291 results about "Bronze" patented technology

The invention relates to a high-stability bronze powder pigment and a preparation method and application thereof.The preparation method comprises the following steps that copper-zinc alloy coarse powder, stearic acid and a dissolved compound passivator are taken and subjected to ball milling in the nitrogen atmosphere, and a ball milling product is screened, washed and subjected to suction filtration to obtain an amino-functionalized passivated base material; the preparation method comprises the following steps: dispersing SiO2 in anhydrous isopropanol to obtain a reaction system, adding deionized water and a catalyst, dissolving tetraethoxysilane and phenyltriethoxysilane in anhydrous isopropanol, slowly dropwise adding, carrying out a heat preservation reaction, and carrying out suction filtration and washing to obtain a phenyl modified SiO2 coated intermediate; the preparation method comprises the following steps: dispersing a compound stabilizer in anhydrous isopropanol to obtain a mixed system, heating and stirring, dissolving the compound stabilizer in anhydrous isopropanol, dropwise adding into the mixed system, reacting, centrifuging, washing, and drying in vacuum to obtain the bronze powder pigment. The bronze powder pigment disclosed by the invention has excellent oxidation resistance, chemical corrosion resistance and long-term storage stability, and can keep the natural color gloss of metal to the greatest extent.

The invention belongs to the technical field of energy-saving materials, and discloses a thermal insulation coating energy-saving material, which is prepared from the following raw materials in parts by weight: 90 to 120 parts of waterborne resin, 10 to 25 parts of modified nano cesium tungsten bronze material, 5 to 20 parts of modified nano silicon dioxide, 1 to 10 parts of light stabilizer, 0.1 to 1 part of coupling agent, 0.5 to 3 parts of flatting agent, 5 to 10 parts of wetting dispersant and 0.05 to 0.1 part of defoaming agent. According to the heat-preservation heat-insulation coating energy-saving material disclosed by the invention, the water-based resin is used as a main film-forming material, the modified nano cesium tungsten bronze and the modified nano silicon dioxide are used as nano functional materials, and the light stabilizer is used as an auxiliary material; by utilizing the excellent visible light transmittance and near-infrared light shielding performance of the modified nano-scale cesium tungsten bronze and the high transmittance and infrared barrier performance of the modified nano-silica, the glass can ensure that the visible light transmittance of the glass is 76% or above, meanwhile, 97% or above of infrared light and ultraviolet light are isolated, and the glass has excellent heat insulation and cooling effects.

The invention relates to the technical field of wood manufacturing, in particular to a preparation method of a multifunctional phase-change transparent wood-based composite material, which comprises the following steps: delignification of wood through acidic sodium chlorite, modification with silica sol to obtain a porous template, dipping in a PEG / MMA / AIBN / acetone mixed solution, and hot press molding to obtain a phase-change transparent base material; and finally, coating a PDMS solution containing cesium tungsten bronze and strontium aluminate, and performing low-temperature drying twice to obtain the multifunctional composite material. Silica sol pretreatment is combined with a PEG / MMA impregnation and compression technology, the preparation process is simple and easy to implement, leakage of the phase change material can be effectively prevented, meanwhile, the stability and performance consistency of the composite material are improved, the material is suitable for large-scale production, meanwhile, cesium tungsten bronze and strontium aluminate are introduced, the material is endowed with hydrophobicity, light-emitting characteristics and heat shielding capacity, and the material is suitable for large-scale production. And the intelligent building has the functions of photo-thermal management, self-cleaning and decoration, so that diversified application requirements are met.

The invention relates to a device for removing an oxide layer on the surface of tin-phosphor bronze before hot rolling treatment, and belongs to the technical field of tin-phosphor bronze surface treatment.The device comprises a supporting structure used for supporting a grinding mechanism, and the supporting structure is provided with a chuck and a driving mechanism which are used in cooperation with the grinding mechanism; a knocking mechanism and a limiting plate which are used for treating tin-phosphor bronze are arranged on one side of the grinding mechanism, and a liquid conveying mechanism used in cooperation with the grinding mechanism is further arranged on the supporting structure. The knocking mechanism comprises a knocking block and a connecting frame arranged above the knocking block, and a mounting shaft for mounting the knocking block is fixed to the bottom side of the connecting frame. After the device for removing the surface oxide layer of the tin-phosphor bronze before hot rolling treatment is used in cooperation with a knocking function, the device for removing the surface oxide layer of the tin-phosphor bronze has remarkable advantages in the aspects of removal efficiency, surface quality, treatment stability, equipment service life, production efficiency and flexibility, environmental protection, energy conservation and the like.

The invention discloses tin-lead bronze and a preparation method and application thereof.The tin-lead bronze comprises, by weight, 5%-11% of Sn, 2%-6% of Pb, 0.09%-4% of Ni, 0.05%-0.3% of P, 0.01%-1% of Zn and the balance Cu and inevitable impurities, the alloy structure of the tin-lead bronze comprises an alpha phase, an alpha + delta eutectoid and elemental Pb particles dispersed and distributed in the alpha phase, the area ratio of the alpha + delta eutectoid is smaller than or equal to 12%, and the area ratio of the elemental Pb particles is smaller than or equal to 10%. The as-cast average grain size of the tin-lead bronze is 20-70 microns, and the difference value delta D between the minimum grain size and the maximum grain size is smaller than or equal to 20 microns. Through improved design of alloy components and microstructures, a cast ingot with a specified structure is obtained by adopting a centrifugal casting process, meanwhile, the problem of dendritic segregation existing in a traditional casting method is solved, and the prepared material meets high requirements of special industries such as aerospace, ships and large engineering machinery.

The invention discloses an LTCC (Low Temperature Co-Fired Ceramic) green tape as well as a preparation method and application thereof, and the preparation method comprises the following steps: mixing LTCC formula powder and additive phase powder to obtain mixed powder; mixing the mixed powder, a dispersing agent and a solvent, and performing first ball milling treatment to obtain a first ball milling product; adding an adhesive and a plasticizer into the first ball-milling product, and carrying out second ball-milling treatment to obtain a second ball-milling product; filtering the second ball-milled product to obtain ceramic slurry for tape casting; drying the casting ceramic slurry to obtain an LTCC (Low Temperature Co-Fired Ceramic) green tape; wherein the weight ratio of the LTCC formula powder to the additive phase powder is (50-95): (5-50); the LTCC formula powder comprises ceramic powder and glass powder; the additive phase powder is at least one of hexagonal boron nitride, fluorophlogopite sheets, bismuthate-based tungsten bronze and phosphate glass. According to the LTCC green tape prepared by the preparation method disclosed by the invention, the technical problem that the machinability and the thermal conductivity of an LTCC green substrate prepared by an existing LTCC green tape are relatively poor can be solved.

The invention relates to the technical field of PVB heat-insulating films, in particular to a PVB heat-insulating film based on indium tin oxide and bronze cesium tungsten compounding and a preparation method thereof.The PVB heat-insulating film is prepared from, by weight, 80-120 parts of PVB resin, 20-50 parts of oily plasticizer, 0.1-2.0 parts of silane coupling agent, 0.1-1.0 part of antioxidant, 0.1-1.0 part of ultraviolet light absorber, 1-5 parts of polyethylene glycol derivative and 1-5 parts of compound dispersion slurry, the weight ratio of the indium tin oxide powder to the bronze cesium tungsten powder in the compound dispersed slurry is (5: 5)-(7: 3). According to the PVB heat-insulating film based on indium tin oxide and cesium tungsten bronze compounding and the preparation method, the prepared PVB heat-insulating film has high visible light transmittance and excellent near-infrared light rejection rate, meanwhile, the Faraday cage effect can be effectively avoided, and the signal shielding problem is avoided.

A brazed joint that can suppress the decrease in joint strength even when brass (50, 60) containing bismuth instead of lead and stainless steel (10) are joined by brazing with a solder material, and a method for producing the brazed joint are provided.A brazed joint made of stainless steel (10) and brass (50, 60), provided with a layered structure in which stainless steel (10), a first brazing material layer (20), a barrier layer (30), a second brazing material layer (40) and brass (50, 60) are arranged successively in layers, wherein the barrier layer (30) is a layer that blocks the transfer of bismuth in the brass (50, 60) to the first brazing material layer (20) by brazing the stainless steel (10) and the brass (50, 60), wherein the barrier layer (30) contains at least either a brass (50, 60) or a phosphor bronze, and a brazing material from which the first brazing material layer (20) and the second brazing material layer (40) consist is liquid at 680 to 800°C.

To provide a brazed joint which can inhibit reduction of joint strength even when a brass which contains bismuth in place of lead and stainless steel are brazed with a brazing material, and to provide a manufacturing method of the brazed joint.SOLUTION: A brazed joint of stainless steel and a brass includes a layer structure in which the stainless steel, a first brazing material layer, a barrier layer, a second brazing material layer, and the brass are sequentially arranged in a laminar manner. The barrier layer blocks bismuth in the brass from being moved to the first brazing material layer by brazing the stainless steel and the brass to each other. The barrier layer is at least one of brass and phosphor bronze. A brazing material forming the first brazing material layer and the second brazing material layer is a liquid at a temperature ranging from 680 to 800°C.SELECTED DRAWING: Figure 1

The invention discloses a high-strength and high-conductivity iron bronze alloy as well as a preparation method and application thereof. The iron bronze alloy comprises the following components in percentage by mass: 2.1-2.4 wt% of Fe, 0.015-0.1 wt% of P, 0.05-0.15 wt% of Zn, less than or equal to 0.1 wt% of impurities and the balance of Cu, the structure of the iron bronze alloy comprises a matrix phase and a second phase, the second phase comprises particle-shaped Fe3P phases and fibrous Fe-rich phases, the size of the particle-shaped Fe3P phases is 100-150 nm, the diameter of the fibrous Fe-rich phases is smaller than 2 micrometers, and the distance between the fibrous Fe-rich phases is smaller than 10 micrometers. The tensile strength of the iron bronze alloy is 600 MPa or above, the electric conductivity is 70% IACS or above, and the iron bronze alloy has wide application prospects in preparation of vehicle gauge grade IGBT contact pins.

Electrical conductor for earthing, comprising at least one metal wire comprising an aluminium core, at least one copper layer cladding said core, at least one coating layer of a metal selected f rom tin, nickel, bronze, brass, zinc, chrome, coating the copper layer. Said at least one coating layer has a thickness of from 2 to 50 pm. Compared to copper, the earthing conductor according to the present invention provides protection against corrosion, is flexible, robust in processing, resistant to bending during installation, provides equivalent performance in terms of melting current and electrical resistance, is about 40% lighter, has lower costs, is equally recyclable but with a different working process that makes it more difficult to recover immediately, thus discouraging theft.

The invention relates to a sliding bearing composite material, comprising a metal support layer and a bearing metal layer (14) applied to the support layer (12) and made of sintered particles of a sinter material (16), wherein the sinter material contains bronze particles and Fe3P particles, wherein the bronze particles consist of a copper alloy of the following composition: 8.0-12.0 wt.% tin, 6.0-11.0 wt.% bismuth, 1.0-4.0 wt.% zinc, optionally phosphorus up to 0.1 wt.%, in particular up to 0.07 wt.%, more particularly up to 0.05 wt.%, optionally impurity-related elements in each case up to a maximum of 0.10 wt.%, and in total at most up to 0.5 wt.%, remainder copper, wherein the proportion of Fe3P particles in the sinter material is 0.5-5.0 wt.%.

The invention relates to the technical field of high polymer materials, in particular to a bronze powder filling modified PTFE composite material and a preparation method and application thereof. The bronze powder filled and modified PTFE composite material comprises bronze powder and PTFE, wherein the bronze powder accounts for 30-50% of the total mass of the bronze powder filled and modified PTFE composite material; the microstructure of the bronze powder is irregular. According to the bronze powder filling modified PTFE composite material, the bronze powder material with a certain proportion and an irregular microstructure is filled into the polytetrafluoroethylene resin, so that the friction and wear properties of the PTFE composite material are effectively improved, and meanwhile, the mechanical properties of the PTFE composite material subjected to filling modification in multiple aspects are remarkably improved.

Access control hardware for a door generally includes an exterior trim, an interior trim, and a plurality of lockset components housed within a cross-bore through the door. At least one of the plurality of the lockset components is a fire-rated component comprised of a fire-resistant material, such as steel or bronze. The fire rated component is configured so that at least one elongated component extending between the exterior trim and the interior trim extends through at least one fire-rated component. The fire-rated components interfaces with the at least one elongated component in order to reduce or eliminate space around the at least one elongated component through which light or flames may pass.

The invention belongs to the technical field of functional materials, and particularly relates to a 1-3 type lead metaniobate piezoelectric composite material and a preparation method and application thereof. The composite material takes lead metaniobate ceramic with a tungsten bronze structure as a one-dimensional piezoelectric phase and takes epoxy resin as a three-dimensional polymer phase. The ratio [lambda] / T of the transverse periodic dimension ([lambda]) of the ceramic column to the thickness (T) of the composite material is 0.1-0.6. The preparation method is characterized in that the ceramic column array is formed through precise cutting, cutting parameters are controlled to achieve the lambda / T ratio, and then resin encapsulation, curing, polishing and electrode preparation are conducted. According to the invention, the electromechanical coupling performance and stability of the composite material at ultrahigh temperature are synergistically improved by selecting the lead metaniobate ceramic with high Curie temperature and combining specific lambda / T structural parameters. The obtained material can still keep good performance at 350 DEG C, the maximum thickness electromechanical coupling coefficient kt can reach 0.35, and the material is suitable for high-temperature acoustic logging and underwater acoustic receiving transducers.

The present invention discloses a high-strength silicon nitride ceramic material and a preparation method thereof, relating to the technical field of ceramic materials and their preparation. The high-strength silicon nitride ceramic material comprises a material layer, a coloring layer, a transition layer and a diamond coating from bottom to top. The ceramic material of the present invention achieves the comprehensive properties of lightweight, high strength and toughness, superhard wear resistance, efficient heat dissipation and corrosion resistance through carbon fiber reinforced phase interface modification, gradient TiCN transition layer design and diamond coating laser microstructuring, and improves the mechanical properties and interface bonding stability of the material. At the same time, it supports multi-color customization, such as black, bronze and yellow. The diversified selection expands the decorative and functional application scenarios of the material. In addition, the introduction of polishing equipment and laser microstructuring technology in the preparation process further optimizes the surface quality and wear resistance, so that the ceramic material has high strength and toughness, corrosion resistance and process controllability.

The invention belongs to the field of corrosion fatigue performance, and particularly discloses a milling workpiece corrosion fatigue life prediction model construction method and a process parameter optimization method.The milling workpiece corrosion fatigue life prediction model construction method comprises the steps that a surface quality prediction model is constructed based on process parameters and corresponding workpiece surface states obtained through tests, and the workpiece surface states comprise surface roughness and hardness; introducing a fatigue stress concentration factor and a work hardening ratio into the initial fatigue life model to respectively reflect local stress concentration caused by surface topography and machining surface hardening caused by milling, and performing surface roughness correction and surface hardness correction on the initial fatigue life model; obtaining a fatigue life model related to the surface state of the workpiece and the corresponding corrosion fatigue life; and combining the surface quality prediction model and the fatigue life model to form a corrosion fatigue life prediction model of the milling workpiece. According to the method, corrosion fatigue life prediction and process parameter optimization of the nickel-aluminum bronze milling workpiece can be realized, and important guidance is provided for actual processing.

The invention discloses a high-strength and high-elongation nickel-silicon bronze strip and a preparation method thereof, and belongs to the technical field of copper-based alloys. The preparation method comprises the following steps: carrying out smelting, refining, two-stage filtering, casting and semi-continuous casting according to nickel-silicon bronze components to obtain a cast ingot, and carrying out hot rolling, annealing, surface milling, rough rolling, first cleaning and brushing, first solid solution, finish rolling, second solid solution, finished product rolling, aging, second cleaning and brushing, straightening, slitting and the like on the cast ingot after heating to obtain the nickel-silicon bronze strip. According to the method, the problem of surface oxidation of the strip is solved, the surface and internal quality of the strip is improved, the strip strength and elongation are improved, the strip yield is increased, and batch production of the large-coil heavy nickel-silicon bronze strip can be met.

The invention discloses a bright annealing process for a copper alloy wire. The bright annealing process comprises the following steps: coating the surface of the copper alloy wire with a composite solid lubricant; the heating / cooling rate of a preheating zone (200-350 DEG C), the heating / cooling rate of a main annealing zone (450-650 DEG C) and the heating / cooling rate of a slow cooling zone (300-450 DEG C) are smaller than or equal to 15 DEG C / s; and an atomized anti-oxidation liquid film is applied to an outlet of the slow cooling area. According to the bright annealing process for the copper alloy wire, the lubricant with specific components is decomposed at a high temperature to form an in-situ protection layer, generation of oxide skin is inhibited in combination with gradient temperature control, and a bright surface with the surface roughness Ra smaller than or equal to 0.2 micron can be achieved without introducing hydrogen or nitrogen. The cost is reduced by more than 40%, and the method is suitable for easily-oxidized copper alloys such as tin-phosphor bronze and cupronickel.

The present invention relates to a method for accurately measuring the chloride ion content of the rust layer on the surface of a bronze object. The method comprises the following steps: mixing water-soluble CS, ALg, and PVA, adding AgNO3 dropwise, stirring to form a homogeneous sol, heating at 50°C to form a cross-linked gel, and obtaining an ALg-CS-Ag hydrogel; preparing artificial rust powder; cutting the hydrogel into small pieces and adding each piece to the rust powder, ensuring that one side of the hydrogel is in full contact with the rust powder for adsorption; simultaneously attaching ALg-CS-Ag hydrogel pieces of the same size to the surface rust layer of a bronze object fragment for adsorption; waiting for 21-27 hours, removing or peeling off the adsorbed hydrogel; soaking the hydrogel in deionized water until it is completely swollen; performing an AC impedance test and fitting the test results to an equivalent circuit to obtain a resistance value; plotting a relationship between the inverse of the resistance value and the chloride ion concentration and performing a linear fit to obtain a fitting function, which is substituted into the fitting function to calculate the chloride ion content of the rust layer on the surface of the bronze object. The method has the advantages of being non-destructive, highly accurate, and convenient and rapid.

The invention discloses a process production method of a tin-phosphor bronze alloy, which is characterized in that the tin-phosphor bronze alloy comprises the following components in percentage by mass: 0.6-0.7% of Sn; the copper alloy comprises the following components in percentage by weight: 0.10-0.25% of P, 0.05-0.10% of Te, less than or equal to 0.10% of other impurity elements and the balance of According to the method, the rod material with the diameter phi of 12.5 mm is produced through 2000 kg horizontal continuous casting. The process route comprises the steps of rod material continuous casting, cold rolling, softening annealing, reverse drawing and peeling, reverse drawing and peeling, softening annealing, reverse drawing and peeling, reverse drawing, softening annealing and reverse drawing of a finished product. According to the process route, the organization structure of the material is converted into a compact cold drawing organization from a coarse as-cast organization. And due to the increase of the tellurium element, the machinability of the material is improved by 15%, and the tin-phosphor bronze material obtained through the process route is compact in structure, fine in grain, high in strength and excellent in comprehensive performance. The tensile strength Rm of the tin-phosphor bronze material is larger than or equal to 800 MPa, the ductility A is larger than or equal to 3%, the machinability is 80% or above, and the electric conductivity is larger than or equal to 14% IACS.

To provide a piezoelectric element that exhibits improved toughness while retaining necessary piezoelectric performance.SOLUTION: A piezoelectric element 10 comprises a piezoelectric body 11 made of a lead-free piezoelectric ceramic composition including a main phase formed of a first crystal phase composed of an alkali niobate-based perovskite oxide, and a subphase including a second crystal phase composed of at least one selected from an M-Nb-O-based tungsten bronze-type compound (where element M is an element having a valence of 1 to 4) and an N-Ti-O-based spinel-type compound (where element N is an element having a valence of 1 to 4), and electrodes 12, 13 in contact with the piezoelectric body 11, wherein the average pore diameter of pores formed in the piezoelectric body 11 is 8 μm or more and 50 μm or less.SELECTED DRAWING: Figure 1

The invention discloses a bronze ware model casting parting design method and system based on Boolean modeling, particularly relates to the field of digital model casting modeling and simulation verification, is used for solving the problems of parting cutting error accumulation and model block seepage stability loss under the complex morphology of a bronze ware, and provides a model casting parting design method and system based on Boolean modeling by constructing a morphology noise mapping and semantic slicing linkage mechanism. Early recognition of pitting corrosion and back-off areas is achieved, Boolean segmentation is driven through curvature constraint, and a flexible buffer surface is introduced into a danger area to achieve transition; a cross-domain parameter evaluation and adjustment mechanism is formed in combination with multi-scale displacement optimization and physical simulation feedback, high-response parameter write-back is realized through local disturbance search, a full-link linkage path from modeling to casting is constructed, and parting integrity and model block stability are improved.

The application discloses a potassium tungsten bronze-based photo-thermal super-hydrophobic coating and a preparation method and application thereof; the preparation method of the coating is as follows: first organic solvent, a tungsten source and a potassium source are mixed at room temperature, and stirring is carried out under ultrasonic waves until the tungsten source is fully dissolved; the concentration of the tungsten source is controlled to be 15 mg / mL-27.5 mg / mL; reaction is carried out at 160-200 DEG C for 22-26 h; after the reaction is completed, washing and centrifugal separation are carried out, and then drying, grinding and petal-shaped potassium tungsten bronze powder are obtained; then, the petal-shaped potassium tungsten bronze powder is reacted with a hydrophobic modifier, and is added to a resin solution and a curing agent for reaction. The coating of the application can enhance near-light absorption performance and improve photo-thermal conversion efficiency without the assistance of nano-particles such as silicon dioxide, and can realize rapid removal of surface ice droplets.

The application provides a preparation method of bronze etching material, which comprises the following steps: preparing a bronze etching blank, homogenizing annealing the bronze etching blank to obtain a bronze etching blank for use; roughing the bronze etching blank for use, rolling the roughed bronze etching blank to a first predetermined thickness and cutting edges, and then annealing to obtain a first blank; first finish rolling and first tempering the first blank to obtain a second blank; second finish rolling and second tempering the second blank to obtain a third blank, and the processing rate of the second finish rolling is 30%-35%; third finish rolling and third tempering the third blank to obtain a fourth blank, and the processing rate of the third finish rolling is 10.0-12.5%; fourth finish rolling and fourth tempering the fourth blank to obtain a first finished product, and the processing rate of the fourth finish rolling is 10.0-15.5%; and cleaning and passivating the first finished product to obtain bronze etching strip material. The preparation method of the bronze etching material can realize rapid forming of the bronze etching material and industrialized mass production.

1. The name of the design product: pot (Xingtuo inlaid with bronze). 2. The use of the design product: for containing liquid. 3. The design points of the design product: in shape. 4. The picture or photo that best indicates the design points: perspective view.

The utility model belongs to the technical field of tin-phosphor bronze belt production, and particularly relates to tin-phosphor bronze belt rolling. The utility model provides a reel for cold rolling of a high-yield-ratio and high-elasticity tin-phosphor bronze belt, which comprises a winding drum suitable for winding the tin-phosphor bronze belt, and a left baffle disc and a right baffle disc are arranged on two sides of the winding drum; the pressing and holding piece is arranged at the edge of the left baffle disc; the locking position is arranged at the edge of the right baffle disc; during locking, the pressing and holding piece stretches across the winding drum to be matched with the locking position, and the tail end of the tin-phosphor bronze belt on the outermost circle is extruded and locked. The pressing and holding piece is arranged on the left blocking disc, the locking position is arranged on the right blocking disc, the pressing and holding piece stretches across the winding drum and stretches into the locking position by rotating the pressing and holding piece, the tin-phosphor bronze belt on the outermost circle of the winding drum is pressed, the phenomenon that the coiled tin-phosphor bronze belt is loose after the winding disc is taken down from the winding device is avoided, and the winding efficiency is improved. And the production continuity of the tin-phosphor bronze belt is improved.

The invention discloses a preparation method of a high-stability bronze-process niobium-tin wire, and relates to the technical field of superconducting wire preparation, and the preparation method comprises the following steps: assembling a composite ingot according to a composite structure which sequentially comprises an outer copper matrix, an outer barrier layer, a bronze-based CuNb layer, an inner barrier layer and an inner copper matrix from outside to inside; the composite ingot is sequentially subjected to heat preservation extrusion and multi-pass cold drawing, and a composite wire is obtained; carrying out heat treatment on the composite wire to obtain a Ni3Sn wire; the outer blocking layer and the inner blocking layer are made of Nb or Ta or Nb alloy or Ta alloy or Ta / Nb alternating composite layers. The Ni3Sn wire is prepared by designing a composite structure with double barrier layers and combining heat preservation extrusion, multi-pass cold drawing and heat treatment, the critical current density and the residual resistance ratio of the wire are increased, and then the stability of the wire is improved.

1. Name of the designed product: copper door (thousand miles of mountains and rivers). 2. Use of the designed product: for outdoor doors. 3. Design points of the designed product: combination of shape and pattern. 4. Picture or photo that best shows the design points: front view.

The invention discloses a large-size electronic packaging shell and a manufacturing method thereof, and belongs to the technical field of electronic packaging. The packaging shell comprises a metal shell body and a metal cover body, wherein the metal shell body is made of 4J29 kovar alloy or carbon structural steel with the carbon content ranging from 0.08% to 1.3%; the sealing insulator is embedded in the bottom of the metal shell and comprises a hollow cylindrical ceramic body, and a tungsten composite metal layer and a metal coating are sequentially formed on the inner surface and the outer surface of the ceramic body from inside to outside; the ceramic body is made of aluminum nitride or silicon nitride; and the leading pin is inserted into the ceramic insulator, and the material of the leading pin is beryllium bronze. According to the packaging shell, the problems of stress deformation of the leading-out end and damage to the sealing area caused by thermal mismatch are avoided, so that the device failure caused by the stress deformation is avoided, and the sealing performance and long-term reliability of the device are ensured.