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385results about How to "Special structure" patented technology

Method for detecting various pesticide residues in tobacco by utilizing multiwalled carbon nanotube

The invention discloses a method for detecting various pesticide residues in tobacco by utilizing a multiwalled carbon nanotube. The method is characterized in that an organic solvent is used for extraction; the multiwalled carbon nanotube is used as a reverse solid phase dispersion adsorbent; the tobacco samples are purified through vortex and centrifugation; a high performance liquid chromatography-tandem mass spectrum coupled technology and a gas chromatography-tandem mass spectrum coupled technology are combined to realize the synchronous detection of various pesticide residues in the tobacco. According to the method, the multiwalled carbon nanotube is used as the reverse solid phase dispersion adsorbent, so that the purification effect, the influence on the adsorption of the target analyte due to the frequently-used polar adsorbents is eliminated while the matrix effects are reduced, and a cleaner solution is provided to decrease the maintenance of the instrument in the using process; the multiwalled carbon nanotube is low in preparation cost and less in dosage and has the effect of greatly reducing the experimental cost; the method provided by the invention has the advantages of being correct in measurement, high in sensitivity and good in repeatability, and has the effect of satisfying the requirement for rapidly analyzing and detecting the large batch samples.
Owner:ZHENGZHOU TOBACCO RES INST OF CNTC +1

Core-shell structure composite material and preparation method thereof, and application of core-shell structure composite material in lithium ion battery

The invention discloses a core-shell structure composite material and a preparation method thereof, and an application of the core-shell structure composite material in a lithium ion battery. In the core-shell structure composite material, the main composition of the core is a hard carbon material, the shell is a composite coating layer formed by compounding nano lithium titanate particles and a carbonized binder, and the nano lithium titanate particles are fixed by the carbonized binder and are dispersed on the surface of the core. The method comprises the following steps: 1) preparing a hardcarbon material as an inner core; 2) by using nano lithium titanate particles, a binder and an inner core as raw materials, fixing nano lithium titanate on the surface of the inner core under the curing action of the binder to obtain a product composed of the inner core and a composite coating layer precursor coating the surface of the inner core; and 3) pre-sintering, and then sintering to obtain the core-shell structure composite material. According to the invention, the core-shell structure composite material has the advantages of high compaction, high capacity, high initial charge-discharge efficiency and good cycling stability, and has a wide application prospect in the field of lithium ion batteries.
Owner:BTR NEW MATERIAL GRP CO LTD

Preparation method for POSS/PDMAEMA organic/inorganic hybrid material according to thiol-ene click chemistry method

InactiveCN104558321AImprove performanceSmall sizeDimethylphenylphosphineDual response
The invention relates to a preparation method for a POSS/PDMAEMA organic/inorganic hybrid material according to a thiol-ene click chemistry method. The preparation method comprises the following steps: obtaining PDMAEMA through synthesis according to an RAFT polymerization method; taking dimethyl phenylphosphine as a catalyst, taking n-hexylamine as a reducer, and conducting a reduction reaction on a dithioester group at the tail end of PDMAEMA to generate sulfydryl; conducting thiol-Michael addition reactions on the double bonds of PDMAEMA containing sulfydryl and POSS containing ethenyl according to the thiol-ene click chemistry method to generate a POSS/PDMAEMA organic/inorganic hybrid material with a temperature/pH dual response. The preparation method has the advantages that the prepared POSS/PDMAEMA organic/inorganic hybrid material is small in size, stable in chemical bond, and uniform in particle diameter; due to a click reaction to PDMAEMA, the hydrophilic performance of POSS is effectively improved; in a water solution, the POSS/PDMAEMA organic/inorganic hybrid material is excellent in temperature sensibility and pH sensibility; due to a special structure and the stimulus response performance, the POSS/PDMAEMA organic/inorganic hybrid material is a new-generation environment-friendly new material product, and can be applied to drug carrying, targeted release, metal ion recovery, environmental pollutant adsorption and other fields.
Owner:TONGJI UNIV

Selenium-doped NANO silica sol used for producing selenium-enriched rice and capable of suppressing absorption and accumulation of heavy metals in paddy rice and preparation method therefor

The present invention discloses a selenium-doped nano-silica sol capable of both inhibiting the absorption and accumulation of heavy metal in rice and producing a selenium-rich rice, and a preparation method thereof. The selenium-doped nano-silica sol of the present invention is prepared mainly by using a nano-silica sol as a carrier, sodium selenite and the like as a raw material, vitamin C and the like as a reducing agent, and polyvinylpyrrolidone and the like as an emulsifier, and doping and dispersing selenium in a specific ratio in a silica sol so as to form a selenium-doped nano-silica sol with a special structure and function. The selenium-doped nano-silica sol prepared according to the invention has high stability and high concentration, and is uniform and transparent, and has a silica content of up to 20% or more, a selenium content of up to 1% or more, and low impurity content. The selenium-doped nano-silica sol of the present invention has a pH close to neutral, wherein selenium, in a nano particle form, is dispersed in colloidal silica, with a particle size of less than 50 nm; and after the foliar application, it can significantly promote the growth of crops, inhibit the absorption and accumulation of arsenic and cadmium in crops, and increase the selenium content in crops, and has no toxic and side effects on crops, and is safe to application.
Owner:GUANGDONG INST OF ECO ENVIRONMENT & SOIL SCI

Polyamide nanofiltration membrane containing sulfoacid betaine type colloid nanometer particle and preparation method thereof

The invention discloses a preparation method of a polyamide nanofiltration membrane containing sulfoacid betaine type colloid nanometer particles, and the preparation method comprises the following steps of: preparing colloid nanometer particles by adopting a soap-free emulsion polymerization method; adding to a water phase monomer solution used for synthesizing a polyamide membrane; preparing the polyamide nanofiltration membrane containing the sulfoacid betaine type colloid nanometer particles through an interfacial polymerization method. The polyamide nanofiltration membrane disclosed by the invention keeps high selectivity of the polyamide membrane on inorganic salt and greatly increases the water permeation flux of the polyamide membrane by utilizing the unique nanometer pore structure and good hydrophilicity of the sulfoacid betaine type colloid nanometer particles. Besides, the sulfoacid betaine type colloid nanometer particles have higher pollution resistance and show good stability pollution resistance in the long-term operating process of a filter membrane, thus the prepared polyamide nanofiltration membrane containing the sulfoacid betaine type colloid nanometer particles has high selectivity, permeability and pollution resistance. The preparation method of the polyamide nanofiltration membrane is simple, easy to operate and low in cost and achieves a good industrialized application prospect.
Owner:ZHEJIANG UNIV

Manganese oxide/nickel micro-sphere with porous structure, and preparation and application thereof

The invention discloses a manganese oxide / nickel micro-sphere with a porous structure, and a preparation method and application thereof. The preparation method comprises the steps of adopting manganese acetate and nickel acetate as a manganese source and a nickel source, adopting urea as a precipitator, adopting water and ethylene glycol as solvents, firstly adopting a hydrothermal method for synthesizing a carbonate precursor of manganese and nickel, and then calcining under an argon atmosphere to obtain the manganese oxide / nickel micro-sphere with the porous structure. Manganese and nickel elements in the micro-sphere are distributed uniformly, the sphere is formed by self-assembly of nanoparticles, meanwhile, a lot of staggered nanosheets exist on the surface of the sphere, each nanosheet is formed by overlapping two layers of thinner nanosheets, a gap exists between the layers, and the specific surface area is larger. The porous structure assembled by secondary particles is not only beneficial for full contact of an electrolyte and an active substance, but also effectively adapt to volume expansion of a material in a charging and discharging process, so that the electrochemical performance of the manganese oxide / nickel micro-sphere when being used as a lithium ion battery cathode material is greatly improved. The preparation method provided by the invention is easy and convenient to operate, controllable in reaction conditions, and easy for scale-up experiment.
Owner:CENT SOUTH UNIV
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