2524 results about "Hydration reaction" patented technology

The invention relates to a preparation method of an amino-functionalized metal organic framework material and application of the prepared material to separation of CO2 / N2 and CO2 / CH4. The preparation method comprises the following steps: dissolving adenine and copper nitrate trihydrate in N, N '-dimethylacetamide to obtain a first mixed solution; dissolving carboxylic acid and potassium carbonate in deionized water to obtain a second mixed solution; and adding the second mixed solution into the first mixed solution, carrying out stirring reaction, and carrying out vacuum drying on an obtained solid product to obtain the amino-functionalized metal organic framework material. The amino-functionalized metal organic framework material prepared by the invention has high CO2 adsorption selectivity and adsorption capacity, and also has good acid-resistant, alkali-resistant and water-resistant stability. The amino-functionalized metal organic framework material prepared by the preparation method disclosed by the invention is applied to industrial CO2 adsorption separation and has an excellent separation effect.

The invention discloses a method for preparing nano cerium oxide through supergravity reinforcement, which comprises the following steps: 1) completely dissolving cerium chloride hexahydrate serving as a cerium source with deionized water to prepare a cerium chloride solution; (2) inputting the cerium chloride solution into a supergravity reactor through a peristaltic pump at normal temperature, then inputting ammonia water into the supergravity reactor through a constant-flux pump, and carrying out premixing reaction in the supergravity reactor to form mixed slurry; and 3) after the premixing reaction is finished, taking out the mixed slurry, and carrying out suction filtration, washing, drying and high-temperature oxidation calcination to obtain the nano cerium oxide. According to the method, the production efficiency can be improved, the particle size of the prepared nano cerium oxide is small, the particle size distribution is narrowed, and the crystallinity of crystals is improved.

Provided is a method and system for predicting a hydration reaction degree of cement based on a cycle generative adversarial network (CycleGAN). The method includes the following steps: S1, acquiring a micro-structure image of a cement paste test specimen; S2, establishing a micro-pore structure image dataset; S3, establishing a cement micro-hydration prediction model based on a CycleGAN; and S4, completing prediction based on a final cement micro-hydration prediction model. A deep learning algorithm is applied to micro-hydration prediction of cement. A complex theoretical formula is replaced with a data driven mode. Dependence on ideal hypotheses is reduced, and the accuracy of prediction on micro-hydration of cement is thus improved.

The invention relates to the technical field of low-carbon olefin hydration, and discloses a modified hydrated filler as well as a preparation method and application thereof. The modified hydrated filler comprises a filler matrix, and a silane layer, a modified layer A and a modified layer B which are sequentially coated on the outer surface of the filler matrix from inside to outside, the modified layer A contains a pyrrolyl group, an amido group and a furyl group; the modified layer B contains phenoxy, pyrrolyl, furyl, sulfonic acid group, phosphate group and acylamino. The modified hydrated filler provided by the invention can obviously improve the mixing effect of water and alkene and promote the improvement of the yield of low-carbon alcohol.

The invention discloses a solid waste-based cementitious material, which comprises the following raw materials based on 100% of the total mass percentage: 10% to 35% of pretreated pyrite tailing powder, 30% to 50% of granulated blast furnace slag powder, 15% to 30% of steel slag powder, and the remainder being gypsum powder. The invention heats the pyrite tailing at 300°C and ultrafinely grinds the pyrite tailing to cause an oxidation reaction of pyrite and pyrrhotite contained therein to generate sulfate minerals, thereby reducing the proportion of sulfide compounds in the tailing and reducing the risk of expansion and cracking of a hardened body of the solid waste-based cementitious material in the later stage. Moreover, the sulfate generated by oxidation and the gypsum contained in the pyrite tailing react with the steel slag and slag in the solid waste-based cementitious material to generate hydrated calcium silicate gel and calcium sulfonite, thereby improving the strength of the solid waste-based cementitious material.

The invention relates to a mass concrete hydration heat internal and external temperature difference and temperature strain prediction method, which is based on a hydration reaction of a concrete cementing material, through observation records of parameters such as concrete mold entering temperature, environment temperature and center temperature, a function relationship between the parameters and a pouring area temperature is established, and through a function model, an overall temperature field is predicted. Forming an internal and external temperature difference prediction model, and outputting an internal and external temperature difference; and in combination with concrete strain records, establishing a relation function of temperature and strain, forming a concrete hydration heat temperature-strain prediction model, and outputting a strain prediction result. The problem of hydration heat of mass concrete pouring construction puzzling major engineering can be solved. The problems of internal damage and surface cracking of the concrete due to overlarge internal and external temperature difference and temperature strain exceeding the initial tensile strain of the concrete caused by low concrete strength, poor bonding force of gravel aggregate, centralized hydration of a large amount of cement, and easy generation of adiabatic temperature rise in the initial stage of pouring are solved.

The invention relates to the technical field of hydrometallurgy, and particularly discloses preparation methods of ultralow-potassium ammonium molybdate and ultralow-potassium derivatives thereof. The preparation method of the ultralow-potassium ammonium molybdate comprises the following steps that S1, roasted molybdenum concentrate is subjected to primary screening, smashing and re-screening, and a raw material is obtained; s2, adding the raw materials and pure water into a reaction kettle, uniformly mixing, adding an acid solution, adjusting the pH value, introducing compressed air, heating, adjusting the pressure in the kettle, cooling and depressurizing, washing, and carrying out solid-liquid separation to obtain hydrated molybdenum trioxide; s3, mixing molybdenum trioxide hydrate with an ammonia water solution, adding ammonium sulfide, mixing for 1-2 hours, carrying out solid-liquid separation, then adding an adsorbent, mixing for 1-2 hours, cooling, aging for 24-48 hours, and carrying out solid-liquid separation to obtain an ammonium molybdate solution; and S4, concentrating the ammonium molybdate solution according to the specific gravity, and then carrying out cooling crystallization, solid-liquid separation, washing and drying to obtain the ultralow-potassium ammonium molybdate. The ammonium molybdate and the derivatives thereof prepared by the invention have relatively low content of potassium.

Techniques for humidifying a gas stream using a hydration system includes directing a gas stream through a contact zone of at least one hydration system; directing a hydration solution into the contact zone using a pump; contacting the gas stream with the hydration solution; evaporating water from the hydration solution into the gas stream to form a humidified gas stream, transporting the humidified gas stream out of the at least one hydration system; and collecting the remaining hydration solution in a hydration solution collection basin below the contact zone. The at least one hydration system is fluidly coupled to at least one downstream process and the humidified gas stream from the at least one hydration system is transported as a feed stream to the at least one downstream process.

The invention relates to the field of film materials, and discloses a degradable antibacterial film material and a preparation method thereof.The film material comprises degradable matrix resin, a modified additive, a plasticizer and a lubricant; the modified additive is prepared by loading a natural antibacterial agent on a modified flame-retardant composite filler; the modified flame-retardant composite filler is prepared by reacting cinnamyl aldehyde with a flame-retardant composite filler and forming a complex with zinc acetate dihydrate; the flame-retardant composite filler is prepared by reacting epoxidized composite filler with 1, 5-naphthalene diamine and then further reacting with phytic acid; according to the invention, the natural antibacterial agent is loaded in the modified flame-retardant composite filler through a vacuum impregnation method, and the mechanical property, antibacterial property and flame-retardant property of the material are enhanced by adding the modifying additive, so that the flame-retardant and antibacterial composite material has the advantages that the flame-retardant and antibacterial properties of the material are improved, and the service life of the material is prolonged. Meanwhile, diffusion / permeation of gas and water molecules in the film is adjusted.

The invention relates to the technical field of chemical engineering, in particular to a method and a device for removing heavy components from cyclohexanol. Comprising the following steps: a, rectifying a cyclohexanol-containing material from a cyclohexene hydration reaction to obtain a first solution containing cyclohexanol and heavy components in a tower kettle; b, carrying out heavy component removal operation on the first solution to obtain a third solution containing a catalyst and heavy components, a first gas phase and a second gas phase; and c, rectifying the first gas phase and the second gas phase to obtain a fourth solution subjected to heavy component removal, namely cyclohexanol subjected to heavy component removal. The entrained catalyst and heavy components are removed together, and the fluidity required by the catalyst waste liquid is maintained by using the heavy components, so that the loss of cyclohexanol is reduced.

The invention provides a self-repairing hydrated salt phase change microcapsule as well as a preparation method and application thereof, and belongs to the field of phase change materials. The preparation method comprises the following steps: preparing a hydrated salt phase change material and sorbitol into eutectic melt by adopting a melting method; strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica are added into the eutectic melt, and blending is performed to obtain a core material; The preparation method comprises the following steps: adding strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica into the eutectic melt; bio-based polyurethane-polyurea is used as a shell material, the core material is coated in the shell to prepare the microcapsule, and the temperature of the coating operation is not higher than the phase change temperature of the hydrated salt phase change material; the surface is coated with a super-hydrophobic coating. According to the invention, a solid filler system is constructed, and a low-temperature preparation process is combined, so that the phase-change microcapsule with high performance, high reliability and high safety is developed.

The present invention generally relates to a method for synthesizing NiO / ZnO nanoparticles using solution combustion synthesis. The method comprising: dissolving 10 grams of Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and 10 grams of Nickel(II) nitrate hexahydrate (Ni(NO3)2·6H2O) in 30 ml of double-distilled water to obtain a solution; adding at least one fuel selected from a group consisting of glucose, urea, and combinations thereof to the solution; stirring the solution for one hour to achieve homogeneity and transferring the homogeneous solution into a Pyrex dish; placing the dish inside a preheated muffle furnace at a temperature range of 440° C. to 460° C. and allowing the solution to boil, froth, and undergo exothermic combustion thereby retrieving the resulting fine nanoparticle powder upon completion of the reaction within 20 minutes; and cooling the synthesized powder to room temperature and grinding the powder to achieve a fine, uniform consistency, thereby forming NiO / ZnO nanoparticles.

The invention relates to the technical field of energy storage nano materials, and provides a ZIF-67-derived CoSe2-atNC hollow nano cubic box material and a preparation method thereof.The preparation method comprises the steps that a solution A is prepared from cobalt nitrate hexahydrate, cetyltrimethylammonium bromide and deionized water, a solution B is prepared from 2-methylimidazole and deionized water, and the ZIF-67-derived CoSe2-atNC hollow nano cubic box material is obtained; adding the solution A into the solution B, stirring to prepare a ZIF-67 precursor solution, and carrying out aging reaction to prepare a ZIF-67 nanocube material; preparing a solution C by adopting a ZIF-67 nanocube material and absolute ethyl alcohol, preparing a solution D by adopting tannic acid, deionized water and absolute ethyl alcohol, and adding the solution C into the solution D for etching reaction to prepare a TA-Co hollow nano cubic box material; carrying out first heat treatment on the TA-Co hollow nano cubic box material, mixing and grinding a product of the first heat treatment and selenium powder, and then carrying out second heat treatment to prepare the ZIF-67 derived CoSe2 (at) NC hollow nano cubic box material. The preparation method can be used for preparing the sodium battery negative electrode material with high specific capacity and high cycling stability.

The invention discloses a low-temperature-rise, high-impermeability and low-carbon concrete nano-fluid additive as well as a preparation method and application thereof, and relates to the technical field of graphene materials. The nanofluid additive comprises water and graphene and a dispersing agent which are dispersed in the water, the dispersing agent comprises polyvinyl alcohol and / or sodium carboxymethyl cellulose, and the preparation method comprises the following steps: adding graphite powder into a dispersing agent solution, and then sequentially carrying out shearing stripping and emulsifying stripping to obtain a mixed solution; and centrifuging the mixed solution, and collecting the supernatant to obtain the nanofluid additive. The graphene nanofluid is added into the cement-based material as an additive, can effectively absorb and disperse hydration heat release in the cement hydration process, and slows down the hydration reaction rate, so that the overall hydration heat is reduced. Meanwhile, the high surface area and the two-dimensional structure of the graphene are beneficial to filling micro-pores of the cement-based material, and the impermeability, the durability and the mechanical property of the cement-based material are improved.

The invention discloses a neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material and a preparation method thereof, the chemical formula of the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material is Sr1-xNdxZr0. 2Fe11.8 O19, and x is more than or equal to 0.1 and less than or equal to 0.4. The method comprises the following steps: (1) mixing strontium nitrate, ferric nitrate nonahydrate, neodymium nitrate hexahydrate, zirconium nitrate pentahydrate, citric acid monohydrate and deionized water, stirring and dissolving to obtain sol; (2) adjusting the pH value of the sol to 6.5-7.5, and then heating to carry out sol-gel reaction to obtain wet gel; (3) drying and grinding the wet gel to obtain precursor powder; and (4) performing heat treatment on the precursor powder in a box-type furnace, cooling and grinding to obtain the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material. According to the material, effective wave-absorbing frequency band broadening is achieved, the matching thickness corresponding to the effective wave-absorbing bandwidth is as thin as 0.55-0.7 mm, and meanwhile, the performance requirements of thinness, width and strength in the field of electromagnetic compatibility are met.

The invention provides a hydrated compound and a preparation method thereof, and relates to the technical field of compound preparation. The hydrated compound is rupatinifen fumarate monohydrate and has a crystal structure. The preparation method of the hydrated compound comprises the following steps: adding rupatinifen fumarate into a reaction solvent at least containing a first organic solvent, heating, stirring and refluxing until the rupatinifen fumarate is completely dissolved, the concentration of the rupatinifen fumarate in a reaction system is not lower than 70% of the concentration of a saturated solution of the rupatinifen fumarate in the reaction system, and carrying out solid-liquid separation to obtain the hydrated compound. And continuously refluxing for 1 min to 24 h, cooling to the temperature not exceeding 8 DEG C, crystallizing, collecting crystals, washing and drying to obtain the product.

The invention belongs to the related technical field of electrocatalysts, and discloses a cross array electrocatalyst and a preparation method and application thereof.The preparation method comprises the following steps that a nickel net subjected to corrosion treatment is put into a corrosion solution to be subjected to heat preservation reaction for preset time, and then the cross array electrocatalyst is obtained, the electrocatalyst is provided with a nanosheet array structure which is mutually crossed and supported; wherein hydrochloric acid is used for carrying out corrosion treatment on the nickel net; the etchant solution is obtained by dissolving sodium thiosulfate pentahydrate, nickel chloride hexahydrate, ferrous chloride tetrahydrate and sodium orthovanadate in an ethylene glycol solution. The catalyst prepared by the invention has a nanosheet array structure which is mutually supported in a crossed manner, and the special structure enables the catalyst to construct an ion confinement space, so that adsorption and enrichment of reactants on the interface of the catalyst are facilitated, a local reactant-rich environment is constructed, and excellent electro-catalytic oxygen evolution activity is shown.

The invention discloses an ion doping method based on first principle calculation and application thereof. Relates to the technical field of building materials. The method comprises the following steps: firstly, constructing a cement clinker mineral phase crystal structure model, and performing structural relaxation on the model to obtain a model crystal structure with a determined lattice constant; secondly, analyzing and optimizing microstructure changes and corresponding energy state changes of various mineral phases in the ion doping process by utilizing a quantum mechanical simulation means, representing the solid solubility of doped ions and mineral phase structures through the defect formation energy of ion doping, forming energy being negative reaction process being spontaneous process, the closer to 0, the better the solid solubility, and the more to 0, the better the solid solubility; therefore, how to enhance the hydration reaction activity and improve the strength by ion doping is disclosed. The mechanical property, durability and corrosion resistance of the cement are improved by accurately regulating and controlling the characteristics of the multi-mineral-phase structure.

The invention provides a long-acting and low-cost Ru-based catalyst for hydrogen production through ammonia decomposition and a preparation method thereof.The preparation method comprises the steps that calcium salt or strontium salt and cerium nitrate hexahydrate are added into deionized water to be prepared into a mixed solution, the pH value of the mixed solution is adjusted, then a precipitate is obtained through closed heating treatment, carrier powder is prepared through roasting and grinding in sequence, and the Ru-based catalyst for hydrogen production through ammonia decomposition is obtained; and adding a proper amount of ruthenium salt, uniformly stirring to form a Ru-carrier dispersion liquid, and finally, sequentially roasting and grinding to obtain the Ru-based catalyst for hydrogen production by ammonia decomposition. The loading capacity of the catalyst is lower than that of conventional Ru, the catalyst can show good ammonia decomposition hydrogen production performance under the conditions that the 10% NH3 / Ar mass space velocity (GHSV) is 30000 ml / (gcat.h) and the low temperature is 450 DEG C, it is accidentally found that the catalyst can keep long-term stability for at least 100 hours or above, and meanwhile the simple synthesis method is suitable for industrial large-scale production.

The invention relates to a method for preparing hexagonal flaky magnesium hydroxide through a hydration modification one-step method, and belongs to the technical field of inorganic material preparation. Hyperbranched sodium polyacrylate containing phosphonic acid and ammonium phosphonate salt is synthesized and serves as a crystal forming agent for magnesium hydroxide crystal growth, the hyperbranched sodium polyacrylate can coordinate with magnesium ions, uniform growth of all crystal faces of the magnesium hydroxide crystal is promoted, and the magnesium hydroxide crystal growth rate is increased. And the hyperbranched structure can better and moderately wrap the formed magnesium hydroxide crystal, so that the uniform growth property of the crystal face is improved. In addition, ammonium phosphate groups and carboxylate in the crystal forming agent have good wetting dispersity, agglomeration of magnesium hydroxide crystals is weakened, and the particle size distribution uniformity is improved. According to the method, the magnesium oxide powder and the crystal forming agent are ground and then subjected to the hydration reaction, the hexagonal flaky magnesium hydroxide is synthesized through a one-step method, and the prepared magnesium hydroxide is in a regular hexagonal flaky shape, has uniform particle size distribution, and has relatively high purity and relatively low impurity content.

The invention relates to the technical field of hydrogen storage material preparation, in particular to a preparation method of a nano magnesium-based hydrogen storage material based on parameter optimization. The preparation method comprises the following steps: preparing a solution A from functionalized graphene powder, tetrabutyl titanate and isopropanol, preparing a solution B from scandium nitrate monohydrate and isopropanol, mixing A and B to obtain gel, grinding, calcining, analyzing a state difference index, optimizing feedback error control temperature to obtain powder A by mixing a catalyst and magnesium powder, heating, preserving heat, cooling, preserving heat and cooling the powder A to obtain powder B, and preparing the graphene / scandium nitrate / magnesium powder composite material. And ball-milling the powder B to obtain the nano magnesium-based hydrogen storage material. According to the method, the influence of the heat transfer non-uniformity characteristic on the calcination treatment temperature error in the catalyst calcination process is analyzed, the temperature data at different time points are integrally divided, and the difference is analyzed, so that the influence of the non-uniformity characteristic on the feedback error analysis on the time interruption characteristic on the temperature data change is reduced; the capability of coping with the influence of the non-continuous difference of calcination treatment on feedback error analysis is improved, and the performance of the nano magnesium-based hydrogen storage material is improved.

Disclosed are composite mineral particles, a preparation method therefor and the use thereof, and a method for treating manganese-containing acidic wastewater to recover manganese oxides. The composite mineral particles are prepared by subjecting preparation raw materials to a hydration reaction, roasting and dehydration condensation, wherein the preparation raw materials comprise bentonite, carbide slag and an excitant. When the composite mineral particles are used for treating manganese-containing acidic wastewater, OH- is continuously released, such that the surfaces of the composite mineral particles are negatively charged to adsorb Mn2+ in the wastewater to form an Mn(OH)2 surface precipitate, which is in contact with dissolved oxygen in the water to generate an autocatalytic oxidation effect, and further by means of the synergistic effect of adsorption-surface precipitation-autocatalytic oxidation by means of contact-aggregation and self-growth, residual composite mineral particles with thin-shell-shaped manganese oxides on the surfaces thereof are obtained, or aggregated and settled manganese oxides and residual composite mineral particles are obtained, thereby realizing the preparation of manganese oxides by means of mineralization and recovery of Mn2+ in the manganese-containing acidic wastewater, and purification treatment of the manganese-containing acidic wastewater.

A method and device for separating and recovering heavy metal ions through membrane-forming mineralization fixation, applicable in the domain of acid wastewater treatment containing heavy metal ions. The process involves mixing composite mineral particles with heavy metal acidic wastewater, then conducting a first hydration reaction under static conditions. This leads to adsorption, precipitation, and crystallization of heavy metal ions in the wastewater via a colloidal liquid membrane, resulting in particles coated with a mineralized membrane. These particles exhibit a gap between the mineralized membrane and their core. The next step is to separate these coated particles and recover them. The preparation of composite mineral particles involves mixing sodium carbonate / sodium silicate, bentonite, carbide slag, and water, followed by a second hydration reaction and subsequent granulation, aging, and dehydration condensation. The particle sizes of both bentonite and carbide slag are maintained at ≤74 m.

The invention belongs to the technical field of nano composite materials, and discloses a novel transition metal-inserted transition metal sulfide composite rare earth oxide photocatalytic material with a solid mediator Z-type heterostructure, and a preparation method and application of the novel transition metal-inserted transition metal sulfide composite rare earth oxide photocatalytic material. The preparation method comprises the following steps: mixing transition metal salt, thioacetamide, nitrate hexahydrate and water to obtain a mixed solution 1; mixing the mixed solution 1 with a hydrazine hydrate solution, and performing hydrothermal reaction to obtain a mixed solution 2; mixing the mixed solution 2 with ammonia water, and sequentially carrying out hydrothermal reaction, drying and calcining to obtain a calcined product; and mixing the calcined product with a sodium borohydride aqueous solution, and drying to obtain the photocatalytic material. The obtained photocatalytic material of the transition metal inserted transition metal sulfide composite rare earth oxide with the solid mediator Z-type body heterostructure has the characteristics of high stability, safe interface contact and rapid charge migration.

The present invention discloses a low-temperature resistant and early-strength type alkali-free liquid accelerating agent and its preparation method, belonging to the technical field of alkali-free liquid accelerating agents. The composition includes 12-15 parts of aluminum sulfate, 2-5 parts of sodium thiocyanate embedded by β-cyclodextrin, 5-8 parts of calcium hydroxide deactivator, 3-5 parts of fiber, 5-10 parts of hydrophilic polymer substance, 3-5 parts of cationic surfactant, 6-10 parts of polyaluminum chloride, and 2-3 parts of air-entraining agent. The low-temperature resistant and early-strength type alkali-free liquid accelerating agent of the present invention can improve the frost resistance of sulfate alkali-free accelerating agents, reduce the viscosity of cement slurry, promote the hydration reaction of C3S, shorten the setting time of concrete, and improve the later strength of concrete.

The invention discloses a nitrogen-containing carbon hollow sphere supported cobalt-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. According to the preparation method, ammonia water, tetraethyl orthosilicate, polyoxyethylene polyoxypropylene ether triblock copolymer, resorcinol and a formaldehyde solution are fully reacted in a mixed solvent of deionized water and ethanol by virtue of a template method, and the nitrogen-containing carbon hollow spheres are obtained after calcination and etching; then carrying out surface modification on the nitrogen-containing carbon hollow spheres, and uniformly loading cobalt metal by virtue of the structure guiding effect of hexamethyleneimine and sodium citrate dehydrate; the prepared nitrogen-containing carbon hollow sphere supported cobalt-based catalyst has abundant highly-exposed Co-N-C active sites, has wide substrate universality, has good catalytic activity and selectivity for amination reactions with various long-chain fatty aldehydes, fatty ketones, cyclic fatty ketones, aromatic aldehydes and ketones as raw materials, and can realize efficient catalytic amination reactions of carbonyl compounds.

The invention relates to the technical field of functional ceramic materials, and discloses complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide, a preparation method thereof and a ceramic glaze, and the preparation method comprises the following steps: mixing zinc oxide, aluminum oxide, silicon oxide, magnesium oxide and rare earth oxide in proportion to obtain a mixture, adding the mixture and an alkoxy compound into a solvent, and dispersing to form nano precursor slurry; carrying out reduction-oxidation calcination treatment on the obtained nano precursor slurry to obtain a calcined product; and carrying out hydration treatment on the obtained calcined product to obtain the complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide. By implementing the preparation method, the obtained complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide contains a zinc oxide phase and a spinel phase, is low in high-temperature lattice distortion rate and has super wear resistance, and a rare earth element R is introduced, so that the catalytic activity of the zinc oxide is improved, the degradation rate of the zinc oxide to formaldehyde and toluene is increased, and the antibacterial property of the zinc oxide is also improved.

The invention discloses a preparation method of a negative-temperature cement-based material capable of being continuously hydrated and hardened in an environment of-20 DEG C, and relates to the technical field of application materials. The negative-temperature cement-based material comprises Portland cement, fine aggregate, water, a mineral admixture, an anti-freezing agent, a water-retention thickener, a fluidity regulator, a microcapsule complex, a penetration enhancer, a silicon-aluminum disordered network precursor and an anti-freezing polypeptide chain material. Additives such as a microcapsule complex and a penetration enhancer are introduced into a cement-based system, a low-temperature activation mechanism with a synergistic effect is constructed, and the microcapsule complex can accurately release latent heat in a negative temperature environment and induce a hydration reaction to be continuously carried out; the permeation enhancer improves the interface diffusivity and breaks through a mass transfer channel of a frozen interface water layer; the silicon-aluminum disordered network precursor is used as a structure inducer to promote the recombination of a C-S-H gel structure at a low temperature; the antifreeze polypeptide chain material endows the slurry with frost crack resistance toughness through conformation adjustment and ice crystal inhibition functions.

The invention belongs to the technical field of hot melt adhesive processing, and particularly relates to a quick-drying polyurethane hot melt adhesive and a preparation method thereof. The preparation method comprises the following steps: mixing polyether polyol, isocyanate, a chain extender A, a chain extender B, a crystallization promoting agent, a surface drying promoting agent and an auxiliary agent, and carrying out extrusion granulation, wherein the chain extender A is obtained by carrying out a reaction on acrylamide and diethanol amine and then carrying out siloxane modification on the reaction product by utilizing methacryloyloxymethyltrimethoxysilane; and the chain extender B is obtained by reacting tetrakis hydroxymethyl phosphonium sulfate and barium hydroxide octahydrate and oxidizing by hydrogen peroxide. The prepared hot melt adhesive has better viscosity and also has a certain flame-retardant effect.