6274 results about "Flame resistance" patented technology

A method of improving surface flame resistance of a substrate is provided. A substrate is provided. An atmosphere pressure plasma process is performed on the surface of the substrate to form an inorganic film layer on the surface of the substrate, wherein a process gas of the atmosphere plasma process includes a flame resistance precursor, a carrier gas, and a plasma ignition gas. Particularly, the flame resistance precursor is selected from a siloxane compound, an inorganic alkoxide compound and a combination thereof. The siloxane compound has a formula of Si(OC_nH_2(n+1))₄, n=1˜5, and the inorganic alkoxide compound has a formula of A(OC_mH_2m+1)4, where A represents Sn, Ti, Zr, Ce and m=2.

Polyester compositions that provide a higher throughput in calendering processes may be prepared from a polyester having crystallization half time of at least 5 minutes, an inherent viscosity of about 0.55 to about 0.75 dL/g, a branching monomer, and a release additive. The polyester compositions show a combination of excellent melt strength with good shear response that permits higher calendering line speeds before melt fracture occurs. Also disclosed are processes for film or sheet by calendering the above compositions and the film or sheet produced therefrom. The polyester compositions, film, or sheet also may include plasticizers and/or flame retardants to increase their flexibility and enable their use in commercial applications requiring flame resistance. The film and sheet have excellent appearance and can be used in a wide range of decorative and packaging applications.

The invention discloses aqueous fire-proof corrosion-proof paint for a steel structure and a preparation method thereof, and belongs to the technical field of paint. The aqueous fire-proof corrosion-proof paint comprises, by mass, 20-45% of a composite emulsion, 12-25% of a charring catalyst, 6-12% of a foaming agent, 8-17% of a charring agent, 5-10% of a fire retardant, 1-5% of layered double hydroxide, 8-18% of an corrosion-proof filling material, 4-12% of a strengthening filling material, 1-5% of modified nano-powder, 0.5-6% of an assistant and 10-30% of water. Through use of the composite modified emulsion as a base material, coating flame resistance, corrosion resistance and decorativeness are obtained and coating defects caused by a single emulsion as a base material are overcome. Through use of a small amount of the nano-powder, the coating is compact because of filling effects of the nano-powder, the coating corrosion caused by O2, H2O and Cl <-> is avoided, good fire-proof and corrosion-proof effects are obtained under the condition of a small addition amount and a cost is reduced. The aqueous fire-proof corrosion-proof paint has the characteristics of green environmental protection and simple preparation processes.

The invention provides an irradiation cross-linking oil resistance type soft low smoke zero halogen flame-retardant cable material which comprises the following components in parts by weight: 60-90 parts of ethylene-vinylacetate copolymer, ethylene-propylene-diene rubber and ethylene-octylene copolymer, 0-20 parts of nitrile rubber, 10-30 parts of interface compatilizer, 80-130 parts of flame retardant, 2-15 parts of flame-retardant synergist, 0.5-1.0 part of antioxidant, 1-2 parts of cross-linking sensitizing agent and 0.5-1.0 part of lubricant. The preparation method of the cable material in the invention mainly comprises the steps of silane surface modification treatment of the flame retardant, mixing and extruding of a double screw mixer-extruder unit or an internal mixer unit, brace water cooling or water ring particle cutting and the like. The cable material provided by the invention has the advantages of superior flame resistance (single cable can vertically burn), good mechanical properties, especially high softness, oil resistance, high-temperature resistance (the cable material can be used in a range of minus 40 DEG C-125 DEG C), low smoke, low toxicity and excellent processability.

The invention relates to insulation materials and sheathing materials, and in particular relates to a wear-resisting flame-retardant polyvinyl chloride insulation and sheathing material. The wear-resisting flame-retardant polyvinyl chloride insulation and sheathing material comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 40 to 60 parts of plasticizer, 6 to 30 parts of wearable modifying agent, 4 to 8 parts of stabilizing agent, 4 to 32 parts of fire retardant, 10 to 40 parts of filling agent, and 0.8 to 3 part(s) of lubricating agent. The insulating and sheathing material has good wear-resisting and flame-retardant properties, high squeezing performance, high rolling performance and high flexing performance, as well as high flexibility and processability.

The invention belongs to the field of building materials, relates to a use of a nano-material in a building exterior wall heat-retaining system and provides a nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick. The nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick is characterized in that nano-particles are used so that compressive strength, tensile strength and bonding strength are improved. The nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick is prepared by adding a nano-material having a nanoscale particle size into a mixed system of cement, an auxiliary gel material, a polymer binder, an inorganic light heat-retaining material, fibers and water, uniformly mixing, carrying out pressing molding of the mixture, carrying out organic polymer crosslinking and cement hydration drying, and carrying out waterproof layer coating. The nano-material-containing high-strength high-heat insulation exterior wall inorganic heat-retaining face brick has the advantages of excellent flame resistance, high compressive strength, high tensile strength, high bonding strength and good insulation effects.

The invention discloses a fireproof and flame-retardant composite polystyrene heat insulation material and a method for preparing a heat insulation board by using the material, which belongs to the technical field of the heat insulation boards. The composite heat insulation board combining an inorganic heat insulation material and an organic heat insulation material has the characteristics of fireproof property, heat insulation, flame-retardant property and low heat conductivity of the organic material, so the fireproof and flame-retardant performance of the composite heat insulation material can be improved based on unchanging the heat conductivity of the polystyrene. The method for preparing the composite heat insulation board is simple and easy to operate; each polystyrene granule is covered with a layer of a fireproof and flame-retardant material on the surface, so that each granule forms an integrated and independent unit, thereby effectively interrupting the conduction of the heat and the spread of the flame to achieve a non-combustion effect. The prepared composite polystyrene heat insulation board has the advantages of light weight, low heat conductivity, good heat insulation effect, high tensile strength, good toughness, high size stability, low moisture absorption and good flame resistance, and the combustion performance can be A2 grade (GB8624-2006).

A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.

The invention relates to a high-performance halogen-free flame retardant ABS modified resin and a preparation method thereof. The resin comprises the following components with the content (in parts by weight): 100 ABS resin, 4-30 polyamide, 5-25 phosphate fire retardant, 0.1-0.5 anti-drippage agent, 5-10 toughening agent, 1-5 nano filler, 1-5 compatilizer, 0.2-1 antioxidant, 0.1-0.5 light stabilizer and 1-5 processing agent. Compared with the prior art, the invention has reasonable technique, and overcomes the defects of poor flame retardant property and low impact strength of the existing halogen-free flame retardant ABS; and the invention adopts a novel high-efficiency halogen-free flame retardant compounding synergism technology, a novel polyamide coal-forming agent, the high-efficiency synergism between organic and inorganic fire retardants, and the master batch method processing technique, thus endowing the resin with high fire resistance on the basis of improving the original good performances (especially the impact performance) of the ABS resin, and having wide application prospect.

The invention discloses a polyamide composition with flame retardance and thermoplasticity. The polyamide composition with flame retardance and thermoplasticity comprises the following components in percentage by weight: 30-90% of thermoplastic polyamide resin, 5-40% of a brominated flame retardant, 0.5-15% of a flame-retardant synergist and 0-50% of a reinforcing material. According to the polyamide composition, the brominated flame retardant, the high-efficiency flame-retardant synergist (namely zinc borate) and organic silicon are added in polyamide resin, on the one hand, the polyamide composition can replace antimony trioxide which is a rare material and is limited to be exploited by the nation at present, limited strategic resources of the nation can be saved, and the cost is lowered; and on the other hand, the flame retardance, a CTI (comparative tracking index) value and GWIT (glow wire ignition temperature) of the polyamide composition can be improved greatly, and the safety guarantee is provided for the use of the flame-retardant polyamide product on electronic appliances with high requirements.

The invention provides halogen-free resin composition, and a copper clad laminate and a printed circuit board applying the halogen-free resin composition. The halogen-free resin composition comprises, by weight, (A) 100 parts of epoxy resin, (B) 1 part -100 parts of benzoxazine resin, (C) 1part -100 parts of styrene maleic anhydride, (D) 0.5 part -30 parts of amine curing agents, and (E) 5-150 parts of halogen-free flame retardants. By means of the specified constituents and ration, the halogen-free resin composition achieves the purposes of low dielectric constant, low dielectric loss, high heat resistance, and high flame resistance, can be manufactured into semi-solidified rubber pieces or resin films, and then achieves the purposes of being applied to the copper clad laminate and the printed circuit board.

The invention relates to an anti-oil and fire-retardant chlorinated polyethylene sheath material with good weather resistance and a preparation method thereof. The sheath material uses chlorinated polyethylene rubber as main raw material and adds chlorosulfonated polyethylene rubber, triallyl isocyanurate, 1,3-bis (tert-butyl peroxide isopropyl) benzene, trioctyl trimellitate, carbon black, antioxidant 1010, ultra-fine talc powder, antimony trioxide, and high-activity magnesium oxide R-150 according to ratios; the preparation method is as follows: at first, mixing part of the auxiliary agents, then mediating, internal mixing, open mixing, granulating and extruding are carried out on the mixture to form cables, thus the cables are obtained. In the formula, high temperature resistant plasticizer is utilized, various auxiliary agents with appropriate proportions are added into the formula, so that chlorinated polyethylene rubber cable material can reach a high temperature of 105 DEG C, and can be used at the lowest temperature of minus 50 DEG C. The sheath material has the advantages of good anti-aging property, excellent electrical insulation and mechanical property, environmental protection and high flame resistance, thereby being suitable for cold and oil-contaminated severe environment and transmission and distribution circuits of which the current-carrying capacities are large and the rated voltages are at or below 450/750V. Meanwhile, compared with traditional chloroprene rubber cable material, the sheath material has the characteristics of low cost, fast extruding speed and high output benefit.

A resin composition, substrate material, sheet, laminated board, resin-bearing copper foil, copper-clad laminate, TAB tape, printed board, prepreg and adhesive sheet are provided which exhibit improved mechanical properties, dimensional stability, heat resistance and flame retardance, particularly high-temperature physical properties.

A resin composition containing 100 parts by weight of a thermosetting resin and 0.1-65 parts by weight of an inorganic compound, the resin composition having a mean linear expansion coefficient (α2) of up to 17×10⁻³ [° C.⁻¹] over the temperature range from a temperature 10° C. higher than a glass transition temperature of the resin composition to a temperature 50° C. higher than the glass transition temperature of the resin composition.

The invention discloses a halogen free flame retardant nylon 6 composite with high CTI value and a preparation method thereof. The composite comprises the following components by mass percent: 643.5-68.8wt.% of nylon, 10-12wt.% of fire retardant, 7-19wt.% of fire retardant synergetic inorganic packing, 8-12% wt.% of toughening agent, 1-3wt.% of bulking agent, 5-10% wt.% of enhance inorganic filler and 0.2-0.5wt.% of anti-oxygen which are prepared into the compound by a high speed premixing dispersing primary extrusion processing. The disclosed composite has as high as 550V CTI value and UL 94V-0 level excellent fire resistance; simultaneously, the polymer has good mechanical property by a comprehensive modified technique, wherein the tensile strength reaches 70.5Mpa, the bending strength reaches 90.7MPa and the impacting strength of a gap reaches 28.1kJ/m2. The invention solves the problem that the flaming resistant and high CTI value are difficult to satisfy simultaneously; the inventive 6 nylon compound is very suitable for preparing a low-pressure vacuum contactor, a transformer coil framework, a high-temperature resistant relay, a breaker, a high voltage electrical apparatus, a handle and a thin wall electronic and electrical appliance elements, and the like.

The invention discloses an insulating and sheathing material of ultraviolet light crosslinking expanding type phosphorus nitrogen flaming resistance polyolefine cables and a preparation method thereof. The invention is characterized in that polyethylene/PEMA and/or ethylene vinyl acetate or maleic anhydride grafted ethylene vinyl acetate or acid amide grafted ethylene vinyl acetate copolymer are taken as base, added with expanding type phosphorus nitrogen halogen-free flame retardants, light trigger, polyfunctional group cross linker and chemical inhibitor and matched with flaming retardant synergistic agent, antismoke agent and processing aid, and then squeezed out and pelleted into photo-crosslinking flame retardant cable materials; and then the flame retardant cable materials are melted and extruded on a cable conductor wire core and clad into an insulating layer and a sheathing layer; hereupon the ultraviolet light irradiation crosslinking is carried on the insulating layer or the sheathing layer. Via detecting, the oxygen index of the insulating layer or the sheathing layer is larger than 30%, the vertical flaming experiment passes through UL-94 V0 level, the tensile strength is larger than 12Mpa, the elongation at break is larger than 350%, and the electric volume resistivity is larger than 8*10 omega.cm.

The invention discloses a halogen-free expansion type flame-retardant glass fiber reinforced polypropylene material. The polypropylene material is prepared from the following ingredients in percentage by mass: 40%-74% of polypropylene resin, 15%-30% of halogen-free expansion type flame retardant, 0%-6% of flame-retardant synergist, 5%-30% of glass fiber, 0%-20% of filling agent, 5%-15% of compatilizer, 0.2%-0.6% of nucleating agent, 0.3%-1% of antioxidant and 0.5%-2% of lubricating agent. According to the flame-retardant glass fiber reinforced polypropylene material disclosed by the invention, as the quantity of addition of the halogen-free flame retardant is little, the flame-retardant effect is good; and the compounded flame-retardant synergist does not affect the performance of the resin, the flame-retardant performance of the material is improved, the cost can be lowered, no precipitation exists on the surface of the compounded flame-retardant product in long-term storage, so thatthe defect that precipitation exists on the flame-retardant product in long-term storage is overcome, and the advantages of no halogen, environmental friendliness, excellent performance and long-termworkability are achieved.

Disclosed is a flame-retardant polyamide composition which has excellent mechanical properties such as toughness, excellent heat resistance and flow ability during reflow soldering, and good thermal stability during molding, without using a halogen flame-retardant. This flame-retardant polyamide composition exhibits stable flame retardance particularly when a thin article is molded. Specifically disclosed is a flame-retardant polyamide composition containing 20-80% by mass of a specific polyamide resin (A), 5-30% by mass of a phosphinate compound (B), and 0.01-10% by mass of a phosphazene compound (C).

The invention relates to fibrous insulation products that exhibit improved flame resistance, relative to previously known products. The insulation product has a fibrous mineral matrix, into which is incorporated a phosphate-containing compound (e.g., an inorganic phosphate salt) and a refractory mineral filler (e.g., alumina or aluminum sulfate). The product exhibits flame resistance superior to the fibrous mineral matrix alone.

An electromagnetic wave absorber comprising (a) soft ferrite having its surface treated with a silane compound having no functional group, (c) magnetite and (d) silicone, or comprising (a) soft ferrite having its surface treated with a silane compound having no functional group, (b) flat, soft magnetic metal powder, (c) magnetite and (d) silicone, which electromagnetic wave absorber excels in electromagnetic wave absorption, heat conduction and flame resistance, exhibiting less temperature dependence, and which electromagnetic wave absorber is soft, excelling in adhesion strength and further excelling in high resistance high insulation properties and in energy conversion efficiency being stable in MHz to 10 GHz broadband frequency. There is further provided a laminated electromagnetic wave absorber comprising the above electromagnetic wave absorber overlaid with a reflection layer of conductor, which laminated electromagnetic wave absorber can be closely stuck onto an unwanted electromagnetic wave emission source such as a high-speed operating device, having such an adhesive strength that even when stuck to a horizontal glassy-surface ceiling face of resin-made cage, would not fall.

The invention discloses an injection molding grade flame retardant PVC/ABS alloy material and a preparation method thereof. The alloy material comprises the following components in parts by weight: 30-80 parts of PVC resin, 35-70 parts of ABS resin, 1-6 parts of a heat stabilizer, 2-5 parts of a processing agent, 2-15 parts of an impact modifier, 1-10 parts of a heat resistant modifier, 2-5 parts of a plasticizer, 2-8 parts of a fire retardant, 3-10 parts of a smoke suppression agent and 3-15 parts of other accessory ingredients. The PVC/ABS alloy material disclosed by the invention adopts the high-fluidity PVC resin and the heat-resistance, high-toughness and high-fluidity ABS resin, so that the PVC/ABS alloy material has excellent mechanical performance and processing fluidity; on the premise of guaranteeing excellent physical performance of the material, the obtained PVC/ABS alloy material further improves the processing fluidity, the heat stability, the flame resistance and the heat resistance of products, and reduces the smoke density.

The invention provides a halogen-free resin composition which comprises (A) 100 parts of cyanate ester resin, (B) 5-50 parts of styrene maleic anhydride, (C), 5-100 parts of polyphenyl ether resin, (D) 5-100 parts of maleimide resin, (E) 10-150 parts of nitrogenous compound, and (F) 10-1000 parts of inorganic filler. As the composition comprises components in special proportion, the halogen-free resin composition is low in dielectric constant, low in dielectric loss, high in heat resistance and high in flame resistance. The halogen-free resin composition can be prepared as a semi-cured film or a resin film, so that the composition can be applied to a copper foil substrate and a printed circuit board.

A lightweight fiber-reinforced composite material that exhibits excellent flame resistance and mechanical properties and does not emit any halogen gas at combustion; an epoxy resin composition and prepreg suitable for obtaining the above fiber-reinforced composite material; and an integrated molding suitable to electrical/electronic equipment cabinet, in which use is made of the above fiber-reinforced composite material. There is provided an epoxy resin composition for carbon-fiber-reinforced composite material, comprising: [A] epoxy resin, [B] amine curing agent, and [C] phosphorus compound, the component [C] contained in an amount, in terms of concentration of phosphorus atoms, of 0.2 to 15 wt.%.

The invention relates to a microporous polyether urethane elastomer composite material and a preparation method thereof. The composite material is formed by the prepolymerization reaction of a polyhydric alcohol component A and a prepolymer component B, wherein the polyhydric alcohol component A comprises the following raw materials in the formula: 20 to 90 parts of polyoxytrimethyl-ene polyhydric alcohol, 5 to 50 parts of polyether polyol II, 5 to 50 parts of polymer polyether polyol, 2 to 30 parts of chain extender, 0.5 to 2 parts of nanometer graphene, 0.2 to 4 parts of foaming agent, 0.2 to 2 parts of foam homogenizing agent and 0.2 to 4 parts of catalyst; and the prepolymer component B comprises the following raw materials in the formula: 30 to 60 parts of diisocyanate, 4 to 20 parts of polyisocyanate modified by carbodiimide and 20 to 60 parts of polyoxytrimethyl-ene polyhydric alcohol. The polyether polyol II is formed by one or two of polyoxytrimethyl-ene epoxyethane copolyether polyol or/and polyethylene tetrahydrofuran polyol. The composite material provided by the invention is excellent in comprehensive mechanical property, antibacterial property and definite flame resistance.

A fabric is provided for use in safety apparel, including a first yarn type comprising at least about 60 percent modacylic fibers and a second yarn type comprising an intimate blend of anti-static fibers and other fibers selected from the group of fibers consisting of polyester, nylon, rayon, modacrylic, cotton, wool, and combinations thereof. The fabric meets the American Society for Testing and Materials standard ASTM F-1506 for flame resistance, Federal Test Method Standard 191A, Method 5931 for electrostatic decay, and the Electrostatic Discharge Association Advisory ADV11.2-1995 voltage potential.

The invention discloses a high-frequency thermosetting resin composition. The high-frequency thermosetting resin composition comprises the following components in part by weight: 10 to 60 parts of halogen-free epoxy resin, 15 to 70 parts of polyphenyl ether resin, and 5 to 60 parts of composite cyanate resin; an accelerator is 0.01 to 2 parts; and the composite cyanate resin comprises thiocyanate resin. The composition can realize halogen-free flame resistance, and does not influence the heat resistance and dielectric performance of a product; and a laminated sheet prepared from the composition has high peel strength and heat resistance of a copper foil and a low dielectric constant and low dielectric loss under the high-frequency condition.

A thermoplastic composition includes a poly(arylene ether), a hydrogenated block copolymer, a pre-blend of a thermoplastic vulcanizate and a hydrogenated block copolymer, an ethylene/alpha-olefin copolymer, and a hydrocarbon resin. Pre-blending the thermoplastic vulcanizate with a portion of the hydrogenated block copolymer was found to markedly improve the flame resistance and physical properties of the composition compared to those of compositions in which the thermoplastic vulcanizate and hydrogenated block copolymer are separately added to the final compounding process. Addition of hydrocarbon resin further improves the balance of flame retardancy and physical properties.

The invention discloses a cold-resistant rubber cable sheath material and a preparation method. The material comprises chlorinated polyethylene, ethylene-propylene-diene monomer (EPDM) rubber, lead oxide, calcium carbonate, N-isopropyl benzene-N'-phenyl p-phenylenediamine serving as an anti-aging agent, antimonous oxide, magnesium oxide, paraffin hydrocarbon oil, chlorinated paraffin, paraffin, carbon black, settled white carbon black, talc powder, gamma-aminopropyl triethoxysilane serving as a surfactant, dicumyl peroxide serving as a vulcanizing agent and triallyl isocyanurate serving as a co-vulcanizing agent. The low temperature performance of the material is improved by blending the chlorinated polyethylene and the EPDM rubber, and meanwhile, the flame-retardant performance of the rubber sheath material is improved by synergy of the antimonous oxide serving as a flame retardant and the chlorinated paraffin; experiments show that the rubber sheath material can pass low-temperature embrittlement test of 40 DEG C below zero, has excellent low-temperature resistance, has the oxygen index of more than 32 and has good flame-retardant performance; and the preparation method is simple and strong in operability.

Disclosed are compositions including engineering plastics; melamine, melamine, melamine salts or melamine derivatives; and linear or branched polyphosphonates or copolyphosphonates which exhibit excellent processing characteristics, thermal and mechanical properties and flame resistance, and articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.

The invention relates to an environmental-friendly polypropylene material with flame resistance and antistatic capacities, which comprises parts by weight of components that: 100pbw of pp resin, 30-50 portions of flame retardant, 10-20 portions of flame-retardant synergist, 40-60 portions of fillers and 10-30 portions of antistatic agent. The PP resin is high fluidity homopolymerization PP; the flame retardant is deca-diphenylethane; the flame-retardant synergist is antimony trioxide; the filler is 2000 meshes talcum powder; the antistatic agent is conductive carbon black; lubrication dispersing agent is aethylenum double fatty acid amide TAS-2A. The preparation method of the material is that: according to the part by weight, 100 portions of PP resin, 30-50 portions of flame retardant, 10-20 portions of flame-retardant synergist, 40-60 portions of fillers, 10-30 portions of antistatic agent and 1-10 portions of lubrication dispersant are weighted and mixed in a high-speed mixer for 3 to 5 minutes, and after mixing, the mixed raw materials are molten, squeezed and made into particles in a parallel twin-screw extruder. The polypropylene material of the invention has the advantages of good mechanical intensity, antistatic effect, flame resistance and being environment-friendly.

The invention discloses a thermosetting resin composition which comprises epoxy resins except brominated epoxy resin, an styrene maleic anhydride copolymer and an additive flame retardant, and further comprises an active ester. The thermosetting resin composition can be used for preparing resin sheet materials, resin compound metal copper foils, prepregs, laminates, copper clad laminates, printed circuit boards, etc. The thermosetting resin composition substantially reduces probability of delamination of PCB substrate, overcomes disadvantages of deterioration of system dielectric properties due to introduction of tetrabromobisphenol A, and has advantages of good heat stability and heat and humidity resistance, low dielectric constant and dielectric loss tangent, and good flame resistance.