8195 results about "Flame resistance" patented technology

The invention provides a polymer additive and application thereof. The polymer additive is prepared from the following components in parts by mass: 30 to 90 parts of diethyl phosphinate, 0.01 to 3 parts of ethyl phosphonate, 5 to 67 parts of dialkyl phosphinate and 0.01 to 5.5 parts of alkyl phosphinate. The dialkyl phosphinate has a structure as shown in a formula I, and the alkyl phosphinate has a structure as shown in a formula II. According to the invention, through design and compounding synergy of various phosphonates, the flame-retardant effect can be obviously improved, so that the polymer additive has excellent and efficient flame retardance. The polymer additive is used in a polymer material, and a polymer composition containing the polymer additive can have excellent flame retardant property, good toughness, high impact strength and excellent mechanical property and humidity and heat resistance under the condition that the addition amount is small.

The invention relates to the technical field of polyamide materials, in particular to a high-heat-resistance bio-based polyamide material and a preparation method thereof, and the high-heat-resistance bio-based polyamide material comprises the following raw materials in parts by weight: 45-50 parts of PA56, 7-11 parts of a balance multi-effect agent doped with a filler modifier, 5-8 parts of a flame retardant, 4-7 parts of a silane coupling agent, 3-5 parts of an antioxidant and 2-4 parts of a lubricant. According to the bio-based polyamide material, the bio-based PA56 is adopted as a matrix, meanwhile, the flame retardant, the silane coupling agent, the antioxidant and the lubricant are added to serve as functional auxiliaries, the balance multi-effect agent doped with the filler modifier is added to be matched with the stable supplement agent, and the raw materials are blended, coordinated and jointly synergized, so that the flame retardant property of the bio-based polyamide material is improved, and the flame retardant property of the bio-based polyamide material is improved. The obtained bio-based polyamide material is harmoniously improved in dielectric loss, flame retardance and wear resistance, and meanwhile, the product is remarkable in weather resistance and high heat stability resistance.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The invention discloses a flame-retardant PC / ABS (polycarbonate / acrylonitrile butadiene styrene) composite material for automobiles and a preparation process thereof, and relates to the technical field of PC / ABS composite materials. The PC / ABS composite material is prepared from the following components in parts by weight: 60 to 70 parts of PC resin, 50 to 60 parts of ABS resin, 6 to 12 parts of hyperbranched modified ATP (Adenosine Triphosphate), 4 to 8 parts of antioxidant flame retardant, 2 to 4 parts of compatilizer and 2 to 4 parts of flexibilizer. Under the synergistic effect of the hyperbranched modified ATP, the antioxidant flame retardant, the compatilizer and the toughening agent, the PC / ABS composite material with excellent flame retardant property, antistatic property and aging resistance is comprehensively prepared, and can be well applied to automobile ornaments.

The invention discloses a preparation method of a B1-grade flame-retardant fire-resistant control cable, belongs to the technical field of flame-retardant fire-resistant cables, and aims to solve the technical problem that the mechanical strength and the fire-resistant and flame-retardant performance of an inorganic flame-retardant modified fire-resistant fire-resistant control cable in the prior art need to be further improved. The method comprises the following steps that a plurality of cable cores are arranged in parallel, gaps among the cable cores are filled with filling ropes to form filling layers, the cable cores filled with the filling layers are wrapped together through a wrapping tape, and a wrapping layer is formed outside the cable cores. According to the invention, maleic anhydride modified polyethylene is used as a phase solvent, and polyethylene is cross-linked and enhanced by modified graphite and modified polysiloxane, so that not only is the mechanical strength of the cable material effectively improved, but also the fire resistance and flame retardance of the cable material are improved.

The invention provides a flame-retardant heat-insulating fabric for fire-fighting clothes and a preparation process thereof, and belongs to the technical field of fire-fighting fabrics. The preparation process comprises the following steps: preparing coated modified ammonium polyphosphate; modified expanded perlite; preparing a flame-retardant outer-layer fabric; preparing a heat insulation core layer fabric; preparing an antibacterial inner layer fabric; and bonding. The flame-retardant heat-insulating fabric for the fire-fighting clothes comprises a flame-retardant outer-layer fabric, a heat-insulating core-layer fabric and an antibacterial inner-layer fabric, ammonium polyphosphate is dispersed in deionized water, polyethyleneimine is added under the acidic condition, amino on the polyethyleneimine and ammonia ions of the ammonium polyphosphate are subjected to an ion exchange reaction, and the flame-retardant heat-insulating fabric for the fire-fighting clothes is obtained. According to the flame-retardant outer-layer fabric, ammonium polyphosphate is preliminarily coated, then a hydroxyethylidene diphosphonic acid solution is added for a salt forming reaction, coated modified ammonium polyphosphate with a core-shell structure is prepared, the coated modified ammonium polyphosphate and polyester powder are mixed and granulated, then the flame-retardant outer-layer fabric is prepared, and the flame-retardant property of the flame-retardant outer-layer fabric can be effectively improved.

The invention relates to the technical field of PVC pipe production and processing, and particularly discloses a PVC pipe composition and a preparation method of a PVC pipe. PVC resin and PE resin are compounded, the problem of PVC decomposition caused by high temperature in the processing process is reduced, meanwhile, the PE resin has good flexibility, and by compounding the PVC resin and the PE resin, the PVC resin and the PE resin have good flexibility, so that the PVC pipe composition is more stable in performance. The mechanical property of the PVC pipe can be improved; 4-carboxyphenylboronic acid in the composite modified attapulgite provided by the invention forms a B-O-B cross-linked network structure at a high temperature, the 4-carboxyphenylboronic acid can have a synergistic effect with composite metal oxides (zinc oxide and manganese oxide), the thermal stability and compactness of a carbon layer are improved, and the flame retardant property of the PVC pipe is further improved; a flexible alkyl long-chain structure is formed through copolymerization of 1, 4-diol, reversible deformation occurs under the action of external force, and the mechanical property of the PVC pipe is further improved.

The invention relates to the technical field of macromolecules, and discloses a preparation method of modified polyurethane toughened epoxy resin, which comprises the following steps: by taking 4-(Boc-amino) phenylboronic acid, diethanol amine, 1, 3-bis (3-glycidyl ether oxypropyl) tetramethyldisiloxane and the like as raw materials, carrying out a series of chemical reactions to obtain a borate siloxane chain extender; the method comprises the following steps: adding a polyurethane prepolymer into the epoxy resin, participating in chain extension of polyurethane, and modifying the epoxy resin by using the polyurethane prepolymer to obtain the modified polyurethane toughened epoxy resin. A'soft segment 'and an Si-O structure in the modified polyurethane can also improve the flexibility of a curing network, effectively change the fracture mechanism of the resin, absorb a large amount of energy when the resin is fractured, and contribute to improving the toughness of the epoxy resin; on the basis of ensuring the strength of the epoxy resin, the toughness and flame retardant property of the epoxy resin are improved, and the epoxy resin can be applied to the fields of composite materials, coatings, adhesives and the like with higher toughness and flame retardant requirements, and has wide applicability.

The invention discloses a scratch repair coating and a preparation method thereof, and relates to the technical field of high polymer materials. When the scratch repair coating is prepared, hydroxylated boron nitride reacts with 1-(3-triethoxysilylpropyl)-2-imidazoline to prepare pre-modified boron nitride, and then the pre-modified boron nitride and 4-chloro-1-butene are subjected to quaternization to prepare modified boron nitride; the preparation method comprises the following steps: reacting styryl phosphonic dichloride with 4, 4, 5, 5, 6, 6, 7, 7, 7-nonafluoro-1, 2-heptanediol to prepare a hydroxyl-terminated phosphorus-fluorine-containing polymer; the preparation method comprises the following steps: reacting isophorone diisocyanate with a hydroxyl-terminated phosphorus and fluorine-containing polymer to prepare a polyurethane prepolymer; reacting the polyurethane prepolymer with hydroxyl-terminated coumarin to generate modified polyurethane; and uniformly mixing the modified polyurethane, the modified boron nitride and a photoinitiator to prepare the scratch repair coating. The scratch repairing coating prepared by the invention has good self-repairing performance, flame retardant property, corrosion resistance and mechanical property.

The present invention relates to the technical field of regenerated plastics, and in particular relates to a flame-retardant regenerated plastic and a preparation method therefor. The regenerated plastic comprises the following specific components: 90-100 parts of regenerated high-density polyethylene, 5-10 parts of high-density polyethylene, 1-2 parts of calcium stearate, 1-2 parts of carbon black, 8-12 parts of maleic-anhydride-grafted polyethylene, 2-3 parts of an antioxidant, and 6-8 parts of a polyurethane elastomer. The regenerated high-density polyethylene is used as a main material, the high-density polyethylene is added thereto, the maleic-anhydride-grafted polyethylene is used as a compatibilizer, and then polyhydroxy polybutadiene, epoxidized hydroxyl-terminated polybutadiene and polypropylene oxide glycol are compounded and react with diphenylmethane diisocyanate to generate a polyurethane elastomer, thereby toughening the regenerated polyethylene; moreover, a flame-retardant effect is achieved by means of the synergy of phosphorus and nitrogen; therefore, a regenerated polyethylene plastic with high tensile strength and good flame-retardant performance is prepared. The regenerated plastic can be widely used in a plurality of fields, and has a relatively high level of practicability.

The invention discloses a flame-retardant high-temperature-resistant fiber and a preparation method thereof, and relates to the technical field of fibers. When the flame-retardant high-temperature-resistant fiber is prepared, 1, 6-hexamethylenediamine, 1, 6-adipic acid, tetrahydrodifuran [3, 4-B: 3 ', 4'-D] furantetraone and a phosphorus-sulfur composite flame retardant are copolymerized to generate a polyamide-polyamide acid solution; 4-aminopyridine and the polyamide-polyamide acid solution are subjected to a reaction, and modified polyamide is prepared; the modified polyamide is subjected to melt spinning, and polyamide fibers are prepared; the preparation method comprises the following steps: pretreating nano titanium dioxide by using 4-bromobutyl trimethoxy silane to prepare modified nano titanium dioxide; mixing the modified nano titanium dioxide and ethanol to prepare a light-resistant antibacterial finishing agent; and carrying out post-treatment on the polyamide fiber by using an anti-light antibacterial finishing agent to prepare the flame-retardant and high-temperature-resistant fiber. The prepared fiber is excellent in comprehensive performance, particularly outstanding in flame retardance and high temperature resistance, and suitable for the fields of special protective clothing, high-temperature filtering materials and the like.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention belongs to the field of environment-friendly materials, and particularly discloses a method for preparing a high-performance exterior wall flame-retardant material from waste plastics. Through a unique formula, for example, waste polyethersulfone and the like are used as base materials, a waste basalt fiber and MOF derived carbon nanosheet composite reinforced phase, multiple novel flame retardants and the like are added, and innovative processes including pulsed electric field treatment, carbon dioxide supercritical fluid assistance and the like are combined, so that the material performance is remarkably improved. The tensile strength, the thermal stability, the flame retardant property and the like of the material are greatly enhanced, the material also has multiple functions of flexibility, self-cleaning, antibiosis and the like, and a new way is provided for high-value utilization of waste plastics and performance optimization of exterior wall materials.

The invention discloses a preparation method of an interface-modified flame-retardant polypropylene-based bamboo-plastic composite material. According to the method, a modification solution composed of a polyphenol component and a boron-containing component is adopted, bamboo powder is treated under the normal-temperature stirring condition, and the interface modified bamboo powder is successfully prepared. The mechanism is that polyphenol and a boron-containing component are subjected to a coordination reaction on the surface of bamboo powder, and a reversible borate dynamic covalent bond is constructed. The dynamic bond has a temperature response characteristic: reversible dissociation is realized during high-temperature processing, so that the melt viscosity of a composite system is reduced, and the processing fluidity is improved; the interface bonding force between the bamboo powder and the polypropylene matrix and the mechanical strength of the composite material are remarkably enhanced. In addition, the introduced boron element is used as an efficient flame-retardant component and promotes generation of a compact protective carbon layer during combustion, so that the flame-retardant property of the composite material is comprehensively improved.

The invention belongs to the technical field of flame-retardant materials, and particularly relates to a phenylboronic acid-based P / N / B-containing halogen-free flame retardant, a preparation method thereof and application of the phenylboronic acid-based P / N / B-containing halogen-free flame retardant in epoxy resin. The preparation method comprises the following steps: by taking diphenyl hypophosphorous chloride as a basis, preparing a flame-retardant intermediate through nucleophilic substitution reaction between diphenyl hypophosphorous chloride and an aldehyde group-containing phenolic compound, then reacting a phenylboronic acid structure with 3-amino-1, 2-propylene glycol to obtain an amino group-containing phenylboronic acid compound, and finally reacting the phenylboronic acid compound with 3-amino-1, 2-propylene glycol to obtain the amino group-containing phenylboronic acid compound. And finally, carrying out a Schiff base reaction on the flame-retardant intermediate and an amino-containing phenylboronic acid compound to obtain the halogen-free flame retardant containing phosphorus, nitrogen and boron elements. The flame retardant provided by the invention can significantly improve the flame retardant property and mechanical property of epoxy resin. A flame-retardant epoxy resin prepared based on the flame retardant; the influence on Tg of an epoxy resin cured product is small, the smoke suppression and char formation performance and the mechanical performance of the cured product can be remarkably improved, and meanwhile, the flame retardant has excellent flame retardant efficiency; the limit oxygen index of the flame-retardant epoxy resin can reach 31%; the vertical combustion grade is V-0 or above, and the carbon residue amount can reach 18% or above.

The invention discloses a halogen-free flame-retardant TPU (thermoplastic polyurethane) material suitable for a charging pile cable and a preparation method of the halogen-free flame-retardant TPU material, belongs to the technical field of TPU material processing, and aims to solve the technical problem that the flame retardance and wear resistance of a TPU material for a cable in the prior art need to be further improved. The material comprises the following raw material components in parts by weight: 80-100 parts of a cross-linked thermoplastic elastomer, 10-20 parts of a modified filler, 10-20 parts of a flame-retardant chain extender, 3-5 parts of a stabilizer, 3-5 parts of an antioxidant, 3-5 parts of an ultraviolet light absorber and 3-5 parts of a lubricant, after the modified thermoplastic elastomer is prepared, the modified thermoplastic elastomer is activated and cross-linked with the flame-retardant cross-linking agent, a silane structure is introduced into the structure, the flame-retardant cross-linking agent and the modified filler enhance the flame-retardant capability of the material through a synergistic effect, and meanwhile, the compatibility of the material and an inorganic material is enhanced by hybridizing a polyurethane chain segment; the wear resistance, flame retardance and other properties of the material are improved.

The invention discloses a corrosion-resistant and anti-aging plastic packaging film and a preparation method thereof, and is used for solving the technical problem that the corrosion resistance and ultraviolet aging resistance of a packaging film in the prior art need to be further improved. The polypropylene composite material comprises the following raw materials in parts by weight: 60-80 parts of modified polypropylene resin, 1-2 parts of a compound nucleating agent, 10-15 parts of a modified filler, 1-2 parts of an antioxidant, 1-2 parts of an ultraviolet light absorber, 1-2 parts of a light stabilizer and 3-5 parts of a plasticizer, the tensile property of the material is improved through crystal form remolding, and the flame retardant property of the material is improved through synergistic cooperation of an internal phosphate structure, an aluminum element and thiocyanuric acid and siloxane chain segments in the material; and the ultraviolet light absorber cross-linked by the compound nucleating agent, the modified filler and the siloxane chain segment are synergistically matched, so that the ultraviolet aging resistance of the material is remarkably improved.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention relates to the field of coatings, and discloses an outer wall light radiation heat preservation and heat insulation decorative sheet and a preparation method thereof.A radiation refrigeration layer on the surface of the outer wall light radiation heat preservation and heat insulation decorative sheet comprises modified acrylate resin, silicon dioxide, ground calcium carbonate, talcum powder, modified hollow glass beads and auxiliaries; the modified acrylate resin is prepared by copolymerizing perfluorooctyl ethyl acrylate, methyl methacrylate, modified isocyano ethyl methacrylate and vinyltriethoxysilane, and the modified isocyano ethyl methacrylate is prepared by using salicylaldehyde and benzothiazole-2-formaldehyde as well as 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator and using 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator. The preparation method comprises the following steps: reacting amino groups at two ends of 1, 5-naphthylenediamine with DOPO, carrying out nucleophilic addition reaction with DOPO, and grafting with isocyano ethyl methacrylate. The modified hollow glass beads are prepared by using tetrabutyl titanate as a titanium source through a sol-gel method, and the prepared radiation refrigeration layer has the super-amphiphobic self-cleaning effect, the radiation refrigeration effect is good, and meanwhile the flame retardant property and the antibacterial effect are excellent.

The invention discloses a high-weather-resistance halogen-free flame-retardant polyamide composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The composite material comprises the following raw materials in parts by weight: 20-60 parts of polyamide resin A, 0-20 parts of polyamide resin B, 10-50 parts of glass fibers, 0.1-2 parts of an ultraviolet absorbent, 0.1-2 parts of a free radical scavenger, 10-20 parts of a halogen-free flame retardant, 1-15 parts of a flame retardant synergist and 0.5-5 parts of a conventional auxiliary agent. The preparation method comprises the following steps: uniformly mixing the polyamide resin A, the polyamide resin B, the ultraviolet absorbent, the free radical scavenger, the flame-retardant synergist and the conventional auxiliary agent in a high-speed mixer according to the proportion to obtain a mixture, then adding the mixture into a double-screw extruder through main feeding, side feeding of the halogen-free flame retardant through a first side feeding and side feeding of the glass fiber through a second side feeding, and carrying out extrusion molding to obtain the flame-retardant polyamide composite material. And carrying out melt blending and extrusion granulation to obtain the high-weather-resistance halogen-free flame-retardant polyamide composite material. The obtained high-weather-resistance halogen-free flame-retardant glass fiber reinforced polyamide composite material is excellent in mechanical property, flame retardance and weather resistance.

The invention relates to an in-situ polymerized flame-retardant perfluorogel electrolyte, a lithium metal battery and a preparation method, the in-situ polymerized flame-retardant perfluorogel electrolyte is prepared from a fluorinated organic solvent, a lithium salt, a fluorine-containing polymer precursor and a thermal initiator, and the fluorine-containing polymer precursor further comprises a fluorine-containing polymer and a cross-linking agent. Compared with the prior art, the composite material has a high electrochemical window and excellent flame retardant property, and can realize matching with a high-voltage high-nickel positive electrode at room temperature and stable circulation of a high-voltage lithium metal battery; the preparation method is simple, the interface performance is optimized, and large-scale preparation is easy to realize.

The invention discloses a heat-aging-resistant automobile wire processing technology, belongs to the technical field of wire processing, and is used for solving the technical problem that the heat aging resistance and the mechanical property of an automobile wire need to be further improved in the prior art. According to the method, modified polyvinyl chloride is taken as a raw material, a modified elastomer and a modified inorganic filler are taken as reinforcing materials, an auxiliary additive is taken as an auxiliary agent, a modified sheath material is prepared through melt grafting, the sheath material is extruded on the surface layer of the symmetrical cable, and the automobile wire is obtained. The heat aging resistance and mechanical property of the automobile wire are improved, and the flame retardant property of the automobile wire is also improved.

The invention discloses preparation of DOPO-based hollow polymer microspheres and application of the DOPO-based hollow polymer microspheres in flame-retardant polymers, and belongs to the technical field of high polymer materials. The preparation method of the DOPO-based hollow polymer microspheres comprises the following steps: preparing a template core through self-stable precipitation polymerization, then polymerizing a DOPO-based flame-retardant monomer, an anhydride monomer and a cross-linking agent on the surface of the template core to construct a cross-linking shell layer in situ to obtain copolymer microspheres with a core-shell structure, and finally removing the template through solvent etching to obtain the DOPO-based hollow polymer microspheres. And the DOPO-based hollow polymer microspheres are prepared. The compatibility between the DOPO-based hollow polymer microspheres and a polymer matrix is greatly improved through rich anhydride groups on the surfaces of the DOPO-based hollow polymer microspheres, the flame retardant property of the polymer composite material is improved, the mechanical property of the polymer composite material is greatly improved, and due to the unique hollow structure of the polymer composite material, the flame retardant property of the polymer composite material is greatly improved. The polymer material is endowed with excellent transparency and low dielectric property.

The invention discloses an extruded and insulated flame-retardant power cable for on-line monitoring of rail transit, and relates to the technical field of power cables, serpentine springs are connected between two adjacent cavity frames and outside corresponding five conductors on the outer side, an outer plastic pipe is connected between two adjacent serpentine springs, the outer plastic pipe is filled with silicone fireproof adhesive, and the outer plastic pipe is connected with the outer side of the serpentine springs. According to the invention, through the cooperation of the cavity frame, the serpentine spring, the inner plastic pipe and the expanding and supporting strip, the outer side of the conductor is provided with a sufficient heat dissipation circulation gap, the heat dissipation speed of the cable is improved, and the inner parts of the outer plastic pipe and the inner plastic pipe are filled with silicone fireproof glue, so that the heat dissipation performance of the cable is improved. The silicone fireproof adhesive expands when meeting fire to form a compact fireproof layer which tightly wraps the outer side of the conductor, and the expanded fireproof layer can fill heat dissipation gaps among the conductors to prevent flame from spreading, so that the cable has good heat dissipation capability, and meanwhile, the flame retardant property of the cable is also ensured.

The invention discloses a multi-element low-alloying high-speed extrusion flame-retardant magnesium alloy and a preparation method thereof. The alloy comprises the following components in percentage by mass: 0.5 to 2.0 percent of Al, 0.2 to 1.0 percent of Zn, 0.1 to 1.0 percent of Mn, 0.2 to 0.8 percent of Ca, 0.2 to 1.0 percent of heavy rare earth element Y, Er or Gd and the balance of Mg and inevitable impurities. Through the synergistic effect of non-rare earth elements Al, Zn, Mn and Ca and trace heavy rare earth elements, matching of low cost, good mechanical property and flame retardant property is realized. After the alloy is subjected to optimized bipolar homogenization heat treatment, the alloy can be subjected to extrusion production at the extrusion rate of 10-30 m / min. The room-temperature ultimate tensile strength is larger than or equal to 270 MPa, the yield strength is larger than or equal to 240 MPa, the ductility is larger than or equal to 12%, and the ignition point is larger than or equal to 850 DEG C. Important support is provided for propelling the magnesium alloy extrusion material to achieve equipment lightweight and low-carbon manufacturing in the fields of rail transit, aerospace and the like.

The invention relates to the technical field of polyurethane foam, and discloses fireproof flame-retardant foaming polyurethane and a preparation method thereof.The foaming polyurethane comprises a component A and a component B. The component A comprises, by weight, 100 parts of polyether polyol, 25-50 parts of a flame-retardant chain extender and the like; and the component B is 62-86 parts by weight of an isocyanate compound. The flame-retardant chain extender contains a plurality of polymerization sites, so that the crosslinking density of a polyurethane molecular chain is improved, a stable crosslinking network is formed, and meanwhile, the flame-retardant chain extender contains a siloxane structural unit with structural stability, so that the foamed polyurethane has higher compression strength. The flame-retardant chain extender contains a phosphate flame-retardant group, and forms a phosphorus-silicon flame-retardant system with a siloxane structure, so that the combustion heat release rate peak value, the total heat release amount and the total smoke release amount of foam are reduced, and the flame-retardant chain extender has good fireproof and flame-retardant properties.

The invention provides a low-smoke halogen-free flame-retardant cable material and a preparation method thereof, and belongs to the field of cable materials. The low-smoke halogen-free flame-retardant cable material is prepared from the following chemical components: 32 to 40 parts of nitrile rubber, 22 to 27 parts of natural rubber, 8 to 12 parts of benzoxazole-siloxane copolymer containing phosphate dynamic bonds, 13 to 15 parts of core-shell-sheath three-stage structure flame retardant, 4 to 6 parts of hexaphenoxy cyclotriphosphazene modified carbon nanotubes, 2 to 3 parts of europium-doped mesoporous cerium dioxide and 3 to 4 parts of nano zinc oxide. The composite material is prepared from the following components in parts by weight: 3 to 4 parts of carbon nanotube grafted montmorillonite hybrid, 2 to 3 parts of lubricant, 0.8 to 1.2 parts of cross-linking agent, 0.3 to 0.4 part of accelerant, 0.4 to 0.6 part of dicumyl peroxide and 0.1 to 0.2 part of antioxidant. Unification of high flame retardance, low smoke, excellent mechanical property and processability of the cable material is realized.

The invention belongs to the technical field of lithium ion batteries, and provides an electrolyte additive composition, an electrolyte containing the electrolyte additive composition, and a preparation method and application of the electrolyte additive composition. The electrolyte additive composition comprises an aluminum alkoxide compound and a phosphazene compound, the structure of the phosphazene compound is shown as a formula I, and R1-R6 are independently selected from fluorine, alkoxy or phenoxy. The electrolyte containing the additive composition has good thermal stability and flame retardance under high voltage, and the safety of the battery is greatly improved; in addition, the electrolyte additive composition can inhibit hydrolysis of LiPF6, so that generation of HF and side effects caused by HF are reduced. # imgabs0 #

A full-bio-based flame-retardant material and a preparation method therefor. The composition of the full-bio-based flame-retardant material comprises a hexaldehyde bio-based phosphazene monomer, and a castor oil polyamine and / or a furyl diamine, wherein the molar ratio of the total amino groups in the castor oil polyamine and furyl diamine to the aldehyde groups in the hexaldehyde bio-based phosphazene monomer is 1 : (0.8-1.2). The full-bio-based flame-retardant material is a full-bio-based material, and the mechanical and the flame-retardant properties thereof can be adjusted and controlled by adjusting the content of the castor oil polyamine and furyl diamine to adapt to the different requirements of different products for the flame-retardant material. Moreover, the full-bio-based flame-retardant material further has self-repairing, reprocessing and degradability properties.

The invention belongs to the technical field of flame-retardant fibers, and discloses a colored flame-retardant master batch and a preparation method of colored flame-retardant fibers.The preparation method of the colored flame-retardant master batch comprises the steps that a flame retardant PDI-MA and a polyester chip powder matrix are blended, extruded and granulated, and the colored flame-retardant master batch is prepared; the preparation method of the colored flame-retardant fiber comprises the following steps: blending the prepared colored flame-retardant master batch and polyester chips, and carrying out melt spinning to obtain the colored flame-retardant polyester fiber. The pigment and the flame retardant in the flame retardant PDI-MA prepared by the invention are carriers for each other, and the advantages of MA and PTCDA are combined, so that the colored flame-retardant polyester fiber prepared from the flame retardant PDI-MA has colored and flame-retardant properties, and the overall flame retardance is improved synergistically.