1000 results about "Copolyester" patented technology

A process for chemically recycling waste polyethylene terephthalate (PET) carpet fibers. The process comprises providing a waste carpet fiber composition comprising at least 75 wt % of PET and 6 wt % or less of ash; reacting the waste carpet fiber composition with methanol to produce a depolymerized poly ester mixture comprising polyester oligomers, dimethyl terephthalate (DMT), and ethylene glycol (EG); and recovering the DMT and the EG from the depolymerized polyester mixture.

Disclosed are methods for enhancing recycled polymer materials for use in manufacturing film / sheet products involves obtaining a polymer starting material for recycling, heating it through melt compounding and / or extrusion processes, and incorporating modifiers such as ethylene / acrylate copolymer, ethylene / acrylate / glycidyl methacrylate terpolymer, and ethylene / glycidyl methacrylate copolymer before extrusion. The resulting modified recycled material can substitute for PVC or other virgin polymers in producing extruded film / sheet products or molded goods. This method enables the creation of mono-layer or multi-layer film / sheet products with improved properties, contributing to sustainable and environmentally friendly manufacturing practices.

The invention discloses a process for preparing a polyester fiber fabric by regenerating polyester waste bottle flakes, belongs to the technical field of polyester fiber fabric processing, and aims to solve the technical problem that the moisture absorption and quick drying performance, friction resistance and pilling resistance of the polyester fiber fabric in the prior art need to be further improved. The method comprises the following steps: adding polyester waste bottle flakes into a pulverizer, pulverizing, sieving with a 60-mesh sieve to obtain polyester regenerated powder, and pretreating the polyester regenerated powder to obtain pretreated polyester powder; composite polyester is prepared from modified polysiloxane enhanced copolyester containing nylon 6 and polyvinyl alcohol blocks, and then the porous composite polyester fiber is prepared by taking polyvinyl alcohol as a pore forming agent, so that the moisture absorption and quick drying performance of the polyester fiber fabric is effectively improved, the wearing experience of the polyester fiber fabric is enhanced, and the service life of the polyester fiber fabric is prolonged. The wear-resistant and anti-pilling performance of the polyester fiber fabric is also improved.

The invention relates to the technical field of polyester fibers, and discloses a waterproof antibacterial polyester fiber fabric and a preparation method thereof. A waterproof antibacterial copolyester polymer with a structure similar to that of PET polyester is obtained through esterification condensation polymerization of raw materials such as N, N '-di-Boc-S-methyl isothiourea and dimethyl terephthalate, the structure of the waterproof antibacterial copolyester polymer contains quaternary ammonium salt, guanidyl and a hydrophobic long-chain structure, the waterproof antibacterial copolyester polymer can be uniformly distributed in a polyester fiber matrix, migration of antibacterial groups is avoided, and the antibacterial property of the polyester fiber is improved. The antibacterial performance on bacteria is better exerted; the C-F bond energy is high, fluorine atoms are more easily embedded into a polymer, a channel for water molecules to migrate into a coating film is blocked, a stable protection layer can be formed on the surface of the fiber fabric, fibers are wrapped, moisture is prevented from permeating into the fibers, and therefore the waterproof effect is achieved; meanwhile, the hydrophobic layer also has certain durability and does not lose efficacy after being washed with water for many times.

The invention discloses a recycling method of polyethylene glycol terephthalate (PET). According to the method, organic acid is used as a catalyst for hydrolysis of PET, the organic acid is selected from one or more of adipic acid, lactic acid and glycollic acid, and then hydrolysis products are directly polymerized with additional monomers and polymerization catalysts to prepare the biodegradable copolyester without any separation treatment step. The prepared copolyester has biodegradability, so that the non-degradable PET is converted into the biodegradable copolyester by the recycling method, and the recycling method has important significance for relieving the problem of environmental pollution.

The invention provides a PEF hydrogen bond reinforced modified polyester material and a preparation method thereof, and the preparation method comprises the following steps: blending 2, 5-furandicarboxylic acid and a third monomer hydroxy acid, and copolymerizing under the action of ethylene glycol to synthesize bio-based furan polyester, namely the PEF hydrogen bond reinforced modified polyester material. The introduced hydroxyl is used as a hydrogen bond donor to enhance the PEF copolyester material, so that the interaction strength and the chain stacking density between PEF chains are improved, the toughness, the melt strength and the crystallization rate of PEF can be improved by only adding a small amount of hydroxyl, and the barrier property of PEF copolyester is maintained to be more than 5 times of that of PET (Polyethylene Terephthalate).

The invention discloses a composite degradable modified atmosphere preservative film, preparation and application thereof and a cherry preservation method. The preparation method comprises the following steps: mixing copolyester PBTF, poly (butylene adipate-succinate)-terephthalate and a solvent to obtain a film casting solution, pouring the film, and drying to obtain the composite degradable modified atmosphere preservative film. The preservative film has the characteristics of high CO2 permeability and low O2 permeability, and can inhibit respiration of fruits and vegetables and slow down metabolism of the fruits and vegetables, so that the storage time is prolonged, the composite degradable controlled atmosphere preservative film is heat-sealed into a bag and is used for preserving Dalian cherries, and an excellent preservation effect can be achieved.

The invention relates to the technical field of organic polymers, and discloses a special copolyester for a high-speed stretch film and a preparation method thereof.The special copolyester is prepared from, by mass, 50-60 parts of terephthalic acid, 20-30 parts of ethylene glycol, 5-20 parts of a polymerizable eutectic solvent, 0.02-0.03 part of a catalyst and 0.002-0.003 part of a stabilizer; the copolyester is prepared by polymerizing terephthalic acid, ethylene glycol, the polymerizable eutectic solvent, the catalyst and the stabilizer, and the polymerizable eutectic solvent has relatively high conductivity after polymerization, so that the melt resistivity of the polyester can be improved, and the toughness and transparency of the polyester can be improved; the problems of polyester crystallization and yellowing caused by electrostatic agents such as metal compounds can be avoided; the copolyester is low in melt resistivity, simple and feasible in preparation method and suitable for high-speed film drawing production.

The invention discloses a method for preparing antibacterial and antistatic polyester fibers by regenerating waste polyester, belongs to the technical field of polyester fiber processing, and is used for solving the technical problem that the antistatic performance, moisture absorption performance and antibacterial performance of polyester fibers in the prior art need to be further improved. The method specifically comprises the following steps: crushing waste polyester, performing alcoholysis to prepare an alcoholysis extract, mixing the alcoholysis extract, polytetrahydrofuran ether glycol, 1, 4-butylene glycol and a catalyst under the protection of inert gas, and performing reaction to obtain the polytetrahydrofuran ether glycol / 1, 4-butylene glycol / polytetrahydrofuran ether glycol / 1, 4-butylene glycol / polytetrahydrofuran ether glycol / 1, 4-butylene glycol composite material. According to the invention, the olefin modified silver-loaded montmorillonite and hydroxyethyl methylacrylate reinforced copolyester polyester fiber with a flexible polyether block structure is subjected to padding modification through the reinforcing modifier, so that the breaking strength and the antistatic property of the polyester fiber are effectively improved, and the moisture absorption property and the antibacterial property of the polyester fiber are also improved.

The invention belongs to the technical field of fruit and vegetable preservation, and provides a preparation method of a silver nanoparticle / titanium dioxide / polydopamine modified montmorillonite antibacterial agent and application of the antibacterial agent in a copolyester / poly (butylene adipate-succinate)-terephthalate degradable film. The preparation method comprises the following steps: firstly preparing montmorillonite modified by polydopamine, and then mixing the montmorillonite modified by polydopamine with AgNO3 / TiO2 composite sol to prepare the antibacterial agent AgNPs / TiO2 / PMMT. The preparation method comprises the following steps: preparing an antibacterial agent, blending the antibacterial agent with PBTF and PBAT to prepare the antibacterial degradable composite air-conditioning film, and the composite air-conditioning film has antibacterial performance, excellent mechanical performance and air-conditioning performance, and can be applied to fruit and vegetable preservation.

The invention relates to the technical field of multi-layer copolyester films, and discloses a high-temperature-resistant antistatic multi-layer copolyester film and a preparation method and application thereof, and the multi-layer copolyester film comprises an ABA three-layer structure obtained through melt co-extrusion; the layer A is prepared from the following raw materials in percentage by mass: 5 to 30 percent of anti-blocking agent master batch and the balance of modified copolyester; the raw material of the layer B is modified copolyester; the modified copolyester is prepared from a binary acid mixture, a dihydric alcohol mixture and a catalyst through an esterification reaction and a condensation polymerization reaction; the binary acid mixture comprises furandicarboxylic acid and 2, 2 '-bifuran-5, 5'-dicarboxylic acid, and the dihydric alcohol mixture comprises ethylene glycol, 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol and 1, 4-cyclohexanedimethanol. According to the invention, the modified copolyester is used as a main raw material, and the film is endowed with good temperature resistance in a copolymerization modification manner, and has stable and lasting antistatic performance.

The invention discloses a full bio-based copolymer based on a citric acid bicyclic monomer, a preparation method and an application, and belongs to the technical field of material synthesis, citric acid-derived bicyclic OPD diol and OPBMC diester are synthesized through oxidation reduction and transesterification, and then 1, 4-butanediol is partially replaced with OPD or 2, 4-butanediol is partially replaced with OPBMC through melt phase polycondensation reaction. Two series of random copolyester PBxOyF copolymer and PBOmFn copolymer of the PBF are prepared by adding 2, 5-dimethyl furandicarboxylate into the PBF, and then adding the PBxOyF copolymer and the PBOmFn copolymer into the PBF. According to the full-bio-based copolymer based on the citric acid bicyclic monomer, the preparation method and the application, the citric acid bicyclic monomer obviously improves the glass transition temperature and shows good mechanical properties; therefore, the bicyclic monomer based on citric acid has huge potential in the aspect of synthesizing novel bio-based copolyester with expected thermodynamic properties, and is expected to further expand the application range of the 2.5 furandicarboxylic acid-based polyester.

The invention relates to the technical field of polyester preparation, and provides isosorbide modified polyethylene glycol terephthalate-1, 4-cyclohexanedimethanol ester and a preparation method of the isosorbide modified polyethylene glycol terephthalate-1, 4-cyclohexanedimethanol ester. The preparation method comprises the following steps: mixing terephthalic acid, ethylene glycol, 1, 4-cyclohexanedimethanol, isosorbide and a compound catalyst, and sequentially carrying out an esterification reaction and a condensation polymerization reaction to obtain the isosorbide modified polyethylene terephthalate-1, 4-cyclohexanedimethanol. By introducing the isosorbide, the heat resistance and oxygen barrier property of the copolyester are greatly improved, the problems of poor heat resistance and poor oxygen barrier property of the existing PETG material are solved, and the obtained copolyester inherits good mechanical properties, transparency and processability of the PETG material and has a wide application prospect. In addition, the preparation method provided by the invention is simple, mild in condition, stable in product performance and suitable for large-scale production.

Disclosed herein are systems and methods of using a coating solution such as an aromatic copolyester thermoset (ACT) to improve the wear, galling, and corrosion resistances of downhole tools and their sub-components. Aromatic copolyester thermoset may be reinforced with filler material. Further, the aromatic copolyester thermoset reinforced with filler material may be used in a borehole as a composite hollow profile, for example. In some examples, the systems may comprise a substrate for downhole applications coated with an aromatic thermosetting copolyester mixed with polytetrafluoroethylene (PTFE).

A variety of methods and apparatus are disclosed, including, in one embodiment, a downhole tool for use in a borehole, comprising: a mandrel; and a sealing element disposed about the mandrel, wherein the sealing element comprises an aromatic copolyester thermoset (ACT).

The invention discloses high-crystallinity copolyester based on furandicarboxylic acid as well as a preparation method and application of the high-crystallinity copolyester. The structural formula of the high-crystallinity copolyester is as follows: # imgabs0 # R1 is-O (CH2) aO-, R2 is-O (CH2) bO-, a, b, x, y, z and n are integers, a = 2-6, b = 6-12, x = 1-10, y = 1-10, z = 1-10, and n = 20-100; and (x + z): y = 1: 1-1: 10. The present invention also provides a highly crystalline copolyester article made from the highly crystalline copolyester. The high-crystallinity copolyester disclosed by the invention not only has excellent crystallization capacity, relatively high crystallinity, excellent thermal stability and mechanical property, but also has excellent barrier property, and has obvious advantages in various gas barrier aspects compared with PET (Polyethylene Terephthalate) on the market; the material can be widely applied to the fields of high-temperature-resistant materials, express packages, food packages, food tableware and the like.

The invention discloses a composite medical suture and a preparation method thereof, and belongs to the field of biomedicine. In order to solve the problems that an existing medical suture is poor in antibacterial effect and biological safety, the composite medical suture comprises a core layer, a degradation regulation and control layer, a slow release layer and an antibacterial layer which are sequentially arranged from inside to outside; the core layer is prepared from a blend fiber of poly (hydroxybutyrate-hydroxyvalerate) and polycaprolactone-co-polyglycolide; the degradation regulation and control layer comprises a mixture of at least two kinds of polyethylene glycol with different molecular weights; the slow release layer comprises quaternary ammonium salt loaded graphene oxide nanofibers; the antibacterial layer comprises titanium dioxide loaded with silver nanoparticles. Through the synergistic effect of the four layers, the comprehensive optimization of mechanical properties, degradation rate, drug sustained release and antibacterial function is realized; the purposes of improving the slow-release antibacterial performance, reducing damage to the human body, reducing inflammation and the like are achieved, and the antibacterial and degradation effects meet the recovery requirements.

The invention belongs to the technical field of copolymerization modification of degradable polyester, and relates to a depolymerization method and application of polybutylene terephthalate. During depolymerization, polybutylene terephthalate, dimethyl carbonate and dihydric alcohol are mixed and then subjected to a depolymerization reaction, and an intermediate ester is prepared; the dihydric alcohol is dihydric alcohol which does not form a ring with dimethyl carbonate in the depolymerization reaction process; the molar weight of the dimethyl carbonate is 10-30% of the molar weight of a repetitive unit of the polybutylene terephthalate; the sum of the molar weight of a 1, 4-butanediol unit in the polybutylene terephthalate and the molar weight of the added dihydric alcohol is a, the sum of the molar weight of a terephthalic acid unit in the polybutylene terephthalate and the molar weight of the added dimethyl carbonate is b, and the ratio of b to a is (1.2-1.5): 1; during application, the prepared intermediate ester is subjected to transesterification under the condition of negative pressure to obtain the copolyester. The depolymerization method is simple and easy to implement; the depolymerization product can be directly applied.

The invention provides a semi-crystalline transparent multicomponent copolyester and a preparation method thereof, and relates to the technical field of polyester synthesis. The preparation method of the semi-crystalline high-transparency multicomponent copolyester comprises the following steps: esterification reaction: mixing terephthalic acid, ethylene glycol, a branching agent, a modified monomer and a main catalyst, and carrying out esterification reaction to obtain an esterification product; and condensation polymerization: mixing the esterification product with a main catalyst, and carrying out condensation polymerization to obtain the semi-crystalline high-transparency multi-component copolyester, the mixture of the esterification reaction and / or the condensation polymerization reaction comprises a cocatalyst. According to the preparation method disclosed by the invention, polyester is subjected to copolymerization modification with relatively low content of alcohol and / or acid modified monomers to obtain the semi-crystalline multicomponent copolyester, and the semi-crystalline multicomponent copolyester is endowed with the advantages of high transparency, high hue, low cost, easiness in processing and the like.

The present invention provides biodegradable composite materials comprising: a) a polymeric matrix comprising about 50-80% by weight of a cellulose alkanoate; about 0.1 to 10% by weight of a polyester, wherein the polyester is an aliphatic-aromatic copolyester, an aliphatic polyester, or a mixture of an aliphatic polyester and thermoplastic starch; about 10 to 20% by weight of a plasticizer; about 10 to 20% by weight of a flame-retardant component; optionally an inorganic filler; and b) a fibrous reinforcement material.

The invention belongs to the technical field of copolymerization modification of degradable polyester, and discloses a preparation method of tertiary amine modified rapidly degradable polyester, which comprises the following steps: in the presence of a catalyst and an auxiliary agent, carrying out esterification, pre-polycondensation and polycondensation on tertiary amine, dibasic acid and dihydric alcohol to prepare the tertiary amine modified rapidly degradable polyester, the structural formula of the tertiary amine is RN (CH2CH2OH) 2, R is a side group, and the side group at least contains one hydroxyl group. The preparation method is simple and easy to implement, the prepared tertiary amine modified rapidly degradable polyester can be hydrolyzed, the mass loss within 49 days can reach 3-20%, especially hydrolysis can be further accelerated after oxidation treatment, and meanwhile the breaking strength of copolyester is enhanced.

The invention relates to an aliphatic copolyester elastomer and a preparation method thereof, and belongs to the field of high polymer materials. The elastomer is prepared through a series ring-opening copolymerization reaction of epoxide and cyclic anhydride, and the method comprises the following steps: under the action of a metal-free catalyst (a phosphazene ligand P1-tert-octyl / triethyl boron system) and an initiator (terephthalyl alcohol), carrying out a series ring-opening copolymerization reaction on epoxide and cyclic anhydride, the preparation method comprises the following steps: reacting epoxide (such as epoxypropane and allyl glycidyl ether) with aliphatic anhydride (such as glutaric anhydride) in a xylene solvent to generate a polyester prepolymer retaining an active end; adding a second group of epoxide (such as cyclohexene oxide) and anhydride (such as tetrahydrophthalic anhydride and norbornene dianhydride), continuously reacting to form a block copolymer, and then crosslinking. The material performance can be regulated by changing the monomer combination, the atom economy is high, and the raw materials can be produced on a large scale. The process is simple and environment-friendly, and a new choice is provided for application of the degradable elastomer in the fields of medical treatment, environmental protection and the like.

The invention relates to the technical field of polyester fibers, and discloses a waterproof and antibacterial polyester fiber fabric and a preparation method thereof. N,N'-bis(2-hydroxyethyl)ethylenediamine, N,N'-di-Boc-S-methylisothiourea and the like are used as raw materials, and the raw materials are subjected to an esterification polycondensation reaction with dimethyl terephthalate to obtain a waterproof and antibacterial copolyester polymer having a structure similar to that of PET polyester. The waterproof and antibacterial copolyester polymer contains a quaternary ammonium salt, a guanidine group and a hydrophobic long chain structure, which can be evenly distributed in a polyester fiber matrix, thereby avoiding the migration of antibacterial groups and better exerting the antibacterial performance against bacteria. The C-F bond energy is high, and fluorine atoms are more easily embedded in the polymer, blocking the channel for water molecules to migrate into the inside of the coating film, and a stable protective layer can be formed on the surface of the fiber fabric to wrap the fiber and prevent water from penetrating into the inside of the fiber, thereby playing a waterproof role. At the same time, the hydrophobic layer also has certain durability and can withstand multiple washings without failure.

The invention discloses a separation method and application of CBDO cis-trans isomers, and relates to the technical field of compound isomer separation. The separation method comprises the following steps: respectively modifying hydroxyl groups of cis-CBDO and trans-CBDO to generate polarity difference, then separating the two isomers by a solvent dissolution-crystallization method, and finally removing protection to respectively obtain the cis-CBDO isomer and the trans-CBDO isomer. Through a modification protection-separation-deprotection method, the method has the advantages that the method is simple, the separation cost is reduced, and CBDO products with different cis-trans ratios and all-trans CBDO isomers can be obtained; the cis-trans ratio of the CBDO product can be up to 39.5 / 1, and compared with the commercially available CBDO, the copolyester prepared by using the CBDO product under the same condition has higher intrinsic viscosity and glass transition temperature, and the copolyester product with a full cis form can be obtained, so that the application range of the polymer can be expanded.

The invention relates to an amorphous low-temperature-resistant polyester composition and a preparation method thereof. The amorphous low-temperature-resistant composition consists of the following raw materials: a rigid structural unit of copolyester consisting of purified terephthalic acid and phenyl glycol; purified terephthalic acid, isophthalic acid and 1, 4-butanediol form an amorphous flexible structure unit; different linear molecular chains are reasonably connected through a branching agent, the acting force between the molecular chains is increased, the defect that the acting force between linear high molecular molecules is low is overcome, and finally the amorphous low-temperature-resistant polyester composition with soft / hard blocks and a branched structure is formed.

The invention provides a modified copolyester film as well as a preparation method and application thereof. The modified copolyester film is prepared from the following raw materials: binary acid, dihydric alcohol and a catalyst, the binary acid comprises 2, 5-furandicarboxylic acid and other binary acid; the dihydric alcohol comprises neopentyl glycol and other dihydric alcohol. 2, 5-furandicarboxylic acid is introduced into a modified copolyester molecular chain, so that the polarity and hydrophilicity of polyester are improved, the interfacial interaction force between the polyester surface and a copper foil is increased, and the adhesive force between the polyester surface and the copper foil is improved; neopentyl glycol is introduced into a modified copolyester molecular chain, so that the regularity of polyester is further destroyed, the crystallinity and the melting point of polyester are reduced, the film is easier to soften or partially melt when in contact with a copper foil, the contact area between the film and the copper foil is increased, mutual diffusion between the film and the copper foil is increased, and the bonding strength between the film and the copper foil is improved.

An electrode constituted by an active material and a binder material, wherein the binder material comprises a copolyester which comprises repeating units derived from a diol, a dicarboxylic acid and a poly(alkylene oxide). The binder material may further comprise a first metal ion-containing component selected from conductive ceramic particulate materials, and / or may further comprise additional metal ions from one or more sources other than said conductive ceramic particulate materials.

The present invention relates to a recyclable skin for the interior of a vehicle. The recyclable skin comprises a surface layer, which surface layer is formed from a material comprising a thermoplastic copolyester elastomer by means of a calendering and / or tape casting process, wherein the thermoplastic copolyester elastomer forming the surface layer comprises a hard segment and a soft segment. The recyclable skin for the interior of the vehicle of the present invention can be integrally recycled without splitting, has the advantages of being green and environmentally friendly, and has good market application prospects.

The present disclosure relates to a PET composite material and a preparation method therefor. The composite material comprises the following components in parts by mass: 50-100 parts of PET, 5-30 parts of an inorganic filler, and 5-30 parts of a PET copolyester. The PET copolyester is obtained by melting a waste pressure-sensitive adhesive product, adding an alcoholysis agent and a catalyst, and then performing polycondensation, wherein the waste pressure-sensitive adhesive product comprises a PET matrix and a pressure-sensitive adhesive layer, the pressure-sensitive adhesive layer comprises a copolyester elastomer, the copolyester elastomer is a copolymer of a carboxyl-terminated polyester and an amorphous carbon dioxide-based polyester diol, and the number-average molecular weight of the PET copolyester is 50,000 or below.

The invention discloses an anti-fouling curtain structure for water dredging engineering, and belongs to the technical field of environment protection of dredging engineering, the anti-fouling curtain structure for water dredging engineering comprises a floating body, an anti-fouling curtain and a vertical body, the floating body is arranged at the top end of the anti-fouling curtain, the vertical body is arranged at the bottom end of the anti-fouling curtain, and the anti-fouling curtain is geotechnical cloth; the geotechnical cloth is prepared from the following components in parts by weight: 100 to 150 parts of polyester, 20 to 50 parts of copolyester and 5 to 30 parts of inorganic filler, the copolyester is a copolymer of terephthalic acid, 5-sulfoisophthalic acid sodium salt, ethylene glycol and dihydroxyl-terminated polyvinyl imidazole, and the geotechnical cloth is further prepared by a post-treatment step. According to the invention, the copolyester composed of terephthalic acid, sodium 5-sulfoisophthalic acid, ethylene glycol and dihydroxyl-terminated polyvinyl imidazole and the inorganic filler are added into the polyester fiber, and the polyester fiber is modified through a post-treatment step, so that the alkali resistance and the antifouling property of the antifouling curtain are improved.