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Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid

Described as one aspect of the invention are polyester compositions A polyester composition comprising at least one polyester which comprises:
    • (A) a dicarboxylic acid component comprising:
      • i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising:
        • (a) 80 to 99 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and
        • (b) 1 to 20 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof;
      • ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues; and
      • iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and
    • (B) a glycol component comprising:
      • i) 5 to 35 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and
      • ii) 65 to 95 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof,
wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %;
the total mole % of said glycol component is equal to 100 mole %;
wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 66 to 120° C. The polyesters may be manufactured into articles.
Owner:EASTMAN CHEM CO

Elastomeric coating for corrosion control and chemical containment

A cost effective, two component, high-solids elastomeric coating. The coating is comprised of a chemically cross-linked resin for the purpose of substrate corrosion control, and chemical containment service. This invention may be applied by conventional application techniques including, but not limited to: brush applied, squeegee applied, roller applied, trowel applied, and both single and plural component spray applied. The coating may be optionally reinforced with fabric or fiber reinforcement layers, and the system components of the elastomeric coating to provide an engineered composite coating. The coating imparts excellent adhesive properties, in particular to: oil-contaminated substrates, a variety of low surface energy substrates, and on a variety of electronegative substrates. The invention's specific chemical resistive properties are designed such: for exposure to boiling water, resistance to brines, and resistance to a broad spectrum of solid and aqueous acids and caustics. The physical properties include excellent flexibility and the ability to elongate and contract across a broad temperature range (−100° F. to +260° F.). Performance properties of the installed coating include: weatherability, abrasion resistance, impact strength, chip resistance, and dimensional stability. Long-term aging properties of the material are exceptional.
Owner:FORTY TEN
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