934 results about "Hydrotalcite" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

This invention discloses a method for preparing a CuZnAlGa-based layered double hydroxide (TLH)-derived catalyst for methanol production from carbon dioxide-rich syngas. Using Cu, Zn, Al, and Ga metal salts as precursors, Na₂CO₃ and NaOH as precipitants, and a mixed alcohol-water solution as an auxiliary solvent, co-precipitation is performed under controlled temperature and pH to obtain a LDH-like catalyst precursor. After high-temperature calcination and in-situ reduction in a hydrogen atmosphere, a layered framework structure of Cu nanoparticles immobilized by oxides is obtained. The LDH-like structure provides lattice confinement, preventing Cu particle aggregation, and the interaction between Cu and the oxides enhances the catalyst surface's adsorption capacity for CO and CO₂, thereby improving the activity and stability of methanol production from carbon dioxide-rich syngas.

The invention relates to the technical field of catalyst materials, and particularly discloses a high-stability hydrogenation catalyst and a preparation method thereof. The invention relates to a preparation method of a high-stability hydrogenation catalyst, which comprises the following steps: preparing a hollow porous microsphere as an inner core from amino-terminated hyperbranched polyaryletherketone and polyvinyl alcohol, and then coating the porous microsphere with a mesoporous silicon dioxide intermediate layer by a sol-gel method; and finally, forming an Mg-Al hydrotalcite layer on the outermost side through a coprecipitation method, dipping and modifying with La (NO3) 3 and Ce (NO3) 3 solutions to obtain a catalyst carrier, dipping the catalyst carrier in an active metal dipping solution, and drying to obtain the catalyst. The high-stability hydrogenation catalyst provided by the invention has excellent mechanical properties and more reaction active sites, has high catalytic activity and catalytic efficiency, and is relatively long in catalytic life.

The invention relates to the technical field of sealing strips, in particular to an anti-aging ethylene propylene diene monomer rubber sealing strip and a preparation method thereof. Comprising the following components in parts by weight: 150-180 parts of ethylene propylene diene monomer, 60-90 parts of carbon black, 8-12 parts of white carbon black, 3-8 parts of a peroxide vulcanizing agent, 6-12 parts of zinc oxide, 12-16 parts of magnesium-aluminum hydrotalcite, 10-18 parts of a plasticizer, 1-3 parts of a crosslinking aid, 1-3 parts of calcium stearate, 1-3 parts of an anti-aging agent and 1-3 parts of a silane coupling agent. The anti-aging agent is a mixture of an anti-aging agent AN245 and an anti-aging agent MBZ. By adding the anti-aging agent, the aging resistance of the ethylene propylene diene monomer can be remarkably improved by inhibiting oxidation and delaying the aging process, a high-crosslinking-density three-dimensional network is formed through the peroxide vulcanizing agent, breakage of molecular chains at high temperature is reduced, thermal aging is delayed, and the ethylene propylene diene monomer sealing strip with excellent aging resistance is prepared.

Clean version of Abstract A catalyst and anode for hydrogen production by electrolysis as well as a preparation method, activation method and use thereof are provided. The anode for hydrogen production by electrolysis includes a catalyst which is nickel iron barium hydrotalcite with a nano hexagonal sheet structure and a thickness of 100-200 nm. The catalyst can be prepared by a one-step solvothermal reaction method. Alkaline-earth metal ions are evenly doped in the nickel iron barium hydrotalcite and are in atomic level dispersion, so that the anode for hydrogen production by electrolysis based on the catalyst, when being applied to a process for hydrogen production by electrolysis of an aqueous solution containing chlorine ions, not only can maintain good catalytic performance, but also has greatly improved chlorine ion corrosion resistance, leading to significant improvement of working stability and service life.

The invention discloses a selective desiliconization method for alkaline vanadium liquid. According to the process, magnesium-aluminum hydrotalcite prepared in advance is introduced into the alkaline vanadium liquid, the pH does not need to be regulated and controlled, silicon can be selectively adsorbed, desilicication slag is desorbed and then recycled as a desilicication agent, and a sodium silicate-containing solution can be used for preparing a water glass product. According to the method for deeply adsorbing silicon in the alkaline vanadium liquid by adopting the magnesium-aluminum hydrotalcite, various conditions of an existing process are not greatly changed, disturbance to existing industrial production is small, meanwhile, the problems that the desilicication limit of the alkaline vanadium liquid is insufficient and vanadium loss is high at present can be solved, silicon in the alkaline vanadium liquid can be reduced to 30 mg / L or below, and the requirements of vanadium products are met.

The invention relates to a spherical hydrotalcite phase desulfurization adsorbent as well as a preparation method and application thereof, the preparation method comprises the following steps: mixing an iron source, a nickel source and organic carboxylate, and then carrying out hydrothermal carbonization reaction to obtain the spherical hydrotalcite phase desulfurization adsorbent. The nickel source and the iron source are selected as the raw materials, hydroxide radicals of laminates and carbonate ions between the laminates of the prepared hydrotalcite phase desulfurization adsorbent can increase the alkalinity of the surface of the desulfurization adsorbent and improve the adsorption capacity to hydrogen sulfide, and meanwhile, the hydrotalcite phase desulfurization adsorbent can react with hydrogen sulfide in a catalytic oxidation manner, so that the removal efficiency is improved. Organic carboxylate is selected as a hydrothermal auxiliary agent, carboxylate radicals can chelate metal ions through multidentate coordination to form a stable complex, so that the nucleation rate of hydrotalcite is delayed, the particle size uniformity is improved, meanwhile, a carbon coating layer is generated through hydrothermal carbonization, and pores in the carbon coating layer and pores in hydrotalcite can form hierarchical pore channels, so that the composite material is prepared. The mass transfer efficiency is synergistically improved, so that the adsorption capacity of the adsorbent is improved.

The invention discloses an HPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The HPVC power cable protection tube is at least prepared from the following raw materials in parts by weight: 100 parts of high-strength polyvinyl chloride, 35 to 45 parts of epoxy acrylate rubber, 5 to 8 parts of vinyl chloride-g-acrylate copolymer, 8 to 12 parts of epoxidized soybean oil, 3 to 5 parts of calcium-zinc composite stabilizer, 5 to 15 parts of modified hydrotalcite, 0.1 to 0.5 part of beta-diketone, 0.8 to 1.5 parts of calcium stearate and 10 to 20 parts of flame retardant. 12 to 15 parts of modified nano calcium carbonate, 5 to 8 parts of talcum powder, 0.6 to 1.2 parts of antioxidant, 1 to 2 parts of anti-aging agent 4010 and 0.5 to 1.5 parts of ultraviolet light absorber UV531; the modified hydrotalcite is obtained by adding a mixed solution of calcium nitrate and lanthanum nitrate, a sodium hydroxide solution and a sodium bicarbonate solution into a lauryl sodium sulfate solution, mixing and aging, and then carrying out a post-treatment process. The HPVC power cable protection tube prepared by the invention has relatively high strength, good mechanical properties, weather resistance and cold resistance, and long service life.

The invention provides a slow-release corrosion-resistant microcapsule applied to reinforced concrete, the slow-release corrosion-resistant microcapsule comprises a capsule core and a capsule wall, and the capsule core comprises a composite corrosion inhibitor, self-repairing microspheres, nano hydrotalcite and an anti-freezing agent; the capsule wall comprises a three-layer structure including an inner layer film, a middle layer film and an outer layer film. The mass ratio of the capsule core to the capsule wall is 1: (0.3-0.5); and the thickness of the capsule wall is 10-17 microns. A pH triggering inner layer, a dynamic self-repairing middle layer and a hydrophobic protection outer layer are designed through three layers of intelligent response capsule walls, and on-demand release and long-term stability of a corrosion inhibitor are achieved; the crack repairing efficiency is remarkably improved through the synergistic effect of the chemical repairing material and the biological spores in the capsule core; the dynamic cross-linked network endows the capsule wall with self-healing ability, resists physical damage, improves the durability of the concrete, prolongs the service life of the concrete, also can enhance the wear resistance of the concrete, and reduces the wear in the use process.

The invention discloses carbon-based material loaded hydrotalcite synergistically modified composite rubber asphalt which comprises the following components in percentage by mass: asphalt, rubber powder, a dispersing agent, a retarder, carbon-based material loaded hydrotalcite, an antioxidant and a heat stabilizer. The carbon-based material loaded hydrotalcite, the antioxidant and the heat stabilizer are compounded, so that the ultraviolet aging resistance, the oxidation aging resistance and the mechanical strength of the composite rubber asphalt can be remarkably improved, the limitation of a single modified material is effectively overcome, and the service life of an asphalt road is greatly prolonged.

The invention discloses a hydrotalcite precursor calcium-based material as well as a preparation method and application thereof. The method comprises the following steps: taking calcium hydroxide and aluminum hydroxide as a calcium source and an aluminum source, and performing constant-temperature water bath and phase transformation in an alkaline environment created by sodium carbonate to obtain a hydrotalcite precursor material with a layered double hydroxide structure; the preparation method comprises the following steps: performing high-temperature calcination on a hydrotalcite precursor, performing phase transformation on the hydrotalcite precursor to form a composite structure containing active CaO and a mayenite skeleton phase, and introducing oxygen vacancies into the material to improve the COadsorption capacity and cycling stability to obtain the calcium-based material based on hydrotalcite phase transformation modification. The problems of high-temperature sintering and agglomeration of the calcium carbonate calcium-based heat storage material in multiple heat charging and discharging processes can be solved, and the service life of the material is prolonged. Meanwhile, oxygen deficiency is introduced into the material in the phase transformation process, the reaction cycle stability and the thermochemical heat storage efficiency are improved, and the material is suitable for the field of medium-high temperature thermochemical industrial energy storage.

The invention discloses a porous CoFe hydrotalcite nano material as well as a preparation method and application thereof, and relates to the field of nano materials. The porous CoFe hydrotalcite nano-material is of a porous layered double hydroxide nano-structure, and the aperture of the porous CoFe hydrotalcite nano-material ranges from 2 nm to 10 nm. The porous CoFe hydrotalcite nano material is prepared through a microwave hydrothermal synthesis method, the preparation method is simple, easy to operate and environmentally friendly, and industrial production can be achieved. The porous CoFe hydrotalcite nano material prepared by the method is stable in structure, has photocatalytic activity and peroxidase-like activity, can effectively catalyze and generate various reactive oxygen free radicals under the illumination condition, realizes efficient synergistic killing of bacteria, and has a good antibacterial effect.

The invention discloses a high-temperature-resistant flame-retardant CPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The high-temperature-resistant flame-retardant CPVC power cable protection pipe at least comprises the following raw materials in parts by mass: 100 parts of chlorinated polyvinyl chloride; 15 to 25 parts of high impact resistance type MCS resin; 8 to 12 parts of poly (1, 2-propylene glycol adipate); 12 to 20 parts of a sepiolite-methyl methacrylate-butyl acrylate compound; 8-15 parts of aluminum-titanium composite coupling agent modified magnesium-aluminum-lanthanum hydrotalcite; 3-6 parts of a rare earth composite heat stabilizer; 2-4 parts of a processing aid; 0.5 to 1.5 parts of an antioxidant; and 1-2 parts of a lubricant. The prepared high-temperature-resistant flame-retardant CPVC power cable protection pipe has high heat resistance, high flame retardance and high impact resistance, and is excellent in comprehensive performance, high in safety and reliability and long in service life.

The invention discloses an efficient treatment process for salt-containing industrial wastewater, and relates to the technical field of wastewater treatment. Salt-containing industrial wastewater sequentially passes through an adjusting tank, a silicon and hardness removal unit, a biochemical unit, a secondary sedimentation tank, a fluorine removal unit, a filter unit, a catalytic ozonation unit, a moving bed bio-membrane reactor treatment unit, a powder carbon sedimentation unit and an ultrafiltration-reverse osmosis double-membrane unit to be treated, produced water is recycled, and concentrated water enters an evaporation and concentration unit; the silicon removal and hardness removal unit is used for treating the wastewater by adding a flocculating agent and a composite coagulant aid; the flocculating agent is a chitosan-based flocculating agent, and the addition amount of the flocculating agent is 10 to 20 mg / L; the composite coagulant aid is composed of a magnesium-aluminum hydrotalcite coagulant aid and alginic acid-silicate hybrid microgel according to the mass ratio of 2: (1-4), and the addition amount of the composite coagulant aid is 5-15 mg / L. The treatment effect of the salt-containing industrial wastewater is remarkably improved.

The invention relates to the technical field of corrosion-resistant coatings, and discloses a preparation method of a 6063 aluminum alloy self-sealing micro-arc oxidation ceramic film layer. Comprising the following operation steps that 1, 6063 aluminum alloy is sequentially subjected to oil removal, acid pickling, washing and drying, and prefabricated 6063 aluminum alloy is obtained; 2, the prefabricated 6063 aluminum alloy serves as an anode, a stainless steel container with a cooling system serves as a cathode, the prefabricated 6063 aluminum alloy and the stainless steel container are immersed in the electrolyte, a constant-current mode is adopted, micro-arc oxidation is conducted for 15-25 min, and a self-sealing micro-arc oxidation ceramic film layer test piece is obtained; 3, (1) carrying out hydrothermal treatment on the self-sealing micro-arc oxidation ceramic film layer test piece and carbonate precursor hydrotalcite at 115-120 DEG C for 20-24 hours to obtain a sample containing an LDH coating; and (2) putting a sample containing the LDH coating into the modified hydroxyquinoline solution, soaking at 40-50 DEG C for 3-4 hours, taking out and drying to obtain a product.

The invention relates to a method for relieving soil salinization through combination of agriculture and forestry solid waste and hydrotalcite and application, and belongs to the technical field of soil improvement. The method comprises the following steps: stripping surface saline-alkali soil, crushing agriculture and forestry solid wastes, spreading the crushed agriculture and forestry solid wastes on the land to form a biomass layer, mixing hydrotalcite powder roasted at a high temperature with the stripped soil, covering the biomass layer with the mixture, and finally flattening and sprinkling water to moisten the soil. According to the invention, rising of soil capillary water is blocked through the biomass layer, salt accumulation is reduced, and meanwhile, the soil salinization degree is reduced by utilizing adsorption and ion exchange effects of hydrotalcite. In addition, the agriculture and forestry solid wastes are decayed to generate organic acid, salt is fixed through chelation, and the soil structure is improved. According to the method, soil salinization can be effectively relieved, the air permeability and the water permeability of the soil can be improved, a good environment is provided for crop growth, the crop yield is remarkably increased, the improvement period is short, the application range is wide, and economic benefits are remarkable.

The invention relates to the technical field of saline-alkali soil improvement, in particular to a compound conditioner for treating sulfate type saline-alkali soil and application of the compound conditioner. The compound conditioner is formed by compounding hydrotalcite, acidic zeolite and humic acid; wherein the hydrotalcite is nitrate intercalated MgAl-LDH or MgFe-LDH, and the molar ratio of divalent metal ions to trivalent metal ions of the hydrotalcite is (2: 1)-(4: 1); the acidic zeolite is clinoptilolite treated by a nitric acid solution; the humic acid is mineral source humic acid, and the purity of the humic acid is greater than 80%. The compound conditioner disclosed by the invention can mineralize Na < + > and SO4 < 2-> which are too high in content in saline-alkali soil, reduce the salt content and pH and prevent plants from osmotic stress and alkaline toxicity; the content of nitrate nitrogen and organic matters in soil is increased, and nutrient substances are provided for plants; the soil structure is improved, the water-retaining property and the air permeability are enhanced, the soil bulk density is reduced, and plant germination and root growth are facilitated.

The invention belongs to the field of thickening agents, and particularly relates to a multi-component copolymerization thickening agent for fracturing and a preparation method of the multi-component copolymerization thickening agent for fracturing. The preparation method comprises the following steps: reacting acryloyl chloride with 4-(p-hydroxyphenyl)-2-butanol to prepare a phenyl-containing monomer; copolymerizing the modified hydrotalcite, a phenyl-containing monomer, a matrix and a functional monomer to obtain a composite polymer; and drying and crushing the composite polymer to obtain the multi-component copolymerization thickening agent for fracturing. The thickening property and the salt resistance of the multi-component copolymerized thickening agent for fracturing are obviously improved, and the multi-component copolymerized thickening agent for fracturing is high in stability at high temperature and under mechanical shearing.

The present invention provides a silica / hydrotalcite composite slow-release fertilizer and a preparation method thereof, comprising the following steps: uniformly mixing amorphous silica, a divalent metal salt, a trivalent metal salt, and water to obtain a mixed solution; subjecting the mixed solution to a hydrothermal reaction, followed by filtering, washing, and drying to obtain a silica / hydrotalcite nanocomposite material; calcining the silica / hydrotalcite nanocomposite material to obtain a silica / metal oxide nanocomposite material; and loading inorganic and organic fertilizers onto the silica / metal oxide nanocomposite material to obtain a silica / hydrotalcite composite slow-release fertilizer. This preparation method is simple, highly feasible, low-cost, and easily scalable for industrial production. The layered and pore-channel structure of the silica / hydrotalcite nanocomposite material effectively provides ample space for the loading of nutrients, thereby improving the slow-release efficiency of nutrients in the fertilizer, increasing nutrient utilization efficiency, reducing fertilization frequency, and minimizing potential environmental impacts.

The invention discloses a rare-earth flame-retardant heat stabilizer for a PVC (polyvinyl chloride) sheet, the PVC sheet and a preparation method of the rare-earth flame-retardant heat stabilizer. The heat stabilizer takes the sodium phytate modified magnesium-aluminum-lanthanum rare earth hydrotalcite as a main component, has the functions of heat stability and flame retardance, and takes industrial inorganic solid wastes such as the fly ash and the rare earth smelting waste residues as inorganic fillers, so that a synergistic effect is formed, and the overall heat stability and flame retardance of a composite system are improved. The prepared rare earth flame-retardant heat stabilizer can be efficiently applied to preparation of PVC sheets, endows the sheets with good heat stability, flame retardance and mechanical properties, and meets the safety and performance requirements in the fields of indoor decoration, building materials, floor covering and the like. And meanwhile, the prepared environment-friendly PVC sheet is beneficial to realizing resource regeneration and comprehensive utilization of industrial solid wastes, and the problems of land occupation, environmental pollution and the like caused by current solid waste hoarding are effectively relieved.

The invention relates to the technical field of solid waste resource utilization, in particular to aluminum-based hydrotalcite synthesized through solid waste coal gangue in-situ crystallization and a preparation method and application of the aluminum-based hydrotalcite. The preparation method comprises the following steps: (1) mixing coal gangue with acid and water, stirring at 80-95 DEG C for 0.5-3 hours to remove impurities, filtering, washing and drying to obtain impurity-removed coal gangue; (2) roasting the impurity-removed coal gangue at 600-850 DEG C for 0.5-5 hours to obtain roasted coal gangue microspheres; and (3) mixing and reacting the roasted coal gangue microspheres with calcium salt / magnesium salt, acid and water, dripping alkali to adjust the pH value to be 7-9, aging, strengthening the phase seed crystal, dripping alkali to adjust the pH value to be 10-12, crystallizing at 100-150 DEG C for 12-72 hours, and post-treating to obtain the product. According to the method, coal gangue is used as an aluminum source, the crystallinity of aluminum-based hydrotalcite is improved, the cost is reduced, and solid waste recycling is achieved. The product can be used for flue gas desulfurization or used as an FCC sulfur transfer agent, has excellent desulfurization and sulfur transfer performance, and has a wide application prospect.

The invention discloses a double-sided flame-retardant aluminum foil reinforced composite film and a preparation method thereof, and relates to the technical field of reinforced aluminum foil veneering. Glass fiber gridding cloth is used as a base material, flame-retardant pressure-sensitive adhesive is coated on two sides of the base material, the glass fiber gridding cloth is covered with an equal-area composite film, and the composite film is formed by coating the flame-retardant pressure-sensitive adhesive on one side of an aluminum foil and compounding an equal-area carbon fiber film. The flame-retardant pressure-sensitive adhesive disclosed by the invention is prepared from the following components in parts by weight: 8 to 12 parts of alkenyl starch, 25 to 35 parts of functional monomer, 10 to 14 parts of hydroxyl silicone oil, 10 to 20 parts of isocyanate ethyl acrylate, 25 to 35 parts of acrylic acid, 0.2 to 1 part of initiator, 3 to 10 parts of hydrotalcite and 3 to 10 parts of magnesium hydroxide. According to the flame-retardant pressure-sensitive adhesive and the preparation method thereof, the flame-retardant pressure-sensitive adhesive with excellent flame retardance, adhesion and holding power can be prepared by properly adjusting the dosage of the pressure-sensitive adhesive, and the flame-retardant pressure-sensitive adhesive can be prepared without any solvent and can be combined with an aluminum foil, glass fiber gridding cloth and a carbon fiber film to further prepare a final product.

The invention discloses a preparation method and application of a modified hydrotalcite-like compound loaded nano zero-valent iron composite material, and relates to the technical field of wastewater treatment. According to the specific technical scheme, the preparation method comprises the following steps: preparing nano silicon dioxide modified hydrotalcite-like compound (SiLDH) by adopting a coprecipitation method; the preparation method comprises the following steps: uniformly mixing SiLDH and a FeSO4. 7H2O solution in an ultrasonic manner, loading nano zero-valent iron (nZVI) on the SiLDH by adopting a NaBH4 reduction method under an anoxic condition, magnetically collecting and washing a black solid after the reaction is completed, and performing surface functionalization modification on the black solid by using glycine to obtain the glycine functionalization modified hydrotalcite loaded nano zero-valent iron composite material (Gly-SiLDH (at) nZVI). SiLDH with a large specific surface area is used as a carrier of nZVI, and glycine functionalization is used as a material surface to introduce an additional active site for adsorbing nitrate, so that the problem that nZVI is easy to agglomerate is solved, secondary pollution caused by metal modification is avoided, and the nitrate removal efficiency is greatly improved.

The invention belongs to the technical field of photovoltaic packaging adhesive films, and particularly relates to a high-temperature-resistant and high-weather-resistant EVA packaging adhesive film for a photovoltaic module and a preparation method of the high-temperature-resistant and high-weather-resistant EVA packaging adhesive film. And / or granulating the silicon dioxide master batch; and hydrotalcite master batch granulation: modifying nano hydrotalcite with a silane coupling agent or stearic acid, then performing drying treatment, premixing with EVA particles according to a mass ratio of (10-30): (70-90), then blending with the EVA particles, extruding at 120-150 DEG C, performing air-drying granulation, and shearing to obtain the hydrotalcite master batch. Uniformly mixing the EVA particles with the high-temperature-resistant master batch and the auxiliary agent, extruding and mixing at 110-120 DEG C, casting, knurling and cooling to obtain the EVA packaging adhesive film; wherein the high-temperature-resistant master batch comprises hydrotalcite master batch, aluminum oxide master batch and / or silicon dioxide master batch.

The invention relates to the field of flame retardants, and particularly discloses a flame retardant, a preparation method thereof and application of the flame retardant in polyvinyl chloride. The flame retardant is prepared from the following raw materials in parts by weight: 2.8 to 3.6 parts of carboxymethyl chitosan microcapsules, 2.5 to 4 parts of hydroxyapatite coated aluminum magnesium hydrotalcite, 3.5 to 4.5 parts of tricresyl phosphate, 0.7 to 0.9 part of expansible graphite and 3 to 5 parts of polyvinyl butyral. The capsule core of the carboxymethyl chitosan microcapsule is magnesium hydroxide loaded bismuth stannate, the capsule wall of the carboxymethyl chitosan microcapsule is carboxymethyl chitosan, and the mass ratio of the carboxymethyl chitosan to the magnesium hydroxide loaded bismuth stannate is (4-5): 1. The flame retardant can be used for polyvinyl chloride and has the advantages of being good in flame retardant and smoke suppression effect and capable of effectively improving the mechanical strength of PVC.

The invention discloses a preparation method and application of a hydrotalcite-like compound derivative magnesium-aluminum composite oxide with a coral spherical structure, magnesium nitrate is taken as a magnesium source, aluminum nitrate is taken as an aluminum source, a proper amount of citric acid and urea are introduced, and under the thermal action of an alcohol-water mixed solvent, a citric acid intercalated hydrotalcite-like compound is obtained in one pot; and further roasting to obtain the derived magnesium-aluminum composite oxide. The magnesium-aluminum composite oxide has a unique coral spherical structure, is endowed with a large specific surface area and a developed pore structure, contains rich alkalescence and moderately strong alkaline sites and oxygen vacancies, shows excellent activity and stability in a high-concentration COS system, and is suitable for being used as a catalyst for a COS hydrolysis reaction.

The invention relates to the technical field of catalysts, and provides a catalyst and a preparation method thereof, and an application of the catalyst in carbon dioxide-based degradable plastics, the catalyst is a supported catalyst, and comprises a carrier and an active component; the carrier comprises ternary hydrotalcite, and the active component comprises double metal cyanide and a rare earth yttrium complex; the raw material of the double metal cyanide comprises a cyano coordination compound; the cyano coordination compound comprises potassium hexacyanomanganate and / or potassium hexacyanocobaltate. According to the technical scheme, the problems of low yield and more byproducts when the catalyst is used for catalyzing and preparing the carbon dioxide-based degradable plastic in the related technology are solved.

The invention discloses a catalyst for preparing cyclohexanone by cyclohexanol dehydrogenation coupled phenol hydrogenation, the catalyst has a composite metal hydrotalcite structure, the metal components comprise ruthenium, magnesium and aluminum, the metal components are uniformly dispersed in hydrotalcite, and the ruthenium, the magnesium and the aluminum respectively account for 1-5wt%, 10-30wt% and 1-10wt% of the total mass of the catalyst. The acid-base property, the specific surface area and the pore structure of the catalyst are optimized by adjusting the ratio of magnesium to aluminum, so that the dispersion of ruthenium is improved, the interaction between ruthenium and a hydrotalcite carrier is increased, and the synergistic effect of all the element components enables active centers in cyclohexanol dehydrogenation, hydrogen transfer and phenol hydrogenation processes to be efficiently combined together, so that the catalytic activity of the catalyst is improved. Rich alkaline sites are generated in the catalyst, the dehydration side reaction of cyclohexanol can be effectively inhibited, meanwhile, the selectivity of cyclohexanone prepared through phenol hydrogenation is improved, it is ensured that the phenol hydrogenation reaction and the cyclohexanol dehydrogenation reaction can be effectively coupled, and cyclohexanone is efficiently prepared.

The invention relates to the technical field of cables, and provides a high-weather-resistance power cable. The high-weather-resistant power cable comprises a cable core and an outer sheath, the outer sheath is prepared from the following raw materials in parts by weight: 40 to 50 parts of low-density polyethylene, 25 to 35 parts of ethylene-vinyl acetate copolymer, 20 to 30 parts of ethylene propylene diene monomer, 10 to 12 parts of maleic anhydride grafted ethylene-vinyl acetate copolymer, 16 to 20 parts of ZrO2 coated modified hydrotalcite, 15 to 20 parts of magnesium hydroxide, 4 to 6 parts of silane coupling agent, 2 to 3 parts of dicumyl peroxide and 3 to 5 parts of zinc oxide; 6 to 10 parts of conductive carbon black, 0.8 to 1 part of antioxidant and 1 to 1.5 parts of zinc stearate. According to the cable prepared in the invention, the protection performance, the service life and the safety of an existing high-weather-resistance power cable under extreme weather conditions are improved, and the mechanical property of the cable is also improved.

The invention relates to the technical field of thermal transfer printing ink, in particular to anti-migration high-stability thermal transfer printing ink as well as a preparation process and application thereof. The anti-migration high-stability heat transfer printing ink is obtained by uniformly mixing the water-based acrylic resin, the pigment, the defoaming agent, the flatting agent, the thickening agent and the epoxy modified organic silicon resin, then adding the modified hydrotalcite and the kaolin, and uniformly mixing. The anti-migration high-stability heat transfer printing ink is prepared from the following components in parts by weight: 80 to 100 parts of waterborne acrylic resin, 10 to 20 parts of epoxy modified organic silicon resin, 20 to 30 parts of pigment, 10 to 20 parts of modified hydrotalcite, 5 to 8 parts of kaolin, 1 to 3 parts of flatting agent, 2 to 4 parts of defoaming agent and 1 to 3 parts of thickening agent. The anti-migration high-stability thermal transfer printing ink prepared by the invention has relatively high adhesive force and relatively low mobility, and can be stably attached to the surface of a base material.