818 results about "Adipate" patented technology

The invention belongs to the field of paper products, and particularly relates to a heat-sealing coating composition for paper products and application of the heat-sealing coating composition, the coating composition comprises a component A, a component B, a component C and a component D, the component A is one or two of a biomass material with a dendritic or network structure or a cationized biomass material with a dendritic or network structure; the component B is selected from one, two or more of polyhydroxyalkanoate, alkyl ketene dimer, polyglycolide, polylactide, copolymer of butylene adipate and butylene terephthalate, cellulose ester and cellulose ether; and the component C is selected from one, two or more of thermoplastic cellulose and derivatives thereof, thermoplastic starch, rosin, cardanol-based epoxy resin, epoxidized soybean oil, epoxidized castor oil, tannic acid and malic acid. The coating composition is simple in preparation process and easy to industrialize, a target mixture can be obtained through physical blending, and the coating composition is low in production cost, energy-saving and environment-friendly.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention discloses a PBAT (poly (butylene adipate-co-terephthalate)) composite material containing nano encapsulation enzyme as well as a preparation method and application thereof. The PBAT composite material is prepared from the following components in percentage by mass: 50 to 90 parts of PBAT resin, 0 to 40 parts of filler and 0.01 to 20 parts of nano encapsulation enzyme. The preparation method comprises the following steps: firstly synthesizing the nano encapsulation enzyme, and then mixing the nano encapsulation enzyme, the PBAT resin and the filler, extruding, and carrying out hot press molding or curtain coating and film blowing. The method is characterized in that 1) the nano encapsulated enzyme has more excellent thermal stability than other immobilized enzymes, and the biological activity of the enzyme can be effectively maintained after high-temperature heat treatment; and 2) as the biological activity of the enzyme is effectively reserved, the PBAT composite material containing the nano encapsulated enzyme has higher environmental degradation speed than pure PBAT or a PBAT composite material containing free enzyme, and the environmental degradation speed can be reflected in various conditions such as aqueous solution and industrial compost.

The invention discloses feruloyl esterase fermentation preparation and application of feruloyl esterase in polyester plastic degradation, and belongs to the field of environmental science. According to the method, feruloyl esterase FAE4 derived from Anerocephalum thermophilum is prepared through fermentation, and is compounded with polyester degrading enzymes which are different in source and are used for degrading polyester plastic oligomers, so that a compound reaction system which remarkably improves the degradation efficiency of poly (butylene adipate-co-terephthalate) or poly (butylene adipate-co-terephthalate) (PBAT) and the content proportion of a final product is obtained; good industrial prospects are realized.

Disclosed in the present invention are a high-strength polylactic acid material, a preparation method therefor, and use thereof, belonging to the technical field of macromolecular materials. The high-strength polylactic acid material comprises the following components in parts by weight: 80-90 parts of polylactic acid, 10-20 parts of polybutylene adipate terephthalate, 1-5 parts of a nucleating agent, and 2-5 parts of a compatibilizing agent. The mesh number of the nucleating agent is 1500-2500 mesh; the compatibilizing agent is polycaprolactone, and the intrinsic viscosity thereof is 1.0-3.0 dL / g. The present invention lowers the melting temperature and shortens the melting time of PLA and PBAT, reduces the negative impact of polymer degradation and aging on mechanical properties, produces a heterogeneous nucleation effect, and performs the function of a crystallization nucleus in the cooling crystallization stage, improving crystallization speed and crystallinity, while causing the crystalline phase structure to tend toward a spherulitic state, improving the tensile strength of the polylactic acid material.

The invention relates to the technical field of biodegradable materials, and particularly discloses a BBM-added bamboo powder biodegradable material and application thereof in beer bottles. The BBM-added bamboo powder biodegradable material is prepared from the following raw materials in parts by mass: 10 to 20 parts of poly (butylene succinate), 10 to 30 parts of poly (butylene adipate-co-terephthalate), 10 to 20 parts of bamboo powder, 1 to 3 parts of dopamine hydrochloride, 0.1 to 0.5 part of n-butylamine, 1 to 2 parts of hexadecyl trimethyl ammonium bromide, 1 to 5 parts of tetraethyl orthosilicate and 1 to 2 parts of tetrabutyl titanate. 1-2 parts of 3-aminopropyltriethoxysilane, 1-2 parts of an antioxidant and 1-2 parts of a plasticizer. The BBM obtained by the invention has excellent mechanical properties, improves the anti-ultraviolet intensity of a degradable material to a certain extent, and has very good biodegradability.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention relates to the technical field of packaging bags, and discloses a moisture-proof medical packaging bag material and a preparation method thereof. The moisture-proof medical packaging bag material comprises a paper layer and a plastic layer, the paper layer comprises modified kraft paper, and the plastic layer comprises the following raw materials in parts by weight: 70-100 parts of polybutylene terephthalate adipate, 30-50 parts of polypropylene carbonate, 5-7 parts of modified mica and 1.5-3 parts of cellulose acetate oleate. The moisture-proof medical packaging bag material prepared by the invention has good water resistance and mechanical properties, also has good degradability, and has a good application prospect.

The invention discloses a preparation method of a completely biodegradable dustproof net based on modified bamboo powder, and belongs to the technical field of biodegradable new materials. The formula comprises the following components in parts by weight: 50-70 parts of poly (butylene adipate-co-terephthalate), 10-40 parts of bamboo powder, 0.1-2 parts of a silane coupling agent, 0.1-1 part of a surfactant, 0.1-1 part of an anti-blocking agent, 0.1-1 part of an antioxidant and 0.1-1 part of an ultraviolet light absorber. The dust screen prepared by the invention not only has biodegradability, but also has the characteristics of being green and environment-friendly by adopting the bio-based material bamboo powder. Meanwhile, in order to realize good combination of the bamboo powder and matrix plastic poly (butylene adipate-co-terephthalate), a silane coupling agent capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a chemical reaction and a surfactant capable of combining the bamboo powder and the matrix plastic poly (butylene adipate-co-terephthalate) through a physical effect are sequentially adopted for composite modification of the bamboo powder; the dispersity of the bamboo powder and the compatibility of the bamboo powder and poly (butylene adipate-co-terephthalate) are effectively improved, and the prepared dustproof net has good mechanical properties.

The invention belongs to the technical field of electrode foil formation treatment, and particularly relates to an electrode foil and a preparation method thereof and an aluminum electrolytic capacitor, the preparation method of the electrode foil comprises the steps of performing multi-stage formation treatment on a corrosion foil, the number of stages of the formation treatment is at least two, and the formation treatment at least comprises first-stage formation and second-stage formation, first heat treatment is carried out after the second-stage formation; a formation liquid used in the second-stage formation is a mixed solution containing adipate and monopotassium phosphate. According to the preparation method provided by the invention, the formation liquid used in secondary formation is the mixed solution containing adipate and monopotassium phosphate, the limitation of traditional single formation liquid is broken through, and synchronous optimization of the structure, hydration resistance and electrochemical performance of the aluminum oxide film is realized through multi-stage formation, mixed solution synergy and the synergistic effect of formation and heat treatment; meanwhile, production cost is reduced, and environmental load is relieved.

The present application relates to the technical field of bio-based polymer material, and more particularly to a full bio-based PBAT-PLA copolymer, a preparation method and an application thereof, which is prepared by melt mixing bio-based polybutylene adipate terephthalate, bio-based polylactic acid and bio-based multi-epoxy chain extender through a twin-screw extruder, so that the tensile strength of the full bio-based PBAT-PLA copolymer is 31.5-44.3 MPa, and the elongation at break is 85-498%. The bio-based multi-epoxy chain extender prepared by specific selection can simultaneously improve the tensile strength and elongation at break of the full bio-based PBAT-PLA copolymer, and solve the technical problems of poor compatibility of traditional bio-based polylactic acid and non-bio-based polybutylene adipate terephthalate, and the technical problem that the addition of existing chain extenders cannot simultaneously improve the tensile strength and elongation at break of the copolymer.

The invention relates to a thermoplastic composition comprising A) polybutylene adipate terephthalate (PBAT), B) CaCO3 powder, C) one or more citric acid triesters, and optionally D) optional auxiliary components, wherein the components A) to D) add up to 100 weight-%. The invention further relates to article comprising such compositions, a stone paper comprising a sheet structure consisting of the thermoplastic composition, and a method for the manufacture of such stone paper.

The invention discloses a preparation method of an environment-friendly degradable single-sided perspective sticker, and belongs to the technical field of modified nano materials. The method comprises the following steps: (1) preparation of a multi-layer composite structure: mixing polylactic acid and poly (butylene succinate), adding nano-montmorillonite and a surface modifier, and carrying out melt blending to form a first-layer melt; stirring poly (butylene adipate-co-terephthalate) and fluorescent carbon nanodots to form a second layer of melt; the first layer, the pressure-sensitive adhesive layer and the second layer are co-extruded and compounded to form a film blank. And (2) construction of the nano-film: biaxially stretching the film blank, imprinting a micropore array, dipping in the silver nanoparticle suspension, and drying to obtain the nano-film. And (3) coating functionalization treatment: immersing into a fluorine-containing nano coating solution, and curing. And (4) post-treatment: carrying out secondary curing. The obtained single-sided perspective sticker is suitable for the fields of buildings, vehicle privacy films and the like, and solves the problems of serious pollution and slow degradation of a traditional sticker.

The invention discloses a degradable express bag material and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a degradable express bag material. The composite material is prepared from the following raw materials in parts by weight: 40 to 50 parts of poly (butylene adipate-co-terephthalate), 20 to 30 parts of polycaprolactone, 5 to 8 parts of modified bamboo fiber, 2 to 4 parts of modified nano montmorillonite, 3 to 6 parts of tributyl citrate, 0.1 to 0.3 part of antioxidant 1076, 1 to 2 parts of iron dithiocarbamate master batch, 2 to 3 parts of maleic anhydride grafted poly (butylene adipate-co-terephthalate) and 0.3 to 0.6 part of zinc stearate. 0.1 to 0.3 part of baicalein; and 1 to 3 parts of chitosan-sorbitol composite coating liquid. According to the degradable express bag material, poly (butylene adipate-co-terephthalate) and polycaprolactone are used as main degradable raw materials, modified bamboo fibers and modified nano-montmorillonite are matched to enhance the mechanical property, an antioxidant 1076, baicalein and the like are added to guarantee the stability and functionality, temperature is accurately controlled in the preparation process, multi-step modification is adopted for optimizing component combination, and the degradable express bag material is prepared. The performance is improved through the composite coating, degradability is achieved, and good usability is achieved.

The biodegradable PBAT / bamboo charcoal master batch is prepared from the following raw materials in parts by mass: 100 parts of poly (butylene adipate-co-terephthalate) (PBAT), 20 to 30 parts of poly (butylene succinate), 10 to 30 parts of modified bamboo charcoal powder and 0.2 to 0.4 part of chain extender, the modified bamboo charcoal powder is obtained by sequentially carrying out persulfate treatment, microwave-assisted reaction and grafting agent modification on bamboo charcoal powder, and the grafting agent comprises polybasic acid and an epoxy compound. The bamboo charcoal powder is subjected to grafting modification, so that the interfacial compatibility with the PBAT base material and the matrix dispersity are remarkably improved, and the mechanical property of the composite material is improved. The modifier compounded according to a specific ratio improves the damp-heat aging resistance of the master batch composite material.

The invention belongs to the technical field of fruit and vegetable preservation, and provides a preparation method of a silver nanoparticle / titanium dioxide / polydopamine modified montmorillonite antibacterial agent and application of the antibacterial agent in a copolyester / poly (butylene adipate-succinate)-terephthalate degradable film. The preparation method comprises the following steps: firstly preparing montmorillonite modified by polydopamine, and then mixing the montmorillonite modified by polydopamine with AgNO3 / TiO2 composite sol to prepare the antibacterial agent AgNPs / TiO2 / PMMT. The preparation method comprises the following steps: preparing an antibacterial agent, blending the antibacterial agent with PBTF and PBAT to prepare the antibacterial degradable composite air-conditioning film, and the composite air-conditioning film has antibacterial performance, excellent mechanical performance and air-conditioning performance, and can be applied to fruit and vegetable preservation.

The present invention discloses a method for preparing a modified PHA composite material using a twin-screw extruder and its application. The method is carried out by in-situ melt blending of polyhydroxyalkanoate PHA, polybutylene terephthalate-adipate PBAT, polyvinyl alcohol PVOH and a chain extender in a twin-screw extruder, so that a multifunctional epoxy or isocyanate chain extender reacts with the terminal groups of PHA, PBAT and PVOH molecules to form a partially cross-linked or grafted structure, thereby achieving enhanced compatibility, improved thermal stability and significant improvement in barrier properties. Experiments have shown that the modified PHA composite material obtained by the present invention has high strength, high elongation, excellent water and oxygen barrier properties and biodegradable properties, and meets the stringent requirements for mechanical properties and barrier properties in multiple fields such as food packaging, agricultural mulch and medical consumables. The preparation method of the present invention is simple and efficient, and can be used for large-scale continuous production on existing twin-screw extrusion equipment.

The present disclosure relates to a biodegradable multilayer film comprising stacked on each other in the following order: a) a first outer layer comprising a first polymer selected from the group consisting of poly (butylene adipate-co-terephthalate) (PBAT), poly (butylene succinate) (PBS), poly (butylene succinate-co-adipate) (PBSA), and mixtures thereof; b) a core layer comprising a blend of thermoplastic starch (TPS) and polybutylene adipate terephthalate (PBAT); c) a second outer layer comprising a second polymer selected from the group consisting of poly (butylene adipate-co-terephthalate) (PBAT), poly (butylene succinate) (PBS), poly (butylene succinate-co-adipate) (PBSA), and mixtures thereof. The present disclosure also relates to a disposable bag, a bioreactor and a container suitable for mixing, packaging, storing or transporting biopharmaceutical substances, wherein the disposable bag, bioreactor and container comprise the biodegradable multilayer film.

The invention discloses a flame-retardant polyurethane hot melt adhesive and a preparation method thereof, and belongs to the technical field of hot melt adhesives. Comprising the following raw materials in parts by weight: 30-50 parts of polybutylene adipate glycol, 35-55 parts of polypropylene oxide glycol, 25-50 parts of MDI, 6-18 parts of modified dihydric alcohol, 0.1-0.3 part of a catalyst, 3-5 parts of a lubricant and 3-7 parts of an antioxidant. The polyurethane hot melt adhesive is prepared by a two-step method, no solvent is added, and the method is environment-friendly; mDI is selected as isocyanate, so that the hot melt adhesive is endowed with excellent stability and mechanical properties; wherein various groups in modified dihydric alcohol molecules can achieve a synergistic effect, so that the flame retardance, the heat resistance and a certain degree of mechanical properties of the hot melt adhesive are remarkably enhanced, and the hot melt adhesive is stable in performance and not easy to fall off; therefore, the prepared hot melt adhesive is excellent in mechanical property, has stable and efficient flame retardance and heat resistance, is environmentally friendly, and has important application value in the technical field of hot melt adhesives.

The invention provides a method for preparing a high-performance PVA / PBAT (polyvinyl alcohol / poly (butyleneadipate-co-terephthalate)) composite film by blow molding, which comprises the following steps: carrying out swelling plastification modification on polyvinyl alcohol by using an environment-friendly plasticizer to obtain modified polyvinyl alcohol; the preparation method comprises the following steps: modifying polyvinyl alcohol, blending the modified polyvinyl alcohol with a certain proportion of PBAT, carrying out screw extrusion granulation to prepare composite granules, and carrying out extrusion blow molding film formation to prepare the PVA / PBAT composite film. According to the method disclosed by the invention, the specific environment-friendly plasticizer is selected, so that the PBAT is well dispersed in a PVA matrix, the phase domain size of a dispersed phase is less than 1 mu m in a breakthrough manner, and the PVA / PBAT composite film with good mechanical properties is successfully prepared for the first time. The prepared PVA / PBAT composite film has good water resistance and blocking resistance, the application scene of the PVA film in the packaging field can be widened, and the PVA / PBAT composite film has good commercial application prospects.

The invention provides a high-performance thermoplastic starch-based TPS / PBAT blended plastic and a preparation method thereof. The preparation method comprises the following steps: preparing pre-plasticized starch, carrying out melt blending on the obtained pre-plasticized starch TPS, poly (butylene adipate-co-butylene adipate) PBAT, a grafting agent and an initiator, cooling, and drying to obtain a grafting material; and putting the grafted material and a cross-linking agent into an internal mixer for melt blending, cooling and drying to obtain the high-performance thermoplastic starch-based blended plastic TPS / PBAT. The method is suitable for industrial large-scale mass production and recycling treatment, the recycling treatment can be realized by directly adopting plastic processing methods such as an internal mixer and an extruder, and the high-performance thermoplastic starch-based blended plastic can be obtained again under the condition that the molecular chain part is degraded.

The invention discloses environmentally degradable plastic as well as a preparation method and application thereof, and belongs to the technical field of degradable plastic. The degradable modified plastic is prepared from the following raw materials: polylactic acid, poly (butylene terephthalate)-adipate, modified thermoplastic starch, modified cellulose, poly (butylene succinate), epoxidized soybean oil, polyvinyl alcohol, glycerol monolaurate and ethylenediaminetetraacetic acid. Wherein the modified thermoplastic starch is obtained by thermoplastic modification of starch through a plasticizer and modification of castor oil and toluene diisocynate; the modified cellulose is obtained by modifying cellulose acetate with chitosan. By regulating and controlling the types and proportions of the raw materials for preparing the plastic, the plastic with excellent degradation performance and mechanical performance can be obtained, the shopping bag is prepared from the plastic, the loading capacity can be remarkably improved, the plastic is easily degraded by microorganisms in the environment after being discarded, and environmental pollution is avoided.

The invention provides a full-biodegradable composite film and a preparation method thereof. The full composite membrane comprises an outer layer, a middle layer and an inner layer, wherein the outer layer comprises modified calcium carbonate, PLA, PBAT and an epoxy chain extender; the middle layer comprises modified montmorillonite, PLA (polylactic acid), PBAT (poly (butylene adipate-co-terephthalate)), PPC (polypropylene carbonate) and an epoxy chain extender; the inner layer comprises PLA (polylactic acid), PBAT (poly (butylene adipate-co-terephthalate)), an epoxy chain extender and an optional anti-blocking agent. The preparation method of the raw materials of the middle layer comprises the following steps: (i) dividing an epoxy chain extender used by the middle layer into an epoxy chain extender A and an epoxy chain extender B, and mixing PPC, modified montmorillonite and the epoxy chain extender A to prepare a first master batch of the middle layer; (ii) mixing PLA, PBAT and an epoxy chain extender B to prepare a middle-layer second master batch; and (iii) uniformly mixing the middle-layer first master batch and the middle-layer second master batch, extruding and granulating to obtain a middle-layer raw material. The full-biodegradable composite film prepared by the preparation method disclosed by the invention is good in uniformity and quality.

The invention relates to the technical field of anti-yellowing, in particular to anti-yellowing lining cloth with a hot melt coating and a preparation method of the anti-yellowing lining cloth. Composite carbon dots, an anti-yellowing agent and a composite chitosan solution are adopted to prepare finishing liquid for finishing the lining cloth; the preparation method comprises the following steps: selecting furfural and urea as a carbon source and a nitrogen source, performing one-step hydrothermal synthesis to obtain a nitrogen-doped furfural-based carbon dot, and grafting an amino-terminated polyimidazolium salt antibacterial compound to obtain a composite carbon dot; wherein the amino-terminated polyimidazolium salt antibacterial compound is an amino-terminated halogen-free polyimidazolium salt antibacterial compound which is prepared by taking ethylenediamine, butyric acid, glyoxal and formaldehyde as raw materials based on amine-aldehyde polycondensation and has good biocompatibility; the preparation method comprises the following steps: by taking polybutylene adipate, toluene diisocynate and isophorone diisocyanate as main monomers, polypropylene oxide triol as a crosslinking monomer, 2, 2-dimethylolpropionic acid and 4, 4 '-diaminodiphenyl disulfide as chain extenders and composite carbon dots as an end-capping reagent, adding water and emulsifying to obtain the waterborne polyurethane hot melt adhesive.

The invention discloses a silane-crosslinked low-smoke halogen-free flame-retardant oil-resistant polyolefin cable material and a preparation method thereof. The method comprises the following steps: preparing a bio-based polyesteramide toughening phase which is pre-polymerized by castor oil-based polyamide and poly (butylene adipate-co-terephthalate) and is terminated by itaconic anhydride; the preparation method comprises the following steps: self-assembling phytic acid and melamine to wrap ammonium polyphosphate, so as to prepare supramolecular flame-retardant gel powder; the method comprises the following steps: grafting aramid pulp fibers by using a phosphorus-containing silane coupling agent to prepare a reactive liquid crystal reinforced phase; the preparation method comprises the following steps: blending and banburying the components with a hydrogenated styrene-isoprene-styrene block copolymer, an antioxidant and a peroxide cross-linking agent, carrying out dynamic vulcanization and interface bonding, and carrying out extrusion and electron beam irradiation to finally crosslink. An interpenetrating-topology network structure is formed in the prepared cable material, the crosslinking degree is larger than or equal to 82%, and the cable material is rapid in crosslinking, excellent in oil resistance, low in smoke and free of toxicity and is particularly suitable for super high-rise building hanging cables, deep sea exploration cables and new energy automobile liquid cooling cables.

The invention provides a food packaging bag and a preparation method thereof. The food packaging bag comprises the following raw materials in parts by mass: 50 parts of polylactic acid, 50-100 parts of poly (butylene adipate-co-terephthalate), 5-10 parts of a plasticizer and 5-10 parts of a modified filler, wherein the modified filler comprises a multi-arm grafted filler, the end group of each arm is an acyl chloride group, and each arm comprises a polyethylene glycol chain segment. According to the food packaging bag, polylactic acid and poly (butylene adipate-co-terephthalate) are used as main materials, meanwhile, the brittleness of the food packaging bag is further reduced and the flexibility of the food packaging bag is improved by using a plasticizer, and in addition, by adding a modified filler comprising a multi-arm grafted filler, the food packaging bag is more environment-friendly. The multi-arm grafted filler can improve the barrier property of the food packaging bag on the premise of not deteriorating the flexibility of the food packaging bag, so that the obtained food packaging bag has good flexibility and barrier property.

The invention discloses an antibacterial sanitary towel packaging bag and a preparation method thereof. The antibacterial sanitary towel packaging bag comprises a base material layer, an antibacterial layer and a leakage-proof layer. The base material layer is prepared by blending modified polylactic acid, polybutylene adipate and the like and contains a degradation accelerant; the antibacterial layer contains antibacterial peptide-loaded nano montmorillonite, chitosan and the like, and loofah sponge fiber enhances slow release; and the leakage-proof layer is an ethylene-vinyl acetate copolymer and modified silicon dioxide blended film and is provided with breathable micropores. The preparation method comprises the steps of forming the base material layer, coating the antibacterial layer and the like, and process parameters of each layer are accurately controlled. According to the packaging bag, through cooperation of three layers, the bacteriostasis rate of the packaging bag on escherichia coli and staphylococcus aureus in 24 hours is higher than 99%, the degradation rate of the packaging bag in 83 days is higher than 88%, the oxygen permeability is 4.5-5.2 cm < 3 > / (m224h 0.1 MPa), and the packaging bag has the advantages of long-acting antibiosis, air permeability, leakage prevention, environmental protection, degradation and good mechanical properties, and meets the storage and use requirements of sanitary napkins.

The invention relates to the technical field of composite film preparation, in particular to a multi-additive synergistic enhanced degradable packaging composite film and a preparation method thereof, and the multi-additive synergistic enhanced degradable packaging composite film comprises a matrix material group, a barrier system, an anti-hydrolysis system and a stable system; the base material comprises the following components in parts by mass: 25-35 parts of polylactic acid; 15 to 25 parts of poly (butylene adipate / terephthalate); and 8-15 parts of thermoplastic starch. Through multi-dimensional collaborative design of the matrix material, the barrier system, the hydrolysis-resistant system and the stable system, the performance bottleneck of a traditional material is broken through, and the contradiction between brittleness and flexibility is solved through rigid-flexible blending of matrix components; according to the present invention, the uniform dispersion and the interface strengthening of the nano-filler are ensured by using the melt co-extrusion and the directional arrangement technology, and the composite film prepared by using the process has characteristics of excellent degradation rate, high strength, high barrier property and environmental adaptability, can be widely used in the high-end fields of cold chain food and medicine packaging, and solves the problems existing in the traditional technology.