1653 results about "Fluorene" patented technology

The invention relates to novel fluorene derivatives, which are especially suitable for use in birefringent films with negative optical dispersion, to novel liquid crystal (LC) formulations and polymer films comprising them, and to the use of the fluorene derivatives, formulations and films in optical, electrooptical, electronic, semiconducting or luminescent components or devices.

A composition comprising a polymer comprising a repeat unit of Formula I.: wherein R<1 >is independently in each occurrence H, C1-40 hydrocarbyl or C3-40 hydrocarbyl containing one or more S, N, O, P or Si atoms, or both of R<1 >together with the 9-carbon on the fluorene, may form a C5-20 ring structure which may contain one or more S, N, or O atoms; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbyloxycarbonyl, C1-20 hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence, 0 or 1; X is O, S, SO2, C(R<3>)2 or N-R<3 >wherein R<3 >is aryl or substituted aryl of C6 to C40, aralkyl of C6 to C24, or alkyl of C1 to C24. Preferably R<3 >is aryl of C6 to C24 and more preferably R<3 >is an alkylated aryl group of C6 to C24; Ar is an aryl or heteroaryl group of C6 to C40 or substituted aryl or heteroaryl group of C6 to C40, preferably C6-C24, and most preferably C6-C14. Y is a conjugated moiety that can vary in each occurrence of the repeat unit.

An object is to provide a light-emitting element having high light-emission efficiency by provision of a novel fluorene derivative as represented by General Formula (G1) below.

In the formula, R¹ to R⁸ independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α¹ to α⁴ independently represent any of a substituted or unsubstituted arylene group having 6 to 12 carbon atoms. Furthermore, Ar¹ and Ar² independently represent any of an aryl group having 6 to 13 carbon atoms in a ring and Ar³ represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. J, k, m, and n each independently represent 0 or 1.

The present invention relates to silico fluorene copolymer and its application. The silico fluorene copolymer is copolymer of 2, 7-silico fluorine and narrow band gap monomer, and has absorption spectrum with absorption side band greater than 500 nm and absorption band side expanded to red light and near infrared region. It is prepared through copolymerizing 2, 7-silico fluorine and narrow band gap monomer containing hetero N and/or S atoms. It may be applied in making polymer solar cell, FET, etc. It has high mobility, high long-term stability and high energy converting efficiency.

A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

The present invention provides a compound represented by formula (1) defined in the specification. The invention further provides a liquid crystal composition comprising at least two compounds, which at least one compound out of them is the above compound. The invention still further provides a polymer obtained by polymerizing the above composition, and uses of the polymer such as a molded article having an optical anisotropy, an optical compensation element, a wavelength functional plate, an optical element, and a liquid crystal display element comprising the polymer.

An organic compound comprising a complex fluorene structure represented by one of the following formulas:

wherein:

The invention discloses a making method of new chain-extending typed fluorenyl dimaleimide, which comprises the following steps: dissolving 9, 9-di(4-amino phenyl) fluorene into N, N-dimethyl acetamide; stirring; dripping maleic anhydride of N, N-dimethyl acetamide with the same molar weight to react for 2h; adding dianhydride directly with the same molar weight; stirring 3h; adding the compound of acetic anhydride and potassium acetate; stirring under indoor temperature to react for 4h; sedimenting in the water; obtaining the product with receiving rate over 95%.

A polymer comprising repeat units of the formula:

wherein R¹ is independently in each occurrence C_1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more heteroatoms of S, N, O, P or Si or both R¹ may form, with the 9-carbon of the fluorene ring, a C_5-20 ring structure containing one or more heteroatoms of S, N, or O; R² is independently in each occurrence C_1-20 hydrocarbyl, C_1-20 hydrocarbyloxy, C_1-20 thioether, C_1-20 hydrocarbyloxycarbonyl, hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence a number from about 0 to about 1;

• m is a number from about 1 to about 2; and
• n is a number from about 3 or greater.

Provided are a silicon-containing compound having carbazole and fluorene in its molecule and an organic electroluminescent device including an organic layer employing the same. The silicon-containing compound is represented by the following formula:

The silicon-containing compound has excellent electrical characteristics and a charge transporting capability, the silicon-containing compound can be used as a hole injecting material, a hole transporting material, and/or a light emitting material that are suitable for all-color fluorescent and phosphorescent organic light emitting devices such as red, green, blue, and white fluorescent and phosphorescent organic light emitting devices. When the silicon-containing compound is used to manufacture an organic electroluminescent device, the organic electroluminescent device has a high efficiency, a low driving voltage, high luminosity, and a long lifetime.

A polymeric material comprising alternate substituted fluorene and phenylene units, as represented by the following formula wherein R1, R2, R3 and R4, which may be identical or different, are each selected from the group consisting of H, a (C1-C22) linear or branched alkyl, alkoxy or oligo (oxyetylene) group, a (C6- C30) cycloalkyl group, and an unsubstituted or substituted aryl group, and n is from about 3 to about 5000.

This invention seeks to provide a resin composition that can simultaneously satisfy resistances such as heat resistance and environmental resistance and moldability at high levels and that has excellent optical properties such as high refractivity and low birefringence and molded article thereof.

The present invention is a resin composition containing a polyester resin formed from a dicarboxylic acid component and a diol component (a) and a polycarbonate resin formed from a carbonate-forming component and a diol component (b), the diol component (a) containing a specific fluorene-containing compound and the diol component (b) containing a specific fluorene-containing compound.

An organic electro-luminescent device exhibiting an excellent heat resistance, a long serving life and a great efficiency of light emission and producing a light emission ranging from a blue light to a red light. The organic electroluminescent device comprising one or more thin-film layers which contain at least a light emitting layer and are interposed between a cathode and an anode, wherein the light emitting layer contains an amine compound represented by any of the following general formula (A) and a fluorene-based compound represented by any of the following general formula (B).

The invention is to provide such a polymerizable liquid crystal composition that is excellent in stability in a solution state, shows good coating property on a supporting substrate, and has uniform homeotropic alignment property. The polymerizable liquid crystal composition of the invention contains an acrylate compound and a bisphenol fluorene compound. The bisphenol fluorene compound is effective for controlling uniform homeotropic alignment of the polymerizable liquid crystal composition.

The present invention relates to fluorene compounds and polymers thereof, having various structures and functional groups, and capable of being used as a luminescent material for organic and polymer-based electro-luminescence (EL) element and other optical element, and to an EL element using the same as a luminescent material.

Disclosed is a resin composition for a PCB, the composition including: (a) a polyphenylene ether resin modified via a redistribution reaction of polyphenylene ether in the presence of 9,9-bis(hydroxyaryl)fluorene or 9,10-dihydro-9-oxa-10-(dihydroxyaryl)-10-phosphaphenanthrene 10-oxide; (b) a dicyclopentadiene epoxy resin represented by Formula 1; and (c) an alkylphenol aldehyde novolak curing agent represented by Formula 2, wherein, when the polyphenylene ether resin is modified via a redistribution reaction of the polyphenylene ether in the presence of 9,9-bis(hydroxyaryl)fluorene, the composition further includes (d) a brominated epoxy resin. Also, a composite substrate and a copper laminate using the same are disclosed.

Disclosed is a resin composition for a PCB, the composition including: (a) a polyphenylene ether resin modified via a redistribution reaction of polyphenylene ether in the presence of 9,9-bis(hydroxyaryl)fluorene or 9,10-dihydro-9-oxa-10-(dihydroxyaryl)-10-phosphaphenanthrene 10-oxide; (b) a polymer binder; and (c) cyanate ester or a prepolymer of the cyanate ester, wherein, when the polyphenylene ether resin is modified via a redistribution reaction of the polyphenylene ether in the presence of 9,9-bis(hydroxyaryl)fluorene, the composition further includes (d) a flame retardant. Also, a composite substrate and a copper laminate using the same are disclosed.

The invention discloses a phosphorus-containing flame retardant with fluorenyl groups and a preparation method thereof, which belong to the field of chemical materials. The flame retardant is a polymer of a structure (I). The flame retardant has relatively higher molecular weight and good compatibility with a polyester substrate and cannot easily shift. Due to the induction of 9,9-bi(4- hydroxyphenyl) fluorene, the defect that the thermal stability of the tradition polymer flame retardant is reduced after a polyester system is added is overcome, and the flame retardant has good flame retarding effect and good flame retarding durability and is favorable to environment-friendliness. The phosphorus-containing flame retardant with fluorenyl groups, provided in the invention, has the advantages of simple preparation method and easily controlled conditions. The phosphorus-containing flame retardant with fluorenyl groups, prepared by the method has broad application range, is suitable for the flame retarding of polyester, polyester alloy, engineering plastics and epoxy resin and can have excellent flame retarding effect. R in the structure (I) is or .

The invention belongs to the technical field of photoelectric materials, and particularly relates to luminescent materials based on thioxanthene-fluorene spiral structures and organic photoelectric devices adopting the materials as luminescent layers. The luminescent materials adopts the thioxanthene-fluorene spiral structures as skeleton units. Intermediates are prepared through Ullmann reactions, and then the target compounds are obtained through Ullmann reactions or Suzuki reactions. The materials are single in structure and definite in molecular weight. The spiral structures of the materials can adjust an intermolecular accumulation manner, thus effectively inhibiting exciplex luminescence. The materials have deep meaning for development of high-effect devices. The organic photoelectric devices adopting the materials as the luminescent layers have good luminescent properties and can be used for small organic molecule light emitting diodes.

The invention provides a fluorene-containing polyimide adhesive having good adhesivity with metal, which is characterized in that: the adhesive at least comprises a fluorene-containing diamine monomer, a fluorene-containing dianhydride monomer and/or a fluorene-containing end capping agent, and at least one of other fluorene-containing diamine monomers, other fluorene-containing dianhydride monomers and/or other end capping agents. A preparation method for the fluorene-containing polyimide adhesive comprises the following steps: A, dissolving a certain amount of diamine, dianhydride or the end capping agent in organic solvent, stirring at room temperature, and obtaining even polyamic acid solution; B, preparing polyimide powder or a partial imidization polyimide film by a chemical imidization method or a heat imidization method; and C, arranging the powder with certain thickness or the film between two metal sheets, and performing hot pressing on a press for a certain period of time to obtain a single-lap joint bonded part with firm adhesivity. The fluorene-containing polyimide adhesive provided by the invention is applied in the fields of high-tech such as aviation, space flight, microelectronics, etc.

The invention discloses an aggregation-induced emission molecule as well as a preparation method and use thereof. The aggregation-induced emission molecule has a structural formula (shown in the description), wherein when Ar1 and Ar2 are same groups, Ar2 is a group shown in the description; and when Ar2 is hydrogen, Ar1 is a group shown in the description. The preparation method comprises the steps of: starting from a group shown in the description, wherein X=br, and Y=H or X=H, and Y=Br and tetraphenyl ethylene boric acid ester, obtaining derivatives of fluorene containing toluene and triphenylamine units by utilizing an acid-induced intramolecular dehydration reaction, linking tetraphenyl ethylene to a ninth site of the fluorine in a conjugated manner by utilizing a Suzuki reaction, and finally obtaining a target compound. According to the compound disclosed by the invention, the heat stability and the aggregation-induced emission property are good, the solid fluorescence quanta of the compound are high in yield and are emitted by blue lights, and the compound can be applied to a luminescent layer material of a blue-light inorganic light emitting diode; and the reaction conditions of the preparation method are mild, and the yield is high.

A method to electrolytically polymerize aromatic hydrocarbons and oxidize cyclopentane structures within the hydrocarbons into cyclopentanone structures is disclosed including a method to electrolyze fluorene in the presence of an ester to produce poly(9-fluorenone). A method to electrolytically oxidize polymers having cyclopentane structures to polymers having cyclopentanone structures is also disclosed including a method to electrolyze poly(fluorene) to produce poly(9-fluorenone). In addition, a method to chemically oxidize polymers containing cyclopentane structures into polymers containing cyclopentanone structures is disclosed, including a method to oxidize poly(fluorene), with a chemically prepared oxidizing agent, to produce poly(9-fluroenone).

The invention provides a triarylamine compound and an organic electroluminescent device thereof, and relates to the technical field of organic photoelectric materials. According to the invention, a substituted or unsubstituted 9-phenyl-fluorene group and a triarylamine group containing benzoxazole/benzothiazole/benzimidazole/benzotriazole undergoes a reaction to obtain the triarylamine compound by9-position (tertiary C) connection of fluorene. The triarylamine compound has a good hole transport capability, is high in glass transition temperature, good in thermal stability, good in film-forming property, high in refractive index and simple to synthesize, can be applied to an organic electroluminescent device to serve as a hole transport layer and/or a covering layer, can effectively solvethe problems of low luminous efficiency and short service life of the organic electroluminescent device, and has the advantages of high luminous efficiency and long service life.

The invention provides a pyridine-fluorene organic electrophosphorescence main body luminescent material and a preparation method thereof, relating to new-generation organic luminescent display materials and technology. Due to the rigid structure, the luminescent material has high triplet energy level and favorable hole injection and transmission performance; and due to the three-dimensional large-volume steric hindrance effect, the luminescent material has stable amorphous state, and thus, can be widely used in organic light-emitting diodes. The specific design structure of the pyridine-fluorene main body material is disclosed in the specification. The invention particularly relates to a preparation method and application in organic light-emitting diode devices. The material has the advantages of high luminescence efficiency, high heat stability, high glass transition temperature and simple synthesis method, and can effectively inhibit concentration quenching and dimer luminescence. The preliminary structure as the main body material implements red-green-blue tricolor organic electroluminescent devices. The compounds have wide application prospects and huge commercial value in the aspects of electrophosphorescent main body materials.

The invention relates to an organic material containing spiro (benzo[de]anthracene-7.9'-fluorene) and an organic electroluminescent device utilizing the same, specifically to a new spiro-typed organic material used to an organic electroluminescent device and an organic electroluminescent device having excellent features of low electric power and high efficiency using the organic material.