The invention discloses a
chlorine-free compound
electrolyte for improving the performance of a
magnesium battery and a preparation method of the
chlorine-free compound
electrolyte, and belongs to the technical field of
magnesium-air battery electrolytes. The
chlorine-free compound
electrolyte for improving the performance of the
magnesium battery is a
mixed solution of
sodium sulfate,
sodium carbonate, 2-methylimidazole and deionized water.
Sodium sulfate is used for replacing
sodium chloride for the first time to prevent
chloride ions from accelerating magnesium
corrosion,
sodium carbonate reacts with a magnesium matrix to form a uniform thin magnesium
carbonate layer, and 2-methylimidazole adsorbs the surface of positively charged magnesium through an electronegative large pi bond structure,
nitrogen atoms and the like to compact a film layer. Through the synergistic effect of the three materials, loose and porous
discharge products can be inhibited from being deposited on the surface of the
anode, the utilization efficiency of the
anode is greatly improved to 87%, and the
discharge voltage is improved to-1.9 V. The
discharge performance of the air battery is improved to the greatest extent by adjusting the ratio of the
solvent to the solute; the prepared battery has the advantages of being
environmentally friendly, convenient to operate, simple in preparation process and the like, and can be applied to remote
electronic equipment.