2515 results about "Flow battery" patented technology

The invention discloses an intelligent energy scheduling method and system for a flow battery, and relates to the technical field of flow batteries, and the method comprises the following steps: collecting energy operation parameters of the flow battery in real time, and dynamically estimating an electrolyte state to obtain multiple pieces of energy state information; a target to be dispatched is set, and a fuzzy control strategy is formulated through retrograde multi-target optimization; executing a fuzzy control strategy to generate a regulation and control signal set and scheduling; and finally, according to a scheduling result, performing reverse tracing to optimize a fuzzy control strategy, and updating a regulation signal set to obtain a multi-stage regulation instruction to perform intelligent scheduling on the energy of the flow battery. The method solves the technical problems of low matching degree between a scheduling strategy and an actual demand, large power loss and fast battery life attenuation caused by difficulty in accurately capturing an energy state in real time in a traditional flow battery scheduling method, and achieves the purposes of intelligent flow battery energy scheduling, power loss reduction, battery life prolonging and energy conservation. And the matching degree between the scheduling and the actual demand is improved.

The invention provides an intelligent management method and system for photovoltaic energy storage equipment, and the method comprises the steps: analyzing the power fluctuation trend through monitoring the output power and environment parameters of the photovoltaic energy storage equipment in real time, and pre-judging the power fluctuation characteristics; according to the operation state parameters of the supercapacitor and the vanadium redox flow battery and the power fluctuation pre-judgment result, the power distribution proportion and the cooperative working mode of the energy storage element are determined; based on industrial load demand characteristics, an energy storage element is controlled to be flexibly switched between an active adjustment mode and a reactive compensation mode; and voltage regulation and harmonic compensation are realized by monitoring electric energy quality indexes of parallel connection points. According to the invention, the rapid response capability of the photovoltaic energy storage system to the industrial load can be effectively improved, the power supply stability and the electric energy quality are remarkably improved, the system power fluctuation is reduced, the utilization efficiency of the energy storage equipment is improved, and reliable clean energy support is provided for industrial users.

The invention discloses a positive electrode material for a zinc-bromine flow battery and a preparation method and application thereof, and belongs to the technical field of zinc-bromine flow batteries, the preparation method comprises the following steps: crushing and sieving an active carbon source, adding the active carbon source into a graphene oxide aqueous dispersion, stirring, centrifuging, removing supernate, drying, mixing with an activating agent, and activating in an inert atmosphere; washing to be neutral, drying and sieving to obtain a graphene / activated carbon composite material; and attaching the graphene / activated carbon composite material to a carbon-plastic bipolar plate to obtain the positive electrode material for the zinc-bromine flow battery. A graphene / activated carbon composite system is combined with a high-conductivity network, graded holes and surface functional groups, so that the reaction kinetics bottleneck of a traditional carbon material Br2 is broken through.

The invention discloses a modified graphite felt electrode for an all-vanadium redox flow battery and a preparation method of the modified graphite felt electrode, and belongs to the technical field of redox flow battery electrode materials. The preparation method comprises the following steps: graphite felt electrochemical oxidation etching treatment; self-assembling a conductive layer on the oxidized and etched graphite felt to obtain the graphite felt attached with the conductive layer; and loading a metal and nitrogen-doped carbon (M and NC) nano catalyst layer on the graphite felt attached with the conductive layer to obtain the modified graphite felt electrode. Various properties of the graphite felt are comprehensively improved through matrix treatment, structure change and load catalysis, mild electrochemical oxidation etching is adopted, a carbon fiber structure is protected, a self-assembled net-shaped conductive layer forms a stable conductive channel, the specific surface area is remarkably increased, a nitrogen-doped carbon shell is adopted to wrap metal nanodots to form an M-NC catalytic layer, and the specific surface area is remarkably increased. The catalyst layer is not easy to dissolve out, the capacity fading rate is obviously improved, the loading capacity of the catalyst layer on the reticular structure conducting layer with a larger specific surface area is larger, and meanwhile, the process is simple and low in cost.

The invention discloses preparation and application of a diatomic catalyst modified carbon felt electrode. The preparation method of the modified carbon felt electrode comprises the following steps: dissolving bismuth salt, cobalt salt and urea in water to obtain a complexing solution; immersing the carbon felt substrate subjected to acid activation into a complexing solution for soaking treatment, then taking out the carbon felt substrate, and drying to obtain a precursor-loaded carbon felt; and sequentially carrying out primary heating, cold shock and secondary heating treatment on the precursor-loaded carbon felt, and cooling to obtain the Bi-Co diatom modified carbon felt electrode. The carbon felt electrode can be applied to an all-vanadium redox flow battery. The innovation point of the invention lies in that through the synergistic effect of double atoms and the mutual cooperation of the nitrogen-doped carbon substrate, the intrinsic activity bottleneck of the traditional catalyst is broken through, the comprehensive advantages of high catalytic activity, excellent stability and low cost are achieved, and a new technical solution is provided for the high performance and large-scale application of the flow battery.

The invention discloses a fuel cell coupled flow battery energy supply system and an operation control method thereof. The energy supply system comprises a basic energy supply unit, an energy storage peak regulation unit, a renewable energy power generation unit, an electrolytic hydrogen production unit, a hydrogen storage unit, a first-stage waste heat recycling unit, a second-stage waste heat recycling unit and a heat storage unit. The basic energy supply unit is used for providing a basic power load of the target building group; the energy storage peak regulation unit is used for providing fluctuation power load of the target building group; the first-stage waste heat recycling unit receives first-stage waste heat generated by power generation of the fuel cell and is used for indoor heating or indoor refrigeration. And the second-stage waste heat recycling unit directly receives the first-stage waste heat or second-stage waste heat from the first-stage waste heat recycling unit and is used for preheating the electrolyzed water and / or the hydrogen storage unit. By arranging the first-stage waste heat recycling unit and the second-stage waste heat recycling unit, waste heat is utilized in a multi-stage mode according to requirements, and the waste heat utilization rate is high.

The invention relates to a flow battery charge state detection device and method, and is applied to the technical field of flow batteries. Compared with the prior art, the reference detection cavity connected with the bipolar plate is formed, the reference electrolyte can be replaced and supplemented without arranging a reference electrolyte storage tank, the adaptability of the detection device is improved, and the reference detection cavity corresponds to the positive electrolyte detection cavity and / or the negative electrolyte detection cavity, so that the detection efficiency is improved. A reference electrode is arranged in a reference detection cavity, the potential deviation of a reference electrolyte can be detected and calibrated in real time, and a calibration voltage value of the reference detection cavity is obtained, so that the potential of a positive electrode electrolyte relative to the reference electrode, the potential of a negative electrode electrolyte relative to the reference electrode and the calibration voltage value are used for calibrating the potential deviation of the reference electrolyte. The concentration of each valence ion is calculated on line through a multi-parameter empirical formula, and the charge state of the flow battery is obtained in real time through the concentration of each valence ion, so that the detection error is reduced, the detection sensitivity is improved, and the real-time monitoring precision of the charge state is improved.

The invention discloses a flow battery state-of-charge estimation method based on a TCN-BiLSTM neural network and EIS data, and belongs to the technical field of flow battery management. According to the method, temperature, flow velocity, frequency, real part impedance and imaginary part impedance are extracted as input characteristics by measuring EIS data of the flow battery under different SOCs, and a hybrid model fusing a time convolutional network (TCN) and a bidirectional long-short-term memory network (BiLSTM) is constructed. The TCN captures a local time sequence dependency relationship through multi-layer expansion convolution and residual connection, the BiLSTM learns global sequence features by using a bidirectional gating mechanism, and finally, the global sequence features are mapped into SOC values through a full connection layer. According to the model, Min-Max normalization preprocessing data is adopted, a mean square error is used as a loss function and is combined with an Adam optimizer for training, and the estimation precision is evaluated through MAE, RMSE and R2 indexes. According to the method, the TCN-BiLSTM neural network model is trained based on the EIS data, the defects of a traditional SOC estimation method under the dynamic operation condition can be overcome, and the method has the advantages of being high in precision, high in robustness and wide in applicability.

The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.

The utility model discloses an active flow equalizing device of a flow battery system, which relates to the field of flow batteries and comprises a flow battery module and a flow battery capacity unit, the active flow equalizing device of the flow battery system adopts a standardized design, and one flow battery module is provided with two adjustable distributed circulating pumps. Data are collected through temperature, pressure and flow sensors, a battery management system performs analysis according to a big data algorithm, and independent control of each flow battery module is realized on each module, so that the flow of each electric pile in the module is uniform and controllable; when it is monitored that the galvanic piles in the modules run abnormally and are not controlled, the battery management system can close the control valves of the galvanic piles in time and give an early warning, subsequent fault detection is facilitated, and meanwhile normal running of the other galvanic piles is not affected. According to the utility model, stable output of the circulating pump is realized, and the pile charging and discharging efficiency is greatly improved.

The invention provides a zinc-nickel air flow battery energy storage cabinet. The zinc-nickel-air flow battery energy storage cabinet comprises a control module and a plurality of flow battery energy storage modules, each flow battery energy storage module comprises a plurality of supporting layers, an electrolyte storage tank is fixed to a first supporting layer in the supporting layers in a limited mode, a galvanic pile is fixed to a second supporting layer above the first supporting layer in a limited mode, and the control module is connected with the control module. The third supporting layer above the second supporting layer is used for installing an electric pile sensor module, a liquid delivery pump is arranged below the first supporting layer, and the electric pile, the liquid delivery pump and the electrolyte storage tank are connected through a liquid circulation pipeline; the control module comprises an air compressor; the air compressor is connected with the electric pile through an air pipeline; the control module further comprises an electric energy management system, and the electric energy management system comprises an energy management system, a power conversion system and a battery management module. According to the embodiment provided by the invention, the integration of the zinc-nickel air flow battery is realized.

The invention provides a flow battery composite electrode, a preparation method thereof and a flow battery. The preparation method comprises the following steps: placing a pretreated carbonaceous substrate in a mixed solution of a surfactant, an electrolyte and a transition metal salt, growing a metal oxide nanosheet array on the surface of the pretreated carbonaceous substrate by using an electrochemical deposition process, washing, drying and roasting to obtain the flow battery composite electrode, wherein the feeding ratio of the surfactant to the transition metal salt is (1-2) g: (0.02-0.2) mol. The invention also provides the flow battery composite electrode prepared by the preparation method and a flow battery prepared from the electrode. According to the preparation method, the electrochemical reaction activity of the electrode in the all-vanadium redox flow battery can be optimized by regulating and controlling the chemical composition and the microstructure of the catalyst loaded on the surface of the carbon fiber.

The invention relates to the technical field of battery testing, and provides a flow battery bipolar plate flow channel diversion performance testing device, which comprises an intelligent testing galvanic pile, which is composed of a plurality of detachable flow channel units, each flow channel unit comprises a bipolar plate and two flow channel frames, the flow channel frames adopt a modular design, and the flow channel units are connected with the intelligent testing galvanic pile; a plurality of micro pressure sensors, temperature sensors and flow sensors are embedded in the shell; the intelligent liquid path system comprises a plurality of independent liquid path circulating units, and each unit is composed of a liquid tank, an intelligent liquid pump, a liquid supply pipeline and a liquid return pipeline; a plurality of independent test chambers are arranged in the multifunctional shell, and a temperature and humidity control system and an intelligent drainage system are arranged in the shell; and the data acquisition and analysis system consists of a high-performance computer, a data acquisition card, a signal amplifier and analysis software. The problems that in the prior art, the local flow characteristic of the electrolyte on the surface of the carbon felt is difficult to accurately evaluate, and the requirement of optimizing flow channel design on refined data cannot be met are solved.

The invention discloses a zinc-bromine flow battery multifunctional negative electrode electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: uniformly stirring and mixing a solvent, deionized water and a cosolvent, adding an electrolyte, stirring until the electrolyte is completely dissolved, then adding a supporting electrolyte and a negative electrode additive, stirring until the supporting electrolyte and the negative electrode additive are completely dissolved, and obtaining the zinc-bromine flow battery multifunctional negative electrode electrolyte. The multifunctional negative electrode electrolyte of the zinc-bromine flow battery is obtained; the negative electrode cosolvent is dimethylformamide; and the negative electrode additive is at least one of saponin and cinnamyl aldehyde. Saponin molecules are adsorbed on the surface of the zinc electrode, and electronegative carboxyl groups of the saponin molecules form an electrostatic repulsion net in an electric double layer, so that zinc ions are forced to be uniformly dispersed, local ion concentration hot spots are eliminated, and dendritic crystal nucleation is inhibited from the source. In cinnamyl aldehyde, the strong electronegativity of oxygen atoms and the electronegativity of aldehyde oxygen are far higher than those of hydrogen, so that electrons are strongly attracted, adjacent carbon atoms are positively charged, polar adsorption sites are formed, the hydrogen evolution reaction is effectively inhibited, and the stability and the cycle life of the battery are greatly improved.

To provide an electrolyte for a redox flow battery that can reduce deposition of a metal forming an organometallic complex.SOLUTION: There is provided the electrolyte for a redox flow battery, including: an organometallic complex; and an auxiliary complexing agent including at least one type selected from the group consisting of a polycarboxylic acid, a polyol, and an aminocarboxylic acid.SELECTED DRAWING: Figure 1

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: dissolving aniline and a dithio compound in an acidic ice bath, dropwise adding a peroxy strong oxidant to generate a polyaniline-disulfide bond copolymer, dialyzing, and freeze-drying to obtain powder; then heating soluble silver salt, a reducing agent, a hydrophilic dispersing agent and an organic sulfydryl silane coupling agent to prepare functionalized nano-silver particles; the powder and nano-silver particles are dispersed in N-methyl pyrrolidone for ultrasonic treatment, and dynamic self-repairing coating slurry is prepared; and performing acid pretreatment on the carbon fiber paper, and performing electrochemical deposition on the slurry to prepare the zinc-bromine battery positive electrode material. According to the zinc-bromine battery positive electrode material, the coulombic efficiency and the voltage efficiency of a zinc-bromine flow battery are remarkably improved and the cycle life of the zinc-bromine flow battery is remarkably prolonged through methods of dynamic covalent bonds, nano-silver catalysis, a hierarchical pore structure, carbon fiber pretreatment and the like, and the zinc-bromine flow battery positive electrode material has chemical stability, efficient bromine adsorption capacity and excellent catalytic activity.

The invention relates to an all-vanadium redox flow battery fault prediction method and system, and the method comprises the steps: collecting the operation data of an all-vanadium redox flow battery, and carrying out the preprocessing of the operation data of the all-vanadium redox flow battery; constructing a Deepseek-R1 model, wherein the model comprises a convolutional neural network layer, a long and short-term memory network layer and a fusion layer; training and verifying the model; preprocessing operation data, and inputting the preprocessed operation data into the model for fault prediction and fault type diagnosis; fault early warning is triggered according to the output prediction result, and the operation parameters of the battery are automatically adjusted according to needs; and fault data is fed back to the model, and the model is optimized through online learning, so that the accuracy of fault prediction is improved. According to the method, local and time-dependent features can be efficiently extracted, rapid response is realized based on real-time data streams, fault response time is shortened, fault types can be accurately distinguished, early warning and adjustment are realized, and system downtime is shortened.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention belongs to the technical field of electrochemical energy storage, and discloses a composite bipolar plate for a zinc-bromine flow battery and a preparation method thereof.The preparation method comprises the steps that carbon fibers, ketjen black and graphene dispersion liquid are stirred to be uniform, and a conductive carbon composite material is obtained; a binder, a dispersing agent and the conductive carbon composite material are subjected to ball milling, and a bipolar plate prefabricated material is obtained; carrying out melt blending on the bipolar plate prefabricated material, and extruding to obtain a substrate; and spraying the nitrogen-doped porous carbon material on the surface of a substrate, and performing hot pressing. The graphene, the carbon fibers and the ketjen black are stirred and compounded, the carbon fibers and the ketjen black enter the space between graphene sheet layers, and the ketjen black is attached to the surfaces of the carbon fibers and the graphene, so that the structure not only can prevent the graphene from generating a re-stacking effect in the mixing process, but also can form a'point-line-surface 'ternary interpenetrating high-conductivity network, so that the conductivity of the graphene is improved. According to the preparation method disclosed by the invention, the deposition uniformity of zinc is improved, so that the voltage efficiency and the cycling stability of the battery are improved.

The invention relates to the technical field of preparation of an electrolyte for a vanadium redox flow battery, in particular to a reduction method of an alkaline vanadium-containing solution during short-process preparation of a vanadium electrolyte. The reduction method comprises the following steps: (1) adding a reducing agent sodium sulfite into an alkaline vanadium-containing solution and dissolving; and (2) acid is added into the solution obtained after dissolving in the step (1), the pH is adjusted, a reduction reaction is conducted, and vanadium is reduced to be tetravalent. The method provided by the invention effectively solves the problem of vanadium loss caused by precipitation generated in the sequential operation process of acidification and reduction of the alkaline vanadium-containing solution in the prior art, and meanwhile, the method provided by the invention is easy for engineering implementation.

The invention provides a flow battery energy storage power station full life cycle health degree assessment management method. The method comprises the following steps: constructing an initial health reference library, collecting electrochemical parameters through a reference electrode, collecting electrolyte physical parameters and environmental parameters through a sensor, synchronously recording operation and maintenance data, and carrying out time-space synchronization processing; introducing a hierarchical fusion assessment mechanism, assessing data integrity and constructing an attention mechanism model, calculating a dynamic weight according to a parameter relative change rate and a health degree correlation coefficient, generating a weighted feature vector, and predicting a short-term health degree index by adopting a bidirectional long-short-term memory network Bi-LSTM; a particle filter (PF) algorithm is introduced to be combined with a physical parameter drift distance to correct a long-term health degree index, and then a real-time health degree index is output through fuzzy comprehensive evaluation. The method can achieve the linkage evaluation of the health state in the operation period and the full life cycle trend, corrects the long-term SOH through the PF algorithm in combination with the physical parameter drift distance, and reduces the error of long-term prediction.

The invention discloses an aqueous flow battery negative electrode electrolyte based on water-soluble organic disulfide, an application of the aqueous flow battery negative electrode electrolyte and an aqueous flow battery, and belongs to the field of flow batteries. The negative electrode electrolyte comprises a water-soluble aliphatic organic disulfide, a catalyst, a supporting electrolyte and water, wherein the general formula of the water-soluble aliphatic organic disulphide is R-S-S-R, wherein R is alkyl of which the end part contains a hydrophilic group; the catalyst is one or a combination of two of selenium, sulfur and tellurium. The obtained negative electrode electrolyte is used in the flow battery, the flow battery has high energy density, excellent rate capability and excellent long cycle stability, and the cycle capacity retention rate of 2000 cycles is still greater than 95%; meanwhile, the cost is low, and the application prospect is wide.

The utility model provides a tubular flow battery liquid storage tank which comprises an electrolyte liquid storage tank body, a turbulent flow mixing part is arranged at the bottom of the electrolyte liquid storage tank body, the liquid outlet end of the turbulent flow mixing part is connected to a liquid outlet pipe, the electrolyte liquid storage tank body is filled with electrolyte, and the electrolyte flows to the liquid outlet pipe through the turbulent flow mixing part. And a plurality of inlet ends are arranged on the turbulent flow mixing part, and the multiple inlet ends are used for carrying out turbulent flow mixing on the electrolyte filled in the electrolyte storage tank body. According to the tubular liquid storage tank for the flow battery disclosed by the utility model, a plurality of inlet ends are arranged aiming at a square groove liquid storage tank which is most commonly used by a prefabricated cabin type flow battery, so that an electrolyte can form vortexes in a plurality of areas in a flowing process in the tank, and the electrolyte can be fully mixed to reduce flowing dead zones; the mixing degree and turbulence degree of liquid in the tank are improved, a flowing dead zone is avoided, and the utilization rate of electrolyte is improved.

The invention discloses an all-vanadium redox flow battery positive and negative electrode storage tank liquid level automatic balance control device which comprises a positive electrode electrolyte storage tank, a negative electrode electrolyte storage tank and a galvanic pile, a first circulation loop is formed between the positive electrode electrolyte storage tank and the galvanic pile, and a second circulation loop is formed between the negative electrode electrolyte storage tank and the galvanic pile. Venturi tubes are arranged on the positive electrode electrolyte return pipeline and the negative electrode electrolyte return pipeline, liquid pumping holes of the Venturi tubes are communicated with the negative electrode electrolyte storage tank and the positive electrode electrolyte storage tank through an electrolyte pumping pipeline, and a liquid level monitoring device is arranged on the electrolyte pumping pipeline. The venturi tube is communicated with the electrolyte suction pipeline, and redundant electrolyte in one electrolyte storage tank is sucked into the other electrolyte storage tank by means of pressure difference generated by the venturi tube, so that the design of the positive and negative electrolyte storage tanks is not limited by the relative height of the electrolyte level, and the space of the storage tanks can be fully utilized; the integration level of the battery system is improved, and the occupied area is reduced.

The invention relates to a method and device for determining the state of health of a flow battery, and relates to the technical field of flow batteries, and the method comprises the following steps: obtaining a plurality of operation parameters of the flow battery; the multiple operation parameters are input into a health feature extraction model, multiple health state parameters are obtained, the health feature extraction model is coupled with a spatial feature extraction module and a time sequence feature extraction module, and the spatial feature extraction module is used for extracting short-term coupling relations and fluctuation features of the multiple operation parameters; the time sequence feature extraction module is used for extracting a long-term dependency relationship and evolution features of a plurality of operation parameters; inputting the plurality of health state parameters into a state evaluation model to obtain an initial health index of the flow battery; obtaining a correction coefficient corresponding to the operation condition of the flow battery, wherein the correction coefficient is used for representing the influence degree of the operation condition on the aging rate of the flow battery; and determining the health state of the flow battery according to the initial health index and the correction coefficient.

The invention discloses a zinc-nickel flow battery purging system and method. The purging system comprises a purging gas supply module, a flow control module, a purging pipeline network, a pressure monitoring module, a gas collection module and an intelligent control system, the purge gas supply module is connected with the flow control module, the flow control module is connected with the purge pipeline network, the purge pipeline network is connected with the zinc-nickel flow battery stack, and the zinc-nickel flow battery stack is connected with the gas collection module. The purging gas supply module, the flow control module, the pressure monitoring module and the gas collection module are all connected with the intelligent control system; and a pressure monitoring module is arranged on the purging pipeline network. The purging system disclosed by the invention can effectively control the content of oxygen and hydrogen in the battery, reduce impurity deposition and gas accumulation on the surface of an electrode, prevent potential safety hazards caused by gas accumulation, reduce explosion risk and internal resistance of the battery, improve charge-discharge efficiency of the battery, improve safety and prolong the service life of an electrolyte and the electrode.

The invention relates to a composite additive for an all-vanadium redox flow battery electrolyte and a preparation method and application thereof, the composite additive comprises an organic ligand, organic sulfonate, phosphate and halide, and the molar ratio of the organic ligand to the organic sulfonate to the phosphate to the halide is 1: (1-2): (1-2): (1-10). Through the synergistic effect of the four added components, the precipitation problem of divalent vanadium ions under a low-temperature condition and pentavalent vanadium ions under a high-temperature condition is remarkably improved, the high-temperature stability of the positive electrode electrolyte and the low-temperature stability of the negative electrode electrolyte of the all-vanadium redox flow battery are effectively improved, the service life of the battery is prolonged, and the service life of the battery is prolonged. Meanwhile, through the synergistic effect of the four effective components, the use amount of the additive is reduced, and the use cost of the additive is reduced.

The utility model relates to the technical field of vanadium redox flow batteries, in particular to a large all-vanadium redox flow energy storage power station SOC balance recovery control system which comprises at least two redox flow battery modules, an energy storage converter and a battery management system. The flow battery module comprises an electric pile group, a positive electrode electrolyte storage tank, a negative electrode electrolyte storage tank, a variable frequency pump and SOC sensors connected in parallel to two ends of the electric pile group. During working, the SOC of each battery module is evaluated in real time through a battery management system (BMS) control system; when the BMS system monitors that the SOC difference value between the electric pile groups is too large, the SOC difference value is generally 5%. The BMS system adjusts the flow of the electrolyte flowing through the galvanic pile groups by controlling the frequency of the variable frequency pumps of the galvanic pile groups, so that the internal resistance of the galvanic pile groups is adjusted, and the charging and discharging power on each galvanic pile group is adjusted.

The invention discloses a preparation method of a modified zinc-bromine flow battery carbon felt negative electrode and the carbon felt negative electrode prepared by the method, and belongs to the field of zinc-bromine flow batteries. According to the method, after the carbon felt is soaked in a mixed solution of cuprous sulfate, water and acetonitrile, the acetonitrile is gradually evaporated from the solution through heating, the cuprous sulfate is gradually subjected to disproportionation reaction, and the copper elementary substance generated by the disproportionation reaction of the cuprous sulfate is deposited on the surface of the carbon felt, so that the purpose of loading the modified carbon felt with the copper elementary substance is achieved. The copper elementary substance is relatively stable in chemical property and has good zinc affinity, and the copper elementary substance is loaded on the surface of the carbon felt, so that the overpotential of zinc nucleation can be reduced, and reaction active sites on the surface of the carbon felt are increased. Besides, relatively strong acting force exists between copper and zinc, so that uniform deposition / stripping of zinc in the charging and discharging process is facilitated, a more uniform zinc deposition layer is formed on the surface of the carbon felt, formation of zinc dendrites is reduced, and the electrochemical performance of the zinc-bromine flow battery is improved.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: firstly, cleaning and activating a carbon-based three-dimensional conductive network substrate by adopting plasmas, performing oxygen / argon plasma etching, and performing chemical vapor deposition on carbon to prepare three-dimensional porous carbon; then growing a metal oxide nanocrystalline array on the three-dimensional porous carbon by a hydrothermal method, and carrying out ammonia gas calcination to convert the metal oxide nanocrystalline array into a metal nitride nanocrystalline array; then preparing an electro-deposition solution containing tin bismuth salt and an aniline-bromine source polymerization solution, and constructing Sn-Bi bimetallic nanoparticles and a polyaniline-bromine complex layer on the metal nitride nanocrystalline array / three-dimensional porous carbon precursor through electro-deposition and electro-polymerization in sequence to finally prepare the high-performance zinc-bromine battery positive electrode material. The positive electrode material has high conductivity, excellent Br2 / Br <-> catalytic activity and structural stability, and the coulombic efficiency, the voltage efficiency and the energy efficiency of the battery are remarkably improved.