The invention discloses a lithium-sulfur battery cathode composite material and a preparation method thereof. According to the cathode composite material, elemental sulfur is cladded by an electric-conduction polymer poly(N-vinylcarbazole), the sulfur cathode material is guaranteed to have good electric conductivity, also sulfur and electro-discharge products thereof are constrained in the sulfur cathode material, so that relatively high sulfur utilization rate and cycling stability are obtained. According to the technical scheme, the disadvantages of sulfur as a lithium ion secondary cell cathode material are overcome, the lithium-sulfur battery cathode composite material, which is long in cycling life, high in capacity, green, environment-friendly, and simple in method, is prepared. The preparation method is simple, equipment is simple, raw material source is wide, cost is low, and the preparation method is in favor of industrial production.