2133 results about "Hydrotalcite" patented technology

A process for producing a high temperature CO_x-lean product gas from a high temperature CO_x-containing feed gas, includes: providing a sorption enhanced reactor containing a first adsorbent, a shift catalyst and a second adsorbent; feeding into the reactor a feed gas containing H₂, H₂O, CO and CO₂; contacting the feed gas with the first adsorbent to provide a CO₂ depleted feed gas; contacting the CO₂ depleted feed gas with the shift catalyst to form a product mixture comprising CO₂ and H₂; and contacting the product mixture with a mixture of second adsorbent and shift catalyst to produce the product gas, which contains at least 50 vol. % H₂, and less than 5 combined vol. % of CO₂ and CO. The adsorbent is a high temperature adsorbent for a Sorption Enhanced Reaction process, such as K₂CO₃ promoted hydrotalcites, modified double-layered hydroxides, spinels, modified spinels, and magnesium oxides.

The invention discloses a granular filtering material for adsorbing and removing heavy metals in water and a preparation method thereof. The granular material consists of the following components in part by mass: 80-120 parts of an adsorbent, 7-14 pats of an additive and 0.5-3 parts of a binding agent, wherein the adsorbent consists of the following components in part by mass: 50-70 parts of coal ash and 30-50 parts of zeolite powder or sea-foam stone powder; the additive consists of the following components in part by mass: 5-7 parts of Mg-Al hydrotalcite, 2-6 parts of biochar and 0.5-1 part of magnesium Lignosulfonate; the binding agent is bentonite. The granular filtering material is prepared through the steps of adsorbent acid modification, biochar preparation, granulation and heat treatment process. According to the invention, the prepared granular filtering material is 3-6 mm in granule size, is large in adsorption capacity and excellent in adsorption effect and can effectively remove heavy metals in water, and no secondary pollutants are dissolved out, so that the granular filtering material can be applied to the treatment on heavy metal micro-polluted water and industrial waste water containing heavy metals, and has good economic and social benefits.

The invention provides a corrosion-inhibiting anionic intercalated hydrotalcite/nano oxide composite material, a preparation method thereof and application of the corrosion-inhibiting anionic intercalated hydrotalcite/nano oxide composite material. The preparation method is as follows: corrosion-inhibiting anions are directly inserted between hydrotalcite layers by the one-step coprecipitation method and the roasting restoring method; the nano oxide is generated by means of in situ synchronization during the process of generation of hydrotalcite crystals by controlling the mixture ratio of divalent metal ions to trivalent metal ions, the pH value of a reaction solution and the reaction temperature; and the corrosion-inhibiting anionic intercalated hydrotalcite/nano oxide composite material with the anti-corrosive function is prepared. The invention is mainly characterized in that the in situ preparation method for the hydrotalcite/oxide composite material provided with a nano lamellar structure improves the release amount of a corrosion inhibitor and reduces the water absorption of a coating by leading into the corrosion inhibitor with the anti-corrosive function and the nano oxide which is generated in situ during the reaction process. The composite material can be used to be pigment of an anti-corrosive metallic coating system, and particularly has potential application value in improving the anti-corrosive performance of a magnesium alloy anti-corrosive coating.

This invention relates to improvements in inhibiting undesirable discoloring of plastic articles within which silver-based antimicrobials have been introduced. Such a method requires the utilization of very low amounts of acid scavengers or stabilizers such as aluminum-magnesium hydroxycarbonate, otherwise known as hydrotalcite (and not a zinc-based compound). Such hydrotalcites are very low in cost, easy to handle, and, utilized in very low levels in combination with a silver-based antimicrobial within a plastic composition, surprisingly substantially prohibits the generation of unwanted aesthetically displeasing colors.

The catalytically cracking assistant capable of lowering the sulfur content in gasoline is composite oxide including aluminum zinc spinel, homogeneously distributed zinc oxide and at least one optional RE oxide. It is prepared through roasting the mixture of laminar aluminum zinc in hdrotalcite structure and optional RE oxide hydrate. The preparation process is simple, and the assistant has the features of high dispersion, high specific surface area, etc. The assistant after being formed is mixed with conventional FCC catalyst and/or active reinforcing assistant for application in catalytically cracking process, and has the function of lowering the sulfur content in gasoline and excellent hydrothermal stability.

The invention relates to a non-metallic bi-functional oxygen catalyst for graphene/nickel iron type hydrotalcite as well as a preparation method and electric catalytic application thereof to oxygen evolution reaction and oxygen reduction reaction in an alkaline medium. The catalyst takes a micelle as a template, and under the hydrothermal and reducing conditions, the nickel iron type hydrotalcite is assembled onto graphene in sequence to form a spherical porous graphene oxide/nickel iron type hydrotalcite compound. The method comprises the following steps: dispersing graphene oxide and metal salt in the micelle, introducing an alkali source, synthesizing the graphene oxide/nickel iron type hydrotalcite compound under the hydrothermal conditions, and performing hydrazine hydrate reduction on an obtained product to obtain the catalyst. The catalyst prepared by the method has high oxygen evolution and oxygen reduction catalytic activity, good stability and excellent methanol tolerance under the alkaline conditions and is low in cost of raw materials used, simple in preparation method, easy to operate and convenient for large-scale production.

The invention belongs to the technical fields of material sciences and electro-catalytic hydrogen production, and particularly relates to a nickel-iron hydrotalcite based electro-catalytic oxygen evolution electrode and preparation thereof, wherein the nickel-iron hydrotalcite based electro-catalytic oxygen evolution electrode can be used in an electrolytic water oxygen evolution reaction in an alkaline medium. An electrode system takes a nickel-iron hydrotalcite structure as a catalytic activity center and takes nickel foam as an electrode material; in the alkaline medium, the nickel-iron hydrotalcite based electro-catalytic oxygen evolution electrode can efficiently electrolyze water to prepare oxygen, the overall overcurrent polishing of electrolytic water is reduced greatly, and good stability is showed; according to the preparation technology of the nickel-iron hydrotalcite based electro-catalytic oxygen evolution electrode, a nickel-iron hydrotalcite composite structure is grownon the nickel foam base through an in-situ electrodeposition method; and the resources of required raw materials are wide, the price is low, the technology is mature and stable, operation is easy, convenient and fast, controllability is high, the process does not produce poison, and the nickel-iron hydrotalcite based electro-catalytic oxygen evolution electrode is suitable for mass production andthe industrial electrolytic water reaction.

The invention relates to an active component morphology controllable loaded noble metal catalyst which uses hydrotalcite as a carrier and is prepared by a precipitation-reduction method. A precipitating agent, a reducing agent, a surfactant, an etchant, a soluble salt solution of +2 and +3-valence metal ions forming the hydrotalcite, and an active component precursor solution are subjected to mixed crystallization, the +2 and +3-valence metal ions are nucleated and grown into the hydrotalcite in an alkaline environment provided by the precipitating agent, and meanwhile, the active component precursor is reduced to 0 valence, and the active component has specific uniform morphology, i.e., the active component morphology controllable loaded noble metal catalyst using the hydrotalcite as the carrier is obtained by one-step reaction. Since the kinetic rate is the key to control the morphology of the active component, and different reducing agents, surfactants and etchants can affect the dynamic process of reduction of the active component, the active component morphology controllable loaded noble metal catalyst of controllable preparation can be attained by controlling the reducing agents, the surfactants and the etchants.

A hydrotalcite-based composite thermal stabilizer for PVC and chlorine-contained high polymer is prepared from hydrotalcite, calcium soap and zinc soap through proportionally mixing.

The invention discloses a gahnitem, zinc oxide and nickel zinc nano-composite photocatalytic material which has a high specific surface area and a mesoporous structure and is prepared by roasting at high temperature by taking ternary hydrotalcite as a precursor. The material is used for the adsorption and the degradation of organic pollutants. The photocatalytic material is prepared by taking zinc nitrate, nickel nitrate, aluminum nitrate, sodium carbonate, sodium hydroxide and the like as raw materials; preparing the raw materials into salt solutions and alkali solutions respectively; mixing the solutions by using a constant-flow pump at the temperature of 80 DEGC with magnetic stirring, transferring the mixed solution into a hydrothermal reaction kettle; performing hydrothermal treatment at 130 to 180 DEG C; performing suction filtration, washing and drying to the precursor; roasting the precursor in Muffle furnace for 2 to 6 hours at the temperature of 400 to 600 DEG C to obtain the product, wherein the specific surface area is greater than 150 m<2>.g<-1>. The photocatalyst disclosed by the invention has regular shape, large specific surface area, and super-high capacity for adsorbing and degrading organics, and can be reused; the raw materials for preparing the composite photocatalyst are abundant, the cost is low, and the process is simple.

The invention discloses a preparation method of two-dimensional nano-graphene. The method includes: mixing acrylic acid and water according to the volume ratio of 1:1-1:2, adding hydrotalcite particles passing a sieve 20-50 in mesh into acrylic acid solution according to the quantity that each gram of hydrotalcite corresponds to 3-5mmol of the acrylic acid, stirring at the temperature of 60-70 DEG C, ageing, separating particles, adding the particles into isopropanol solution, adding ammonium persulfate, heating to 60-90 DEG C for reaction for 8-10h, drying at the temperature of 70-90 DEG C, grinding, and passing a sieve 20-40 in mesh to obtain powder; heating the power to 600-700 DEG C in vacuum, calcining for 2-4h, adding calcined powder into hydrochloric acid solution 20%-40% in concentration, stirring under the protection of nitrogen, precipitating, separating and drying; and heating an obtained product to 2000-2500 DEG C in vacuum, subjecting the product to heat treatment for 3-6h and cooling so that the two-dimensional nano-graphene is obtained. The method is simple in material sources and simple and mild in process.

The invention relates to the technical field of chemical stabilizers, in particular to a transparent environment-friendly calcium zinc stabilizer and a preparation method thereof. The transparent environment-friendly calcium zinc stabilizer is prepared from the following raw materials in percentage by mass: 10 to 30 percent of calcium salt main stabilizer, 10 to 30 percent of zinc salt main stabilizer, 30 to 50 percent of hydrotalcite, 10 to 20 percent of lubricant, 1 to 5 percent of antioxidant, 1 to 5 percent of ultraviolet absorber and 1 to 5 percent of auxiliary stabilizer. The preparation method for the transparent environment-friendly calcium zinc stabilizer comprises the following steps of: adding the raw materials into a high speed stirrer in three stages, jointly stirring at the temperature of between 55 and 56DEG C for 30 minutes, and making the rotating speed of the stirrer 1,000-1,500r/min. The prepared transparent environment-friendly calcium zinc stabilizer has high heatresistance, high transparency and copper rust resistance.

The invention discloses a fire-extinguishing agent. The fire-extinguishing agent is prepared by uniformly mixing hydrophilic solid powder and water or an aqueous solution, adding hydrophobic solid particles and then carrying out mixing and dispersing, wherein the hydrophilic solid powder is one or more of magnesium hydroxide powder, aluminum oxide powder, aluminum hydroxide powder, magnesium carbonate powder, calcium carbonate powder, calcium hydroxide powder, zinc borate powder, montmorillonoid powder, hydrotalcite powder, hydrotalcite like compound powder, fly ash powder, diatomite powder, mica powder and attapulgite powder. The fire-extinguishing agent disclosed by the invention can exert stifling, cooling, separating and chemically restraining functions at the same time, and has the advantages of no toxicity, small environment pollution, high fire extinguishing efficiency and the like. According to the fire-extinguishing agent disclosed by the invention, the hydrophilic solid powder with a certain fire extinguishing performance and smaller solubility in water is added into a water phase so as to reduce the using amount of water-soluble substances, thus the cost of the fire-extinguishing agent is reduced when higher fire-extinguishing efficiency is kept, and the fire-extinguishing agent is easier to clean after being used for extinguishing fire.

A low temperature copper/zinc/aluminum water gas shift catalyst is described. The catalyst is formed from a precursor, wherein the precursor includes aluminum in the form of hydrotalcite and aluminum separate from the hydrotalcite. A method of making the catalyst and a process for using the catalyst are also described.

The invention provides a supported bimetal nanocrystal catalyst which is a binary bimetal catalyst taking aluminum oxide as a supporter and is abbreviated to P-M/MgO-AlO3, wherein P represents noble metal such as Pd, Au, Pt, Ag and the like, and M represents one or two of metal cations such as Cu<2+>, Zn<2+>, Ni<2+>, Ga<3+> and Fe<3+>. The particle size of the P-M bimetal nanocrystal is 2-10 nm, the dimension distribution is narrow, the nanocrystal particles are highly dispersed on the surface of the supporter uniformly and stably, and the crystal form is complete. The preparation method of the catalyst comprises the following steps: preparing soluble Mg<2+> salt for MgMAl-LDH (layered double hydroxide) preparation and an endogenous active metal salt solution into a mixed solution; then simultaneously adding precipitant and the aluminum oxide supporter into the reaction system; enabling hydrotalcite to grow on the surface of the aluminum oxide supporter through an in-situ growth method; supporting exogenous active metal through a wet impregnation method; and performing high-temperature reduction on the obtained catalyst precursor under a reducing atmosphere, thus obtaining the supported bimetal nanocrystal catalyst which is stably and highly dispersed.

A supported non-noble metal catalyst used for preparation of an azo compound from an aromatic nitro compound by hydrogenation coupling is disclosed, an active component of the supported non-noble metal catalyst is any one or more than two of Co, Mn, Fe, Ni and Cu, a carrier is a nitrogen-doped carbon-inorganic oxide composite, the content of the active component in the catalyst is 0.1-15wt%, and an inorganic oxide is any one of alumina, aluminum hydroxide, magnesium oxide, magnesium hydroxide, silica, SBA-15, magnesium aluminum hydrotalcite, titanium oxide and cerium oxide. A preparation process is as follows: the active component and a nitrogen-containing complex are together impregnated on the inorganic oxide, and then calcined at certain temperature. The catalyst has excellent catalytic performance in the preparation of the azo compound from a nitro compound by selective hydrogenation coupling one-step method. The catalyst is simple in preparation, and has high catalytic activity and stability.

The invention relates to a heavy-metal ion absorber, which is the baked product of binary hydrotalcite, wherein the formula of binary hydrotalcite is A2+(1-x)B3+x(OH)2(CO32+)x/2 .mH2O, while 0 B01J 20/08 C02F 1/28 C02F 1/62 3 4 1 2006/10/20 1962046 2007/5/16 000000000 Shandong University 250061 Su Jixin Zhang Weihong Wang Xiaopeng Yin Jing Qu Wen Pan Qi xude shan 37219

The invention relates to fully-degradable heat-insulation mulch and a preparation method thereof. The fully-degradable heat-insulation mulch comprises the following components in parts by mass: 30-60 parts of PBAT (poly(butylene adipate terephthalate), 10-30 parts of polylactic acid, 10-30 parts of starch, 5-10 parts of plasticizer, 0-2 parts of chain extender, 5-10 parts of fillings, 5-20 parts of fully-degradable hydrotalcite master batch and 0-5 parts of fully-degradable color master batch. The preparation method of the fully-degradable heat-insulation mulch comprises the following steps of: carrying out extruding pelletizing on hydrotalcite powder and the PBAT in double screws to obtain the hydrotalcite master batch, preparing a material for the fully-degradable heat-insulation mulch from the hydrotalcite master batch, the PBAT, the starch, the polylactic acid, the plasticizer, the chain extender and the fillings according to a specific production process, and finally carrying out secondary processing on the obtained material in coordination with the fully-degradable color master batch to obtain the fully-degradable heat-insulation mulch. The fully-degradable heat-insulation mulch disclosed by the invention has the capability of completely degrading in soil and is good in heat insulation property, low in production cost, favorable in economic and social benefits and worthy of popularization and application.

The invention relates to a preparation method of a foamed nickel composite material. The method comprises the following steps that oxidized graphene and a surfactant are added to a water and methanol mixed solution, and ultrasonic processing is carried out to obtain a oxidized graphene solution; nickel nitrate and cobalt chloride are added into the oxidized graphene solution and stirred and mixed to form a uniform suspension; and the uniform suspension is poured into a hydro-thermal reactor kettle, foamed nickel is immersed into the suspension, solvothermal reaction is carried out at 100-200 DEG C, the oxidized graphene is changed to graphene by reduction while nickel and cobalt hydroxide is generated at the surface of the foamed nickel in situ, and thus, the foamed nickel composite material whose surface is covered with a graphene and nickel-cobalt hydrotalcite like layer is obtained. The invention also relates to the obtained foamed nickel composite material and application thereof. The preparation method is simple, easy to control and low in cost, and the obtained foamed nickel composite material which serves as electrode material of a super capacitor has higher specific capacitance and high cycle stability.

The invention relates to synthesis of novel zinc-aluminum-magnesium hydrotalcite and preparation of a PVC complex heat stabilizer from the hydrotalcite and calcium soap, zinc soap and the like according to a certain ratio. The complex heat stabilizer comprises the main components shown in the description, wherein X is more than or equal to 0.25 and less than or equal to 0.5, n is more than or equal to 0 and less than or equal to 0.1, and m is more than or equal to 0 and less than or equal to 4; while the popular hydrotalcite in market at present has the general molecular formula shown in the description. The complex heat stabilizer prepared from the hydrotalcite has the advantages of higher initial hue and long-lasting heat stability for PVC and other chlorine-containing high polymers, and has the characteristics of no toxin, no pollution, low cost, rich raw materials and the like.

The present invention discloses a loaded type amorphous alloy catalyst for preparing cyclohexanone by means of phenol catalytic hydrogenation and its preparation method. Said invention utilizes isochoric impregnation KBH4 reduction method to prepare amorphous alloy catalyst, said preparation method includes the following steps: preparing hydrotalcite carrier; making metal salt precursor solution and hydrotalcite carrier undergo the process of isochoric impregnation treatment; drying; roasting; drop-adding reductant KBH4 solution to make reduction; successively using deionized water and absolute ethyl alcohol to wash black solid precipitate obtained by above-mentioned solution reaction to neutrality so as to obtain the invented amorphous alloy catalyst.

The invention relates to an Mg/Al hydrotalcite modified charcoal composite material and a preparation method and application thereof. According to the composite material, charcoal is used as a substrate, and roasted Mg/Al hydrotalcite is loaded on the surface of the substrate. The preparation method comprises the specific steps that biomass powder is soaked with an Mg/Al water solution at first, then, a composite of Mg/Al hydrotalcite and biomass is prepared, and finally the composite of Mg/Al hydrotalcite and biomass is pyrolyzed through a tubular atmosphere furnace in N2 atmosphere to obtain the product. In the preparation process of the Mg/Al hydrotalcite modified charcoal composite material, biomass pyrolysis and hydrotalcite roasting are carried out in one heat treatment process, the preparation cost is reduced, and the preparation time is shortened. The structure of the roasted Mg/Al hydrotalcite can be partially recovered to be hydrotalcite of an orderly stratified structure after the roasted Mg/Al hydrotalcite makes contact with the water. The Mg/Al hydrotalcite modified charcoal composite material has the good adsorption effect on dye in waste water.

Anionic clay compounds such as hydrotalcite-like compounds can be made by a process wherein a non-hydrotalcite-like compound (or a hydrotalcite-like compound) are heat treated and then hydrated to form hydrotalcite-like compounds having properties (e.g., increased hardness and/or density) that differ from those of hydrotalcite-like compounds made by prior art methods wherein non-hydrotalcite-like compounds (or hydrotalcite-like compounds) are not similarly heat treated and hydrated to form such hydrotalcite-like compounds.

The invention discloses a manufacturing method of hydrotalcite layer-shaped hydroxide, which comprises the following steps: blending bivalent metal salt solution and tervalent metal solution according to molar rate; adopting parallel flow method; adding sodium hydroxide and sodium carbonate solution; setting the sediment temperature at 40-100 Deg C; stirring; controlling the flow of parallel flow at 5-10L/min; controlling sedimenting pH value, sedimenting time and aging time; filtering; washing; drying; producing hydrotalcite layer-shaped hydroxide continuously.

The invention discloses a multiphase catalytic synthetic method for preparing cyclic carbonate by additional reaction of carbon dioxide and epoxy compound. The cyclic carbonate can be prepared at a high selectivity of up to more than 87% at 100-180 DEG C under the initial pressure of carbon dioxide of 0.1-6 MPa in the presence of metal composite oxide as the catalyst which is made by calcining Zn-M-Al hydrotalcite, wherein M is alkali earth metal, and organic tertiary amine is solvent and co-catalyst. The catalyst has simple preparation, good stability, no halogen, and repeated utilization.

The invention provides magnesium-aluminum-iron hydrotalcite, a preparation method and application thereof as a coadsorbent. The preparation method comprises the following steps of: adding a mixed salt solution to an alkali solution to carry out a coprecipitation reaction by controlling the pH of the reaction ending point to 8.0-12; and then aging, filtering, washing and drying to obtain the magnesium-aluminum-iron hydrotalcite, wherein the mixed salt solution comprises magnesium salts, aluminum salts and iron salts, and after the magnesium-aluminum-iron hydrotalcite is roasted at 300-800 DEG C for 1-10 hours, an adsorbent for coadsorbing phenol and chromium (VI) in water is obtained. The invention has the advantages of moderate reaction condition, easy raw material obtaining, low production cost and reusability, and the adsorption rates of the phenol and the chromium (VI) can both reach higher 70 percent, thus the magnesium-aluminum-iron hydrotalcite has good application prospect. The chemical structural general formula of the magnesium-aluminum-iron hydrotalcite is as follows: [M2<+1>-xM3+x(OH)2]x+(CO3<2->)x/2.yH2O.

The invention discloses a low-carrying-capacity high-activity supported gold catalyst using hydrotalcite as a carrier and a preparation method thereof, which belong to the technical field of catalyst preparation. The preparation method of the supported gold catalyst comprises the following steps of: selecting a hydrotalcite precursor with a higher isoelectric point as the carrier; and using a uniform hydroxyl lattice of the hydrotalcite and different crystal face orientations of the hydrotalcite to ensure that gold atoms with catalytic activity are highly dispersed and are closely anchored on a high-energy crystal face of the hydrotalcite so as to expose more active gold particles. If the catalyst is used for synthesizing phenyl ethylene oxide through catalytic oxidation of styrene, the conversion rate of reactants is high, and the selectivity of products is high.

An organohalide-flame retardant polymer containing as a stabilizer blend:a) an acid scavenger, for example a hydrotalcite or an amorphous basic aluminum magnesium carbonate;b) a heat stabilizer comprising an organotin compound; andc) a polyhydroxyaliphatic costabilizer.

The invention provides a three-dimensional multi-level structure type high-dispersion nickel-based electro-catalytic material and a preparation method thereof. The method takes foam nickel as a conducting matrix and a nickel source needed by reaction is provided; urea is used as a precipitating agent, ammonium fluoride is used as an etching agent and an NiAl-LDH//NF precursor grows on the surfaceof a foam nickel framework structure in situ; negative ions including H2PO4<-> and B(OH)4<-> are introduced into hydrotalcite layers through an ion exchanging method; a hydrotalcite intermediate containing the negative ions is reduced at high temperature to obtain the three-dimensional multi-level structure type high-dispersion nickel-based electro-catalytic material; a chemical formula is NiY-Al2O3/NF, wherein Y is one of P or B. The material is used for electro-catalytic oxygen evolution reaction under an alkaline condition; when the current density reaches 10mA.cm<-2>, the overpotential ofthe oxygen evolution reaction is 270 to 190mV. When the material is used for carrying out selective electro-catalytic oxidization reaction on 5-hydroxymethylfurfural under the alkaline condition, theconversion rate and the selectively reach 92 to 100 percent and 95 to 100 percent respectively, and the invention proves that the material is suitable for being used as the electro-catalytic material.

The invention discloses a high-performance ultrathin nitride electro-catalyst with functions of producing hydrogen and oxygen by means of electrochemically totally decomposing water, a method for synthesizing the high-performance ultrathin nitrite electro-catalyst and application thereof. A chemical formula of the high-performance ultrathin nitride electro-catalyst is (Fe<X>Ni<1-X>)<4>N, and the x is larger than 0 and is smaller than 1. The nitrite electro-catalyst is of an ultrathin nanometer plate structure, the size of the nitrite electro-catalyst is 50-100nm, and the thickness of the nitrite electro-catalyst is 1.5-3nm. The method includes synthesizing NiFe hydrotalcite precursors at first; nitriding the NiFe hydrotalcite precursors at high temperatures under the protection of ammonia gas to obtain end products. The high-performance ultrathin nitride electro-catalyst, the method and the application have the advantages that series of nitrite have large specific surface areas, are good in electron conductance and are excellent in performance during electro-catalytic water total-decomposition reaction, limiting currents are higher than limiting currents of Pt/C during electro-catalytic hydrogen evolution reaction (HER), and the performance of the nitride in various aspects are superior to the performance of corresponding oxide NiFe-MMO during oxygen evolution reaction (OER); the electro-catalyst is low in cost, easy and convenient to operate, simple in process and excellent in catalytic performance, and fundamental application research on materials in the field of electro-catalysis can be provided.