The invention relates to a preparation method of ZrB2-SiC composite ceramic coating, in particular to a preparation method of ZrC ceramic material surface ZrB2-SiC composite coating, and solves the problem that ZrC superhigh-temperature ceramic has poor high temperature protection. The preparation method comprises the specific steps of weighing raw powders in molar percentage, ball-milling, and wet-stirring to obtain a slurry; evaporatively drying the slurry, and grinding to obtain mixed powder; subjecting the mixed powder to hot-pressing sintering, cooling with a furnace, taking out to obtain ZrB2-SiC-ZrC superhigh-temperature ceramic block material; crushing the ceramic block material, grinding, and screening to obtain ZrB2-SiC-ZrC mixed spraying powder; pretreating a ZrC-SiC composite ceramic base, washing, and drying for use; spraying the ZrB2-SiC-ZrC composite coating to the pretreated ZrC-SiC base by means of plasma spraying technique. Interfacial bonding is enhanced through good chemical compatibility of ZrB2 and ZrC.