The invention belongs to the technical field of
electrochemical energy storage, and relates to a positive and negative differential integrated
electrode for a static filmless
zinc-
bromine battery and a battery stack. The
electrode comprises a flexible
graphite composite bipolar plate, one side of the flexible
graphite composite bipolar plate is compounded with a non-conductive negative
electrode thin pre-oxidized felt subjected to oleophobic modification, the other side of the flexible
graphite composite bipolar plate is compounded with a positive electrode thick activated graphite felt which has a gradient pore structure and is loaded with a
bromine oxidation reduction catalyst, the contact side of the bipolar plate and the negative electrode felt is activated, and the three
layers are compounded into an integrated structure. The stack is horizontally placed, positive and negative electrode felts of adjacent electrodes are directly attached and compressed, no diaphragm exists, and the
compression ratio is controlled by a limiting column. Three-dimensional uniform deposition of
zinc is guided through the negative electrode non-conductive felt, the
bromine oil phase is locked through cooperation of positive electrode gradient pores and gravity
settling, the
contact resistance is reduced through the integrated structure, non-film static operation is achieved, the cycle life exceeds 500 times, the self-
discharge rate is lower than 0.45%, the energy efficiency is higher than 80%, the structure is simplified, and the
lithium ion battery is suitable for large-scale production.