727 results about "Poly ether ether ketone" patented technology

The invention relates to the technical field of heavy anti-corrosion coatings, in particular to a graphene enhanced epoxy modified organic silicon resin heavy anti-corrosion powder coating. The coating is prepared from the following components in parts by weight: 42 to 58 parts of epoxidized epoxy modified organic silicon resin, 0.8 to 2.5 parts of hydroxylated graphene, 6 to 11 parts of nano zirconium dioxide coated boron nitride, 2.5 to 5.5 parts of lanthanum iso-octoate-titanate composite coupling agent, 1.5 to 3.5 parts of bis (3-triethoxysilylpropyl) disulfide, 4 to 7 parts of polyhedral oligomeric silsesquioxane, 5 to 8 parts of curing agent, 0.8 to 1.8 parts of flatting agent and 0.4 to 0.9 part of defoaming agent. 2.5 to 4.5 parts of polyether-ether-ketone micro powder and 1.2 to 2.8 parts of fluorine-containing phosphate ester. According to the invention, the resin is modified through chemical bridging, the modified graphene and the nano-coated powder are matched to construct a synergistic enhancement system, and the interface bonding is optimized by the composite coupling agent. The coating is excellent in adhesive force, corrosion resistance and mechanical property, good in processing fluidity and high in aging resistance and thermal stability, solves the problem that a traditional product is short in performance, and meets the industrial requirement.

The invention relates to an electromagnetic shielding resistant PPS alloy material containing modified carbon nanotubes, and belongs to the technical field of polymer composite materials. The PPS alloy material comprises 70-85 parts of polyphenylene sulfide, 5-15 parts of polyether-ether-ketone or a liquid crystal polymer, 3-8 parts of carbon nanotubes subjected to acyl chloride-amido double-step modification and 5-12 parts of carbon fibers subjected to oxidation treatment, and the carbon fibers subjected to oxidation treatment are covalently connected with the carbon nanotubes subjected to double-step modification. 0.5 to 1.5 parts of a coupling agent, 0.3 to 0.8 part of an antioxidant and 0.2 to 0.6 part of a lubricant. According to the invention, the carbon nanotubes are subjected to surface grafting group modification, and the carbon fibers are subjected to surface oxidation treatment, so that the technical problems that the carbon nanotubes are easy to agglomerate, the interface between the carbon fibers and the matrix is weak, and the shielding efficiency and the mechanical property are difficult to consider are solved, and the carbon nanotubes and the PPS matrix form a composite reinforced structure; the comprehensive improvement of the material in the aspects of electromagnetic shielding, mechanical property, thermal stability and the like is realized.

An article, a method of making the same, and a method of using the same are provided. Such an article includes at least one coated layer, which includes a substrate and a coating disposed on the substrate. The coating includes a layered nanomaterial and a solute embedded and distributed in the layered nanomaterial. The solute comprises at least one salt soluble in a solvent. The substrate comprises a polymer, for example, a high-performance polymer such as polyether ether ketone and poly(para-phenylene terephthalamide). The article is used for thermal management applications, for example, as protective garment.

The invention relates to a filter screen and a preparation method and application thereof, and belongs to the technical field of filtering equipment, the filter screen comprises a hydrophobic enhancement layer, a pre-filtering layer and a core filtering layer which are stacked in sequence; the hydrophobic reinforcing layer comprises the following components: metal fibers; the pre-filtering layer is prepared from the following components: basalt fibers; and the core filter layer comprises the following components: polytetrafluoroethylene fibers and polyether-ether-ketone fibers. By designing the structure of the filter screen, the filter screen which can stably work in a high-temperature environment, has excellent hydrophobic performance and filtering efficiency and is controllable in manufacturing cost is obtained.

The invention discloses a preparation method of a tinned copper core fluorinated ethylene propylene insulated cable for aerospace, and relates to the technical field of aerospace cable preparation methods. The preparation method comprises the following steps: S1, preparing a nickel-plated copper core; s2, preparing a heat insulation layer; s3, a composite insulating layer is prepared, the composite insulating layer is composed of a first insulating layer, a second insulating layer and a third insulating layer from inside to outside, the first insulating layer is a fluorinated ethylene propylene layer, the second insulating layer is a polyimide / fluorinated ethylene propylene composite layer, and the third insulating layer is a polyether-ether-ketone layer; s4, preparing a shielding layer; and S5, preparing a protective layer. The invention provides the preparation method of the tinned copper core fluorinated ethylene propylene insulated cable for aerospace, the insulated cable prepared by the preparation method has high performance and high reliability in an extreme aerospace environment, and all key requirements of electrical performance, radiation resistance, mechanical strength and wear resistance are comprehensively met.

The invention discloses a digital stable jaw pad designing and manufacturing method, and relates to the technical field of oral rehabilitation and digital medical technology.The digital stable jaw pad manufacturing method comprises the following steps that a, three-dimensional point cloud data of oral dentition and mucosa of a patient is obtained through a three-dimensional scanner; b) determining a stable jaw position coordinate model by using an optical motion capture system; c) designing a jaw pad three-dimensional entity model with an anterior tooth area, a posterior tooth area and an edge structure based on the three-dimensional point cloud data and the stable jaw coordinate model; and d) manufacturing the jaw pad through 3D printing equipment, wherein the 3D printing equipment is formed by adopting a polyether-ether-ketone material. By integrating digital acquisition, design and manufacturing technologies, the pain point of a traditional method is solved, and personalized, high-precision and rapid manufacturing of the stable jaw pad is realized.

The invention relates to the technical field of biological materials for 3D printing, in particular to a polyether-ether-ketone composite material with an enhanced 3D printing function and a preparation method of the polyether-ether-ketone composite material. The invention discloses a polyether-ether-ketone composite material with an enhanced 3D printing function. The material is prepared from the following raw materials in parts by mass: 75-85 parts of polyether-ether-ketone, 5-10 parts of a modified bioactive material, 1-3 parts of carbon nanotubes, 0.5-2 parts of an organic nucleating agent, 0.1-1 part of a biological regulator and 0.1-1 part of an antibacterial agent, the modified bioactive material is modified hydroxyapatite and / or modified tricalcium phosphate. According to the basic formula, the synergistic effect of multifunctional components is achieved, the defects of an existing PEEK material in the aspects of biological activity and crystallization performance are overcome through the components such as polyether-ether-ketone, the modified bioactive material and the carbon nanotubes which are meticulously proportioned, and excellent mechanical performance and biocompatibility are provided.

The invention relates to the technical field of anion exchange membranes, in particular to a dual-ion-channel synergistic enhanced conduction anion exchange membrane for alkaline water electrolysis hydrogen production and a preparation method of the dual-ion-channel synergistic enhanced conduction anion exchange membrane for alkaline water electrolysis hydrogen production, and the dual-ion-channel synergistic enhanced conduction anion exchange membrane for alkaline water electrolysis hydrogen production is prepared by blending and crosslinking quaternized polyether-ether-ketone and carboxylated polyether sulfone, the carboxylated polyethersulfone provides a cation channel to form a double-ion synergistic conduction structure; the preparation process of the anion exchange membrane comprises the steps of quaternized polyether-ether-ketone synthesis, carboxylated polyether sulfone synthesis, membrane casting solution preparation, tape casting drying, crosslinking treatment and alkali liquor ion exchange. By constructing a double-ion channel structure, the synergistic conduction of anions and cations is realized, and the total ion conduction efficiency of the membrane is remarkably improved. The two polymer components form a continuously interlaced channel network, so that the defect that the conduction path of the traditional single ion channel membrane is isolated is avoided.

The invention discloses a high-conductivity porous polymer composite material and a preparation method thereof, and relates to the technical field of conductive composite materials. The high-conductivity porous polymer composite material is prepared by mixing polyether-ether-ketone, amino-functionalized graphene, a silver nanowire / carbon nanotube hybrid filler, a porous polyimide microsphere carrier, an ionic liquid and an antioxidant. The preparation method comprises the following steps: preparing amino-functionalized graphene; preparing a hybrid filler microsphere complex; performing mixing; preparing a porous prefabricated body; and carrying out mould pressing and shaping. According to the composite material disclosed by the invention, through multi-scale structural design and environment-friendly process innovation, high conductivity, high-strength mechanical properties and light weight are realized under the condition of low filler addition amount.

The invention belongs to the technical field of polymer chemical production, and discloses a method for continuously and efficiently preparing polyether-ether-ketone. The method comprises the following steps: dissolving 4, 4 '-difluorobenzophenone and diphenyl sulfone in a first dissolving tank to obtain a 4, 4'-difluorobenzophenone solution; hydroquinone, a catalyst and diphenyl sulfone are placed in a second dissolving tank to be dissolved, and a hydroquinone solution is obtained; the preparation method comprises the following steps: injecting a 4, 4 '-difluorobenzophenone solution and a hydroquinone solution into a reactor for polymerization reaction to obtain a mixed solution; injecting the mixed solution into a separator through a heat exchanger for separation to obtain polyether-ether-ketone and liquid; distilling the liquid to obtain diphenyl sulfone and sodium fluoride, and returning the obtained diphenyl sulfone to participate in dissolution; all the steps are carried out in a protective atmosphere. The preparation process provided by the invention is a brand new PEEK production process flow, and realizes continuous PEEK production and efficient energy recycling.

The invention relates to polyether-ether-ketone resin with extremely narrow molecular weight distribution as well as a preparation method and application of the polyether-ether-ketone resin. The preparation method of the polyether-ether-ketone resin comprises the following steps: uniformly mixing 4, 4 '-difluorobenzophenone, a phenolic monomer, a salt-forming agent and a solvent in an inert atmosphere, carrying out gradient heating, and then carrying out end capping; the gradient heating comprises the following steps: in the initial stage, the heat preservation temperature is 140-210 DEG C, in the transition stage, the heat preservation temperature is 250-280 DEG C, and in the final stage, the heat preservation temperature is 300-320 DEG C. The prepared PEEK resin has very narrow molecular weight distribution, the chemical, heat-resistant stability, anti-fatigue performance and mechanical performance of the PEEK resin can be remarkably improved, and the high-performance and high-quality requirements of PEEK in the high-end manufacturing field such as aerospace, medical treatment, electronics and semiconductors are met.

The invention discloses a low-dielectric-constant polyamide material, and relates to the technical field of high polymer materials. The invention discloses a low-dielectric-constant polyamide material. The composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of polyamide 66, 5 to 10 parts of polytetrafluoroethylene micro powder, 8 to 12 parts of modified porous siloxane microspheres, 3 to 7 parts of modified nano zinc oxide, 10 to 15 parts of glass fibers, 4 to 8 parts of polyether-ether-ketone, 1 to 3 parts of graphene nanosheets, 3 to 5 parts of fluororubber, 1 to 2 parts of a titanate coupling agent, 0.3 to 0.7 part of an antioxidant 1010, 0.5 to 1.0 part of ethylene bis stearamide and 0.1 to 0.3 part of an ultraviolet absorbent UV-531. The low-dielectric-constant polyamide material has the remarkable advantages that the raw materials are scientifically proportioned, and various modified components are contained to enhance the performance; all the components are subjected to special treatment, so that the compatibility is good; the preparation process is rigorous, and the material has excellent dielectric properties; and the material also has good heat resistance and weather resistance and strong mechanical properties, and is suitable for various scenes with high dielectric constant requirements.

The invention discloses a polyphenol modified carbon fiber reinforced sulfonated polyetheretherketone composite material and a preparation method thereof, and belongs to the field of polymer composites.The preparation method comprises the steps that a resin matrix and filler are filled into a mold to be sintered, the resin matrix is sulfonated polyetheretherketone, the filler comprises modified carbon fibers and nano-silicon dioxide, and the modified carbon fibers and the nano-silicon dioxide are sintered to obtain the polyphenol modified carbon fiber reinforced sulfonated polyetheretherketone composite material; the modified carbon fiber is prepared by taking carbon fiber, catechol and polyethyleneimine as raw materials in a Tris buffer solution. The hydration lubrication performance of a resin matrix is improved through sulfonated polyetheretherketone, the hydrophilic property is enhanced, a polyphenol coating is formed through self-polymerization reaction on the surfaces of the carbon fibers, the adhesion performance of the surfaces of the fibers is improved through the pi-pi stacking effect, and the interface bonding force between the carbon fibers and the modified resin matrix is enhanced; the nano silicon dioxide is introduced to modify the matrix of the composite material, so that not only is the overall wettability of the material optimized, but also the mechanical property and the wear resistance are effectively improved, and the final composite material has the characteristics of high strength and low friction.

The invention discloses a high-temperature-resistant composite material for manufacturing a wafer chuck and a preparation method of the high-temperature-resistant composite material, and belongs to the technical field of composite materials. The high-temperature-resistant composite material for manufacturing the wafer chuck is characterized by comprising the following components in parts by weight: 40-60 parts of maleic anhydride grafted polyvinylidene fluoride, 10-20 parts of modified glass fibers, 20-40 parts of polyether-ether-ketone, 1-5 parts of a compatibilizer, 0.5-2 parts of a lubricant and 1-3 parts of an antistatic agent, wherein the modified glass fiber is polyimide coated modified glass fiber. By reasonably selecting and proportioning the maleic anhydride grafted polyvinylidene fluoride, the modified glass fiber, the polyether-ether-ketone and other components and adding the compatibilizer, the lubricant and the antistatic agent, the high temperature resistance of the material and the compatibility among the components are effectively improved, so that the service life of the composite material is remarkably prolonged.

The invention relates to a corrosion-resistant, radiation-resistant and wear-resistant magnetic stirring rotor which comprises a magnetic core and an outer coating layer, and the outer coating layer is made of a carbon fiber and carbon black reinforced polyether-ether-ketone composite material and has corrosion-resistant, radiation-resistant and wear-resistant performance. The compression molding mold for the corrosion-resistant, radiation-resistant and wear-resistant magnetic stirring rotor comprises a bottom plate, an upper plate A and an upper plate B. The manufacturing method of the corrosion-resistant, radiation-resistant and wear-resistant magnetic stirring rotor comprises the following steps: firstly preparing outer coating layer half parts through the bottom plate and the upper plate A, then wrapping a magnetic core with the two outer coating layer half parts, and carrying out integrated compression molding through the bottom plate and the upper plate B, so as to obtain the corrosion-resistant, radiation-resistant and wear-resistant magnetic stirring rotor. The corrosion-resistant, radiation-resistant and wear-resistant magnetic stirring rotor has the advantages of high reliability, long service life, high stirring efficiency and high control precision.

The invention discloses a carbon fiber reinforced wear-resistant polyether-ether-ketone composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. According to the invention, the modified carbon fiber is obtained by one-step synergistic treatment of carbon fiber through oxidizing agent oxidation-silane grafting-nano oxide loading. In the carbon fiber reinforced wear-resistant PEEK composite material, specific modified carbon fibers are used as reinforcing fibers, so that the high-temperature performance of a PEEK matrix can be enhanced, the high-temperature wear resistance can be improved, and meanwhile, high mechanical properties are kept. The material performance synergism is excellent, and through the synergistic effect of the modified carbon fiber (enhanced interface), the nano oxide (enhanced matrix) and the inorganic lubricating material (lubrication barrier), the problem that high-temperature wear resistance and mechanical performance are difficult to consider at the same time in the prior art can be solved. In addition, the invention also has obvious cost and environmental protection advantages.

The invention discloses a modified aramid fiber reinforced polyether-ether-ketone composite material as well as a preparation method and application thereof, and belongs to the technical field of fiber reinforced resin-based composite materials. The preparation method comprises the following steps: firstly activating the surface of aramid fiber by adopting plasma treatment, then coating polydopamine as a middle adhesion layer, then depositing amino-functionalized metal organic framework MOF-808-NH2 nanoparticles, and finally compounding the interface modified aramid fiber and polyether-ether-ketone to prepare the fiber-reinforced polyether-ether-ketone composite material. The method is different from a common fiber modification means in the prior art, a gradient functional interface is constructed through organic combination and supplement of functions of all the steps, the interface performance is greatly improved, and the overall mechanical property of the composite material is greatly improved based on the excellent interface bonding force between the aramid fiber and the polyether-ether-ketone matrix. Meanwhile, the dielectric strength and the electric insulation reliability of the whole material are also improved, so that the material is more suitable for harsh electric insulation application occasions.

The invention relates to the technical field of equipment lubricating oil monitoring, in particular to a wear debris electrostatic monitoring method and system based on combination of characteristic mode decomposition and time-frequency images, and an electrostatic sensor monitoring system comprises a sensor shell, an annular copper probe, a polyether-ether-ketone pipeline, a shielding cover, a signal processing circuit and other modules. An insulating pipe in the sensor is a polyether-ether-ketone pipeline, lubricating oil passes through the inside of the polyether-ether-ketone pipeline, and a red copper probe of the sensor is attached to the outer surface of the polyether-ether-ketone pipeline. The method comprises the following steps of: firstly, constructing a signal enhancement model based on characteristic modal decomposition and a kurtosis measurement criterion, and screening out a key modal component with high sparsity for reconstruction by calculating a Gini coefficient of each modal component; further enhancing the signal pulse of the wear debris through modal component optimization reconstruction and a sparse representation model; and finally, identifying the wear debris impact signal based on the continuous wavelet transform time-frequency image to realize real-time monitoring of the wear debris.

The invention discloses a dental implant containing a bioactive surface and a preparation method of the dental implant, relates to the technical field of implants, and aims to improve the biological activity of the dental implant, perform multiple treatments on the surface of the dental implant, and form a microcosmic concave structure on the surface of the implant through sand blasting and laser etching to induce bone growth. Acid liquor and alkali liquor are used for treating the surface of the implant, active hydroxyl is introduced to the surface of the implant, the surface hydrophilicity is improved, and the reaction activity of subsequent reaction steps is improved; then, polyether-ether-ketone with antibacterial performance and hydroxyapatite with biological activity are further introduced into the surface of the dental implant, so that the biological activity of the dental implant is effectively improved.

The invention discloses a high-strength, high-temperature-resistant and anti-static polyether-ether-ketone composite material for electronic equipment and a preparation method of the high-strength, high-temperature-resistant and anti-static polyether-ether-ketone composite material. Comprising the following components in percentage by mass: 60%-70% of polyether-ether-ketone, 15%-20% of carbon fibers, 7%-10% of polytetrafluoroethylene, 3%-5% of boron nitride, 1%-3% of carbon nanotubes, 1%-2% of a silane coupling agent and 0.5%-1% of an antioxidant, and the sum of the mass percentages of all the components is 100%. When the prepared polyether-ether-ketone composite material is applied to electronic components, the mechanical strength, the thermal conductivity, the thermal stability, the chemical corrosion resistance and the antistatic property of the polyether-ether-ketone composite material can be further improved while the original excellent temperature resistance of the polyether-ether-ketone can be kept, so that the range of manufacturing and using the material as the electronic components is wider.

The invention discloses an acid-resistant nanofiltration membrane and a preparation method thereof, and belongs to the technical field of membrane separation. The gradient heterojunction active layer is formed on the base film through sequential interfacial polymerization and comprises a polysulfonamide bottom layer adjacent to the base film and a polyamine-metal organic framework composite layer located on the polysulfonamide bottom layer; the gradient heterojunction active layer is coated with the pH response self-repairing layer, and the self-repairing layer comprises pH response type microcapsules dispersed in cross-linked polyvinyl alcohol hydrogel; the membrane has excellent self-repairing capability and maintenance convenience, the repairing efficiency of artificial microcosmic damage in an acid environment within 24 hours can reach 85% or above, tiny scratches and defects generated in the operation or installation process of the membrane can be automatically repaired, the failure of the whole membrane element caused by tiny damage expansion is avoided, and the service life of the membrane element is prolonged. And the unplanned shutdown risk and the special repair and maintenance cost are reduced.

The invention discloses polyether-ether-ketone resin with a microporous structure and a preparation method thereof, and relates to the technical field of high polymer materials. The foaming agent is added in the polymerization reaction process of the polyether-ether-ketone resin, a chemical foaming method and a physical foaming method are combined, and the polyether-ether-ketone resin is foamed through a two-step method, so that the cell density and the foaming ratio of the polyether-ether-ketone resin with a microporous structure are improved; the material density of the polyether-ether-ketone resin with the microporous structure is reduced. According to the invention, a polymerization process and a foaming process of the polyether-ether-ketone resin are combined, and compared with direct foaming of a polyether-ether-ketone material, the prepared polyether-ether-ketone resin with the microporous structure has the advantages of higher cell density, higher foaming ratio and lower material density.

The invention provides a polyether-ether-ketone composite membrane as well as a preparation method and application thereof, and belongs to the field of composite materials. The invention provides a polyether-ether-ketone composite membrane. The polyether-ether-ketone composite membrane comprises a coating, a first aramid fiber composite membrane and a second aramid fiber composite membrane, the coating is arranged on the surface of the first aramid fiber composite film; the first aramid fiber composite membrane comprises first polyether-ether-ketone and first deprotonated aramid fiber dispersed in the first polyether-ether-ketone; the second aramid fiber composite film comprises second polyether-ether-ketone, and graphene, multi-walled carbon nanotubes and second deprotonated aramid fibers which are dispersed in the second polyether-ether-ketone; the coating comprises soluble polyaryletherketone and mica sheets and / or boron nitride wrapped by the soluble polyaryletherketone; the coating is of a porous structure. The polyether-ether-ketone composite film disclosed by the invention has excellent radiation cooling performance, solar heating performance and heat-conducting performance.

The invention relates to the technical field of high-molecular compounds, in particular to a PTFE microporous membrane and a preparation method and application thereof. The composite conductive material is prepared from the following components in parts by weight: 55 to 65 parts of PTFE dispersion resin, 5 to 8 parts of graphene quantum dot / carbon nanotube and metal organic framework composite conductive phase, 6 to 9 parts of POSS-graphene hybrid modified nano silicon dioxide, 7 to 10 parts of fluorosilane grafted polyether-ether-ketone-polyimide block copolymer, 3 to 5 parts of nano hydroxyapatite-chitosan composite particles and 10 to 15 parts of composite pore-foaming agent. 1 to 3 parts of organic montmorillonite; wherein the grafting rate of the block copolymer is 25-30%, the fluorine content is 12-15 wt%, and the silicon-oxygen bond density is 0.8-1.2 mmol / g. The preparation method has the advantages of good mechanical properties and stability, multifunction synergy, pollution resistance, good biocompatibility, process optimization, improvement of consistency, meeting of multi-field requirements, and wide application prospect.

The invention discloses a metamaterial RFID (Radio Frequency Identification) anti-interference antenna structure for a severe environment and a manufacturing method of the metamaterial RFID anti-interference antenna structure. The middle layer of a substrate of the antenna structure is made of corrosion-resistant polyether-ether-ketone resin doped carbon nanotubes; the upper-layer metal patch of the electromagnetic band gap unit array and the lower-layer metal layer of the annular gap are respectively attached to the upper surface and the lower surface of the middle layer of the substrate; and a self-adaptive impedance matching module is arranged at the joint of the equipment antenna and the feeder line. And each unit in the electromagnetic band gap unit array vertically penetrates through the substrate through a metalized via hole and is connected with the upper-layer metal patch and the lower-layer metal grounding layer of the substrate to form an LC resonance unit. The skin effect of eddy current on the metal surface can be counteracted through the reverse induction current, the loss of energy on the metal surface is greatly reduced, and the radiation efficiency of the metal surface is remarkably improved. In a complex electromagnetic environment, signals can be radiated and received more efficiently, the communication stability and reliability of an RFID system are effectively enhanced, and the probability of signal loss and error codes is reduced.

The embodiment of the invention discloses an injection-molded long carbon fiber reinforced polyether-ether-ketone alloy composite material and a preparation method thereof. Nano filler modified polyether-ether-ketone alloy powder is prepared from polyether-ether-ketone, modified resin and a nano modifier; preparing soft and hard sizing agent hybrid modified long carbon fibers from continuous carbon fibers and the prepared sizing solution; nano-filler modified polyether-ether-ketone alloy powder, a deionized water solution containing a surfactant and a thickening agent and soft and hard sizing agent mixed modified long carbon fibers are adopted to prepare long carbon fiber master batches; and carrying out injection molding on the long carbon fiber master batch by adopting an optimized injection molding process to prepare the long carbon fiber reinforced polyether-ether-ketone alloy composite material. The mechanical properties, electric conduction, heat conduction and friction properties of the composite material are greatly improved, and the defects of a polymer material in the aspect of functionality are further made up; moreover, the effective retention length of fibers in the injection molding master batch is greatly increased, the organic solvent is prevented from damaging molecular chain segments of a resin matrix, and the injection molding master batch is more environment-friendly.

The invention discloses a preparation process of polyether-ether-ketone, and relates to the technical field of preparation of inorganic compounds. The preparation process comprises the following steps: reacting 4, 4 '-difluorobenzophenone, sodium carbonate and hydroquinone to generate polyether-ether-ketone, taking a polyaryletherketone block oligomer as an end-capping reagent, reacting 4, 4'-difluorobenzophenone with 4, 4 '-dimercaptodiphenyl sulfone, and then reacting with pentaerythritol phosphate to obtain the polyaryletherketone block oligomer. The thioester bond reversibly breaks at the polymerization temperature, exposed active sulfenyl reacts with hydroxyl at the tail end of the polyether-ether-ketone to form a more stable covalent bond, volatilization of the end-capping reagent is avoided, meanwhile, the initial decomposition temperature of the end-capped polyether-ether-ketone is increased, and the stability of the end-capping reagent is improved. The polyether-ether-ketone generated in the polyether-ether-ketone resin product is subjected to treatment procedures of crushing, organic solvent extraction, water washing, filtering, drying and the like, so that the product polyether-ether-ketone is obtained, less three wastes are generated, the solvent can be recycled, the atom economy is relatively high, and the preparation process of comprehensive utilization of resources is realized.

The invention discloses a high-temperature-resistant and high-voltage-resistant cable for aerospace. The high-temperature-resistant and high-voltage-resistant cable sequentially comprises a conductor core layer, an inner semi-conductive layer, a combined insulating layer, an outer semi-conductive layer and a shielding layer from inside to outside, wherein the combined insulating layer is of a combined structure formed by wrapping a polyimide composite film and extruding polyether-ether-ketone. According to the cable disclosed by the invention, the high temperature resistance, the high pressure resistance and the irradiation resistance are remarkably improved by optimizing the material and the structural design; meanwhile, the device is suitable for a spacecraft high-voltage system, and has the advantages of high reliability, long service life and the like.

The invention relates to the technical field of polymer composite materials, in particular to a cable polymer composite material for a wind turbine blade, which is prepared from the following raw materials in parts by weight: a polymer base material; a reinforcing material; a polymer modified material; a functional additive; a performance modifier; the functional additive is prepared from an anti-ultraviolet agent, an antioxidant, a silane coupling agent and nano titanium dioxide. According to the invention, the epoxy modified polyether-ether-ketone and bisphenol A epoxy resin compounded base material is matched with a continuous glass fiber, carbon fiber chopped strand and nano silicon nitride multi-element reinforcing system, so that the core short board of insufficient mechanical properties of the traditional material is thoroughly solved, and a magnesium hydroxide, aluminum hydroxide, expanded graphite and nano montmorillonite compounded flame-retardant system is also selected, so that the flame-retardant performance of the material is greatly improved. The flame-retardant cable material is high in flame retardance, free of toxic gas release, capable of meeting the environment-friendly requirement, capable of improving the material interface bonding force and long-term service reliability and capable of meeting the requirement for the service life of 20 years or above of wind power blade cables.

The present invention provides a sulfide-polymer composite solid electrolyte and a preparation method thereof, belonging to the field of batteries. In the present invention, lithium sulfide reacts with phosphorus pentasulfide to generate a partially crystallized sulfide network, and high-valent metal ions are doped to optimize the lattice structure, enhancing conductivity and chemical stability; the crystalline phase provides an efficient ion migration channel, and the amorphous region reduces the grain boundary effect and improves the conduction uniformity; a metal chloride and lithium fluoride coating layer is used to isolate moisture and oxygen, and polyaniline coating reduces the interfacial impedance and enhances the cycle stability. The crystallinity is reduced and the amorphous region is increased by sulfonated polyether ether ketone, providing a low-impedance path for lithium ions; the polyethylene glycol chain segment improves the flexibility and ion migration ability, and the three-dimensional network structure is formed by crosslinking to enhance the mechanical strength and interfacial stability. The inorganic phase and the polymer act synergistically to construct a bicontinuous ion conductive network to improve the comprehensive performance.