318 results about "Glycidol" patented technology

The invention belongs to the field of chemical engineering, and relates to a process device and method for continuously synthesizing glycidyl (3-chloro-1, 2-propylene glycol and sodium hydroxide (hereinafter referred to as NaOH) as raw materials). The device comprises a raw material feeding pump, a heat exchanger, a micro-reactor, a delay tube reactor 1, a neutralization micro-reactor and a delay tube reactor 2 which are sequentially in fluid communication through pipelines, the heat exchangers are divided into two groups, one group is used for heat exchange of 3-chloro-1, 2-propylene glycol solution, and the other group is used for heat exchange of alkaline solution. According to the method, a 3-chloro-1, 2-propylene glycol solution and a sodium hydroxide solution (NaOH) are adopted as raw materials, glycidol is continuously prepared through a microchannel reactor, on the basis, an acid-base neutralization reaction can be carried out in situ according to needs to remove redundant alkali, redundant heat generated by the acid-base neutralization reaction is absorbed through a low-temperature material, and energy consumption is reduced; the product is analyzed by gas chromatography, and the generated glycidol does not have hydrolysates or auto-polymerization products, so that the product selectivity is higher.

Challenges are to provide an epoxy resin composition for RTM which achieves both viscosity stability at the time of injection and stiffness at the time of demolding, and a cured resin of which is superior in balance among elastic modulus under wet and heat conditions, heat resistance under wet conditions, and fracture toughness, and to provide a large fiber-reinforced composite material having a high Vf and including the epoxy resin composition. Provided is an epoxy resin composition for RTM including an epoxy resin and a curing agent component, containing the following components [A] and [C] as the epoxy resin, containing the component [B] as the curing agent component, and containing 50 to 85 parts by mass of the component [A] in 100 parts by mass of the epoxy resin, [A] Tetrafunctional glycidyl amine type epoxy resin [B] a curing agent that is liquid at 150°C [C] Aniline type epoxy resin represented by Formula (I): (In Formula (I), R1 and R2 each represent at least one selected from the group consisting of aliphatic hydrocarbon groups having a carbon number of 1 to 4; n is an integer of 0 to 4; and m is an integer of 0 to 5; when n or m is 2 or more, R1 and R2 each may be the same or different at each occurrence; X represents -O- or -S-).

The invention relates to the technical field of electrolyte, in particular to a thioether cross-linked solid polymer electrolyte membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: taking N, N-dimethylformamide, respectively adding 3, 6-dioxa-1, 8-octane dithiol and triglycidyl isocyanurate, and uniformly stirring to obtain a mixed solution; adding bis (trifluoromethylsulfonyl) imide lithium into the mixed solution, putting magnetons on a magnetic stirrer, and completely dissolving the magnetons to obtain a precursor solution; and pouring a proper amount of the precursor solution into a polytetrafluoroethylene mold, spreading, and carrying out cross-linking polymerization in a blast oven to form the film. The three-dimensional thioether cross-linked network structure has a large number of weakly coordinated thioether groups, dissociation of lithium salt can be promoted, a large number of free Li < + > is generated, the number of Li < + > is increased, meanwhile, the crystallinity of a polymer is remarkably reduced, the ionic conductivity is improved, the mechanical stability of a film can be improved, and the service life of a battery is effectively prolonged.

The invention relates to the technical field of high polymer materials and protective coatings, and discloses a single-layer anti-ultraviolet heavy-duty powder coating as well as a preparation method and application thereof. The preparation method of the single-layer anti-ultraviolet heavy anti-corrosion powder coating comprises the following steps: adding carboxyl polyester resin, triglycidyl isocyanurate, modified nano silicon dioxide, modified chitosan, 2-(2H-benzotriazole-2-yl)-4, 6-di-tert-pentylphenol, bis (2, 2, 6, 6-tetramethyl-4-piperidinyl) sebacate, flaky aluminum powder, zinc phosphate, BYK-3920, 2-hydroxy-1, 2, 4-triazole-2-yl)-1, 3, 4-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5- The preparation method comprises the following steps: stirring and mixing 2, 2-diphenylethanone and gamma-aminopropyltriethoxysilane at room temperature at 300-350rpm for 10-15min to obtain a mixture, extruding the mixture through a double-screw extruder at the extrusion temperature of 110-120 DEG C and the screw rotation speed of 450-500rpm, and grinding to obtain the single-layer anti-ultraviolet heavy-duty anticorrosive powder coating. The single-layer anti-ultraviolet heavy anti-corrosion powder coating can be applied to metal base material protection. The coating prepared by the invention has good ultraviolet resistance and corrosion resistance.

The invention discloses a high-strength self-degradable gel temporary plugging agent and a preparation method thereof, and relates to the technical field of oil-gas field development. The temporary plugging agent is prepared by the following steps: firstly, reacting a diprimary amine compound with unsaturated glycidyl to prepare a multi-arm cross-linking agent, then reacting an acrylamide monomer, an acidic monomer, a rigid monomer and a 2-methacryloyloxyethyl phosphorylcholine monomer under the action of the multi-arm cross-linking agent and an initiator, and after the reaction is finished, crushing, drying and granulating to obtain the temporary plugging agent. The high-strength self-degradation gel temporary plugging agent prepared by the invention not only has relatively high strength, but also can be self-degraded, and the permeability recovery rate of a reservoir after degradation is relatively high, so that the influence on the reservoir is relatively small.

The invention provides a preparation method of a single-ended vinyl hyperbranched polyether macromonomer, which can be applied to the technical field of hyperbranched polyether synthesis. The method comprises the following steps: carrying out ring-opening polymerization reaction on any one of an epoxy group-containing vinyl monomer, a hydroxyl group-containing vinyl monomer or a carboxyl group-containing vinyl monomer and glycidol in the presence of a catalyst and a polymerization inhibitor to form the single-ended vinyl hyperbranched polyether macromonomer with an amino group, ester group or ether group structure. The invention also provides a single-ended vinyl hyperbranched polyether macromonomer product.

The invention provides a high-flame-retardant burnthrough-resistant PC alloy and a preparation method thereof. The PC alloy comprises the following components: branched PC resin with a special blocking rate, 4-10 parts of aryl p-toluenesulfonate and glycidyl ester, wherein the blocking rate of the branched PC resin is 85-95%. The heat resistance, melt strength and burnthrough resistance of the PC alloy are remarkably improved, the heat deformation temperature is increased to 132 DEG C from 122 DEG C, the needle flame S.2 burnthrough time is increased to 150 s or above from 15 s, high flame retardance and burnthrough resistance of a PC product are achieved, and meanwhile the original mechanical performance and thermal performance of PC resin are not affected.

The invention provides a special fiber material and a preparation method thereof, and belongs to the technical field of polymer composites.The preparation method comprises the following steps that cellulose and an ethanol solution are mixed, polyvinyl alcohol and a 3-glycidoxypropyltrimethoxysilane solution are added, the pH is adjusted to be acidic, heating, suction filtration and drying are conducted, and modified cellulose is obtained; mixing expanded graphite, deionized water, ammonium persulfate and dilute sulphuric acid, heating, cooling, dropwise adding amino polyethylene glycol silane, heating, washing and drying to obtain modified expanded graphite; the preparation method comprises the following steps: mixing modified cellulose, modified expanded graphite, phosphate montmorillonite, 3-(methacryloyloxy) propyltrimethoxysilane, bisphenol A diglycidyl ether and 2-methylimidazole, stirring, heating, defoaming, and carrying out two-stage constant-temperature treatment to obtain the special fiber material. The special fiber material disclosed by the invention has good flame retardance, mechanical strength, water resistance and filtering performance, and can be applied to various organic composite boards, filter membranes and the like with high quality requirements.

The invention provides solvent-resistant polyurethane resin, which is prepared from the following substances in parts by mass: 60 to 90 parts of diol, 15 to 25 parts of diisocyanate, 3 to 8 parts of auxiliaries, 1.5 to 3 parts of 1, 4-bis (2-hydroxyethyl) piperazine, 2 to 4 parts of 2, 2-dimethylolpropionic acid, 0.5 to 2 parts of catalysts, 0 to 3 parts of 4, 4 '-dithiodibenzoic acid diglycidyl ester and 0 to 2 parts of sodium alginate. Meanwhile, the invention further provides a simple preparation method, and the prepared solvent-resistant polyurethane resin is low in soaking swelling rate, good in solvent resistance, high in tensile strength and simple in preparation process and can be applied to the industries such as chemical anticorrosive paint, printing ink and electronic packaging.

The application relates to a preparation method and application of a hard carbon negative electrode material, and comprises the following steps: 1) dissolving an epoxy resin derivative and an amine catalyst in an organic solvent to obtain a mixture, ultrasonically dispersing alkali-activated biomass powder in the mixture, and performing reaction by increasing temperature to obtain modified biomass powder; the epoxy resin derivative comprises phenolic epoxy resin and isocyanuric acid triglycidyl ester; 2) carbonizing the modified biomass powder. The reaction in step 1) is used for reinforcing the easily-oxidized and weakly-connected structure on the alkali-activated biomass powder, so that the modified biomass powder with enhanced crosslinking degree and a complex three-dimensional crosslinking structure is obtained; and the modified biomass powder is carbonized in step 2). The hard carbon negative electrode material obtained by the method makes the battery have excellent cycle stability.

The invention discloses a single-chain alkylamino glycerol compound, a preparation method and application. The structural general formula of the single-chain alkylamino glycerol compound is R-NH-CH2-CHOH-CH2OH, the single-chain alkylamino glycerol compound is used for preventing and controlling peach monilinia and / or botryosphaeria dothidea, and R is a C8-C18 straight chain or branched chain and saturated or unsaturated alkyl. The single-chain alkylamino glycerol compound provided by the invention can be prepared by reacting glycidol and alkylamine under mild conditions, has a remarkable inhibition effect on peach monilinia and botryosphaeria dothidea, and can induce fungal membrane rupture, anti-oxidation system imbalance and lipid peroxidation, so that fungus killing is realized. The device can be widely used for fruit and vegetable postharvest preservation, orchard spraying and green pesticide development.

The invention discloses a coumarin-based bio-based epoxy resin monomer and a preparation method and application thereof, and the structure of the monomer is DPE, DCE and DHE. The monomer takes dihydrocoumarin and biomass amine compounds (including putrescine, cadaverine and 1, 6-hexamethylenediamine) as raw materials, biomass bisphenol DP, DC and DH are prepared through a simple ring-opening reaction, and then the monomer is prepared through a glycidyl reaction. A bisamide structure is innovatively introduced into the epoxy resin monomer, so that the epoxy resin monomer has the advantages of simple and convenient synthesis process, high yield, easily available raw materials, good biological safety and the like, and the performance is superior to that of traditional petroleum-based epoxy resin. The bio-based epoxy resin prepared based on the monomer shows a novel molecular structure and excellent mechanical properties and heat resistance.

The application discloses a degradable rosin-based epoxy foam and a preparation method and application thereof, and belongs to the technical field of shielding materials, and comprises the following steps: stirring and uniformly mixing propylenediamine-based latent foaming agent, propylenediamine, propylene abietic acid glycidyl ester and 1,3-bis(3-glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane, and obtaining the degradable rosin-based epoxy foam through reaction.The foaming agent used in the application is rapidly decomposed under heating conditions to release carbon dioxide and the curing agent propylenediamine, and the preparation is simple, environment-friendly and residue-free; the prepared epoxy foam is easy to degrade, excellent in electromagnetic shielding and joule heating performance, and has a wide application prospect in the fields of military equipment, aerospace and wearable electronic devices.

The invention belongs to the technical field of high polymer materials, and particularly discloses glycidyl ester type epoxy resin and a preparation method thereof, the preparation method comprises the following steps: (1) melting polymerized rosin, adding a first catalyst, maleic anhydride, methacrylic acid and hydroxyl-terminated hyperbranched polyester, and reacting to obtain a precursor; and (2) adding bisphenol A epoxy resin and a second catalyst into the precursor, and reacting to obtain the glycidyl ester type epoxy resin. According to the invention, maleic anhydride, methacrylic acid, hydroxyl-terminated hyperbranched polyester and bisphenol A epoxy resin are combined; the three-dimensional synergistic enhancement of rigidity-flexibility-branching is realized, the proportion of rigid and flexible chain segments in a molecular structure is effectively coordinated, reaction active sites and crosslinking density are effectively improved, more reaction active sites and reaction activity are provided, and the mechanical property of a product is effectively improved.

The invention relates to the technical field of paper wet strength agents, in particular to an environment-friendly wet strength agent and a preparation method thereof. The preparation method of the wet strength agent comprises the following steps: under the action of a catalyst, succinic acid, maleic acid and triethylene tetramine react to obtain an unsaturated polyamide polyamine prepolymer; adding water into the unsaturated polyamide polyamine prepolymer to adjust the solid content, heating, adding double-bond-containing nanocellulose, tea saponin, glycidyl acrylate and an initiator, and reacting to obtain an intermediate emulsion; cooling the intermediate emulsion to room temperature, adding epichlorohydrin to react for 0.5-3 hours, heating to 50-75 DEG C, continuing to react for 1-5 hours, cooling reaction liquid to 25-30 DEG C, adding glyoxal to react for 0.5-1 hour, adjusting the pH value of the reaction liquid after the reaction is completed, and adding water to adjust the solid content, thereby obtaining the product. The preparation method is simple in process, and the prepared wet strength agent can reduce organic chlorine residues.

The invention relates to automobile film surface protection, and provides a scratch-resistant coating composition and a preparation method thereof. The composition is prepared from polymer resin containing an acrylate group, polysiloxane acrylate containing a hydrolyzable alkoxy silicon group, composite silane modified double-particle-size nano silicon dioxide, a photoinitiator, an organic silicon cross-linking agent and an auxiliary agent, wherein the nano silicon dioxide is composed of a small-particle-size group and a large-particle-size group; and gamma-methylacryloyloxypropyl silane and gamma-glycidoxypropyl silane are respectively grafted to the two monomers. A micro-thin transparent hard coating is formed on the surface of a polyester base material through staged ultraviolet curing and damp-heat curing, so that the coating has high surface hardness and abrasion resistance and excellent damp-heat aging adhesive force and whitening resistance while keeping high light transmittance and low haze.

The invention relates to the field of ceramic packaging materials, in particular to a packaging material for a high-voltage-resistant ceramic side wall and a preparation method of the packaging material. The packaging material is prepared from an epoxy-silica hybrid prepolymer, an aluminum oxide and silicon dioxide core-shell composite filler, methylhexahydrophthalic anhydride and 2-ethyl-4-methylimidazole, wherein the hybrid prepolymer is prepared by carrying out hydrolytic condensation on bisphenol A diglycidyl ether, hydroxyl-terminated PDMS (Polydimethylsiloxane) and 3-glycidoxypropyltrimethoxysilane; low viscosity and low volatile matter are realized; the core-shell filler takes aluminum oxide as a core and silicon dioxide as a shell, and a shell layer is grafted with epoxy silane so as to be chemically bonded with resin. And after curing, the power frequency short-time electrical strength of the packaging layer is greater than or equal to 20 kV / mm, the partial discharge initial voltage is greater than or equal to 3 kV, the volatile matter is less than or equal to 1.0 wt%, and the water content is less than or equal to 0.2 wt%.

This application discloses a harmonica tube and a preparation method thereof, a liquid cooling plate, a battery, and an electric apparatus, where a material of the harmonica tube includes a polyphenylene sulfide composition, and the polyphenylene sulfide composition includes a polyphenylene sulfide resin and a toughening agent; the toughening agent includes a copolymer of an olefin and a glycidyl ester. By providing the polyphenylene sulfide composition as the material for the harmonica tube, this application facilitates reducing issues such as material breakage or poor extrusion flow during extrusion molding, enabling the formed harmonica tube to exhibit excellent mechanical strength, deformation resistance, corrosion resistance, heat resistance, heat dissipation, and creep resistance, lowering the risk of cracking under pressure during use, and enhancing production capacity and product quality.

The application discloses a self-emulsifying degradable carbon fiber sizing agent and a preparation method and application thereof. Raw materials of the self-emulsifying degradable carbon fiber sizing agent include the following components in parts by weight: diglycidyl ester epoxy resin monomer 20-30 parts, fatty amine 1-3 parts, amine curing agent 5-10 parts, sodium p-aminobenzenesulfonate 1-3 parts, water 15-20 parts and acetone 20-30 parts. The self-emulsifying degradable carbon fiber sizing agent can significantly improve wear resistance of the carbon fiber and interface performance of a composite material, and can be degraded under mild conditions, and the carbon fiber recovered has good performance.

The application relates to a conductive silver glue and a preparation method and application thereof, and belongs to the technical field of bonding materials.The conductive silver glue comprises an epoxy resin, an active diluent, a curing agent, an accelerator and silver powder; the epoxy resin comprises a main body resin and an auxiliary resin; the main body resin comprises a glycidyl amine type epoxy resin; and the auxiliary resin comprises a combination of a phenolic epoxy resin, a triphenylmethane type epoxy resin and an alicyclic epoxy resin.The conductive silver glue provided by the application is a high-reliability conductive silver glue of an epoxy resin system, has the characteristics of high moisture and heat resistance, high high-temperature bonding force, high residual glue rate and low resin overflow, effectively solves the problem that the existing conductive silver glue has low reliability under high-temperature and high-humidity conditions, is suitable for complex scenes, and has a simple preparation method and controllable cost.

The invention provides macroporous silicon dioxide with the surface covalently expressed by single-layer branched polyethyleneimine and a preparation method of the macroporous silicon dioxide. The preparation method comprises the following steps: mixing and stirring branched polyethyleneimine and an aqueous solution of a water-soluble anionic surfactant to obtain a supramolecular micelle system; the preparation method comprises the following steps: mixing tetraethoxysiloxane, glycidoxypropyltrimethoxysilane and an optional organic solvent to form a siloxane solution; dropwise adding a siloxane solution into the supramolecular micelle system under stirring to obtain a concentrated emulsion; and incubating the concentrated emulsion at normal temperature, crushing, washing and drying in vacuum. According to the synthesis of surface polyaminated silicon dioxide, due to the use of a small amount of glycidoxypropyltrimethoxysilane, branched polyethyleneimine can form a small amount of covalent bonds with silicon dioxide so as to be fixed on the pore surface, and meanwhile, a large amount of active amino hydrogen of polyethyleneimine can be retained; the hydrolysis rate of the siloxane can be adjusted by the polarity of the organic solvent.

The application discloses a kind of eluent and its preparation method and application, preparation method includes: adding potassium methoxide methanol solution to the trimethylolpropane in molten state, after stirring, vacuumizing, then droping glycidol monomer, after reaction, add methanol, dry, obtain hyperbranched polyglycerol ether;Add carbonyl imidazole to the N,N-dimethylformamide solution of saturated fatty acid, after stirring and mixing, drop to the N,N-dimethylformamide solution of hyperbranched polyglycerol ether, reaction is heated in nitrogen atmosphere, after reaction, the product is treated, obtain temperature-sensitive hyperbranched polyglycidol ether eluent.The eluent prepared in the application can greatly reduce the treatment cost of elution waste liquid while efficiently removing heavy metals.

The invention relates to a process for the synthesis of triglycidyl catechol based on eugenol. The object of the invention is to synthesize plastics, in particular epoxy resins, fiber-reinforced plastics, etc., based on renewable resources, especially for cabin construction in aviation, with a significantly increased bio-content. This object is achieved according to the invention by a process according to claim 1.

A demulsifying agent may comprise the structureR1 may be a hydrocarbyl group or heterohydrocarbyl group comprising from 1 to 20 carbon atoms. m may be from 2 to 10, n may be from 5 to 20, and p may be from 2 to 15. R2 may comprise a residue of propylene oxide. R3 may comprise a residue of glycidol. Embodiments of the present disclosure may further comprise methods of making the demulsifying agent and methods of using the demulsifying agent to demulsify a hydrocarbon emulsion.

The invention discloses an SERS (Surface Enhanced Raman Scattering) flexible sensor based on dual-ion modification as well as a preparation method and application of the SERS flexible sensor, and belongs to the technical field of biomedical detection. A bacterial cellulose membrane (BCM) is used as a base material, cation modification (QBCM) is carried out through glycidyl trimethyl ammonium chloride (EPTMAC), anion modification (TABCM) is carried out through tannic acid (TA), a functional substrate with asymmetric charge distribution and a porous structure is constructed, then Ag NPs are loaded on the modified base material through an in-situ reduction method, the QBCM-coated AgNPs and TABCM-coated AgNPs dual-ion active substrate is formed, and the AgNPs / TABCM-coated AgNPs dual-ion active substrate is used for preparing the composite material. The SERS flexible sensor is integrated through a layer-by-layer self-assembly (LbL) technology; the SERS flexible sensor can realize specific enrichment and synchronous detection of anionic kynurenic acid (KYNA) and cationic spermine (Spm) in urine, and is low in detection limit and good in reproducibility.

Provided is a light-curable composition that includes one or more monofunctional (meth)acrylate monomers with at least one monomer having a homopolymer glass transition temperature of from 0°C to 200°C; a crosslinker selected from multifunctional oligomeric (meth)acrylates, aliphatic urethane (meth)acrylates, aromatic urethane (meth)acrylates, polyester (meth)acrylates, and epoxy (meth)acrylates; one or more adhesion promoters selected from glycidyl (meth)acrylate, 2-hydroxyethyl(meth)acrylate acid phosphate, phosphonate ester-containing (meth)acrylic monomer, phosphate ester-containing (meth)acrylic monomer, silane, and (meth)acrylic acid; a photoinitiator; a flame retardant; and one or more fillers comprising hollow fillers, refractory fillers comprising kaolin, intumescent fillers, or mixtures thereof. The cured composition can function as an electrical insulator in battery assemblies, while protecting components from hot particles and gases in case of thermal runaway events.

An epoxy resin-based adhesive composition used for a vehicle includes a bisphenol A epoxy resin, a polyalkylene glycol diglycidyl ether, a dimer acid diglycidyl ester, and a compound having a phenol group.

This invention relates to the field of chemical synthesis technology, specifically disclosing a method for preparing vinyl ethylene carbonate. The method uses glycidyl as a starting material, first converting it to glycidaldehyde via a mild oxidation reaction with high selectivity. Then, using a cross-linked imidazole polymeric ionic liquid as a catalyst, glycidaldehyde undergoes an atom-economical cycloaddition reaction with carbon dioxide to construct a cyclic carbonate intermediate. Finally, under catalytic conditions, a condensation reaction introduces a vinyl functional group to obtain the vinyl ethylene carbonate product. This invention uses widely available, low-toxicity, and inexpensive glycidyl instead of highly toxic raw materials, and utilizes greenhouse gas carbon dioxide as a carbonyl source for resource utilization. The process route is highly atom-economical, the reaction conditions are mild, and the catalyst is easy to separate, recover, and recycle, effectively solving the prominent problems of high raw material toxicity, expensive catalysts, and difficult byproduct treatment in traditional preparation techniques.

The application relates to the technical field of PET sheets, in particular to an anti-static impact-resistant PET sheet and a preparation method thereof. The anti-static impact-resistant PET sheet of the application comprises PET resin and a modifier. The PET resin and the modifier are melt-blended, extruded and sliced to prepare the anti-static impact-resistant PET sheet. The modifier has an important influence on the anti-static performance and the impact resistance of the PET sheet. The preparation method of the modifier comprises the following steps: firstly, unsaturated glycidyl ester is reacted with amino siloxane; then, the unsaturated glycidyl ester is grafted on the POE molecular chain through melt grafting; finally, the acid-doped polyaniline layer is coated by using an in-situ polymerization method. The modifier obtained through the above preparation method has good compatibility with the PET resin, the interface bonding strength between the POE and the polyaniline is high, in addition, organic montmorillonite and nano zinc oxide can be introduced into the above modifier, and the anti-static performance and the impact resistance of the PET sheet can be further improved.

The application discloses a natural monophenol grafted dimer acid diglycidyl ester plasticizer and a preparation method and application thereof, and belongs to the technical field of bio-based plasticizers. The natural monophenol grafted dimer acid diglycidyl ester is synthesized by ring-opening etherification of dimer acid diglycidyl ester and natural monophenol. The prepared natural monophenol grafted dimer acid diglycidyl ester has a high-polarity hydroxyl group, a good-flexibility ether bond group and a compatibilized benzene ring group in the structure, and can endow a PLA product with excellent ductility and migration resistance. The application not only realizes high-value utilization of the natural monophenol in the material field, but also provides a new method for preparing a high-quality environment-friendly plasticizer, and has good practicability.