The application discloses a kind of
sulfur-coordinated iron single-atom modified
radial gradient pore
nitrogen-
doped carbon lithium-
sulfur battery positive
electrode carrier materials and preparation method and application, belong to
lithium-
sulfur battery positive
electrode material technical field.Oxidized
graphene is mixed and dispersed in water with
cellulose nanofiber, to form dispersion,
zinc salt and iron salt are prepared
mixed metal salt solution is added to the dispersion, composite hydrogel is formed by electrostatic self-
assembly and is immersed in the solution containing sulfur organic precursor, to obtain sulfur-containing composite hydrogel;After directional freezing, freeze-
drying, the
aerogel precursor with
radial gradient pore structure is obtained;In
inert atmosphere protection, with
solid-state
nitrogen source in isothermal zone but non-contact, program temperature
carbonization treatment is carried out, and the sulfur-coordinated iron single-atom modified
radial gradient pore
nitrogen-
doped carbon lithium-sulfur battery positive
electrode carrier material is obtained.By sulfur-coordinated regulation atomic activity and radial gradient pore optimization
mass transfer
synergy, the
sulfur utilization, rate performance and cycle life are significantly improved.