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1413 results about "Polyurethane adhesive" patented technology

Hydrolysis-resistant double-component polyurethane adhesive for structure adhesion

The invention relates to a hydrolysis-resistant double-component polyurethane adhesive for structure adhesion. The hydrolysis-resistant double-component polyurethane adhesive for structure adhesion consists of a component A and a component B, wherein the component A comprises the following components in part by weight: 30 to 70 parts of polyisocyanate resin, 5 to 20 parts of plasticizing agent, 0.25 to 5 parts of thixotropic agent, 10 to 50 parts of incremental filler and 0.25 to 1 part of water-removing agent; and the component B comprises the following components in part by weight: 5 to 30 parts of polyester polyol, 5 to 30 parts of vegetable oil polyol, 5 to 30 parts of polyether polyol, 3 to 15 parts of water-absorbing filler, 1 to 10 parts of thixotropic agent, 3 to 15 parts of incremental filler, 0.1 to 10 parts of pigment, 0.1 to 5 parts of adhesion force accelerator, 0.1 to 2 parts of chain extender and 0.01 to 0.2 part of catalyst. An adhesion system improves adhesion property, solves the problem that a thermosetting composite material is subjected to surface roughening treatment before adhesion and improves the using efficiency. Aiming at the problem of poor hydrolysis resistance of a polyester type polyurethane adhesive system, the hydrolysis resistance is improved through molecule design of polyurethane soft and hard sections.
Owner:TONSAN ADHESIVES INC

Method for preparing aqueous polyurethane adhesive and superfine fiber synthetic leather

The invention relates to a method for preparing an aqueous polyurethane adhesive and superfine fiber synthetic leather, which belongs to the technical field of chemical products and preparation methods thereof. The method is characterized by comprising the following steps: mixing polyester polyol, isocyanate, a hydrophilic chain extending agent, a micromolecule chain extending agent and an amine environment friendly catalyst to obtain a hydrophilic aqueous polyurethane prepolymer; adding a neutralizing agent to the aqueous polyurethane prepolymer to obtain an aqueous polyurethane latex; then adding an amine chain expanding agent, a thickening agent, a defoaming agent and a flatting agent to the aqueous polyurethane latex to obtain the aqueous polyurethane adhesive; coating the aqueous polyurethane latex on release paper; drying the release paper; then coating the aqueous polyurethane adhesive on the dried release paper; and pressing the release paper and base cloth together to obtain the superfine fiber synthetic leather. The high solid content aqueous polyurethane adhesive prepared by the method has better initial tack and rebound resilience and higher final strength, and the prepared superfine fiber synthetic leather has higher peel strength and low-temperature folding endurance. The preparing process of the method greatly reduces the use and the discharge of organic solvents, reduces the energy consumption and furthest reduce the environmental pollution.
Owner:HUADA CHEM GRP CO LTD

Water-based plastic-plastic compound adhesive for food and drug flexible package and preparation method thereof

The invention discloses a water-based plastic-plastic compound adhesive for food and drug flexible packages and a preparation method thereof. The preparation method comprises the following steps of: carrying out pre-emulsification by using 20-30 parts by weight of deionized water, 0.4-1.0 part by weight of emulsifying agents and 75-90 parts by weight of monomer mixtures to obtain a pre-emulsion A; then carrying out the pre-emulsification by using 5-8 parts by weight of the deionized water, 0.2-0.3 part of the emulsifying agents and 3-20 parts by weight of the monomer mixtures to obtain a pre-emulsion B; preparing an initiator water solution C by using 1-3 parts by weight of the deionized water and 0.2-0.8 part by weight of initiators; and dropping the monomer mixture I with lower polarity and the monomer mixture II with higher polarity step by step by adopting a pre-emulsification seed emulsion polymerization process to obtain the water-based plastic-plastic compound adhesive for the food and drug flexible packages. The water-based plastic-plastic compound adhesive disclosed by the invention has the advantages of no organic solvent, no formaldehyde release, good adhesivity and high stripping strength and permanent adhesion and can be applied to a flexible package industry and substitute for a solvent type two-component polyurethane adhesive maturely applied to the present market.
Owner:DONGGUAN STAR COSM POLYMER

High-bonding-strength and high-temperature-resisting phenolic resin modified polyurethane adhesive and preparation method thereof

The invention discloses a high-bonding-strength and high-temperature-resisting phenolic resin modified polyurethane adhesive and a preparation method thereof. The preparation method comprises the following steps of: synthesizing modified phenolic resin, preparing polyurethane prepolymer, synthesizing modified polyurethane prepolymer, and synthesizing the modified polyurethane adhesive, wherein the step of synthesizing the modified phenolic resin is carried out by adding methoxyl dimethylbenzene monomer and phenols in phenolic resin to react under the effect of an acid catalyst, cooling the mixture, and then adding a basic catalyst, solvent and formaldehyde in the mixture for dehydration reaction under vacuum until the mixture is transparent, thus obtaining the modified phenolic resin; the step of preparing the polyurethane prepolymer is carried out by adding polyisocyanates and polyester polyol in the modified phenolic resin for reacting; the step of synthesizing the modified polyurethane prepolymer is carried out by modifying the polyurethane prepolymer through the modified phenolic resin to obtain the modified polyurethane prepolymer; and the step of synthesizing the modified polyurethane adhesive is carried out by adding water to the modified polyurethane prepolymer, and dispersing the modified polyurethane prepolymer through dispersing agent, and finally adding neutralizing agent, cross-linking agent and chain extender into the dispersed modified polyurethane prepolymer to obtain the modified aqueous polyurethane adhesive. The preparation method disclosed by the invention is simple, and improves the bonding strength and high temperature resistance of the polyurethane adhesive.
Owner:高金技术产业集团有限公司

Waterborne polyurethane adhesive with high solid content and preparation method thereof

The invention discloses a waterborne polyurethane adhesive with high solid content and a preparation method thereof. The method comprises the following steps: adding polyisocyanate to polyester polyol and polyether polyol, which are dewatered in vacuum, and adding a catalyst for chain extension to obtain a polyurethane prepolymer; adding a sulfamate hydrophilic monomer for chain extension to obtain a waterborne polyurethane polymer; adding deionized water to shear at a high speed for dispersion, and removing acetone to obtain an emulsion-type waterborne polyurethane adhesive with high solid content. By adopting composite polyols, on one hand, good compatibility of a soft segment and a hard segment of polyurethane is ensured, and on the other hand, the flexibility of a polyurethane chain segment is ensured. By adopting the sulfamate hydrophilic monomer, on one hand, the waterborne polyurethane with high stability, high solid content and high crystallinity can be prepared by a little of hydrophilic monomer on the basis of strong acid and base characteristics of the sulfonate, and on the other hand, the problems of poor water tolerance, poor acid-base resistance and the like of carboxylate polyurethane because that the adding amount of the sulfamate hydrophilic monomer is large, and the sulfamate hydrophilic monomer needs to be neutralized by amine are avoided.
Owner:SHAANXI COAL & CHEM TECH INST
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