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3832 results about "Hydration reaction" patented technology

In chemistry, a hydration reaction is a chemical reaction in which a substance combines with water. In organic chemistry, water is added to an unsaturated substrate, which is usually an alkene or an alkyne. This type of reaction is employed industrially to produce ethanol, isopropanol, and 2-butanol.

Method for separating and reclaiming vanadium and chromium from solution containing vanadium and chromium

This invention relates to an entirely new technology of completely recovering chromium and vanadium from vanadium-chromium miscible liquid. The main procedures include: first a primary-secondary compound amine extracting agent contacts the vanadium-chromium miscible liquid by means of countercurrent contact and extract, so as to extract most of vanadium and a small amount of chromium into a organic phase while most of chromium stays into a aqueous phase; and a reduction reaction is conducted with pH of acid adjustable faffinate (aqueous phase) and a certain amount of a reducing agent; the sodium hydroxide is used for adjusting pH value of the solution and filter, and finally the product is hydrous chromium oxide; at that time, the lye is used as a stripping agent; the vanadium is stripped from the vanadium-rich organic phase into water in the manner of countercurrent contact; and the vanadium is separated from the solution witthe method of ammonium precipitation and in the form of ammonium metavanadate; and finally the supernatant clear solution of the one is processed with deposited vanadium with a high-efficient distillation technology, and the strong aqua ammonia is left in the tower top and deamidization solution is left in the tower bottom until the extraction process is reached. The invention uses the primary-secondary compound amine as the extracting agent, extracts and separates vanadium and chromium selectively at a low temperature. The invention not only has a simple process flow, but also is low-cost, quite applicable in large-scale industrial production. In addition, the invention also provides high-purity ammonium metavanadate and 16 percentage strong aqua ammonia, and makes sure the vanadium and chromium can be completely recovered through re-use of the solution.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Liquid alkali-free chloride-free accelerating agent as well as methods for preparing and using same

The invention discloses a liquid alkali-free chloride-free accelerating agent and methods for preparing and using the same. Raw materials for preparing the accelerating agent include one or a plurality of the following components of aluminum sulfate, magnesium sulfate, hydramine, an early strength agent, a synergist and water. The aluminum sulfate is the purchasable industrial-grade aluminum sulfate hydrate Al2(SO4)3.18H2O and has the solid content of 51%-52%. The magnesium sulfate is MgSO4.7H2O with the solid content of 48%-49%. The hydramine is one or a plurality of mono ethanol amine, diethanolamine, triethanolamine or isopropoxide. The early strength agent is one or a plurality of calcium sulfate, calcium formate or calcium nitrite. The synergist is magnesium fluosilicate and / or magnesium fluoride. The liquid alkali-free chloride-free accelerating agent provided by the invention has the characteristics of good adaptability, low price, low mixing amount, good performance, good stability and the like; and moreover, the liquid alkali-free chloride-free accelerating agent is added into the concrete to be used as sprayed concrete, has the characteristics of low resilience, small dust pollution and the like and can satisfy the requirements of the 'JC477-2005 sprayed concrete accelerating agent' standard.
Owner:北京冶建特种材料有限公司 +1

Reproducible phosphorus-uptake ceramsite and preparation method thereof

The invention discloses a reproducible phosphorus-uptake ceramsite and a preparation method thereof. The technical scheme provided by the invention comprises the following steps of: respectively drying 70-85 wt% of fly ash, 10-16 wt% of pore-forming agent and 5-14 wt% of clay powder and uniformly mixing the raw materials; after balling the mixture, baking at a temperature in a range of 950-1100 DEG C for 30-50 min to obtain a baked porous ceramsite; sequentially immersing the baked porous ceramsite with HCl, washing with water and drying; and loading zirconium oxide hydrate to obtain the phosphorus-uptake ceramsite. The phosphorus-uptake ceramsite prepared by the invention can be directly added into or filled as a filtering column to remove phosphorus in the water and the adsorbed phosphorus-uptake ceramsite can be desorbed by a NaOH solution to be reproduced; the saturated adsorption capacity to the phosphorus is 10-11 mg / g and the adaptability to the change of the phosphorus concentration in the water is good; after the treatment, the solid-liquid separation is easy to realize and the water quality of the discharged water is better. The reproducible phosphorus-uptake ceramsite provided by the invention has the advantages of strong phosphorus-uptake capability, easiness of realizing the solid-liquid separation, good cyclic usability and higher cost performance, so that the reproducible phosphorus-uptake ceramsite is applicable to phosphorous removal of various types of wastewater and surface water.
Owner:WUHAN UNIV OF SCI & TECH

Colored aluminum pigment with high color depth and preparation method thereof

The invention relates to a colored aluminum pigment with high color depth and a preparation method thereof. The colored aluminum pigment is obtained by depositing a layer of silicon dioxide on a flaky metallic aluminum sheet substrate and then depositing one or more layers of metal oxide on the surface of the silicon dioxide, and the colored aluminum pigment exists in the form of dry powder. The preparation method comprises the following steps: a. stirring to disperse commercially available aluminum pigment slurry in alcohol, alcohol ether or a ketone solvent; b. regulating the temperature to 30-80 DEG C, respectively adding tetraethoxysilane and aqueous solution to the dispersed aluminum pigment slurry with the mol ratio of the tetraethylorthosilicate to the water ranging from 1:0.5 to 1:20, adding a catalyst such as ethylenediamine solution or aqueous ammonia, and obtaining aqueous aluminum pigment slurry by vacuum filtration and washing after the reaction; and c. cladding the aqueous aluminum pigment slurry obtained in the step b with the hydrated metal oxide on the powdered aluminum surface in a liquid phase. The preparation method help prepare the colored aluminum pigment with diversified colors and high color depth without reducing brightness of the original aluminum pigment slurry.
Owner:WENZHOU YOUNGBIO CHEM

Clean production process of plateau sulfate type boron-lithium salt lake brine

InactiveCN102910652AHigh purityReduce the ratio of magnesium to lithiumChemical industryAlkali metal halide purificationHydration reactionSylvinite
The invention relates to a clean production process of plateau sulfate type boron-lithium salt lake brine. The process comprises the following steps of: (1) arranging a pre-airing pond, a mirabilite pond, a NaCl pond, a carnallite pond, an epsom salt pond I, a magnesium removing pond, an epsom salt pond II, a boron pond, a lithium pond and an old brine pond; (2) controlling the sodium ion concentration in plateau sulfate type boron-lithium salt lake brine, precipitating mirabilite out in winter to obtain brine A, naturally evaporating the brine A, and salting out to obtain brine B; (3) naturally evaporating the brine B, and precipitating sylvine and carnallite out in sequence to obtain brine C; (4) naturally evaporating the brine C, precipitating an epsom salt out, and performing solid-liquid separation to obtain brine D and a solid A; (5) blending the brine D with mirabilite, removing magnesium to obtain brine E, and naturally evaporating brine E to obtain brine F and a solid B; (6) performing a hydration reaction on brine F, naturally evaporating, and precipitating reservoir water/inderite and brine G out; and (7) evaporating brine G or refrigerating for precipitating lithium sulfate, and processing the lithium sulfate into a corresponding product. The process has the advantages of comprehensive utilization of natural energy, saving in energy and environment friendliness.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI +1

Curing agent and curing method for heavy metals in fly ash from mswi (municipal solid waste incineration)

The invention provides a curing agent and a curing method for heavy metals in fly ash from mswi (municipal solid waste incineration). The curing agent comprises an aluminum-rich high-silicon material and an alkaline exciting agent, wherein the mass of the aluminum-rich high-silicon material is 15% to 25% of the mass of the fly ash from mswi; the mass of the alkaline exciting agent is 3% to 5% of the mass of the fly ash from mswi. The curing agent adopts industrial waste residues, and raw materials are cheap and easy to obtain; according to the curing method, lots of calcium oxide, chloride and sulfide existing in the fly ash from mswi have a hydration reaction with the aluminum-rich high-silicon material to generate a C-S-H (calcium silicate hydrate), Friedel (calcium chloroaluminate) phase and Aft (ettringite) phase system; during the formation process of the mineral system, a solid solution is formed through ion exchange, a new phase is formed through coprecipitation, and a relatively strong stable constraint effect can be played on heavy metals through physical adsorption and coating, so that wastes can be treated by using wastes, and harmless treatment of the fly ash from mswi and resource utilization of the industrial waste residues are realized.
Owner:CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY

Morphology-controlled carbon quantum dot/nickel cobaltate composite electrode material and preparation method

The invention belongs to the technical field of nanometer materials, and particularly relates to a morphology-controlled carbon quantum dot / nickel cobaltate composite electrode material and a preparation method. The preparation method specifically comprises the following steps of (1) dissolving carbon quantum dot powder, nickel nitrate hexahydrate, cobalt nitrate hexahydrate and urea into a mixed solvent of water and ethanol, mixing, putting into a polytetrafluoroethylene-lined reaction kettle, adding foam nickel, sealing, heating to react, cooling, taking out foam nickel, flushing and drying; (2) performing heat treatment on the dried foam nickel, so as to obtain the carbon quantum dot / nickel cobaltate composite electrode material using the foam nickel as a substrate. The preparation method has the advantages that by adjusting the feeding amount of carbon quantum dots, different morphologies of the composite material, such as urchin shape, corolla shape and waxberry shape are formed on the micro structure; the preparation method is simple, the implementing is easy, and the cost is low; the chemical and physical property of obtained material is stable, and the application prospect is good in the fields of electrochemical energy storage and catalyzing.
Owner:FUDAN UNIV

Method for producing caprolactam by taking high-purity benzene as raw material

The invention provides a method for producing caprolactam by taking high-purity benzene as a raw material, and the method comprises the following steps of: A. preparing cyclohexene from the raw material benzene through hydrogenation; B. separating and purifying cyclohexene; C. carrying out hydration on the cyclohexene for preparing cyclohexanol; D. separating and purifying cyclohexanol; E. carrying out dehydrogenation on cyclohexanol for preparaing cyclohexanone; F. refining cyclohexanone; G. carrying out oximation on cyclohexanone so as to prepare cyclohexanone-oxime; H. refining cyclohexanone-oxime; I. carrying out rearrangement on refined cyclohexanone-oxime so as to prepare caprolactam; and J. refining caprolactam, wherein the high-purity benzene is adopted as a raw material, so that the purity of benzene is more than 99.95%, the sulphur content is less than 5ppm, and the methylbenzene is not more than 100ppm. The method has the beneficial effects that the high-purity benzene is adopted as a raw material, so that the impurity is less, and the product quality is high; the raw material is high in comprehensive utilization rate and low in hydrogen consumption; and the mass of the raw material and intermediate products generated in all the steps of reaction can be strictly controlled, so that the direct commercial value of the intermediate products is fully exerted, and the optimal quality of the product caprolactam can be reached.
Owner:CHINA TIANCHEN ENG +3
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