751 results about "Polyurethane coating" patented technology

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The present invention relates to a preparation method of an intelligent self-repairing, flame-retardant and light-resistant water-based polyurethane coating. The method comprises the following steps: preparing a self-made hyperbranched flame retardant and using it in the synthesis of a polyurethane prepolymer; cooling the mixture to 58° C., adding 2,2-dimethylolpropionic acid, reacting the mixture for 1 to 2 hours, adding 1 to 2 parts of a disulfide compound, reacting the mixture for 1 to 2 hours at 60 to 80° C., adding 1 to 2 parts of a hydrogen bonding agent, reacting the mixture for 1 hour at 60 to 80° C., adding 0.5 to 1.5 parts of a coumarin derivative, and reacting the mixture for 60 to 90° C. The mixture was stirred for 1-2 hours, and then spiropyran, diethanol monoisopropanolamine, and 0.01 parts of p-toluenesulfonamide were added, and the mixture was reacted at 50°C for 30 minutes. The temperature was lowered to 40-45°C, and 1-2 parts of triethylamine were added, and the mixture was reacted for 1-2 hours. The mixture was cooled to room temperature, and 60-65 parts of water were added. The mixture was stirred at a speed of 1800-2000 r / min for 0.5-1 hour to obtain an intelligent self-healing, flame-retardant, and light-resistant water-based polyurethane coating. The flame retardancy and self-healing properties of the obtained water-based polyurethane were significantly improved.

The invention provides a preparation method of a self-repairing waterborne polyurethane coating based on a synergistic effect of a dynamic disulfide bond and a pH response microcapsule. The preparation method comprises the following steps: step 1, preparing a dynamic disulfide bond-containing waterborne polyurethane (D-WPU) emulsion; step 2, preparing a pH response microcapsule; step 3, preparing a self-repairing waterborne polyurethane coating; a dynamic disulfide bond of the self-repairing waterborne polyurethane coating rapidly repairs macrocracks at 50-60 DEG C through mercaptan catalysis, and pH < lt > is caused by local corrosion of a pH response microcapsule; when the pH value is 4.0, cysteine is released, sulfydryl accelerates recombination of dynamic bonds, and amino enhances cohesive force of the coating and neutralizes H < + >. And in combination with a hydrogen bond network of the nanocellulose, the coating has low-temperature repair (the mechanical strength recovery rate is greater than or equal to 90%), high toughness (the water absorption rate is less than or equal to 2.1%) and long-acting corrosion resistance (the salt spray resistance life is greater than or equal to 600 hours), and is suitable for severe environments such as ocean engineering and new energy equipment.

The invention discloses a bio-based thermoplastic polyurethane coating material easy to degrade quickly and a controlled-release fertilizer. The coating material comprises 0.8-2.0 parts of a biological chain matrix and 0.5-1.5 parts of a chain reinforcing agent; the biological chain matrix is formed by mixing pre-oxidized vegetable oil diol and bio-based polyester diol; the chain reinforcing agent is formed by mixing a curing agent, a hardening agent and a toughening agent. The bio-based thermoplastic polyurethane coated controlled-release fertilizer comprises fertilizer particles and a bio-based thermoplastic polyurethane coating material sprayed on the surfaces of the fertilizer particles, the spraying amount of the bio-based thermoplastic polyurethane coating material is 0.8-10% of the mass of the fertilizer particles. By accurately regulating and controlling the formula of the film material, the physical properties such as tensile strength and toughness of the bio-based thermoplastic coating material can be jointly improved, so that a more excellent controlled release effect is achieved, and the contradiction between the degradability and the controlled release property of the existing bio-based polyurethane coating material is solved.

The invention relates to an anti-corrosion treatment process for a ship lock steel structure. The anti-corrosion treatment process comprises the steps that S1, the surface of the ship lock steel structure is pretreated; s2, the surface of the pretreated steel structure is coated with an anti-corrosion coating containing graphene modified zinc powder to serve as primer; s3, the surface of the primer is coated with super-strong epoxy paint, intermediate paint is formed, and the super-strong epoxy paint is amine adduct cured high-solid epoxy finish paint; s4, the surface of the intermediate paint is coated with a polyurethane coating to serve as finish paint; by selecting proper paint as primer, intermediate paint and finish paint, one scheme is suitable for all areas and can resist corrosion for a long time, and finally the problem that different areas need to be constructed in different areas is solved. According to the anti-corrosion scheme, the adhesive force is high, the shielding property is high, the water resistance is good, and the ultraviolet resistance is high.

The invention discloses a corrosion-resistant insulating aerial cable which sequentially comprises a conductor layer, an insulating layer, a shielding layer, a corrosion-resistant layer and an outer sheath from inside to outside. The conductor layer is an aluminum alloy stranded wire of which the surface is coated with an anti-oxidation coating; the insulating layer is made of crosslinked polyethylene doped with 3-5% of nano silicon dioxide; the corrosion-resistant layer is a fluoroplastic or polyurethane coating; and the outer sheath is polyvinyl chloride added with an antioxidant and an ultraviolet light absorber. The fluoroplastic coating is formed through electrostatic spraying, and the surface of the copper wire shielding layer is subjected to phosphating pretreatment; the doped nano material enhances the mechanical strength and ultraviolet resistance of the insulating layer; the spiral groove design accelerates drainage and reduces accumulated water corrosion.

The invention relates to the field of school uniform fabric production, in particular to a preparation method of an environment-friendly quick-drying school uniform fabric, which comprises the following preparation steps: S1: material selection, S2: fiber functionalization treatment, S21: plasma surface modification, S22: enzymatic polishing, S3: blended yarn preparation and fabric weaving, S4: fabric dyeing, S5: multifunctional composite finishing, S51: spraying of a waterborne polyurethane coating, S52: ozone washing water softening, s6, carrying out post-treatment; the regenerated polyester, the organic cotton and other raw materials are adopted, the regenerated polyester is made of recycled PET plastic bottles and is environmentally friendly and economical, polar groups on the surface of the regenerated polyester are activated through plasma surface modification, the hygroscopicity is greatly improved, the quick-drying performance is enhanced, and by means of a unique double-layer honeycomb mesh structure and a double-strand yarn optimization treatment mode, the moisture absorption performance is greatly improved. A multidirectional moisture guiding channel is formed, and the moisture evaporation rate is increased, so that the prepared school uniform fabric is environment-friendly, durable and comfortable while maintaining high-breathability and quick-drying performance.

The invention discloses an antifouling waterborne polyurethane coating for ships, and relates to the technical field of waterborne polyurethane coatings, and the antifouling waterborne polyurethane coating is prepared from the following raw materials in parts by weight: 5 to 8 parts of polytetrahydrofuran, 3 to 5 parts of diphenylmethane diisocyanate, 4 to 5.2 parts of chain extender and 0.45 to 0.7 part of functional filler. According to the antifouling waterborne polyurethane coating for the ship, the chain extender I tends to be distributed on a coating-water interface through the hydrophilicity of triethanolamine in the chain extender I, meanwhile, boric acid groups are preferentially in contact with seawater and are distributed on the surface layer of a coating, the water solubility is high, boric acid ions are rapidly released at the initial stage, and the antifouling waterborne polyurethane coating is good in antifouling property. The initial adhesion of marine microorganisms is inhibited through ion repulsion; an MDI fragment in the chain extender II provides an extra-NCO reaction site, and chemical crosslinking is generated between the MDI fragment and a network formed by the chain extender I, so that the overall crosslinking density is improved, and the toughness and weather resistance of a coating film are improved.

The invention discloses a preparation method of an ethyl cellulose and isocyanate cross-linked coated urea slow-release fertilizer, and relates to a preparation method of a urea slow-release fertilizer. The invention aims to solve the problems that the existing nitrogen fertilizer is low in utilization rate and easy to absorb moisture and cake, a polyurethane coating material is non-degradable, and pure ethyl cellulose is insufficient in mechanical strength and limited in water resistance and is not beneficial to being used as a coating matrix of the fertilizer. The method comprises the following steps: 1, preparing an ethyl cellulose cross-linked isocyanate enveloping solution; and 2, preparing the ethyl cellulose and isocyanate cross-linked coated urea slow-release fertilizer. According to the preparation method, etherified derivative ethyl cellulose of cellulose is taken as a raw material, and the defects that a pure ethyl cellulose membrane is insufficient in mechanical strength, limited in water resistance and low in nutrient separation control precision are overcome by utilizing isocyanate crosslinking modification. The prepared slow-release fertilizer has the advantages of being simple in process, low in cost, environmentally friendly, degradable in matrix, capable of effectively preventing urea from absorbing moisture and caking and the like, and is suitable for large-scale preparation and used in agricultural production.

The invention discloses a bionic anti-drag protective film based on a surface micro-nano structure and a preparation method of the bionic anti-drag protective film, and relates to the technical field of anti-drag film preparation. According to the preparation method, the high-strength nitrogen-containing thermoplastic polyurethane film layer with the flame retardant property is prepared, one layer is coated with the hyperbranched polyurethane coating, the drag reduction functional layer with the microstructure is formed through embossing and photo-thermal dual curing, and the hyperbranched polyurethane coating can form a high-density cross-linked network during curing, so that the drag reduction performance is improved; according to the present invention, the hyperbranched polyurethane coating material has characteristics of good mechanical property and good weatherability, the hyperbranched structure can assist in dispersion of shrinkage stress and maintenance of coating surface flatness during heating, and the hyperbranched polyurethane coating material further contains nitrogen rings so as to provide the coating material with certain fire resistance.

The invention discloses resin composite liquid with dual self-repairing and high ethanol solvent wiping resistance as well as a preparation method and application of the resin composite liquid, and belongs to the technical field of polyurethane emulsion coatings. Aiming at the problems that an existing waterborne polyurethane coating is poor in ethanol resistance due to residual carboxyl / hydroxyl of a hydrophilic chain extender and the self-repairing efficiency of a single dynamic bond is low, a metal ion buffer solution is added into a hydroxyl-terminated polyurethane emulsion to coordinate with the carboxyl of the hydrophilic chain extender, so that a hydrophilic group is closed, and the crosslinking density is increased; meanwhile, a boric acid compound is introduced to form dynamic boric acid ester bonds with residual hydroxyl groups of the system, and hydrophilic groups in the system are consumed while a dual self-repairing network is constructed. The coating prepared by the invention has good self-repairing and ethanol wiping resistance.

The invention discloses a radiation refrigeration coating as well as a preparation method and application thereof, and relates to the technical field of material preparation. The preparation method comprises the following steps: sintering hexagonal boron nitride, and removing boron oxide to obtain modified boron nitride powder; the preparation method comprises the following steps: reacting supramolecular polysiloxane with methoxypolyethylene glycol to obtain hyperbranched polysiloxane; the modified boron nitride powder and hyperbranched polysiloxane are subjected to hydrolysis on boron nitride under the alkaline condition, and silane modified boron nitride is obtained; the silane modified boron nitride is added into a polyurethane coating matrix to form the radiation refrigeration coating. The silicon-oxygen modified group is introduced to the surface of the boron nitride, so that the interaction between the boron nitride and the coating group is greatly improved, and the stability of the coating is improved; the coating can be cured under different environmental conditions, and construction on power equipment is facilitated; the formed radiation refrigeration coating is high in sunlight reflectivity, high in mid-infrared emissivity and high in heat dissipation capacity for power equipment.

The invention belongs to the technical field of preparation and surface protection of polyurethane coatings, and particularly relates to weather-resistant polyurethane and a preparation method thereof. The coating provided by the invention is composed of a component A and a component B according to a weight ratio of 1: (0.2-0.4). The component A is prepared from water-based fluorine-containing hydroxy acrylic dispersion resin with a high hydroxyl value, GMA (glycidyl methacrylate) grafted modified water-based acrylic dispersion resin, a benzotriazole ultraviolet light absorber, a light hindered amine stabilizer, rutile titanium dioxide, wet sericite powder, nano zinc oxide and auxiliaries; and the component B comprises an aliphatic isocyanate curing agent and propylene glycol diacetate. By constructing a quadruple synergistic weather-resistant mechanism of ultraviolet absorption, free radical capture, physical shielding and structural densification, the weather resistance and corrosion resistance of the coating are remarkably improved while the coating keeps excellent adhesive force (0-1 level) and hardness (2H-3H), the color change delta E is smaller than or equal to 1.8 after artificial accelerated aging for 1000 hours, the gloss loss rate is smaller than or equal to 23%, and the weather resistance and corrosion resistance of the coating are greatly improved. And the corrosion spreading width of a 600-hour salt spray test lineation is less than or equal to 2.3 mm.

The invention discloses a preparation method of an infrared and radar stealth fabric, which comprises the following steps: S1, ultrasonically impregnating a fabric, soaking with an alkaline solution, washing and drying to obtain a pretreated fabric; s2, mixing wave-absorbing powder with a coating adhesive, then adding a thickening agent, coating a fabric with the mixture, and drying the fabric to obtain a compound fabric; s3, the MAX phase material is etched, and an MXene dispersion liquid is obtained; and S4, coating the composite fabric with the coating adhesive, coating the composite fabric with the MXene dispersion liquid, drying the composite fabric, and repeatedly coating the composite fabric for 1-3 times to obtain the MXene / wave-absorbing powder / fabric. The radar stealth layer is formed by utilizing the wave-absorbing powder, meanwhile, MXene is coated after the polyurethane coating adhesive is coated, it is ensured that the MXene forms a stable and continuous film, the emissivity is reduced to achieve infrared stealth, it is avoided that the integrity of the MXene structure is damaged by traditional mixed coating, the infrared low emissivity and the radar wave absorbing performance are balanced by accurately controlling the using amount of the MXene, and the infrared stealth effect is improved. And high-performance infrared and radar dual-band stealth is realized.

The invention relates to the technical field of fertilizers, in particular to a urea-containing slow-release coated fertilizer and a preparation method thereof. The urea-containing slow-release coated fertilizer comprises urea particles and a bio-enzyme polyurethane coating layer coated on the surfaces of the urea particles, and the bio-enzyme polyurethane coating layer comprises the following components in parts by mass: 10-20 parts of urea particles, 10-20 parts of urea particles and 10-20 parts of urea particles. Comprising the following raw materials: 20 to 25 parts of castor oil, 18 to 25 parts of castor oil-based polyester polyol, 25 to 30 parts of hydrophobic modified starch, 16 to 22 parts of diphenylmethane diisocyanate, 0.03 to 0.05 part of a catalyst, 1.5 to 2 parts of a dispersant, 1.5 to 2 parts of a high-temperature-resistant bio-enzyme, 2 to 3 parts of glycerin and 14 to 18 parts of N, N-dimethylformamide. The polyurethane coating layer material of the bio-enzyme is prepared through the cross-linked network design of the molecular level and the collaborative regulation and control of the macroscopic coating layer thickness, the balance among efficient nitrogen utilization, environmental friendliness, mechanical properties and weather resistance is achieved, and a solution with technical innovation and practical value is provided for the field of slow-release fertilizers.

The invention relates to the field of polyurethane, and discloses a preparation method of a linear reaction type phosphorus-nitrogen-silicon synergistic flame-retardant solvent-free polyurethane coating, which comprises the following steps: S1, carrying out exchange reaction on phosphonate and alcohol amine ester to obtain a phosphorus-nitrogen polyol intermediate; s2, carrying out condensation polymerization on the phosphorus-nitrogen polyol intermediate and chlorosilane to obtain phosphorus-nitrogen-silicon polyol; s3, mixing polyester / polyether polyol, a chain extender and an amine / metal catalyst to obtain a component A; mixing and reacting isocyanate, part of polyester / polyether polyol and phosphorus-nitrogen-silicon polyol to obtain a component B; mixing the component A and the component B, spraying the mixture on release paper, and curing. Through a synergistic flame-retardant mechanism of phosphorus, nitrogen and silicon, the balance of efficient flame retardance, mechanical properties and excellent coating properties is realized. The solvent-free system realizes zero emission of volatile organic compounds, and the linear reaction type design ensures that the mechanical properties and durability of the coating are not influenced.

The invention discloses an anti-radiation fabric and a preparation method thereof, and relates to the technical field of fabric preparation. When the anti-radiation fabric is prepared, bismuth powder is pre-modified with (3-chloropropyl) trimethoxysilane and then reacts with an anti-aging agent to prepare modified bismuth powder; the preparation method comprises the following steps: enabling 4-aminophenylethanol and 4-(2-ethoxyl) benzaldehyde to react to prepare a flame-retardant monomer, and then enabling the flame-retardant monomer to react with isophorone diisocyanate and 1, 4-butylene glycol to prepare polyurethane; the preparation method comprises the following steps: reacting dimethylallylamine with 1, 3-bis (chloromethyl)-1, 1, 3, 3-tetramethyldisiloxane to obtain an antibacterial cross-linking agent; the modified bismuth powder, N, N-dimethylformamide, polyurethane, an antibacterial cross-linking agent and benzoyl peroxide are mixed to prepare a polyurethane coating, the outer side surface of polyester base cloth is coated with the polyurethane coating, drying is conducted, and the anti-radiation coating fabric is prepared. The anti-radiation fabric prepared by the invention has good anti-radiation, anti-light aging, flame-retardant and antibacterial properties.

The invention belongs to the technical field of photovoltaic backboards, and particularly relates to a high-reflection integrally-formed backboard for a single-glass assembly and a preparation method thereof.The preparation method comprises the following steps that S1, a PET film base material is provided, plasma surface treatment is conducted, then polyurethane coating is coated on the two sides to form an outer-layer weather-proof fluorine coating and an inner-layer functional coating respectively, and the outer-layer weather-proof fluorine coating and the inner-layer functional coating are formed; a CPC backboard base material is obtained; s2, white high-reflection EVA granules are fused and plasticized, a white EVA adhesive film is obtained through extrusion of a hanger type T-shaped flat die head, then the white EVA adhesive film is compounded with the inner functional coating of the CPC backboard base material, and a firm complex without a definite physical interface is obtained through rolling; s3, cooling the composite body through at least two stages of cooling rollers to obtain a coiled material; and S4, the coiled material is irradiated, and the high-reflection integrally-formed backboard is obtained.

The present invention discloses a high- and low-temperature resistant environmentally friendly water-based polyurethane coating and a preparation method thereof, belonging to the technical field of chemical coatings. The preparation method comprises: reacting isophorone diisocyanate with cyanuric acid at 80-90°C to generate a prepolymer containing a triazine ring cross-linked network; adding hyperbranched polycaprolactone to the prepolymer, and vacuum dehydrating the prepolymer to form a mixed prepolymer; using dimethylolpropionic acid to extend the chain and neutralizing it with triethylamine, adding a coating additive and shearing and emulsifying to obtain a high- and low-temperature resistant environmentally friendly water-based polyurethane coating. Through the synergistic effect of the rigid triazine ring network and the hyperbranched chain segments, the coating has both brittle crack resistance and creep resistance over a wide temperature range; the amphiphilic chain extender ensures emulsion stability and low VOC content.

The invention discloses a silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating and preparation, and belongs to the technical field of paints.The silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating is prepared by the steps that natural graphite powder serves as a raw material, and graphene oxide is prepared through a Hummer method; n-(beta-aminoethyl)-gamma-aminopropyl trimethoxy silane is grafted to the surface of the graphene oxide through a chemical reduction method, and GO-AATS composite filler is obtained; then, castor oil is used as a soft segment, isophorone diisocyanate is used as a hard segment, and a series of GO-AATS-WPU emulsions are prepared. According to the silane functionalized graphene oxide / waterborne polyurethane hydrophobic coating and preparation, chemical bonds are formed between graphene oxide and waterborne polyurethane, and the interfacial compatibility of graphene oxide and waterborne polyurethane is improved, so that the mechanical property, water resistance, corrosion resistance and thermal stability of the waterborne polyurethane coating are improved.

The invention discloses a waterborne polyurethane coating with corrosion-resistant and antifouling characteristics as well as a preparation method and application thereof, and the waterborne polyurethane coating is prepared from the following raw materials in parts by weight: 30 parts of diisocyanate, 15-30 parts of polycarbonate diol, 0.01-0.02 part of a catalyst, 3-5 parts of polydimethylsiloxane, 3-5 parts of a hydrophilic chain extender and 1-3 parts of a micromolecule chain extender. The preparation method comprises the following steps: preparing the following components in parts by weight: 0.5-3 parts of modified silicon dioxide nanoparticles, 1-3 parts of triethylamine, 4-10 parts of acetone and 130-150 parts of water; the modified silicon dioxide nano particles are nano silicon dioxide modified by a silane coupling agent and dodecyl triethoxy silane. The waterborne polyurethane coating can effectively prevent corrosion of seawater to metal equipment and adhesion of marine organisms to the surface of underwater metal equipment, and has important significance in expanding the application of the waterborne polyurethane coating in the field of marine protection.

The invention relates to the technical field of protective films, and discloses a mobile phone protective film and a preparation method thereof. Modified graphene oxide is used as a filler, a modified waterborne polyurethane emulsion is used as a film forming substance, a flatting agent and a defoaming agent are used as auxiliary materials, a waterborne polyurethane coating is prepared, the surface of a PET base material is coated with the waterborne polyurethane coating, then drying is conducted, and the mobile phone protection film is obtained. A quaternary ammonium salt group and negative charges on a bacterial cell membrane generate electrostatic attraction, so that the original structure and function of the cell membrane are destroyed, and a bactericidal effect is achieved; silanol groups generated by hydrolysis of silane groups can react with hydroxyl groups and carboxyl groups on the surface of a PET base material, so that the interface bonding force between the coating and the base material is improved; nitrogen atoms in pyrrolidone groups form hydrogen bonds with hydroxyl groups and carboxyl groups on the surface of a base material, so that the bonding strength of the coating and the base material is further improved; the adamantyl group is grafted into the graphene oxide, so that the supporting effect of the graphene oxide on the waterborne polyurethane is enhanced, and the mechanical property of the mobile phone protective film is improved.

The present invention relates to the technical field of the preparation of polyols. Disclosed are a method for preparing a bio-based polyol and a use of the bio-based polyol. In the present invention, a tartrate is selected as a first ring-opening reagent to carry out a first ring-opening reaction on an epoxy group, a second ring-opening reagent containing a secondary alcohol is then used to carry out a second ring-opening reaction, and finally, a primary alcohol is used to carry out a third ring-opening reaction on the rest epoxy group to obtain a bio-based polyol product having an epoxy value close to 0. The bio-based polyol prepared in the present invention is moderate, has a uniform distribution and a relatively low viscosity, and can replace traditional petrochemical polyols. A polyurethane coating prepared from the bio-based polyol prepared by the method of the present invention has remarkably improved performance.

The invention relates to the technical field of wave-absorbing coatings, and discloses a radar wave-absorbing coating and a preparation method thereof.The radar wave-absorbing coating is prepared from, by weight, 100 parts of waterborne polyurethane emulsion, 0.4-1.6 parts of graphene oxide, 0.3-2 parts of modified ferroferric oxide and the like; a plurality of hydrophilic hydroxyl groups and carboxyl groups are introduced on the surface of the nano ferroferric oxide, so that the surface hydrophilicity is improved, and the nano ferroferric oxide is uniformly dispersed in the waterborne polyurethane coating, so that the coating has higher mechanical strength and tensile property. And a plurality of hydroxyl groups and carboxyl groups introduced on the surface of the nano ferroferric oxide and hydroxyl groups and carboxyl groups on the surface of the graphene oxide interact with each other to form hydrogen bonds and the like, so that the interface action between the nano ferroferric oxide and the graphene oxide is improved, the impedance matching performance of the nano ferroferric oxide and the graphene oxide is improved, the interface polarization effect is formed, and the absorption effect of the coating on electromagnetic waves is improved.

The invention belongs to the technical field of high polymer materials, and particularly relates to a boron nitride modified waterborne polyurethane coating with high mechanical property and a preparation method thereof. Through in-situ polymerization of dopamine on the surface of graphene oxide, abundant active groups are introduced, and covalent crosslinking of graphene oxide and waterborne polyurethane is enhanced; meanwhile, the surfactant modified boron nitride nanosheet and the coated modified graphene oxide form a three-dimensional heterostructure through hydrogen bonds and electrostatic interaction, and a multi-stage enhanced network is constructed in a polyurethane matrix. The method not only solves the problem of dispersion of the nanofiller, but also optimizes stress distribution through a brick-mud structure, and significantly improves the mechanical properties and wear resistance of the coating. Compared with traditional single filler modification, the technology realizes the synergistic breakthrough of filler-matrix interface performance and macroscopic mechanical performance, and provides a new idea for development of high-performance waterborne polyurethane coatings.

The present invention relates to the technical field of polyurethane coatings, and in particular to a polyurethane coating with sufficient tack-free dryness and a preparation method therefor. In the present invention, ethylene glycol, potassium methoxide, and glycidol are used to prepare a branched polyglycidyl ether and silicon dioxide is modified using the branched polyglycidyl ether. The addition of the branched polyglycidyl ether improves the compatibility of the modified silicon dioxide in a modified polyurethane emulsion, thereby enhancing the hydrophobicity and corrosion resistance of the coating. The backbone of the branched polyglycidyl ether has a high molecular weight, providing a large number of crosslinking sites, and by adding the branched polyglycidyl ether-modified silicon dioxide to the polyurethane coating, the water resistance of the polyurethane coating is enhanced. In the present invention, benzotriazole is also loaded on the silicon dioxide as a corrosion inhibitor, thereby imparting a corrosion-resistant effect to the coating.

A panel and a panel production method are provided wherein an elastomeric coating, and preferably, a water-based elastomeric polyurethane coating, is applied to a pre-existing, finished panel construct, by pressing the coating onto the panel construct, and thereby bond the coating to the surface of the panel construct. The method is used to produce enhanced panels which can be used in the production of flooring materials, wall panels, furniture, countertops, and the like. The resultant panels typically have an enhanced surface that products the surface layer of the panel construct. The coated panel can also be made abrasion resistant, and can also be enhanced so as to provide better acoustical properties while providing a soft touch, haptic surface.

The invention discloses a method and a system for detecting the quality of an outer package using a polyurethane coating, and relates to the technical field of outer package material detection. Comprising the following steps: acquiring spectral data of a polyurethane coating outer package; based on the spectral data, extracting coating material information of the outer package; according to the coating material and the discrimination index, correcting the light source attribute and generating correction data; distributing defect grades for the outer package of the polyurethane coating according to the correction data and the discrimination indexes; and obtaining projection data of the outer package of the polyurethane coating at the packaging position. According to the method, the wavelength-reflectivity data matrix is constructed, principal component extraction and curvature feature analysis are performed on the wavelength-reflectivity data matrix, the spectral feature vector representing the coating material is constructed, and then the feature vector is matched with the preset material database, so that the coating material is identified; the problem that in the prior art, the detection accuracy of high-reflectivity coatings such as polyurethane coatings is insufficient is solved, and the reliability of extracting the intrinsic characteristics of materials is remarkably improved.

The invention provides a preparation method of a self-repairing waterborne polyurethane leather coating material containing a polyurethane colloid capsule, which comprises the following steps: firstly, preparing an O / W type Pickering emulsion by taking modified SiO2 nanoparticles as a stabilizer and a polyurethane solution as an oil phase; the preparation method comprises the following steps: firstly, taking the polyurethane colloid capsule as a template, forming the colloid capsule capable of being dispersed in a water system through a sol-gel reaction, and finally, uniformly dispersing the colloid capsule into a waterborne polyurethane leather finishing emulsion to prepare the waterborne polyurethane leather self-repairing coating material containing the polyurethane colloid capsule. According to the invention, the polyurethane healing agent is used as a core material, and the modified SiO2 nanoparticles are used as a shell wall, so that the prepared spherical colloid capsule is high in encapsulation efficiency and strong in stability. According to the preparation method provided by the invention, the problems of poor self-repairing performance and mechanical property caused by low compatibility of a healing agent and a polyurethane matrix for leather finishing and easy agglomeration of a traditional microcapsule in a waterborne polyurethane emulsion in a traditional external aid type self-repairing polyurethane coating are solved; and the wear resistance of the leather polyurethane coating is remarkably improved by introducing SiO2.

A two-part coatings system is provided. The system includes a resin component and a crosslinking component. The resin component includes a mixture of an epoxy resin and a polyurethane resin. The crosslinking component includes a curing agent and a catalyst. The polyurethane resin includes a donor for a Michael addition reaction and an acceptor for a Michael addition reaction. The catalyst is configured to facilitate a Michael addition reaction between the donor and the acceptor of the polyurethane resin. The curing agent is configured to react with the epoxy resin.