboxyl groups in the polylipoic acid form supramolecular coordination, so that uniform dispersion and stable bonding of the filler in a matrix are realized, the interface thermal resistance is remarkably reduced, and a continuous heat-conducting passage is formed. The preparation method of the thermal interface material is simple in process, and the thermal interface material has high thermal conductivity and self-adhesion, has soft elasticity and is suitable for various application fields needing efficient thermal conduction and interface thermal management.