5015 results about "Electronic conductivity" patented technology

The invention discloses a lithium ion battery internal short circuit fault detection method based on time-frequency fusion, and the method comprises the steps: firstly constructing a fractional order equivalent circuit model fused with an electrochemical aging mechanism, and simulating the paths of conductivity reduction, active material loss and lithium inventory reduction in combination with an aging empirical formula; joint modeling of the aging process and the random internal short circuit is achieved, and multi-cycle voltage and current and electrochemical impedance spectroscopy data are obtained; secondly, extracting time domain features by using a time domain attention enhanced long-short-term memory network, and analyzing frequency domain information by using a multi-scale frequency sensing convolutional neural network; and then weighting and screening two types of modal features through a dynamic gating fusion module, introducing a cross attention mechanism to establish dependency mapping between time-frequency domain features, and finally outputting an internal short circuit fault detection result. The method can solve the problems that in the lithium ion battery aging process, due to lithium dendrite growth, the internal short circuit early fault is high in concealment, and single time-frequency characteristics are difficult to detect, and early high-precision recognition of the internal short circuit fault can be achieved.

The invention discloses a hybrid Lp regularization magnetotelluric two-dimensional inversion method based on adaptive weight, and the method comprises the steps: reading magnetotelluric observation data, carrying out the quadrilateral finite element grid discretization of a whole inversion region, building an inversion grid, and building an initial model and a prior model of the inversion conductivity of the inversion region; based on the initial model and the prior model of the inversion conductivity and the magnetotelluric observation data, constructing a mixed Lp regularization inversion objective function comprising an L1 regularization item, an L2 regularization item and a data fitting item; in an inversion iteration process, adaptively adjusting weight factors of the L2 regularization item and the L1 regularization item; and based on the inversion grid, performing magnetotelluric two-dimensional inversion according to the inversion objective function mixed with Lp regularization, the initial model and magnetotelluric observation data, and outputting optimal model parameters of Gaussian Newton inversion to obtain underground electrical structure information. According to the invention, the resolution and accuracy of the inversion result are improved.

The invention discloses a phosphonic acid-based metal organic framework solid electrolyte as well as a preparation method and application thereof, and belongs to the technical field of solid electrolyte materials. The method comprises the following steps: mixing a metal salt, an organic phosphonic acid ligand and an organic solvent, carrying out a coordination reaction, and treating to obtain MOF powder; heating and activating the MOF powder to obtain activated MOF powder; the method comprises the following steps: mechanically grinding lithium salt and MOF powder to form a mixture, heating to enable the molten lithium salt to permeate and fill MOF channels, and cooling to obtain solid electrolyte powder. The ionic conductivity of the solid electrolyte at 30 DEG C reaches 1.01 * 10 <-4 > S cm <-1 >, and the solid electrolyte is kept stable in a 4.4 V high-voltage window. The symmetrical battery based on the phosphonic acid-based MOF solid electrolyte can stably operate, and shows excellent compatibility and stability of the electrolyte and a lithium metal negative electrode. The method has the advantages of simple operation, cheap and easily available components, and is expected to be suitable for large-scale preparation.

The invention relates to the technical field of integrated circuit manufacturing, in particular to a precise electroplating control system and method for an electroplated layer of a double-layer circuit board, and the method comprises the steps: building a multi-physical field coupling simulation model, and simulating the internal current density and ion concentration distribution of a via hole; constructing a mapping relation between the current density and the side wall electroplating thickness based on a simulation result, and predicting the electroplating thickness; through thickness prediction feedback, a time sequence adjustable pulse current control strategy is designed, the pulse amplitude, the duty ratio and the on-off period are dynamically adjusted, and current distribution optimization is guided; the state of the electroplating process is sensed in combination with real-time monitoring and analysis of multi-source parameters of electrode potential, conductivity and fluid velocity; and based on the prediction model and the real-time parameters, adjusting the pulse waveform and the time sequence through closed-loop compensation. According to the method, the uniformity and controllability of the thickness of the electroplated layer on the side wall of the via hole can be remarkably improved.

The invention belongs to the technical field of solid-state lithium batteries, and relates to a fluorinated double-salt cross-linked solid-state electrolyte adaptive to a lithium-free negative electrode, a solid-state lithium battery and a preparation method thereof.The preparation method comprises the steps that double-lithium salt is dissolved in a fluorinated solvent to obtain an electrolyte, then a monomer, a cross-linking agent and an initiator are added, the mixture is stirred to be uniform to obtain a precursor solution, and the precursor solution is prepared; and assembling the precursor solution, a positive electrode, a negative electrode and a solid-state electrolyte composite diaphragm into a battery, and performing gradient polymerization to form the solid-state lithium battery. According to the invention, the ionic conductivity of the solid electrolyte is more than 5 * 10 <-4 > S / cm and the oxidation potential of the solid electrolyte is more than 5.8 V by adopting a fluorinated solvent consisting of fluorinated carbonate and fluorinated carboxylate and a double-lithium-salt synergistic system and combining an in-situ interface fusion technology, so that the solid electrolyte can be matched with a 4.8 V high-voltage lithium-rich manganese-based positive electrode and a lithium-free negative electrode; and the energy density and the safety of the solid-state lithium battery are improved. The electrolyte scheme is low in cost, high in safety and good in positive and negative electrode matching performance, can be compatible with an existing battery production line, and is convenient for large-scale production.

The invention discloses an electrochemical descaling process ion concentration dynamic balance control method and system, and relates to the field of water treatment of a circulating cooling water system.The method comprises the steps that a multi-parameter sensor is deployed to collect calcium and magnesium ion concentration, pH, conductivity, flow and other multi-dimensional data in real time, and an electrochemical deposition dynamic model is combined; dynamically evaluating the time sequence change trend of the ion concentration; according to the method, an ion concentration dynamic balance control algorithm is constructed, and the current density adjusting quantity is calculated by synthesizing ion concentration deviation and historical integral deviation, so that the target current density of the electrochemical reactor is adaptively adjusted, and the system is always maintained in a target concentration interval under different inlet water quality and load conditions; precise electrolysis control is achieved by periodically adjusting power output, and the descaling efficiency and energy consumption are effectively balanced. Therefore, the self-adaptive adjustment of the electrochemical descaling process is realized, and the stability and the self-adaptability of the descaling process are remarkably improved.

The invention relates to the technical field of batteries, in particular to a solid electrolyte material and a preparation method thereof, a solid electrolyte membrane and a battery. The solid electrolyte material has a core-shell structure, the core-shell structure comprises an inner core and a coating layer arranged on the surface of the inner core, the inner core comprises a sulfide electrolyte, and the coating layer comprises an amide compound. According to the solid electrolyte material disclosed by the invention, the coating layer containing the amide compound is arranged on the surface of the sulfide electrolyte, so that the air stability of the solid electrolyte material can be effectively improved, and meanwhile, the solid electrolyte material is ensured to have proper conductivity without influencing the charge-discharge performance of a battery.

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

The invention belongs to the technical field of design and preparation of solid electrolyte materials, and particularly relates to a LiBH4-based composite solid electrolyte material and a preparation method thereof.The LiBH4-based composite solid electrolyte material is obtained by performing high-energy ball milling on a mixture of LiBH4 and one or two metal halides MX2 in a certain molar ratio in an argon atmosphere; m is Mg, Zn, Ni or Bi; x is F, Cl, Br or I. According to the LiBH4 composite solid electrolyte prepared by the preparation method disclosed by the invention, the ionic conductivity at room temperature is improved to 10 <-4 > S cm <-1 > or above, and the ion diffusion activation energy is only 0.16 eV; the process is simple, the preparation time is short, the repeatability is high, no pollution is caused to the environment, and the industrial production requirement is met, so that the all-solid-state lithium ion battery electrolyte is expected to realize commercialized application.

The invention provides an aerogel reinforced composite electrolyte thin film for a solid-state lithium battery and a preparation method of the aerogel reinforced composite electrolyte thin film, and belongs to the technical field of composite electrolytes.The thin film comprises a three-dimensional porous aerogel skeleton, a solid-state electrolyte compound and lithium salt nanocrystals; wherein the three-dimensional porous aerogel skeleton is prepared from inorganic oxide nanoparticles and a polymer precursor through a sol-gel method; pores of the three-dimensional porous aerogel skeleton are filled with the solid electrolyte compound, the solid electrolyte compound comprises lithium lanthanum zirconium oxide nanowires and a polyoxyethylene-lithium salt composite matrix, and the lithium lanthanum zirconium oxide nanowires are directionally arranged in the thickness direction of the film; the lithium salt nanocrystals grow on the surface of the pore wall of the three-dimensional porous aerogel in situ; the mass ratio of the aerogel skeleton to the solid electrolyte compound is (1: 3)-(1: 15). According to the thin film, the ionic conductivity, the mechanical strength and the interface stability of the electrolyte are remarkably improved.

The invention discloses a high-reliability self-adaptive temperature-adjusting immersed battery module. The immersed battery module comprises a shell assembly provided with an accommodating cavity and a device cabin, the battery module main body is immersed in the accommodating cavity; the reversing temperature control assembly is arranged in the battery module main body and hermetically penetrates through the accommodating cavity; the BMS is fixedly arranged in the device cabin; the gas-liquid valve assembly is arranged in the device cabin in a sealing and penetrating manner; the electronic liquid level meter and the conductivity monitor are respectively arranged in the device cabin in a sealing and penetrating manner and are respectively in contact with the cooling liquid; the reversing temperature control assembly comprises a plurality of reversing temperature control plates; the first connecting pipe mechanism and the second connecting pipe mechanism are respectively arranged on two opposite sides of the plurality of reversing temperature control plates and are respectively communicated and connected with the plurality of reversing temperature control plates; and the temperature control reversing regulator is fixedly and hermetically arranged on the inner wall of the accommodating cavity. The immersed battery module effectively solves the problems that an existing immersed battery module cannot adaptively adjust the temperature and cannot automatically monitor the amount of cooling liquid in real time.

The invention belongs to the field of atmospheric environment particulate matter monitoring, and particularly relates to an atmospheric environment salt mist concentration real-time monitoring device and method. The monitoring device comprises a computer control module, a container and a buoy, a conductivity electrode, a temperature sensor, a displacement sensor, an air inlet pipe and an air outlet pipe are integrated on the top of the container, and the air outlet pipe is connected with a reciprocating cylinder with a piston and a limit switch. The monitoring method comprises the following steps: calibrating the initial volume V < initial > of liquid and the volume V < initial > of a reciprocating cylinder; circularly collecting the conductivity k0 and k1, the temperature T0 and T1 and the displacement D and Dtotal of the buoy before and after ventilation; correcting the salt mass increment delta M through the dynamic volume, and finally outputting the salt mist concentration C; according to the invention, the defects of inaccurate ventilation volume metering, solution density change and interference of moisture in high-humidity air on concentration monitoring in the prior art are overcome, full-automatic continuous monitoring of the salt mist concentration is realized, the measurement error is effectively reduced, the measurement precision and the monitoring capability are remarkably improved, and the method has relatively good environmental adaptability.

The invention discloses a modularized ultrapure water preparation and on-line monitoring system, which comprises a pretreatment module, a purification module, a monitoring module and a control module, and is characterized in that a dynamic monitoring end is arranged, and when ultrapure water preparation is monitored in real time, a multi-parameter fusion detection mechanism and self-adaptive threshold analysis are integrated; meanwhile, the abnormal state of the water quality is dynamically judged based on the conductivity, TOC and particulate matter data collected in real time, the sudden change risk of the water quality output by the purification module can be recognized in real time, error accumulation caused by traditional single-point monitoring is avoided, and therefore the purity detection reliability of the ultrapure water is improved; and the reverse osmosis unit and the electrode deionization unit of the purification module can immediately respond to the effluent parameter change of the pretreatment module, so that the hidden dangers of membrane blockage and recovery rate reduction caused by water quality fluctuation are reduced, and the energy consumption redundancy is reduced while the water quality stability is ensured.

The invention provides a sphere-like silicon-carbon negative electrode material and a preparation method and application thereof, and particularly relates to the technical field of negative electrode materials, the negative electrode material comprises a sphere-like porous carbon skeleton, silicon nanoparticles distributed in the sphere-like porous carbon skeleton, and an amorphous carbon layer coating the surface of the sphere-like porous carbon skeleton, the particle appearance of the sphere-like porous carbon skeleton is of a round irregular or asymmetric polyhedral structure and comprises one or more of a potato shape, an ellipse shape, an olive shape, a long strip shape and a pomegranate shape, the particle of the sphere-like porous carbon skeleton is provided with a plurality of asymmetric faces, fillets are formed between the faces, and the radius of the fillets does not exceed 20 microns. The problem of structural damage of the material under the action of external force such as rolling can be effectively relieved, good mechanical stability is kept, excellent bonding performance can be achieved in the electrode coating process, the ion transmission path of the material is improved, and the electronic conductivity and the lithium ion diffusion performance are improved.

The invention belongs to the technical field of halide solid-state electrolyte, and relates to a high-conductivity and high-lithium-stability modified halide solid-state electrolyte material constructed by solid source plasma, and a preparation method and application of the high-conductivity and high-lithium-stability modified halide solid-state electrolyte material. According to the preparation method, a halide solid electrolyte is taken as a matrix, halogenated ammonium salt is taken as a solid source, and the halide solid electrolyte is subjected to synergistic doping modification of elements such as nitrogen, fluorine / chlorine / bromine and the like by utilizing a plasma technology, so that the modified halide solid electrolyte material is obtained. The modified halide solid electrolyte material shows excellent conductivity and lithium-lithium symmetrical battery performance, and has a wide market application prospect. Meanwhile, the preparation method provided by the invention is simple, rapid, efficient and convenient, is easy to control, and contributes to promoting the development and application of the high-performance halide solid electrolyte material.

The invention discloses a sulfide-based composite solid-state electrolyte, a preparation method thereof and a lithium metal solid-state battery, sulfide is subjected to specific bifunctional surface grafting modification by using a silane coupling reagent with sulfydryl and epoxy bonds, then the sulfide is introduced into a polymer precursor liquid, and the sulfide-based composite solid-state electrolyte is prepared through light-heat curing reaction synergy. A flexible and rigid cross-linked network is formed, the sulfide-based composite solid-state electrolyte with high ionic conductivity and high mechanical strength is obtained, the interface stability of the sulfide-based composite solid-state electrolyte in the charge-discharge process is ensured, for example, the sulfide-based composite solid-state electrolyte in the embodiment 1 has high ionic conductivity (3.81 mS / cm), and the interface stability of the sulfide-based composite solid-state electrolyte in the embodiment 2 is ensured. The lithium-lithium symmetric battery prepared by the method has the advantages of excellent flexibility, high tensile strength (7.9 Mpa) and wide electrochemical window (5.1 V), the lithium-lithium symmetric battery can stably circulate for 2000h, and the whole battery can stably circulate for 2000 circles at the room temperature at the rate of 4C, so that the lithium-lithium symmetric battery has great industrial application value.

The invention relates to a preparation method of a nickel ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrode materials. The nickel ion doped modified ferric sodium pyrophosphate positive electrode material is prepared by adopting an integrated process system of liquid phase uniform mixing, spray granulation and precise segmented calcination. According to the process system, atomic-scale uniform doping of nickel ions and a specific microstructure of a precursor are realized through spray drying, and a plurality of inherent key technical problems of low electronic conductivity, low ion diffusion rate, impurity phase generation and the like of an NFPP material are solved together through a synergistic effect with a subsequent calcining process; furthermore, the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, so that the battery has relatively high cycling stability.

The invention belongs to the technical field of electrochemical energy storage, and provides an immersed energy storage system and a thermal management method thereof, the immersed energy storage system comprises a sealed cabin, a battery module, an immersion liquid, a liquid cooling unit, a cooling liquid, a liquid cooling pipeline, a temperature sensor, an electrical device and a thermal management controller; the non-conductive immersion liquid with the conductivity smaller than 10 <-6 > S / m and the flash point larger than 200 DEG C is adopted to completely wrap the battery module, it is ensured that the energy storage battery cells are located in the same temperature physical environment, the temperature consistency of the system is greatly improved, the problem of uneven heat dissipation is fundamentally solved, the service life of the energy storage cabinet is directly prolonged, the immersion liquid has the flame-retardant characteristic, and the service life of the energy storage cabinet is prolonged. Thermal runaway of a battery cell can be effectively restrained, fire and explosion risks are reduced from the source, system operation safety is guaranteed, meanwhile, the type selection standard of cooling liquid is defined, the design of a sealed cabin is optimized, the heat exchange efficiency is improved through a double-circulation branch of a liquid cooling unit, the key bottleneck of an immersed cooling technology in energy storage system integration is thoroughly solved, and the energy storage system integration efficiency is improved. And full landing of technical advantages is realized.

The invention discloses a solid electrolyte, a preparation method thereof and an all-solid-state battery, and belongs to the technical field of solid electrolytes. According to the preparation method, a nano inert oxide and a solid electrolyte raw material are compounded through mechanical grinding, and the solid electrolyte with a core-shell structure is prepared; the device comprises an inner core, an interface layer and a shell from inside to outside, the inner core is a solid electrolyte matrix, the interface layer is a transition layer generated by reaction of the solid electrolyte matrix and a nano inert oxide, and the shell is a nano inert oxide layer. The material combines the advantages of high moisture resistance and wide electrochemical window of the nano inert oxide and the characteristics of high ionic conductivity and excellent mechanical property of the solid electrolyte, and the comprehensive performance of the material is remarkably improved through the synergistic effect of the components. The composite structure design not only solves the problem of performance limitation of a single material system, but also realizes collaborative optimization of ionic conductivity, environmental adaptability and electrochemical stability while ensuring the material stability.

The invention provides a phenolic resin-based spherical silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium battery materials. The preparation method comprises the following steps: preparing spherical phenolic resin by adopting a suspension polymerization method, curing to obtain phenolic resin microspheres, preparing porous carbon spheres by taking the phenolic resin microspheres as a carbon precursor in a carbonization and alkali activation manner, carrying out CVD vapor deposition on nano silicon, and carrying out carbon coating to obtain the phenolic resin-based spherical silicon-carbon composite material. The phenolic resin is utilized to form a highly cross-linked network structure after curing, the carbon spheres obtained after carbonization have good mechanical strength and rigidity, the porous structure of the porous carbon spheres provides a volume change buffering structure for nano-silicon, the lithium ion path is shortened, the spherical structure is beneficial to uniform dispersion, nano-silicon particles are prevented from gathering, and the performance of the lithium ion battery is improved. And the porous carbon spheres with high specific surface area can also improve the interface reaction activity, so that the problems of high volume expansion, low conductivity and slow ion diffusivity of silicon are solved.

The invention discloses an oxyhalide solid electrolyte, a preparation method thereof and an all-solid-state battery, and relates to the technical field of batteries. The solid electrolyte is LiaMbNcXdOe, M and N are the same elements or different elements, and M and N are at least one of Zn, Ba, Al, In, Y, Cr, Ti, Zr, Hf, Nb, Ta, La, Ce, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; x is at least one of F, Cl, Br and I. The oxyhalide solid electrolyte with high ionic conductivity and cost advantage is prepared by selecting high-valence metal oxide, halide and lithium halide through a ball milling method and combining annealing and hot pressing processes, and the oxyhalide solid electrolyte can show good electrochemical performance when being applied to all-solid-state lithium metal batteries.

The present application relates to the field of solution measurement, in particular to an electrode conductivity sensor conductivity measurement circuit and method, first, the AC excitation generation module generates an amplitude and frequency adjustable AC sine excitation signal under the control of the single-chip microcomputer; then the AC sine excitation signal passes through the precision resistor R0 and the conductivity cell of the electrode sensor to the system ground in turn; then the differential amplification circuit differentially amplifies the voltage between the precision resistor R0 and the electrode sheet of the conductivity cell; the amplified voltage signal is collected by the ADC, and then the voltage data is transmitted to the single-chip microcomputer; finally, the single-chip microcomputer can obtain the conductivity of the solution after the collected voltage data is operated. The present application directly collects the peak and valley voltage values of the AC signal, subtracts to obtain the amplitude of the AC signal, and does not need a rectification filter circuit to detect the amplitude of the AC signal, which can quickly respond to the change of the solution conductivity, eliminates the influence of common-mode interference factors, and simplifies the circuit design.

The invention relates to the technical field of lithium ion batteries, in particular to a composite lithium-rich manganese-based positive electrode material and a preparation method and application thereof. The composite lithium-rich manganese-based positive electrode material is of a three-layer structure and sequentially comprises a lithium-rich manganese-based oxide positive electrode material matrix, a first coating layer and a second coating layer from inside to outside, the first coating layer is a mixture of halide solid electrolyte and lithium-containing oxide; and the second coating layer is an oxide solid electrolyte. The conductivity of a contact interface with a positive electrode material can be improved, the resistance is reduced, the moisture absorption degradation of halide is inhibited, the packaging difficulty is reduced, and the cycle performance of the halide-added solid electrolyte after moisture absorption is improved.

The invention discloses a silicon-carbon composite negative electrode material, a negative electrode plate, a preparation method and application. The silicon-carbon composite negative electrode material is of a double-coating structure and sequentially comprises inner core silicon, a lithium phosphate layer and a fluorine-containing carbon layer from inside to outside, and the mass ratio of the lithium phosphate layer to the inner core silicon is (1-5): 100. When the composite material is applied to a lithium ion battery, the core silicon and the specific double coating layers can improve the fast charging performance and the first effect while optimizing an ion transmission path; a specific double-coating structure can be used as a buffer layer, stress generated by volume expansion of silicon can be released, and pulverization of particles is avoided; and moreover, LiF with high ionic conductivity and higher mechanical strength and an SEI film with more stable regulation and control are formed through reaction with an electrolyte, so that the structural integrity of the material is kept, and the cycle performance of the material is improved.

The invention provides a fast-charging type solid-state lithium battery alloy negative electrode material, a preparation method and a solid-state lithium battery, and relates to the technical field of lithium batteries. The alloy negative electrode material comprises the following element components in percentage by mass: 30-38% of indium In, 30-35% of tin Sn, 28-35% of bismuth Bi and 0-1.5% of doping elements, crystal phases formed by the alloy negative electrode material of the fast-charging type solid-state lithium battery at least comprise two crystal phases, namely InSn4 and InBi. The alloy negative electrode material has relatively high surface capacity, lithium ion conductivity and lithium ion diffusion coefficient, lithium dendrites do not grow on a negative electrode when a solid-state lithium battery assembled by the alloy negative electrode material is charged and discharged under high current density, and the battery is high in energy density and long in cycle life.

The invention relates to a composite diaphragm with high ionic conductivity, a composite solid electrolyte and a preparation method thereof. The composite diaphragm is composed of a lithium lanthanum-based fluorine-doped solid electrolyte LLMOF and a base membrane, the chemical general formula of the LLMOF is Li < x > La < y > M < 1 > < z > M < 2 > < w > M < 3 > O < 6 > F, wherein M1 is a tetravalent cation, M2 is a pentavalent cation, and M3 is a hexavalent cation; 1 < x + 3y < 5, 0 < x < = 2, and 1 / 3 < y < 5 / 3; 0 < = z < = 2, 0 < = w < = 2, 0 < = u < = 2, z + w + u = 2; the base membrane is a large-aperture base membrane, and the aperture r is more than or equal to 200nm and less than or equal to 1mu m; the particle size D50 of the LLMOF is 50 nm to 1 [mu] m, and the particle size D50 of the LLMOF is less than or equal to the aperture r of the base film. According to the composite diaphragm disclosed by the invention, the LLMOF solid electrolyte with an ion channel function is introduced, so that efficient conduction of ions is realized; the particle size is matched with that of a large-aperture base membrane, the membrane can be uniformly embedded into membrane holes, a continuous conduction path is constructed, and the ionic conductivity is improved; meanwhile, the composite diaphragm has excellent thermal stability and interface wettability, interface impedance is effectively reduced, and growth of lithium dendrites is inhibited.

The present invention belongs to the technical field of polymer binders, and particularly relates to a solid-state battery binder and a preparation method thereof, the solid-state battery binder comprises: a viscous monomer which is an acrylate monomer having a C3-C12 alkyl side chain; the lithium-supplying monomer is a monomer containing phosphate ester or a monomer which contains hydroxyl and amino and is easy to prepare phosphate ester through a phosphate esterification reaction; the lithium-conducting monomer is polyethylene glycol acrylate containing an ethyoxyl structure and a derivative of the polyethylene glycol acrylate; the adhesive monomer, the lithium-supplying monomer and the lithium-conducting monomer are polymerized together through a multifunctional integrated design, the adhesive has high solubility in an ester solvent due to a large number of ester groups contained in the adhesive, so that the bonding effect and the ionic conductivity of the solid-state battery can be improved, and the adhesive provided by the invention has high bonding force, and can be applied to the lithium-ion battery. The composite material has the advantages of high conductivity, high flexibility, high ionic conductivity, high solubility, high electrochemical stability, high temperature resistance and excellent comprehensive performance.

The invention relates to the technical field of batteries, in particular to a composite solid electrolyte material as well as a preparation method and application thereof. A composite solid electrolyte material comprises a base material and a composite coating layer located on the surface of the base material, the composite coating layer comprises a first coating layer and a second coating layer, the first coating layer is located on the surface of the base material, and the second coating layer is located on the surface of the first coating layer; the matrix material comprises a sulfide electrolyte material; the first coating layer is prepared from Li3PS4 and LiCl; the second coating layer contains LiF and LiPO4. According to the composite solid electrolyte material disclosed by the invention, the first coating layer (Li3PS4 and LiCl) and the second coating layer (Li3PS4 and LiCl) are arranged on the surface of the base material and are coordinated and matched, so that the composite solid electrolyte material has high ionic conductivity and high chemical and electrochemical stability.

An electrode structure for a solid-state or semi-solid-state battery is provided in which NCM electrode particles coated with an interphase layer and a nitrogen-containing carbon layer are disposed. [Solution] The NCM electrode particles comprise NCM (nickel-cobalt-manganese oxide) particles (15), primary particles (30) that coat the outer surfaces of the NCM particles, an interphase layer (16) that includes a glass phase layer (241) and a plurality of ceramic particles (242), and a nitrogen-containing carbon layer (35) that coats the exterior of the primary particles. Nitrogen-doped carbon molecules in the nitrogen-containing carbon layer aid in the conduction of electrons and lithium ions, modifying the electrical potential of the NCM particles. The nitrogen-containing carbon layer is formed by coating the surfaces of the primary particles with a nitrogen-containing polymer material and calcining the material in an inert atmosphere. Conjugated bonds are formed between the carbon and nitrogen, modifying the energy band structure, reducing the energy required for electrons to transition to the conduction band, and improving overall electronic conductivity.

The invention discloses a composite sulfide solid-state electrolyte and a preparation method and application thereof, and relates to the technical field of solid-state batteries. The composite sulfide solid electrolyte comprises sulfide solid electrolyte particles and nano ion conductor particles which are stable to water vapor, wherein the nano ion conductor particles are uniformly distributed on the surfaces and gaps of the sulfide solid electrolyte particles to form a composite structure. Therefore, through the composite structure that the nano ion conductor particles are uniformly distributed on the surfaces of the sulfide particles and in the gaps, the surface coverage of the sulfide solid electrolyte can be increased, the hydrolysis reaction rate can be reduced, and the sulfide solid electrolyte is well protected while the reduction amplitude of the lithium ion conductivity is reduced; the stability to air is improved; and the electrochemical stability is also improved. In addition, the method is simple in process, has good mass production capacity, and has high application value for actual production.