1578 results about "Esterification reaction" patented technology

A boron-containing polyethylene glycol fatty acid ester surfactant belongs to the field of organic chemistry and functional materials. The boron-containing polyethylene glycol fatty acid ester surfactant is prepared as follows: polyethylene glycol (PEG), boric acid and fatty acid are used as raw materials, first esterification reaction of the PEG and the boric acid is performed, then esterification reaction of the PEG and the fatty acid is performed to obtain boron-containing poly ethylene glycol fatty acid ester; by changing the species of fatty acids and catalysts and molecular weight of the PEG, the esterification rate can be enhanced, the boron-containing poly ethylene glycol fatty acid ester product can be used as a surfactant, and the boron-containing poly ethylene glycol fatty acid ester can reduce water surface tension and has good emulsifying properties.

The invention belongs to antibacterial materials, and particularly relates to antibacterial modified waterborne polyurethane and a preparation method and application thereof.The preparation method of the antibacterial modified waterborne polyurethane comprises the following steps that polyol and diisocyanate are mixed and subjected to a prepolymerization reaction, and a polyurethane prepolymer is obtained; mixing the polyurethane prepolymer and a chain extender, and carrying out chain extension reaction; in the chain extension reaction, adding the graft and carrying out esterification reaction to obtain a first intermediate; mixing the first intermediate with triethylamine and carrying out neutralization reaction to obtain a second intermediate; and emulsifying the second intermediate in deionized water to obtain the antibacterial modified waterborne polyurethane. Compared with the prior art, the antibacterial waterborne polyurethane has the advantages that the problems of poor intermiscibility, low durability and the like in physical addition and the problems of limited binding objects and weak antibacterial effect in covalent binding in the antibacterial waterborne polyurethane in the prior art are solved. According to the scheme, arginine and chitosan are grafted to a molecular chain of waterborne polyurethane, so that the waterborne polyurethane is endowed with a synergistic antibacterial property.

The invention provides a polyester polyol production method, a polyester polyol production device and application, according to the polyester polyol production method, single-stage gas-liquid separation in the prior art is improved, and at least two-stage series gas-liquid separation is carried out in the esterification reaction process, so that the total production time is shortened, the production efficiency is improved, and the production cost is reduced. By-products such as polyether can be effectively removed, and the product quality stability of the polyester polyol can be effectively improved.

The invention belongs to the technical field of thin film capacitors, and particularly relates to a chemical grafting modified polypropylene capacitor film material and a preparation method and application thereof. According to the preparation method of the chemical grafting modified polypropylene capacitor film material, provided by the invention, diethylenetriamine ethyl acrylate with a plurality of specific groups such as amino groups and carboxyl groups and unsaturated double bonds is synthesized through esterification reaction, and the diethylenetriamine ethyl acrylate is introduced into a polypropylene material through chemical grafting to obtain chemical grafting modified polypropylene; the prepared polypropylene capacitor film material has the excellent properties of good compatibility, difficulty in film breakage, capability of adsorbing and removing residual moisture, difficulty in oxidation corrosion, excellent breakdown resistance and the like, and the preparation method is a preparation method of the high-performance polypropylene capacitor film material; therefore, the technical problem that a polypropylene capacitor film material prepared in the prior art is low in performance is solved.

The invention discloses a hyperbranched water reducing agent for high-tensile wet joint UHPC (Ultra High Performance Concrete) as well as a preparation method and application of the hyperbranched water reducing agent, and belongs to the technical field of concrete admixtures. The preparation method comprises the following steps: mixing pentaerythritol and maleic anhydride, adding a catalyst p-toluenesulfonic acid, and carrying out an esterification reaction to prepare an esterification product; carrying out amidation reaction on the esterification product, diethanol amine and a catalyst sodium ethoxide to obtain a prepolymer; acrylic acid, maleic anhydride and the prepolymer are dissolved in deionized water, an initiator ammonium persulfate is added for a free radical copolymerization reaction, and a main chain polymer is obtained; carrying out phosphorylation reaction on the main chain polymer and phosphorus pentoxide to obtain a phosphorylated main chain polymer; the phosphorylated main chain polymer, methoxypolyethylene glycol and a catalyst p-toluenesulfonic acid are subjected to an etherification reaction, a hyperbranched comb-shaped polymer water reducing agent solution is obtained and then subjected to aftertreatment, and the water reducing agent is prepared. According to the hyperbranched comb-shaped polymer water reducing agent prepared by the preparation method disclosed by the invention, the problems of poor flowability and high viscosity of ultra-high performance concrete (UHPC) are solved by combining a linear side chain of a comb-shaped structure and a three-dimensional branch of hyperbranched topology.

The invention provides a glyceryl triacetate production parameter control method and system based on reinforcement learning, and relates to the technical field of optimization control methods, and the method comprises the steps: obtaining the production parameters of glyceryl triacetate; based on the kinetic model, constructing a kinetic equation of the esterification reaction of glycerol and acetic acid; constructing a digital twinborn simulation environment of the glyceryl triacetate production process; defining a reinforcement learning framework by taking a digital twin simulation environment as a scene; according to the reinforcement learning framework, taking the Elman neural network as a state predictor, and predicting the state of the glyceryl triacetate; solving the reinforcement learning framework through an MO-MPO algorithm, and determining an optimal control strategy and an optimal production parameter sequence corresponding to the optimal control strategy; judging whether the process capability index is smaller than a process capability index threshold value or not; if yes, continuing to solve the reinforcement learning framework; otherwise, outputting an optimal production parameter sequence; and controlling the optimal production parameter sequence through a PID (Proportion Integration Differentiation) control algorithm.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention relates to the technical field of multi-layer copolyester films, and discloses a high-temperature-resistant antistatic multi-layer copolyester film and a preparation method and application thereof, and the multi-layer copolyester film comprises an ABA three-layer structure obtained through melt co-extrusion; the layer A is prepared from the following raw materials in percentage by mass: 5 to 30 percent of anti-blocking agent master batch and the balance of modified copolyester; the raw material of the layer B is modified copolyester; the modified copolyester is prepared from a binary acid mixture, a dihydric alcohol mixture and a catalyst through an esterification reaction and a condensation polymerization reaction; the binary acid mixture comprises furandicarboxylic acid and 2, 2 '-bifuran-5, 5'-dicarboxylic acid, and the dihydric alcohol mixture comprises ethylene glycol, 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol and 1, 4-cyclohexanedimethanol. According to the invention, the modified copolyester is used as a main raw material, and the film is endowed with good temperature resistance in a copolymerization modification manner, and has stable and lasting antistatic performance.

The invention discloses polymer graft modified graphene oxide as well as a preparation method and application thereof, and belongs to the field of building materials. The polymer grafted modified graphene oxide comprises graphene oxide and a polymer grafted on the surface of the graphene oxide through an ester bond, and the grafting mass ratio of the graphene oxide to the polymer is 1: (0.15-0.75). The preparation method of the polymer grafted modified graphene oxide comprises the following steps: firstly, carrying out esterification reaction on hydroxyl on the surface of graphene oxide and a reversible addition-fragmentation chain transfer polymerization (RAFT) chain transfer agent to generate GO of which the surface is grafted with the RAFT chain transfer agent; and adding a methacrylic acid monomer and an initiator, and carrying out RAFT polymerization on the surface of the GO to obtain a target product. The polymer grafting modified graphene oxide provided by the invention can achieve the effects of high polymer grafting ratio and capability of improving the fluidity of cement paste.

The invention relates to a continuous production method of high-purity tetraethoxysilane, and belongs to the technical field of tetraethoxysilane preparation. The method comprises a raw material pretreatment stage and a purification and rectification stage: in the pretreatment stage, silicon tetrachloride and ethanol are subjected to an esterification reaction in a molar ratio of 1: (3-4) under the protection of nitrogen, the pH is adjusted to be neutral through triethylamine, and triethylamine hydrochloride is removed through reduced pressure distillation; then, a cerium oxide-molecular sieve composite adsorbent with the specific surface area larger than or equal to 800 m / g and the pore diameter of 2-5 nm is adopted for dehydration under the pressure of 0.8-1.2 MPa till the water content is smaller than or equal to 5 ppm, and volatile impurities are removed through high-purity nitrogen purging; in the purification stage, metal ions and Cl are synergistically removed through a titanate modified resin layer and a nano TiOtube layer, and then step-by-step separation is performed through a four-stage differential pressure rectifying tower. Through collaborative optimization of structural design of the composite adsorbent, construction of an organic-inorganic hybrid interface of the resin layer and pressure gradient rectification, 72-hour continuous production is achieved, the single-pass yield of the product is 92%, and the total amount of metal impurities is smaller than or equal to 5 ppb.

The invention provides a method for preparing diglyceride oil by a solventless enzymatic method, which comprises the following steps: S1, mixing saturated fatty acid A and saturated fatty acid B to prepare a liquid eutectic mixture; s2, mixing the eutectic mixture, glycerol and lipase in a reaction system, and carrying out esterification reaction to obtain diglyceride; s3, separating the prepared diglyceride, adding the saturated fatty acid A and / or the saturated fatty acid B into the reaction system again to form a liquid eutectic mixture again, and repeating the step 2; wherein in the step S1, the saturated fatty acid A and the saturated fatty acid B are selected from C10-C20 alkanoic acid, in the step S2, the mass ratio of the eutectic mixture to the glycerol is 1: (1-5), and the temperature of the esterification reaction is 35-78 DEG C. The method solves the problem that the high-melting-point saturated fatty acid is difficult to utilize in the existing technology for preparing the diglyceride oil by the solvent-free enzymatic method.

The invention provides a semi-crystalline transparent multicomponent copolyester and a preparation method thereof, and relates to the technical field of polyester synthesis. The preparation method of the semi-crystalline high-transparency multicomponent copolyester comprises the following steps: esterification reaction: mixing terephthalic acid, ethylene glycol, a branching agent, a modified monomer and a main catalyst, and carrying out esterification reaction to obtain an esterification product; and condensation polymerization: mixing the esterification product with a main catalyst, and carrying out condensation polymerization to obtain the semi-crystalline high-transparency multi-component copolyester, the mixture of the esterification reaction and / or the condensation polymerization reaction comprises a cocatalyst. According to the preparation method disclosed by the invention, polyester is subjected to copolymerization modification with relatively low content of alcohol and / or acid modified monomers to obtain the semi-crystalline multicomponent copolyester, and the semi-crystalline multicomponent copolyester is endowed with the advantages of high transparency, high hue, low cost, easiness in processing and the like.

The invention discloses a functional intermediate for polycarboxylic acid synthesis modification and a preparation process thereof, the intermediate is a copolymer containing a phosphate group, an acrylate group and a hyperbranched polyether polyol chain segment, the molar ratio of all structural units is 1: (1-3): (0.5-2), and the preparation method comprises the following steps: esterification reaction; carrying out phosphorylation reaction; and carrying out gradient vacuum to remove small molecules. The intermediate is high in content of effective components, the viscosity is 500-2000mPa. S, the dispersing performance and the slump loss resistance of the polycarboxylate superplasticizer are remarkably improved through the synergistic effect of phosphate tackifying, acrylate dispersing and hyperbranched compatibilizing, the intermediate is particularly suitable for concrete construction under complex gravel geological conditions, the doping amount is reduced compared with that of traditional hydroxyethyl acrylate, and the service life of the polycarboxylate superplasticizer is prolonged. And the slump of the mother liquor can be kept lossless for a long time.

The invention discloses diglyceride prepared by an enzymic method as well as a preparation method and application thereof, and belongs to the technical field of deep processing of grease. The method comprises the following steps: adding fatty acid into a choline chloride-glycerol-urea ternary eutectic solvent, uniformly mixing, and then adding candida antarctica lipase B for esterification reaction to obtain a reaction mixture; separating the reaction mixture, and recovering an upper-layer oil phase; and separating and purifying the upper-layer oil phase to obtain the diglyceride. According to the method, the reaction rate is high, the selectivity of the diglyceride in the esterification process is high, the yield of the diglyceride can reach 65% or above by reacting for 1 h, the selectivity of the diglyceride is 75% or above, and the purity of the separated and purified diglyceride is 90% or above; in addition, the method is simple to operate, and the reaction product and the eutectic solvent can be separated through simple centrifugation after the reaction is finished; in addition, the monoglyceride content in the product is low, and the subsequent separation and purification difficulty is greatly reduced.

The synthesis method comprises the following steps: S1, adding furandicarboxylic acid into a reaction container, adding a certain amount of methanol, adding a double-acid-site strong acid solid catalyst, starting stirring, controlling the reaction temperature to carry out esterification reaction, and after the reaction is finished, filtering, washing and drying to obtain furandihydrazide; separating out the double-acid-site strong acid solid catalyst to obtain clear liquid, namely dimethyl furandicarboxylate; s2, transferring dimethyl furandicarboxylate serving as a raw material into another reaction container, adding a certain amount of sodium formate serving as a catalyst, then adding a proper amount of hydrazine hydrate, controlling the reaction temperature, keeping a reflux state, reacting for a period of time, cooling to room temperature after the reaction is finished, and performing centrifugal separation to obtain white solid furandihydrazide. The synthesis method has the advantages of simple reaction steps, no need of toxic and harmful catalysts, mild reaction conditions, high conversion rate and high yield, and can realize efficient, green and low-cost production of furandihydrazide.

The invention discloses an expansion-resistant lithium battery pole piece material for an unmanned aerial vehicle and a preparation method of the expansion-resistant lithium battery pole piece material, and belongs to the technical field of lithium batteries. Silicon dioxide / carbon fiber composite powder serves as a matrix, the surface of the matrix is coated with a long-chain alkyl cardanol grafted glucose layer, and pyrolysis carbonization is performed to obtain the expansion-resistant lithium battery pole piece material. Carboxyl groups in glucose and isocyanate on the surface of the modified silicon dioxide / carbon fiber composite powder are subjected to an amine esterification reaction, carbon dioxide is generated, the porosity of the material is further improved, cardanol-coated lithium-containing composite powder is obtained, nanometer aluminum oxide is deposited on the cardanol-coated lithium-containing composite powder through a coprecipitation method, and the composite material is obtained. By forming a ternary composite structure with the silicon dioxide / carbon fiber composite powder as a core layer, the carbonized long-chain alkyl cardanol grafted glucose as a middle layer and the nanometer aluminum oxide as an outermost layer, the volume expansion can be better and synergistically relieved on the premise that the porosity is not affected.

The invention relates to an early-strength water reducing agent as well as a preparation method and application thereof. The synthesis of the early-strength water reducing agent comprises two steps of polymerization reaction of low-molecular-weight polycarboxylic acid and ring-opening esterification reaction of polyether glycidyl ether. According to the low-molecular-weight polycarboxylic acid, unsaturated carboxylic acids such as acrylic acid, methacrylic acid, maleic acid and itaconic acid are used as raw materials, and the low-molecular-weight polycarboxylic acid with the molecular weight of 1000-5000 is synthesized through water-phase free radical polymerization; and then carrying out ring-opening esterification reaction on the low-molecular-weight polycarboxylic acid and polyether glycidyl ether to synthesize the ester type polycarboxylic acid water reducer with a comb-shaped molecular structure. Compared with the prior art, the early-strength water reducing agent and the preparation method thereof have the performance advantages of simple synthesis process, high esterification rate and good early-strength effect.

The invention discloses a peracetylated polysaccharide derivative mixing accelerator as well as a preparation method and application thereof, and relates to the technical field of polysaccharide derivatives. Alkyl polyglucoside and glycidyl ether are subjected to etherification reaction to obtain polysaccharide derivatives; and adding acetic anhydride and an organic weak base catalyst into the polysaccharide derivative, and carrying out esterification reaction to obtain the peracetylated polysaccharide derivative. The obtained peracetylated polysaccharide derivative can be used for reducing the minimum miscible pressure of CO2 in an offshore oilfield. The polysaccharide derivative provided by the invention is simple in synthesis process, and the molecular activity of the polysaccharide derivative can be regulated and controlled by changing the number of carbon dioxide-philic groups and the length of oleophylic unsaturated hydrocarbon chains, so that the polysaccharide derivative can be used in the CO2 oil displacement process of oilfield exploitation, and the minimum miscible pressure in the CO2 oil displacement process is effectively reduced.

The invention discloses an isosorbide-based heat-resistant yellowing-resistant biodegradable polyester and a preparation method thereof.The preparation method comprises the following steps that under the condition of an esterification catalyst, dibasic acid and dihydric alcohol are subjected to an esterification reaction, the dibasic acid is composed of terephthalic acid and 1, 1-cyclohexanedicarboxylic acid, and the dihydric alcohol is composed of 1, 1-cyclohexanedicarboxylic acid; the dihydric alcohol is composed of isosorbide and aliphatic dihydric alcohol; after the esterification reaction is finished, adding a polycondensation catalyst, a stabilizer and a toner into an esterification reaction product to carry out polycondensation reaction; after the polycondensation reaction is finished, the polycondensation product is subjected to bracing and grain-sized dicing, and the isosorbide-based heat-resistant and yellowing-resistant biodegradable polyester is obtained. 1, 1-cyclohexanedicarboxylic acid is introduced to replace part of terephthalic acid, aromatic ring structures on polyester chains are reduced, the yellowing resistance of polyester is improved, meanwhile, biomass-sourced isosorbide is added as a heat-resistant modified component, and the isosorbide-based heat-resistant and yellowing-resistant biodegradable polyester is obtained through a direct esterification method.

The invention belongs to the technical field of synthetic ester, and particularly relates to a preparation method of fatty acid pentaerythritol ester base oil, which comprises the following steps: carrying out esterification reaction on pentaerythritol and fatty acid in the presence of a catalyst and a color retention agent, and carrying out post-treatment to obtain the fatty acid pentaerythritol ester base oil, the catalyst comprises at least one of stannous octoate, stannous oxalate, stannous oxide, tetrabutyl titanate, isopropyl titanate and sodium hydrogen sulfate; the color retention agent comprises at least one of sodium hypophosphite, hypophosphorous acid, activated carbon and sodium sulfite. The color retention agent sodium hypophosphite is matched with the specific catalyst such as stannous oxalate, so that the petroleum color number of the produced fatty acid pentaerythritol ester base oil is smaller, and meanwhile, the esterification reaction time is shorter.

The invention relates to the technical field of rice bran processing, and discloses a rice bran degreasing and nutrition retention edible process synergistic treatment method which comprises the following steps: (a) in an NADES-aqueous solution medium, adding an immobilized catalyst A, and hydrolyzing ferulate bonds and phospholipids in rice bran at low temperature; (b) carrying out intermediate dehydration on the slurry obtained in the step (a) to reduce the water activity; (c) adding an immobilized catalyst B into the dehydrated slurry in the step (b), carrying out esterification reaction, and grafting free ferulic acid generated by hydrolysis to glyceride in situ; and (d) carrying out solid-liquid separation on the slurry obtained in the step (c) to obtain finished oil and finished powder. According to the method, an NADES medium is adopted to replace an organic solvent, the whole process is carried out at low temperature, degradation of heat-sensitive nutrient substances is avoided, and resource utilization of ferulic acid is achieved. The prepared functional rice bran oil is rich in feruloyl glyceride, total tocopherol and oryzanol, and is low in acid value and peroxide value.

The invention relates to a bacteriostatic washing machine tank cleaning block composition and a preparation method thereof, and the bacteriostatic washing machine tank cleaning block composition comprises the following components: peroxide salt, a surfactant, a chelating agent, an acid substance, modified silicon dioxide, an active oxygen activator, a release agent, an adhesive, a filler and water; wherein the modified silicon dioxide is obtained by firstly hydroxylating silicon dioxide, then carrying out esterification reaction with hexadecenoic acid and linolenic acid, and finally polymerizing with sodium acrylate. The modified silicon dioxide can generate mechanical friction with stubborn dirt to promote the dirt to fall off, a high-crosslinking-degree net-shaped organic chain segment formed on the surface of the modified silicon dioxide has amphipathicity, after the modified silicon dioxide is compounded with the surfactant and other components, a synergistic effect is generated to improve the decontamination effect, the compatibility of all the components can be improved, and the cleaning effect is improved. Falling stubborn dirt can be wrapped, and the decontamination effect is further improved; all the components are compounded, so that a good antibacterial effect and the like are achieved, and a good prospect is achieved.

The invention relates to a method for preparing high-molecular-weight polyethylene furandicarboxylate by a one-step method, and belongs to the technical field of bio-based polyester materials. The method comprises the following steps: weighing raw materials including 2, 5-furandicarboxylic acid, ethylene glycol, an end group regulator, a protective agent, a decarboxylation inhibitor and a catalyst, mixing and adding into a reaction container, introducing nitrogen, maintaining the pressure of the nitrogen in the reaction container to be 50-150 kPa, carrying out esterification reaction, heating and vacuumizing until the pressure is less than or equal to 50 Pa after the esterification reaction is completed, and carrying out polycondensation reaction to obtain the 2, 5-furandicarboxylic acid. And carrying out extrusion and drying so as to obtain the high-molecular-weight polyethylene furandicarboxylate, wherein the high-molecular-weight polyethylene furandicarboxylate is obtained. According to the method, the FDCA conversion rate is larger than or equal to 98%, the number-average molecular weight of the obtained product is larger than or equal to 32 kg / mol, no heavy metal residues exist, and the method is suitable for large-scale production of high-end bio-based packaging materials.

The invention discloses a method for preparing poly (butylene adipate-co-terephthalate) by a one-step method. The method comprises the steps of terephthalic acid esterification, adipic acid esterification, secondary esterification of terephthalic acid esterification liquid and adipic acid esterification liquid, and condensation polymerization, wherein terephthalic acid esterification and adipic acid esterification are synchronously carried out; in the terephthalic acid esterification process, a catalyst and a heat stabilizer are mixed and heated to obtain a mixed catalyst, and after terephthalic acid esterification reaction generates water, the mixed catalyst is added into a reaction system in a manner of feeding under the liquid level, so that on one hand, hydrolysis of the catalyst is reduced, and the catalytic efficiency of the catalyst is improved; on the other hand, the heat exchange efficiency is reduced and the energy consumption is increased due to the fact that a catalyst hydrolysis product covers a heat exchange pipeline; under the condition of not supplementing a catalyst, the synthesized product with qualified indexes such as PBAT melt index, color value, terminal carboxyl group and the like can be realized through subsequent secondary esterification and polycondensation.

The invention belongs to the technical field of organic synthesis, and provides a preparation method of a cationic lipid compound, which comprises the following steps: (1) reacting 1, 5-dihalopentane, 2-tert-butyl glycolate and alkali to obtain a product G; (2) hydrolyzing the product G under an acidic condition to obtain a product H; (3) carrying out esterification reaction on the product H, the raw material C, 4-dimethylaminopyridine and a condensing agent in dichloromethane to obtain a product J; and (4) carrying out amination reaction on the product J, the raw material L and alkali in acetonitrile to obtain the cationic lipid compound. Compared with the prior art, the method has the relatively remarkable advantages that when the first part of halogenated long-chain alkyl ester H is synthesized by the method, 1, 5-dihalopentane and 2-tert-butyl glycolate are used as raw materials, the halogenated long-chain alkyl ester J is synthesized by a simple method, the product is obtained at a higher yield in synthesis, and the method is suitable for kilogram-level production. The route synthesis only comprises four steps of chemical reactions, and is suitable for industrial production.

The present application relates to a kind of powder coating hydroxyalkylamide matting curing agent and its preparation method, the matting curing agent using including citric acid, 2-methyl-1,3-propanediol, dimethylbenzene, anhydrous methanol, N-methyl monoethanolamine, catalyst, nanometer titanium dioxide is reacted to obtain raw materials.In first, citric acid and 2-methyl-1,3-propanediol are grafted to carry out reaction, then the remaining four carboxyl groups of grafting are methyl esterification reaction, obtain methyl esterification product, then with N-methyl monoethanolamine acylation reaction obtains hydroxyalkylamide curing agent;Add nanometer titanium dioxide, fully mix and process to obtain the matting curing agent.The curing agent product functionality is higher, the hardness of coating film after curing is higher, and the boiling water resistance is excellent;And the coating film after curing has obvious matting effect, coating film gloss is basically reached 50-70%, and the decorative property is excellent.

The invention discloses a low-loss resin composition containing active ester, a prepreg and a copper-clad laminate, the resin composition comprises the following main components by weight: 30-70 parts of epoxy resin, 30-70 parts of an epoxy curing agent, 0-3 parts of a curing accelerator, and 20-100 parts of a filler; wherein the epoxy curing agent is tetraphenol fluorenyl active ester; the prepreg is prepared by dipping glass cloth in a glue solution formed by the low-loss resin composition and baking the glass cloth in an oven at 80-200 DEG C for 1-20 minutes after dipping is completed, the copper-clad plate is prepared from the prepreg, fluorine-containing tetrafunctional active ester is synthesized through esterification reaction of tetraphenol fluorene and pentafluorobenzoyl chloride, and the fluorine-containing tetrafunctional active ester is used for preparing the copper-clad plate. A rigid fluorene ring structure is introduced, so that the thermal performance of the cured epoxy composite material is favorably improved; therefore, the invention effectively solves the problems that the existing resin composition for preparing the copper-clad plate is insufficient in heat resistance, and in order to meet the requirement of low polarity, the dosage of the filler is increased, the interfacial compatibility of the resin and the filler becomes poor, and the dielectric loss is further improved.

The invention discloses a bio-based recoverable high-thermal-conductivity dynamic ordered network composite material and a preparation method thereof, and is characterized in that the material takes a bio-based multifunctional epoxy system and a carboxylic acid compound containing disulfide bonds as reaction monomers, and the reaction monomers are reacted under the conditions of high temperature and metal salt catalyzed epoxy-carboxylic acid esterification reaction to obtain the bio-based recoverable high-thermal-conductivity dynamic ordered network composite material. A dynamic ordered network structure simultaneously containing disulfide bonds and beta-hydroxyl ester bonds is constructed, and the dynamic ordered network can be used as a springboard for phonon transmission, serves as an efficient'thermal bridge ', and plays a role similar to an ordered'crystal domain', so that higher heat-conducting property is shown when heat-conducting filler is not introduced, high flexibility and intrinsic heat conduction are realized, and the service life of the material is prolonged. And the material is endowed with reprocessing and recycling characteristics. Due to the synergistic existence of carboxyl, hydroxyl generated by epoxy ring opening and metal coordination in the system, and in combination with electrostatic interaction, Van der Waals force and hydrophobic interaction, the material has the adhesion characteristic suitable for a thermal interface at the same time.

The invention discloses an environment-friendly automobile decoration material containing a bio-based material and a preparation method of the environment-friendly automobile decoration material, belongs to the technical field of preparation of environment-friendly materials, and aims at solving the technical problem that the environment-friendly performance and flame-retardant performance of a decoration material in the prior art need to be further improved. The flame-retardant polyurethane material specifically comprises the following components in parts by weight: 40-60 parts of mixed polyol, 15-25 parts of flame-retardant cellulose, 35-45 parts of isocyanate and 10-15 parts of an auxiliary additive. According to the preparation method, biomass-containing mixed polyol is prepared through esterification reaction, modified cellulose is prepared through acid treatment, alkali treatment and esterification reaction, the modified cellulose is combined with the modified cellulose through covalent bonds, flame-retardant cellulose is obtained, the environment-friendly performance and flame-retardant performance of the decorative material are improved, and the mechanical strength of the decorative material is also improved.

The invention relates to the technical field of surfactants, and particularly discloses a preparation method and application of a sulfosuccinate type surfactant, and the preparation method specifically comprises the following steps: (1) esterification reaction: under the protection of inert gas, adding fatty alcohol and carboxylic acid anhydride, introducing gas for 10-20 minutes, adding a difunctional acidic site catalyst, heating to 95-105 DEG C, and reacting for 2-3 hours to obtain an esterification product; and (2) sulfonation reaction: cooling the esterification product to 70-80 DEG C, dropwise adding 20-40wt% of sulfonating agent aqueous solution, preserving heat for 1-2 hours after dropwise adding, and then performing post-treatment to obtain the sulfosuccinate type surfactant. In the preparation process, one-pot preparation is realized by regulating and controlling process conditions and developing a catalyst to efficiently catalyze esterification and sulfonation, intermediate products do not need to be separated between esterification and sulfonation, material loss caused by transfer and separation is avoided, the adopted catalyst can be used for inhibiting premature oxidation of a sulfur source in the sulfonation process, and the sulfonation efficiency is improved. The generation of byproducts is reduced, and the yield is improved.