14128 results about "Phenol formaldehyde resin" patented technology

Low viscosity ternary mixtures of benzoxazine, epoxy and phenolic resins have been developed. The blends render homogeneous and void free cured specimen with a wide range of properties. Melt viscosity values as low as 0.3 Pa.s at 100° C. can be achieved. The phenolic resin acts as a cure accelerator to the system, besides its typical function as a hardener of epoxy resin. Glass transition temperatures Tg as high as 170° C. can also be obtained.

A process for forming a thermoplastic vulcanizate compromising the steps of dynamically vulcanizing a rubber within a blend that comprises the rubber and a thermoplastic polymer, where said step of vulcanizing is carried out by using a phenolic resin in the presence of a catalyst system formed by combining a metal halide and a metal carboxylate. Also, a thermoplastic vulcanizate having low moisture pick-up with a technologically useful cure.

Disclosed herein are free flowing coated particles and low temperature methods of making same. Each particle has a curable coating disposed upon a substrate. The substrate is a particulate substrate including an inorganic material, a particulate substrate including an organic material, a composite substantially homogeneous formed particle including a first portion of an at least partly cured binder and filler particles, or a hybrid particle having an inorganic particle as a core and a composite coating including at least partially cured resin and filler. The curable coating includes a continuous phase including resole resin and reactive powder particles embedded or adhered to the continuous phase. The reactive powder particles typically include resole resin, novolak resin, polyester, acrylic and / or urethane. A method including applying a coating including the continuous phase including resole resin and reactive or non-reactive powder particles embedded or adhered to the continuous phase.

The invention relates to a hydrophobic granule and a preparation method thereof, and a waterproof breathable structure and a forming method thereof. The hydrophobic granule comprises aggregate and a hydrophobic resin film coated on the aggregate, wherein the aggregate size is 6-300 meshes, and the hydrophobic resin film is made of one or a plurality of hydrophobic epoxy resin, bakelite, polyurethane resin and silicone resin, and coated on the aggregate. The preparation method of the hydrophobic granule comprises the following steps: heating the aggregate to 50-400 DEG C; adding the hydrophobic resin, evenly stirring so that a film is coated on the aggregate surface; and cooling, crushing and screening to obtain the hydrophobic granules. The hydrophobic granule can be widely used as a waterproof breathable layer in desert planting, lake bottom seepage-proofing, river course seepage-proofing, landscape water system bottom seepage-proofing, and has favorable waterproof and breathable properties.

The invention relates to a method for preparing a C / SiC composite material through a low-cost fused silicon impregnation method, which comprises the following steps: performing calcining pretreatment on a carbon felt or graphite felt at 400-600 temperature; immersing the pretreated carbon felt or graphite felt in a melamine and boric acid solution, thus coating a boron nitride protective layer; immersing in a carbon / silicon carbide slurry water solution, performing impregnation to ensure that pores of the carbon felt or graphite felt are fully filled with carbon / silicon carbide, placing in a sintering furnace, and performing primary fused silicon impregnation treatment at 1600-1800 DEG C; immersing in liquid phenolic resin, and performing carbonization treatment under the protection of an inert atmosphere at 800-1000 DEG C to ensure that all the resin is carbonized; and finally, performing secondary fused silicon impregnation treatment to ensure that carbon produced by carbonization of the resin totally reacts with silicon to generate silicon carbide, thus obtaining the C / SiC composite material. The obtained C / SiC composite material is high in density, low in air pore and free silicon content, and favorable in material strength, toughness and frictional wear performance, and can be used for manufacturing of brake pads.

Disclosed herein are free flowing coated particles and low temperature methods of making same. Each particle has a curable coating disposed upon a substrate. The substrate is a particulate substrate including an inorganic material, a particulate substrate including an organic material, a composite substantially homogeneous formed particle including a first portion of an at least partly cured binder and filler particles, or a hybrid particle having an inorganic particle as a core and a composite coating including at least partially cured resin and filler. The curable coating includes a continuous phase including a curable liquid resin and reactive powder particles embedded or adhered to the continuous phase. The reactive powder particles typically include one or more of a resole phenolic-formaldehyde resin, a novolak phenolic-formaldehyde resin, a polyester resin, an acrylic polymer resin, a urethane resin or an epoxy resin. A method including applying a coating including the continuous phase including the curable resin and reactive or non-reactive powder particles embedded or adhered to the continuous phase.

The invention discloses a preparation method for a fiber reinforced carbon-silicon carbide-zirconium carbide-based (C / C-SiC-ZrC) composite material. The preparation method comprises the following steps of: (a) evenly dispersing ZrC nanopowder in absolute ethyl alcohol; (b) mixing phenolic resin and ZrC dispersion liquid to form slurry; (c) immersing a two-dimensional carbon fiber sheet into the slurry for dipping and drying, then carrying out continuous superposition paving on the two-dimensional carbon fiber sheet, and carrying out curing and post-curing treatment to prepare a fiber-reinforced sintered body; (d) cracking the fiber-reinforced sintered body to obtain a porous C / C prefabricate; (e) placing silicon powder into a graphite crucible, burying the porous C / C prefabricate into the silicon powder, heating to 1,500-1,650 DEG C, and preserving heat for preset time so as to carry out liquid silicon permeation. The method can be used for improving the high-temperature oxidizing property and ablation property of the carbon fiber reinforced ceramic (C / C-SiC) composite material.

The invention discloses a kind of laminated granule for oil extraction, proppant having the laminated granule and oil extraction method using the proppant. The laminated granule comprises aggregate granules and oil permeating waterproof thin film coated on surface of the aggregate granules. The oil permeating waterproof thin film comprises resin. Weight ratio of the resin to quartz sand is 0.2-15:100. The laminated granule is oil permeating waterproof granule. The oil permeating waterproof thin film is one formed by one or more of oleophylic hydrophobic ethoxyline resin, phenolic resin, polyurethane resin and silicon resin. The laminated quartz sand and proppant thereof are oil permeating and water proof at regular atmospheric pressure. Oil permeation resistance in pressurized condition is less than water permeation resistance. Therefore, in oil extraction industry, water yield is reduced effectively and oil yield is improved.

Disclosed herein are free flowing coated particles and low temperature methods of making same. Each particle has a curable coating disposed upon a substrate. The substrate is a particulate substrate including an inorganic material, a particulate substrate including an organic material, a composite substantially homogeneous formed particle including a first portion of an at least partly cured binder and filler particles, or a hybrid particle having an inorganic particle as a core and a composite coating including at least partially cured resin and filler. The curable coating includes a continuous phase including resole resin and reactive powder particles embedded or adhered to the continuous phase. The reactive powder particles typically include resole resin, novolak resin, polyester, acrylic and / or urethane. A method including applying a coating including the continuous phase including resole resin and reactive or non-reactive powder particles embedded or adhered to the continuous phase.

Cleaning and multifunctional coating compositions containing hydrogen peroxide and an organosilane quaternary compound in aqueous formulations are used to improve water and soil repellency and residual antimicrobial activity. Various surfaces may be treated including metal, glass, plastics, rubber, porcelain, ceramic, marble, granite, cement, tile, sand, silica, enameled appliances, polyurethane, polyester, polyacrylic, melamine / phenolic resins, polycarbonate, siliceous, painted surfaces, wood, and the like.

A moisture-curable adhesive composition that may be formulated to be free of volatile organic compounds, or substantially free of volatile organic compounds which is safe for chronic exposure, resistant to combustion, and provides a high peel strength useful for securing a rubber membrane material to a rigid roof deck includes a polymer having silicon-containing hydrolyzable terminal groups, a phenolic resin, and a non-polymeric silicon-containing hydrolyzable compound, wherein the ratio of the amount of polymer having silicon-containing hydrolyzable terminal groups by weight to the amount of phenolic resin by weight is greater than 2:1.

A phenolic resin composition which is stable against an environmental moisture change and, further, excellent in fast curing property, flexibility and heat resistance. The phenolic resin composition contains 70-97% by weight of a phenolic resin and 3-30% by weight of a silicone-based rubber component and has a ratio of an ortho-bonding to a para-bonding at a methylene bonding in the phenolic resin of 2-9.

The invention discloses a specific nanometer paint of energy-saving environment-protective typed aluminium alloy section bar (door and window), which comprises the following parts: 90-100% filming agent, 0.1-10% hardener, 0.5-8% levelling agent, 0.5-10% nanometer material, 20-50% fill and 10% hollow microball, wherein the filming agent is one or more of epoxy resin, polyester resin, acrylic acid resin, amino resin, phenol resin or alkide resin; the hardener is one or more of dicyandiamide, imidazole, dihydrazide, polybasic carboxylic acid, beta-hydroxyalkyl amide or triglycidol isocyanuric ester hardener; the levelling agent is one or more of polyacrylic resin, siliceous acryl resin, polyvinyl butyral, benzoin, hydrocastor oil, cellulose acetate butyrate or epoxy soy oil; the nanometer material is nanometer zinc oxide; the hollow micro-ball is hollow ceramic microball.

The present invention provides a dicing / die bonding sheet which can be used as a dicing tape during dicing, enables ready separation of the semiconductor element and the adhesive layer from the pressure-sensitive adhesive layer during pickup, and in which the adhesive layer has satisfactory adhesiveness as a die bonding material. A dicing / die bonding sheet in which the pressure-sensitive adhesive layer comprises a compound (A), containing intramolecular, radiation curable carbon-carbon double bonds with an iodine value of 0.5 to 20, and at least one compound (B) selected from a group consisting of polyisocyanates, melamine-formaldehyde resins, and epoxy resins, and the adhesive layer comprises an epoxy resin (a), a phenolic resin (b) with a hydroxyl equivalent of at least 150 g / eq., an epoxy group-containing acrylic copolymer (c), comprising from 0.5 to 6% by weight of glycidyl acrylate or glycidyl methacrylate, and with a weight average molecular weight of at least 100,000, a filler (d), and a curing accelerator (e).

The invention relates to a lithium ion battery composite cathode material and a preparation method. The cathode material comprises a hard carbon precursor material containing hetero atoms, and natural spherical graphite, wherein the hard carbon precursor material selects one or more than two of phenolic resin, polyfurfural, furan resin, polyvinyl alcohol, epoxide resin or polyacrylonitrile as raw materials, and accounts for 5 to 45 percent of the natural spherical graphite by mass; modifier of the hetero atoms is boron-containing modifier including boric acid and diboron trioxide, phosphor-containing modifier including phosphoric acid and phosphorus pentoxide, and nitrogen-containing modifier HNO3; and one of the modifiers accounts for 5 to 35 percent of the hard carbon precursor by mass. An analog battery formed by the cathode material which is prepared by the method has the capacity over 350 mAH / g and first coulomb efficiency up to 95.8 percent, and has good circulation performance. The preparation method has the advantages of low cost and simple process.

A high-solids anticorrosive coating composition which comprises a main ingredient (A) comprising an epoxy resin (a1) and a hardener ingredient (B) comprising an alicyclic amine hardener (b1) and / or a Mannich type hardener (b2), the ingredient (A) and / or the ingredient (B) containing at least either of an additive (a2) selected among epoxidized reactive diluents and modified epoxy resins and a coating film modifier (ab) selected among petroleum resins, xylene resins, coumarone resins, terpene phenol resins and vinyl chloride copolymers. The high-solids anticorrosive coating composition especially of the rapidly curable type is characterized by containing a high-boiling organic solvent having a boiling point exceeding 150° C. and containing substantially no organic solvent having a boiling point of 150° C. or lower.

A method and drilling fluid additive composition are provided for reducing lost circulation and seepage loss when synthetic or oil based drilling fluid is used. The method includes injecting drilling fluid and 1 to 50 pounds per barrel of a loss control additive having a composition comprising 20 to 80 parts by weight fibrous particles, 10 to 40 parts by weight lignite, and 10 to 40 parts by weight phenol-formaldehyde resin.

A process for the manufacturing of a core forming a carrying structure for decorative laminates. The core comprises particles of cured, and optionally foamed, rigid, polyurethane, polyisocyanurate and / or phenolic resin. The particles are bonded to each other in a pressing procedure with a bonding agent comprising an adhesive such as a polymerizing monomer.i) The particles are achieved by grinding cured, and optionally foamed, rigid, polyurethane, polyisocyanurate and / or phenolic resin so that it passes through a 2 mm screen, preferably a 1 mm screen,ii) 100 parts per weight of particles is mixed with 1-100 parts per weight of fiber, the fiber additive having an average length in the range 1-15 mm.iii) The particle-fiber mixture is allowed to absorb a selected amount of water, the amount of water being in the range 1-15% by weight, The water is either added at any stage before the adding of bonding agent, and / or being used as a solvent in the bonding agent, and that,iv) 85 parts per weight of the particle mixture is mixed with 2-15 parts per weight of a bonding agent, the bonding agent selected from the group consisting of,a) A mixture of polyols, such as polyester or polyether, crude methylene diphenyl diisocyanate and possibly a small amount of blowing agent in a ratio forming a polymeric resin with a density in the range 600-1400 kg / m3.b) A formaldehyde based resin such as phenol-formaldehyde resin, urea-formaldehyde resin, melamine-urea-formaldehyde resin, melamine-urea-phenol-formaldehyde resin or phenol-resorcinol-formaldehyde resin, orc) Polyvinyl acetate resin.v)The mixture is applied between the belts of the continuos belt press or the press plates of a static press, optionally with at least one intermediate carrier web, the belts or press plates allowing a mainly uniform and specified material thickness to form. A slightly porous and preconditioned core with a selected water content in the range 0.8-12% is hereby achieved. The invention also relates to a decorative laminate achieved through the process.

A process is provided for producing fast curing bonded with phenolic resin, which comprises pulverulent phenolic resins mixed with or applied to the substrate to be adhered together with pulverulent addition polymers selected from the group consisting of polyvinyl alcohols and addition polymers, stabilized by hydroxyl-containing protective colloids of at least one monomer selected from the group consisting of the vinyl esters of branched or unbranched carboxylic acids of 1 to 12 carbon atoms, the esters of acrylic acid and methacrylic acid with branched or unbranched alcohols of 1 to 12 carbon atoms, vinylaromatics, vinyl halides, olefins and dienes, and subsequently, by the employment of elevated temperature and optionally elevated pressure, cured and processed into a shaped article.

Digestion of cellulosic biomass solids may be complicated by release of lignin therefrom. Methods for digesting cellulosic biomass solids may comprise: providing cellulosic biomass solids in the presence of a digestion solvent, molecular hydrogen, and a slurry catalyst capable of activating molecular hydrogen; at least partially converting the cellulosic biomass solids into a phenolics liquid phase comprising lignin, an aqueous phase comprising a glycol derived from the cellulosic biomass solids, and an optional light organics phase; wherein at least a portion of the slurry catalyst accumulates in the phenolics liquid phase as it forms; combining the glycol with the phenolics liquid phase, thereby forming a combined phase; and heating the combined phase in the presence of molecular hydrogen; wherein heating the combined phase reduces the viscosity of the phenolics liquid phase and transforms at least a portion of the glycol into a monohydric alcohol.

A method is provided for carbonizing and activating carbonaceous material, which comprises supplying the material to an externally fired rotary kiln maintained at carbonizing and activating temperatures, the kiln having a downward slope to progress the material as it rotates, the kiln having an atmosphere substantially free of oxygen provided by a counter-current of steam or carbon dioxide, and annular weirs being provided at intervals along the kiln to control progress of the material. There may further be provided an externally fired rotary kiln for carbonizing and activating carbonaceous material having a hollow rotary body that has a downward slope towards a discharge end thereof, and which is provided at intervals along its length with annular weirs for controlling progress of the carbonaceous material. In embodiments, there is also provided a process is for producing discrete solid beads of polymeric material e.g. phenolic resin beads having a mesoporous structure, which may be useful as feedstock for the above mentioned carbonization / activation process or which may have other utility e.g. as ion exchange resins. The process may produce resin beads on an industrial scale without aggregates of resin building up speedily and interrupting production. The process comprises the steps of: (a) combining a stream of a polymerizable liquid precursor e.g. a novolac and hexamine as cross-linking agent dissolved in a first polar organic liquid e.g. ethylene glycol with a stream of a liquid suspension medium which is a second non-polar organic liquid with which the liquid precursor is substantially or completely immiscible e.g. transformer oil containing a drying oil; (b) mixing the combined stream to disperse the polymerizable liquid precursor as droplets in the suspension medium e.g. using an in-line static mixer; (c) allowing the droplets to polymerise in a laminar flow of the suspension medium so as to form discrete solid beads that cannot agglomerate; and (d) recovering the beads from the suspension medium. There is also provided apparatus for forming discrete solid beads of polymeric material, said apparatus comprising: a first line for conveying s stream of a polymerizable liquid precursor; a second line for conveying a stream of a dispersion medium with which the polymerizable liquid precursor is substantially or completely immiscible; an in-line mixer configured to receive a combined flow from the first and second lines and to disperse the polymerizable liquid precursor as droplets in the dispersion medium; a vertical polymerization column configured to receive the dispersion medium with the droplets dispersed therein and to permit the polymerizable liquid precursor polymerize while descending the column in a descending flow of polymerization medium; and a vessel at the base of the column for receiving the descending flow of dispersion medium and collecting polymerized solid beads.

A solvent-containing coating composition contains at least one hydroxyl-containing saturated copolyester, a phenol-formaldehyde resin, a benzoguanamine-formaldehyde resin and / or a blocked polyisocyanate, a catalyst and at least one solvent, and can further contain aids and additives.

The invention relates to a high-molecular composite material having performances of high heat conduction and high flame retardation, the invention is characterized in that the composite material does not contain any halogen or a non environmentally-friendly heavy metal fire retardant, the flame resistance is capable of reaching a UL94 V0 standard, simultaneously, the composite material has good heat conducting performance, the heat conduction coefficient is more than 0.5 W / m. DEG C. The composite material provided in the invention has good injection moulding performance, extruding performance and hot pressing performance. The composite material comprises the following basic components: 1) one or a plurality of metal hydroxides, such as aluminum hydroxide, magnesium hydroxide, zinc hydroxide and the like, wherein the weight content is 10-70%, 2) about 0.2%-60% of the weight content of expandable graphite flaky powder, the lamina size is more than 10 um, and the expandable coefficient is more than or equal to 20 times; 3) 15%-70% of the weight content of matrix resins, such as epoxy resin, organic silicone resin, phenolic resin, thermosetting polyester resin and thermoplastic resins of nylon 6, nylon 66, PBT, PP, HDP and the like. The composite material component of the invention can be directly used for radiators such as LED, electric appliances and electronic components, the heat can be radiated into colder environment so that the operating temperature of the electronic device can be reduced.

A novel environmental protective urea-formaldehyde resin and a preparation method belong to the field of wood processing adhesives. The urea-formaldehyde resin is formed by the reaction of urea, formaldehyde, aldehyde, one or more stabilizers and modifier according to the route of weak base-weak acid-weak base. The method firstly controls the F / U feed ratio, the pH value and the temperature during the reaction process to reduce the content of free formaldehyde in the resin; then the aldehyde is introduced to allow the resin to generate the stable alkyl ether (-(CH2)n-O-(CH2)n-) structure, thus reducing the content of methylene-ether bond (-CH2-O-CH2-) in the resin structure, simultaneously reducing the using amount of the formaldehyde and further greatly reducing the release amount of the formaldehyde during the using process of a plate from the two aspects; in addition, the introduction of a long chain and polyaldehyde can ensure the resin to have great bonding strength and water resistance. The urea-formaldehyde resin which is prepared by the invention has the advantages of low content of free formaldehyde, simple process, low cost, etc., the release amount of the formaldehyde of the plate which is prepared by using the adhesive achieves the E0 level standard, and the high bonding strength can be maintained after being boiled in hot water.

A composite material of sandwich structure integrating loading, heat insulation and ablation and the manufacturing method are characterized in that an integrated pre-forming body is acquired by puncture and suture of the reinforcing material of a bearing layer, the reinforcing material of an ablating cover, and a heating insulation layer positioned between the two layers; an epoxy resin system and a phenolic resin system are injected simultaneously into a vacuum-pumped mould, in which the integrated forming body is pre-placed, by two sets of RTM injection systems respectively, then, the reinforcing materials of the bearing layer and the ablating layer are soaked by epoxy resin and phenolic resin respectively; and the composite material of sandwich structure integrating loading, heat insulation and ablation can be obtained by solidified molding after mould filling. The invention has the advantages that the composite material of sandwich structure integrating loading, heat insulation and ablation is put forward and can be integrally formed by one-time operation, the function of the interlayer between every layer of the composite material is enhanced greatly, the integrality is good; the stratifying and peeling of the composite can be reduced effectively, and the products have good designable property and can be widely applied to the structural parts of aerospace which need heating insulation and thermal protection.

The present invention belongs to the field of porous ceramic material technology, and is the preparation process of one low cost and high performance porous silicon nitride / silicon carbide ceramic. The preparation process includes compounding material, forming and sintering as the conventional ceramic material preparing steps. It features that phenolic resin used as pore creating agent and carbon source is in-situ produced into SiC phase through the carbon hot reduction during sintering; and that Si3N4, Al2O3, Y2O3 and phenolic resin in certain proportion are produced into slurry through adding anhydrous alcohol and mixing for 12-24 hr and stoved into powder; and that the ceramic powder is processed through formation, cracking to eliminate glue, carbon hot reduction and sintering to produce the porous ceramic material with porosity of 40-70 %, strength of 70-160 MPa and low cost.

The invention provides a phenolic resin / phosphate hybrid adhesive and a preparation method thereof, relating to an adhesive and a preparation method thereof. The invention solves the problems of low working temperature, rigorous curing process and low adhesion strength of the conventional high-temperature resisting phenolic resin adhesive. The adhesive is prepared from phenolic resin, heat-resistant reinforced resin, a coupling agent, a toughening agent, phosphate, a curing agent, a framework material, fillers and a dispersing agent. The preparation method comprises the following steps of: mixing the phenolic resin, the heat-resistant reinforced resin, the coupling agent and the toughening agent and then evenly stirring to obtain a phenolic resin component; then mixing the phosphate, the curing agent, the framework material and the fillers and then evenly stirring to obtain a phosphate component; and then adding the phosphate component and the dispersing agent into the phenolic resin component and evenly stirring. The adhesive can be applied in aerospace, military and machining industries with the working temperature above 800 DEG C.

An electrically conductive adhesive composition which has flexibility and folding endurance and is feasible for use as a shield against electromagnetic waves from a flexible printed circuit, comprises 100 parts by weight of (a) an acrylonitrile-butadiene copolymer, 20 to 500 parts by weight of (b) a phenolic resin and / or an epoxy resin, 1 to 100 parts by weight, per 100 parts by weight of the components (a) and (b) in total, of (c) an electrically conductive filler and 1 to 50 parts by weight, per 100 parts by weight of the components (a) and (b) in total, of (d) a bromine-containing flame retardant.

Disclosed is an abrasive tool made of epoxy resin-bonded compound abrasive material, which comprises epoxy resin, abrasive material and curing agent. The weight percentages are as follow: the epoxy resin is 15 to 78 percent, the abrasive material is 2 to 44 percent and the curing agent is 4 to 18 percent. Wherein, the abrasive material comprises one of diamond, silicon carbide or corundum or the combination of more than one material. The curing agent comprises one of 4.4`-methylenedianil, solid diaminodiphenyl methane or liquid modified diaminodiphenyl methane or the combination of more than one material. The component of the abrasive tool also comprises the other auxiliary material, which comprises one of alumina, barium chloride, sodium chloride, quartz sand, organobentonite, wetting agent, zirconium silicate, calcium carbonate, graphite powder, garnet, magnesium sulfate, phenolic resin, zinc stearate and magnesium stearate, or the combination of more than one material. The product can be made into any shape the same with the present product, which can be applied in various grinding and polishing equipment with wide application scope.

The invention belongs to the field of chemical engineering and industry, and particularly relates to a mesoporous-macroporous carbon production method. The production method comprises: completely mixing a phenol formaldehyde resin, an epoxy resin and the like or a mixture thereof, and a curing agent according to a certain weight ratio, carrying out heating curing, adding polyvinyl alcohol and the like as pore forming agents and adding graphite powder and the like as support agents after the cured material is crushed, completely mixing, pressing to form a preform, and carrying out high temperature carbonization under the protection of gas to obtain the mesoporous-macroporous carbon. The mesoporous-macroporous carbon prepared by using the production method has advantages of simple preparation method, easy pore size control and the like, wherein the pore size of the mesoporous-macroporous carbon can be adjusted within 50 nm-10 mum, has a specific surface area of 100-1000 m<2> / g, and can be used in electrode materials of supercapacitors, electrode materials of lithium ion batteries, electrode materials of capacitance method desalination devices, blood purification, catalyst carriers, water treatments, gas purification, solvent recovery and the like.