2824 results about "Resorcinol" patented technology

The present invention relates to the use of certain resorcinol derivatives as skin lightening agents.

A process for preparing 2-(2,4-dihydroxyphenyl)-4.6-diaryl-s-triazines in three steps starting with cyanuric chloride is described. Step 1 involves the nucleophilic (basic) displacement of one chlorine atom with a phenolic moiety. Step 2 involves a Friedel-Crafts reaction using a Lewis acid catalyst (preferably aluminum chloride) to replace the remaining two chlorine atoms with aryl groups such as xylyl. Finally, step 3 involves replacing the phenolic moiety with resorcinol using either a Lewis acid or protic acid catalyst or combinations thereof. Some additional processes only peripherally related to the three-step process outlined above are also described for the preparation of various s-triazine compounds. The s-triazines prepared are useful as UV absorbers for the stabilization of organic substrates against the adverse effects of actinic light.

Skin lightening / even toning compositions are provided for reducing skin pigmentation of normal skin and for lightening hyper-pigmented skin said compositions comprising (i) highly purified hexylresorcinol which is substantially free or resorcinol, (ii) optionally, at least one other skin lightening agent, and (iii) a dermatologically acceptable carrier.

The invention is a fibrin glue that avoids the use of fibrinogen and thus eliminates the need for premixing and premature clot formation. The fibrin glue of the invention comprises thrombin, thromboplastin and calcium and may have clotting Factors, VII, IX and X, and the like. The invention also comprises a biosealant for use with the fibrin glue without fibrinogen or for use alone. The biosealant is a two component mixture of gelatin / resorcinol and glyoxal / glutaraldehyde / 4-(p-maleimidophenyl) butyric acid. The two components are mixed on use.

Methods for preparing formaldehyde-free resorcinol resins are disclosed. The methods generally comprise reacting resorcinol first with dicyclopentadiene and then reacting that mixture with an olefinic compound. The resins produced by this method are also disclosed, as are rubber compositions utilizing the present resins. The resins are characterized as having a free resorcinol content of about 1 wt. % or less, and yielding a suitable softening point when used in rubber applications.

An orthogonal process for photolithographic patterning organic structures is disclosed. The disclosed process utilizes fluorinated solvents or supercritical CO2 as the solvent so that the performance of the organic conductors and semiconductors would not be adversely affected by other aggressive solvent. One disclosed method may also utilize a fluorinated photoresist together with the HFE solvent, but other fluorinated solvents can be used. In one embodiment, the fluorinated photoresist is a resorcinarene, but various fluorinated polymer photoresists and fluorinated molecular glass photoresists can be used as well. For example, a copolymer perfluorodecyl methacrylate (FDMA) and 2-nitrobenzyl methacrylate (NBMA) is a suitable orthogonal fluorinated photoresist for use with fluorinated solvents and supercritical carbon dioxide in a photolithography process. The combination of the fluorinated photoresist and the fluorinated solvent provides a robust, orthogonal process that is yet to be achieved by methods or devices known in the art.

The invention relates generally to pyrimidines and triazines ultraviolet light absorbers containing a phenolic aromatic group(s) and a non-phenolic aromatic group(s) and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants, and combinations thereof. The new class of pyrimidines and triazines includes two (one) non-phenolic aromatic groups with hydrocarbyl groups that are ortho to each other and one (two) resorcinol or substituted resorcinol group attached to a triazine or pyrimidine ring. The pyrimidines and triazines may be included in a polymeric structure. A method for stabilizing a material by incorporating the novel pyrimidines and triazines is also disclosed.

Methods of making low molecular weight methylene acceptors are provided. The methylene acceptors are prepared by reacting a polyhydric phenol with an aromatic olefinic compound in the presence of an acid catalyst, and then further reacting the products of the first reaction with an N-methylol lactam derivative. Derivatives made by the above method, as well as rubber compositions using these derivatives are also provided.

Cosmetic compositions containing a micronized metal oxide along with a 4-substituted resorcinol derivatives of the general formula I exhibit improved storage stability: where each R1 and R2, independently, represents a hydrogen atom, —CO—R (acyl group), —COO—R, CONHR; where R represents saturated or unsaturated, linear, branched or cyclic C1-C18 hydrocarbon groups; andR3 represents (1) an alkyl group, having from 1 to 18 carbon atoms, preferably having from 2 to 12 carbon atoms, with or without substitution of one or more hydrogen atoms of a linear alkyl group with a methyl or ethyl group; e.g., R3 constitutes linear or branched chain alkyls, or (2) a group of the general formula formula (II) Where X is preferably H, n is 0 to 3 and the dashed lines represents an optional double bond.

Provided herein are methods and compositions comprising resorcinol derivatives for the use of treating, regulating or preventing a skin condition characterized by oxidative stress or a degenerative process. Methods of preventing, lightening or reducing the appearance of visible discontinuities of the skin resulting from skin pigmentation, skin aging, or other disorders are also disclosed.

A method for the preparation of high strength air-dried organic aerogels. The method involves the sol-gel polymerization of organic gel precursors, such as resorcinol with formaldehyde (RF) in aqueous solvents with R / C ratios greater than about 1000 and R / F ratios less than about 1:2.1. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogeis, this approach generates wet gels that can be air dried at ambient temperatures and pressures. The method significantly reduces the time and / or energy required to produce a dried aerogel compared to conventional methods using either supercritical solvent extraction. The air dried gel exhibits typically less than 5% shrinkage.

Blends of polyimides, polyetherimides or polyetherimide sulfones with resorcinol based polyesters, or resorcinol based polyester carbonate polymers, and silicone copolymers, have improved flame resistance. Peak heat release energy is reduced and the time to reach peak heat release is increased. In some instances the flame retardant blends show high percent transmission with low haze. Addition of metal oxides may further improve flame resistance.

The present invention is directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, a free radical initiator, and a catechol. The present invention is also directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, a free radical initiator, and a resorcinol. Rubber compositions of the present invention may be present in any one or more of a core layer, a cover layer, or an intermediate layer.

The invention relates to an environment-friendly fiber framework material dip solution and a dipping process. The dip solution comprises, by weight parts, 3.3-190 parts of blocked isocyanate compound by dry weight, 6.6-140 parts of epoxy compound by dry weight, 80-100 parts of rubber latex by dry weight, 0.5-20 parts of rubber modifier by dry weight, and the balance water. The content of the dip solution is 5-25%, and a one-bath or double-bath dipping process is adopted to perform coating on a fiber framework material. The dip solution does not contain harmful substances such as resorcinol and formaldehyde and does not cause pollution to the environment, the dipping process is simple in steps and easy to operate, an organic fiber after dipping treatment is low in rigidity and facilitates postprocessing, and the dip solution has a good effect of being bonded to rubber and has a better dipping effect than conventional RFL.

The invention relates to a gel plugging agent for deep profile control of a higher temperature oil reservoir, and a preparation method of the gel plugging agent. The gel plugging agent comprises 0.3-0.8 percent of nonionic polyacrylamide, 0.6-1.3 percent of a cross-linking agent A, 0.45-1.44 percent of a cross-linking agent B, 0.02-0.04 percent of a temperature stabilizer and 0.01-0.08 percent of a pH value regulator, wherein the cross-linking agent A is methenamine; the cross-ling agent B is hydroquinone or resorcinol; the temperature stabilizer is sodium thiosulfate, sodium bisulfite or sodium sulfite; and the pH regulator is sodium hydroxide, potassium hydroxide, sodium carbonate or sodium bicarbonate. The gel plugging agent disclosed by the invention has strong temperature resisting performance and can be used for the profile control operation of the high temperature oil reservoir with 100-160DEG C; the gel plugging agent has the characteristics of high strength after being gelatinized, stronger plugging capability for the stratum and favorable thermal stability; and in addition, after the gel plugging agent is stood at the temperature of 130 DEG C for 90 days, the strength change is little and gel breaking and hydration are avoided.

Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.

Cosmetic compositions containing organic sunscreens along with a 4-substituted resorcinol derivatives of general formula I exhibit improved storage stability and oxidative stability: where each R1 and R2, independently, represents a hydrogen atom, —CO—R (acyl group), —COO—R CONHR; where R represents saturated or unsaturated, linear, branched or cyclic C1-C18 hydrocarbon groups; andR3 represents (1) an alkyl group, having from 1 to 18 carbon atoms, preferably having from 2 to 12 carbon atoms, with or without substitution of one or more hydrogen atoms of a linear alkyl group with a methyl or ethyl group; e.g., R3 constitutes linear or branched chain alkyls, or (2) a group of the general formula formula (II) Where X is preferably H, n is 0 to 3 and the dashed lines represents an optional double bond.

This invention provides a preparation method for a high ratio surface area carbon gel, which takes resorcin and formaldehyde as the raw materials, sodium carbonate as the catalyst to prepare carbon gel by sol-gel reaction and ordinary pressure and high temperature carbonization and takes CO2 as the activating agent to carry out gas activation process to get the high ratio surface area carbon gel, which avoids the traditional complicated technology of exceeding critical dryness and makes up the shortcomings of low ratio surface area brought with the normal pressure dryness.

The present invention provides a rubber composition with superior properties with respect to processability, low fuel consumption, complex modulus, and durability, and tires prepared by using the rubber composition. The rubber composition of the present invention comprises: 2 to 2.9 parts by weight of (B) sulfur, 0.6 to 10 parts by weight of (C) at least one compound selected from the group consisting of a cresol resin, a resorcin condensate, and a modified resorcin condensate, and 10 to 55 parts by weight of (D) a carbon black and / or silica, based on 100 parts by weight of (A) a rubber component comprising a natural rubber and / or isoprene rubber and at least two kinds of synthetic rubbers selected from the group consisting of butadiene rubber, modified butadiene rubber, styrene-butadiene rubber, and modified styrene-butadiene rubber. The tire of the present invention is prepared by using the rubber composition.

Disclosed is a herbicidal mixture comprising (a) at least one herbicide compound selected from the pyrimidines of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof:whereinR1 is cyclopropyl, 4-Br-phenyl or 4-Cl-phenyl;X is Cl or Br;R2 is H, C1-C14 alkyl, C2-C14 alkoxyalkyl, C3-C14 alkoxyalkoxyalkyl, C2-C14 hydroxyalkyl or benzyl; and(b) at least one additional herbicide or herbicide safener compound selected from the group consisting of (b1) ACCase inhibitors, (b2) AHAS inhibitors, (b3) photosystem II inhibitors, (b4) photosystem I electron diverters, (b5) PPO inhibitors, (b6) EPSP synthase inhibitors, (b7) GS inhibitors, (b8) VLCFA inhibitors, (b9) auxin mimics, (b10) auxin transport inhibitors, (b11) other herbicides selected from the group consisting of flamprop-M-methyl, flamprop-M-isopropyl, difenzoquat, DSMA, MSMA, bromobutide, flurenol, cinmethylin, cumyluron, dazomet, dymron, methyldymron, etobenzanid, fosamine-ammonium, isoxaflutole, asulam, clomazone, mesotrione, metam, oxaziclomefone, oleic acid, pelargonic acid and pyributicarb, (b12) herbicide safeners selected from the group consisting of benoxacor, 1-bromo-4-[(chloromethyl)sulfonyl]benzene, cloquintocet-mexyl, cyometrinil, dichlormid, 2-(dichloromethyl)-2-methyl-1,3-dioxolane, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen-ethyl, mefenpyr-diethyl, methoxyphenone, naphthalic anhydride and oxabetrinil, and their salts. Also disclosed is a method for controlling the growth of undesired vegetation comprising contacting the vegetation or its environment with a herbicidally effective amount of a mixture of the invention (e.g., as a composition described herein).

A thermoplastic composition comprises a polyester-polycarbonate polymer comprising isophthalate-terephthalate-resorcinol ester units and carbonate units, and a poly(alkylene ester) comprising ethylene terephthalate units, 1,4-cyclohexyldimethylene terephthalate units, or a combination of ethylene terephthalate units and 1,4-cyclohexyldimethylene terephthalate units, wherein the sum of the mole percentage values of isophthalate-terephthalate-resorcinol ester units in the polyester-polycarbonate polymer, and of the mole percentage values of 1,4-cyclohexanedimethylene terephthalate units in the poly(alkylene ester) polymer, is a value greater than 40. In other embodiments, polycarbonate may be included. Also disclosed is a method for forming the thermoplastic compositions, and articles prepared therefrom.

The invention relates to a preparation method of a nitrogen and phosphor co-doped porous carbon nanotube. The method includes the following steps: 1) preparing a carboxylation carbon nanotube; 2) preparing a melamine-phenolic resin wrapped carbon nanotube by taking melamine-resorcinol-presence of formaldehyde resin as a precursor; and 3) conducting phosphatization: mixing the melamine-phenolic resin wrapped carbon nanotube obtained from the step 2) with a phosphatization agent, dispersing the mixture in deionized water in an ultrasonic manner, drying the mixture, enabling a dried product to rise to 600-900 DEG C in an inert atmosphere and to be phosphatized for 120-180min, naturally cooling the product to a room temperature, washing obtained black powder with water, performing pumping filtration until the powder is neutral, drying and finally obtaining the nanotube. The prepared nitrogen and phosphor co-doped porous carbon nanotube enables the specific capacitance of a capacitor to be substantially increased.

Blends of siloxane copolymers, notably siloxane polyimides, with polyaryl esters or polyaryl ester carbonates containing linkages derived from resorcinol, show improved flame resistance, as measured by two minute and peak heat release, compared to conventional polycarbonates. In some instances transparent flame retardant blends can also be prepared. The compositions show good melt processability, high impact strength and high elongation, and can be used to make various flame retardant articles including sheets and films.

Halogen-free TPU compositions comprise in weight percent based on the weight of the composition: A. 1 to 99% thermoplastic polyurethane (TPU), B. 1 to 50% tris(2-butoxyethyl)phosphate (TBEP), C. 1 to 70% metal hydrate, and D. 1 to 70% organic phosphate ester other than tris(2-butoxyethyl)phosphate. These compositions exhibit better smoke suppression as compared with conventional organic phosphate flame retardant TPU compositions such as those based on resorcinol bis(diphenyl phosphate) (RDP) and bisphenol-A bis(diphenyl phosphate) (BPADP) in the absence of TBEP.

The invention is a cosmetic or dermatological preparation effective as light-protective, comprising (a) at least one bis-resorcinyltriazine derivative and (b) at least one benzoxazole derivative. The invention is also a cosmetic or dermatological preparation comprising at least one bis-resorcinyltriazine derivative and at least one benzoxazole derivative of a specified chemical structure. The invention is also a method of treating or preventing cosmetic or dermatological changes in the skin, a method of tanning or accelerating tanning of the skin, and a method of protecting the skin against light-induced aging, each comprising applying the preparation to the skin. The invention also includes a wipe impregnated with the preparation.

The invention discloses temperature-resisting salt-tolerant high-temperature self-cross-linking onsite polymerization water plugging gel which mainly consists of, by mass, main agent 4%-6%, cross-linking agent 1%-2% and the balance saline water. The main agent consists of a monomer A and a monomer B, wherein the monomer A is acrylamide, and the monomer B is ester matter. The cross-linking agent is one of or a mixture of two or more formaldehyde, phenolic resin, resorcinol, hexamethylene tetramine, paraformaldehyde and polyethyleneimine. The temperature-resisting salt-tolerant high-temperature self-cross-linking onsite polymerization water plugging gel spontaneously produces cross-linking polymerization under the condition of high temperature, an initiator is not added, the gelling time can be controlled to be 2 hours to 28 hours at the temperature of 120 DEG C, the water plugging gel can be directly prepared by high-salinity water, the gelling strength can be up to the visual inspection code level I, and synaeresis does not occur after 90 days. The temperature-resisting salt-tolerant high-temperature self-cross-linking onsite polymerization water plugging gel is low in initial viscosity, has the advantages of being few in components, good in instant solubility and pumping injection performance, high plugging strength, good in thermohaline stability, low in cost and the like and has wide application prospect on the aspect of high-temperature high-salinity oil reservoir profile control water plugging.

An anhydride and resorcinol latent catalyst system for a phenolic resole resin provides a resin having long pot life and long shelf life, yet cures quickly thereafter.

One embodiment relates to an, article and a method for producing an article including a plurality of substrates, and an adhesive bonded between at least two of the plurality of substrates. The adhesive can include a polycarbonate copolymer that includes reacted resorcinol, siloxane, and bisphenol-A. Another embodiment relates to an article having a first polyimide substrate, a second polyimide substrate, and an adhesive bonded between the first substrate and the second substrate. The article can have a 2 minute integrated heat release rate of less than or equal to 65 kilowatt−minutes per square meter (kW−min / m2) and a peak heat release rate of less than 65 kilowatts per square meter (kW / m2) as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853(d).