The invention relates to an active substance modification method, a bipolar plate, a lead-based battery and an
energy storage device. The active substance modification method comprises the following steps: mixing a
raw material to be modified with modified
graphite powder to form a mixture, and adding a plurality of
impact balls; a high-speed stirring device is used for stirring the mixture, and under the high-
energy impact of the
impact balls, particles of the
lead sulfate generate cracks and molecular lattices generate lattice
distortion, so that fine particles of the
graphene can enter the particle cracks and the molecular lattices of the
lead sulfate. As fine particles of
graphene exist in particle cracks and molecular lattices of the modified
lead sulfate, the modified lead
sulfate has good
conductivity and continuously keeps good
conductivity during charging and discharging, good
conductivity and excellent activity can be ensured even if the proportion of the lead
sulfate in a positive active material or the positive active material is 100%, and the positive active material can be applied to the field of
lithium ion batteries. The specific capacity and the specific power of the lead-based battery are greatly improved, irreversible
sulfation of a polar plate is prevented, and the service life is prolonged.