The invention discloses a preparation method of a
sodium ion battery
biomass hard carbon negative
electrode material with a high micropore structure. The preparation method comprises the following steps: S1, pretreating raw materials to obtain refined hard carbon raw materials; s2, functional group modification: placing the hard carbon
raw material and a modifier in a reaction kettle for
temperature control reaction to obtain a modified hard carbon
raw material rich in functional groups; s3, cross-linking modification: putting the modified hard carbon
raw material and a cross-linking agent into a reaction kettle, and reacting at a controlled temperature to obtain a cross-linked hard carbon raw material; s4,
drying treatment:
drying the cross-linked hard carbon raw material to obtain a cross-linked hard carbon raw material; s5, pre-
carbonization: pre-carbonizing the cross-linked hard carbon raw material in a protective
atmosphere to obtain a pre-carbonized material; s6, crushing and refining to obtain a refined pre-carbonized material; and S7, high-temperature
carbonization: carrying out high-temperature
carbonization on the refined pre-carbonized material in a protective
atmosphere to obtain the hard carbon negative
electrode material with a high microporous structure. The method has the characteristics of
high sodium storage capacity, high coulombic efficiency and high process
operability.