623 results about "Hexafluoropropylene" patented technology

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.

The invention discloses a continuous synthesis and purification method of hexafluoropropylene oxide, which comprises the following steps: introducing hexafluoropropylene, oxygen and a fluorine-containing solvent into a supergravity reactor to carry out oxidation reaction at the reaction temperature of 100-200 DEG C under the reaction pressure of 1.0-2.5 Mpa for 10-120 seconds, and after the reaction is finished, overflowing and leading out reaction liquid to obtain the hexafluoropropylene oxide. And purifying to obtain the hexafluoropropylene oxide. According to the method, the problems of mass transfer and heat transfer can be effectively solved by using the supergravity reactor, the reaction selectivity is remarkably improved, meanwhile, the productivity is effectively improved, and the supergravity reactor is combined with extractive distillation treatment, so that the conversion rate of the hexafluoropropylene reaches 79% or above, the selectivity of the hexafluoropropylene oxide is 85% or above, and the purity of the hexafluoropropylene oxide after extractive distillation reaches 99%. The invention further discloses a device used in the continuous synthesis and purification method, and cyclic utilization of hexafluoropropylene and the fluorine-containing solvent can be achieved.

The invention discloses a polyion liquid / polyvinylidene fluoride-hexafluoropropylene-based solid electrolyte with a microscopic liquid phase and a preparation method and application thereof, and the preparation method comprises the following steps: adding a lithium salt into N-methyl-2-pyrrolidone, and stirring until the lithium salt is completely dissolved; then adding imidazolyl polyion liquid to prepare a solution A; adding polyvinylidene fluoride-hexafluoropropylene into N-methyl-2-pyrrolidone to prepare a solution, adding the solution into the solution A, continuously stirring until the solution is fully dissolved to obtain a precursor solution of the solid electrolyte, casting the precursor solution onto a polytetrafluoroethylene mold, and carrying out vacuum drying to obtain the solid electrolyte. And the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte added with the imidazolyl polyion liquid is prepared by adding the imidazolyl polyion liquid into the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte. The polymer-based solid electrolyte with a microscopic liquid phase is obtained through an electrolyte preparation process which is mild in condition, simple to operate and easy for large-scale production, and the solid electrolyte has good conductivity and mechanical properties.

The invention belongs to the technical field of lithium battery materials, and particularly relates to an integrated positive electrode / solid-state electrolyte sheet, a preparation method thereof and application of the integrated positive electrode / solid-state electrolyte sheet in a solid-state lithium battery. When the integrated positive electrode / solid electrolyte sheet provided by the invention is prepared, polyvinylidene fluoride-hexafluoropropylene is used as a flexible framework, poly (1, 3-dioxolame) is used as an additive, and an ionic liquid is used as an ionic conductor, solid electrolyte slurry is prepared by mixing, then the slurry is directly coated on the positive electrode sheet, and the integrated positive electrode / solid electrolyte sheet is obtained. The thickness of the solid-state electrolyte layer in the obtained integrated positive electrode / solid-state electrolyte sheet is less than 20 [mu] m, so that the requirement on high energy density of a solid-state lithium battery in industry is met. Meanwhile, the integrated positive electrode / solid-state electrolyte sheet can be randomly bent under the condition of keeping high ionic conductivity and mechanical modulus, so that the solid-state lithium battery assembled by adopting the electrolyte sheet at room temperature has higher specific capacity and good cycling stability, and has good popularization and application prospects in high-energy-storage lithium batteries.

The invention provides a high-temperature-resistant fast-charging PVDF-HFP-based all-solid-state electrolyte membrane as well as a preparation method and application thereof, and relates to the technical field of power batteries. The preparation method comprises the following steps: uniformly mixing a polyvinylidene fluoride-hexafluoropropylene copolymer, a lithium salt and a polar solvent to obtain a PVDF-HFP solution; then uniformly mixing the PVDF-HFP solution with a cross-linking agent and a 2, 2-bis (4-allyloxy-3, 5-dibromophenyl) propane monomer, so as to obtain a precursor solution; uniformly mixing an initiator with the precursor solution to obtain a reaction solution; and finally, coating a substrate with the reaction solution, and heating at 70-80 DEG C for 12-16 hours to obtain the high-temperature-resistant fast-charging PVDF-HFP-based all-solid-state electrolyte membrane. When the high-temperature-resistant and fast-charging PVDF-HFP-based all-solid-state electrolyte membrane is applied to a lithium metal battery, the thermal safety and the high-temperature-resistant and fast-charging performance can be remarkably improved.

The invention provides a lithium supplement composite layer and a preparation method thereof, a lithium supplement method, a pre-lithiated negative pole piece, a secondary battery and an electronic device, the lithium supplement composite layer comprises an interface layer and a lithium supplement layer which are laminated, the interface layer comprises interface particles and a binder, the interface particles comprise a lithium intercalation material and / or a conductive agent, and the binder comprises a lithium intercalation material and / or a conductive agent. The lithium intercalation material is selected from at least one of artificial graphite, natural graphite, hard carbon, a silicon-carbon material, a silicon-oxygen material, lithium titanate, tin and a tin-copper alloy, and the conductive agent is selected from at least one of conductive carbon black, carbon fiber, graphene and a carbon nanotube; the binder is selected from at least one of polytetrafluoroethylene, an ethylene-tetrafluoroethylene copolymer, a tetrafluoroethylene-hexafluoropropylene copolymer, polyvinylidene fluoride and polyoxyethylene; the lithium supplementing layer comprises lithium metal and / or lithium alloy. The lithium supplement composite layer meets the above characteristics, lithium supplement is carried out on the negative pole piece, the first coulombic efficiency of the secondary battery can be improved, the cycle capacity attenuation is reduced, and the energy density of the secondary battery is improved.

The invention discloses a gradient membrane based on continuous distribution of PVDF-HFP-silicon dioxide electronic injection microspheres and a construction method of the gradient membrane, and belongs to the field of gradient membranes, an improved electrostatic spinning and electrostatic spraying technology is utilized, a PVDF-HFP fiber membrane is prepared through the electrostatic spinning technology, PVDF-HFP / SiO2 composite microspheres are electrostatically sprayed, and a collector receiving device is combined, so that the gradient membrane is obtained. The traction speed change of the substrate film is controlled on the blade electrode, and a wettability gradient film with the continuously-changed surface appearance is constructed; on the surface of the prepared fiber membrane, the distribution form of the polyvinylidene fluoride-hexafluoropropylene / silicon dioxide composite microspheres on the surface of the membrane is in gradient change, a microstructure with continuous change is constructed, the contact angle of the fiber membrane is increased from 128 degrees to 153 degrees along with the change of the surface position, and a gradient surface gradually changing from hydrophobicity to super-hydrophobicity is obtained. And the preparation method has an excellent application prospect in the field of gradient films, bubble transmission and bubble micro-reaction.

The invention belongs to the technical field of lithium battery materials, and particularly relates to a preparation method of a polyvinylidene fluoride-hexafluoropropylene-based solid-state lithium battery, and the preparation method comprises the steps of preparing a composite solid electrolyte membrane and assembling the battery. Polyvinylidene fluoride hexafluoropropylene, lithium salt and nitrogen-methyl pyrrolidone are used as raw materials, and the plasticizer and the dendritic mesoporous nano silicon dioxide are added to prepare the composite solid electrolyte membrane, so that more conductive channels are provided for migration of lithium ions, and the electric capacity of the electrolyte is improved; according to the preparation method, the interface compatibility between the PVDF-HFP and the dendritic mesoporous nano silicon dioxide is improved, the electrochemical performance is improved, the crystallinity of the PVDF-HFP is reduced, and short circuit and explosion caused by the fact that dendritic crystals pierce the diaphragm are avoided; the invention solves the potential safety hazards caused by the traditional liquid electrolyte, such as leakage, combustion, explosion and the like, and has the advantages of simple preparation method and low cost, and is suitable for industrial large-scale production.

The invention discloses a preparation method and application of a composite PVDF-HFP and polylysine nanofiber diaphragm, and belongs to the technical field of lithium batteries. The composite material is prepared by blending polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) and polylysine and then carrying out an electrostatic spinning process. The PVDF-HFP is utilized to provide excellent mechanical strength and chemical stability, rich polar amino functional groups in a polylysine molecular chain are utilized to improve the lyophilic property of the membrane, and anions in an electrolyte are fixed through an intermolecular acting force, so that the transference number of lithium ions is increased, and the lithium ions are induced to be uniformly deposited. The nanofiber membrane combines the characteristics of PVDF-HFP and polylysine, has high porosity, good thermal stability and excellent interface compatibility, can effectively inhibit the growth of lithium dendrites and prevent the diaphragm from being punctured, and can significantly prolong the cycle life and improve the safety performance of the lithium metal battery when being applied to the lithium metal battery.

The invention relates to the technical field of inorganic material preparation and new energy materials, and particularly discloses a lithium metal battery composite solid electrolyte as well as a preparation method and application thereof. Lithium niobate with high lithium ion conductivity and high dielectric constant is used as an inorganic filler, polyvinylidene fluoride-co-hexafluoropropylene is used as a polymer matrix, and the lithium metal battery composite solid electrolyte is prepared. The lithium metal battery solid electrolyte with a continuous lithium ion transport path is constructed through a freeze casting technology, the dielectric constant of the solid electrolyte is effectively improved by adding the dielectric inorganic filler lithium niobate, lithium salt dissociation is promoted, preparation of the modified electrolyte can be simply completed on a large scale, industrial expansion is facilitated, coulombic efficiency is improved, and the lithium metal battery solid electrolyte is suitable for industrial production. According to the present invention, the lithium metal battery electrolyte meets the industrial requirement on the high lithium utilization rate, the lithium negative electrode can be well protected, the cycle life of the lithium electrode can be improved, the battery electrolyte and the lithium electrode show the good interface compatibility and the good cycle stability, and the new feasible way is provided for the application of the lithium metal battery.

The invention discloses a fluororubber cloth clamping material for a V-group sealing element of a large oil cylinder and a preparation method of the fluororubber cloth clamping material. The fluororubber cloth clamping material comprises polyester cloth serving as a framework material and fluororubber compounded on the surface of the polyester cloth through a treating agent, the treating agent is a dopamine-grafted silane coupling agent KH-550, and the curing agent is a curing agent; and the fluororubber is vinylidene fluoride-hexafluoropropylene co-fluororubber. According to the invention, the problem of bonding of fluororubber and polyester cloth is solved, and the obtained fluororubber cloth clamping material has excellent water resistance and salt spray resistance in a marine environment, and can meet the high reliability requirement of a large-scale oil cylinder V-group sealing element within the service life of 20 years.

The invention discloses a preparation method of carbonyl fluoride, which comprises the following steps: with hexafluoropropylene and oxygen as raw materials, introducing gas into a reactor filled with a catalyst for reaction at high temperature; the catalyst is one of palladium oxide, ruthenium oxide, platinum oxide and molybdenum oxide. According to the scheme, the cost is low, the raw material utilization rate is high, and compared with other carbonyl fluoride synthesis methods, the reaction does not involve phosgene, fluorine and other dangerous chemicals, and reaction by-products are few. In addition, according to the method, the toxicity of raw materials is small, hexafluoropropylene can be completely reacted under the condition of excessive oxygen, the reaction process is environment-friendly and simple, and basically no three wastes are generated. According to the method, hexafluoropropylene and oxygen are adopted as raw materials which are common chemical raw materials and are cheap and easy to obtain, and the method is simple in reaction process, mild in reaction, easy to operate and suitable for industrial production.

The invention discloses a two-phase immersed fluorine-containing cooling liquid, the fluorine-containing cooling liquid comprises a hexafluoropropylene dipolymer and hydrofluoroolefin, the molecular formula of the hexafluoropropylene dipolymer is C6F12, and the molecular formula of the hydrofluoroolefin is C6H2F10, the fluorine-containing cooling liquid not only has good electrical insulation performance, but also has the advantage of high heat transfer coefficient, and the fluorine-containing cooling liquid is suitable for being used as a cooling liquid for a motor vehicle. The fluorine-containing cooling liquid provided by the invention is continuously subjected to the phase change process from the liquid state to the gas state and then from the gas state to the liquid state in the circulating heat dissipation process, the evaporation latent heat of the cooling liquid is fully utilized, and the heat dissipation requirement of a high-power heating element can be met.

To provide a heat transfer fluid having a relatively high boiling point.SOLUTION: The present disclosure provides a composition for a heat transfer fluid, which contains hexafluoropropene trimers having specific three structures, (I), (II), and (III), and in which a compound having the structure (I) is contained in an amount of 10 mass% or more and less than 85 mass% relative to the total amount of the hexafluoropropene trimers having the three structures.SELECTED DRAWING: None

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit, and a fluoro(alkyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 8.6 to 11.9% by mass with respect to the whole of the monomer units, a content of the fluoro(alkyl vinyl ether) unit of 0.5 to 1.9% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 4.6 to 14.4 g / 10 min, and a total number of —CF2H, a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 90 or less.

The invention discloses a PEM proton exchange membrane for water electrolysis and a preparation method thereof, and relates to the technical field of water electrolysis. The proton exchange membrane is composed of five layers of structures including a modified sulfonated composite resin layer, an enhancement layer, a water retention layer, a catalyst layer and an anti-permeation layer, the preparation method comprises the following steps: the modified sulfonated composite resin layer is prepared by dispersing perfluorinated sulfonic acid resin and sulfonated lignin in a solvent, coating and drying; the reinforcing layer is prepared by blending a PTFE (Polytetrafluoroethylene) emulsion, a carbon nanotube and a tetrafluoroethylene-hexafluoropropylene copolymer, and then carrying out casting sintering, plasma treatment and hot press molding; the water retention layer is prepared by adopting an electrostatic spinning technology; the catalyst layer is formed by spraying a precursor solution step by step and drying; the anti-permeation layer is prepared through photoetching-etching array construction, resin coating and fluorosilane modification. The prepared proton exchange membrane has excellent mechanical strength, proton conductivity and stability, and is suitable for the field of PEM water electrolysis.

The invention relates to a method for separating octafluoropropane and hexafluoropropane, which comprises the following steps: carrying out adsorption separation on a mixed gas containing hexafluoropropane and octafluoropropane by using an adsorbent containing a metal organic framework material, the metal organic framework material comprises metal ions and an organic ligand, and the organic ligand comprises a compound as shown in formula I; the metal ions are selected from one or more of transition metal ions and alkaline earth metal ions. The metal organic framework material has good material stability, the synthesis conditions are mild and simple, and the raw materials are low in price. The metal organic framework material provided by the invention has very high adsorption separation selectivity on hexafluoropropylene and octafluoropropane, and has a good industrial application prospect. # imgabs0 #

The invention discloses a method for preparing 2-(R)-fluoromethyl propionate with optical activity, and relates to the technical field of organic synthesis.The method comprises the steps that 1, an organic solvent and amines are added into a sealing system under nitrogen protection, hexafluoropropylene is added, a heat preservation reaction is conducted, then aftertreatment is conducted, and a fluorinating agent is obtained; and step 2, adding the fluorinating agent obtained in the step 1 and L-methyl lactate into a closed system under the protection of nitrogen, and carrying out heat preservation reaction to obtain the 2-(R)-fluoromethyl propionate. The method disclosed by the invention has the advantages of simple preparation process, low raw material cost, high yield, low safety risk, less generated three wastes and low treatment cost of the three wastes.

The invention discloses a series of azeotropic or azeotrope-like compositions for solvent and single-phase or two-phase cleaning applications, and the formula of the azeotropic or azeotrope-like compositions mainly comprises trans-1, 2-dichloroethylene and hexafluoropropylene dimer; the composition may include at most one of 1, 1, 2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether or 1, 1, 2, 3, 3, 3-hexafluoropropyl-2, 2, 2-trifluoroethyl ether, for example, 60 to 80% by mass of trans-1, 2-dichloroethylene, 20 to 40% by mass of hexafluoropropylene dimer or 60 to 65% by mass of trans-1, 2-dichloroethylene, or may also include any at most one of 1, 1, 2, 2-tetrafluoroethyl-2, 2, 2-trifluoroethyl ether or 1, 1, 2, 3, 3, 3-hexafluoropropyl-2, 2, 2-trifluoroethyl ether, for example, 60 to 80% by mass of trans-1, 2-dichloroethylene, 20 to 40% by mass of hexafluoropropylene dimer or 60 to 65% by mass of 1, 1, 2, 2- 25 to 30% by mass of a hexafluoropropylene dimer; and 10 to 15% by mass of any one of HFE347 or HFE449. According to the present invention, the component capable of generating the azeotrope-like composition with the trans-1, 2-dichloroethylene component can inhibit the flash point of the trans-1, 2-dichloroethylene component so as to improve the safety performance of transportation, storage and use. The multi-component composition described by the formula can be used for high-efficiency degreasing of metal parts or high-efficiency cleaning of precise devices in the metal processing process, can also be used as a solvent, a degreasing agent, a desoldering agent or a drying agent and the like, and can meet multiple application requirements.

Provided is a composition for a heat transfer fluid, the composition containing perfluorotripropylamine and a hexafluoropropene trimer represented by C9F18.

The invention provides a synthetic method of hexafluoropropylene oxide and application thereof, and relates to the technical field of fluorine chemical industry, and the synthetic method comprises the following steps: under supercritical conditions, hexafluoropropylene and oxygen are subjected to complete mixed flow induction to generate reaction free radicals, then the reaction free radicals are subjected to a reaction through a microchannel reactor, and the hexafluoropropylene oxide is continuously synthesized. The invention solves the technical problems of low conversion rate, low selectivity and rearrangement of hexafluoropropylene oxide into hexafluoroacetone during synthesis of hexafluoropropylene oxide in the prior art, and achieves the technical effects of high conversion rate, high selectivity and green continuous synthesis of hexafluoropropylene oxide.

The invention discloses a fluorinated COF enhanced PVDF-HFP composite gel polymer electrolyte. The fluorinated COF enhanced PVDF-HFP composite gel polymer electrolyte is prepared from the following raw materials: polyvinylidene fluoride-co-hexafluoropropylene, a fluorinated covalent organic framework containing an ether oxygen bond and a carbon-carbon unsaturated double bond, bis (trifluoromethylsulfonyl) imide anion ionic liquid and fluorine-containing imide lithium salt, the fluorinated covalent organic framework containing the ether-oxygen bond and the carbon-carbon unsaturated double bond is prepared by carrying out condensation reaction on a perfluorophenylene-containing module and the ether-oxygen bond-containing aromatic module. According to the electrolyte, PVDF-HFP is used as a polymer matrix, bis (trifluoromethylsulfonyl) imidogen ionic liquid is used as a functional phase and a plasticizer, imide lithium salt is used as a lithium ion source, fluorinated COF containing ether oxygen bonds and olefinic bonds is introduced, and the electrolyte has high ionic conductivity, high lithium ion transference number, excellent mechanical property and interface stability; the method is especially suitable for a high-safety lithium metal battery system.

The invention discloses a preparation method of peroxide vulcanized fluororubber with high fluorine content and low compression deformation, and relates to the field of fluororubber synthesis. According to the method, vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene are used as mixed monomers to carry out polymerization reaction; wherein in the polymerization reaction process, a vulcanization point monomer is added. The peroxide vulcanized fluororubber which is high in fluorine content, resistant to a new energy battery medium and low in compression deformation is prepared by adjusting the component proportion of mixed monomers and uniformly and continuously adding vulcanization point monomers. According to the peroxide vulcanized fluororubber prepared by the method provided by the invention, the fluorine content is stabilized at 70-71%, the compressive deformation stability is less than or equal to 20%, the tensile strength is about 22MPa, and the elongation at break is greater than 180%; the problem of high compressive deformation of peroxide vulcanized fluororubber (especially peroxide vulcanized fluororubber with high fluorine content) applied to new energy batteries is effectively solved.

The invention discloses a low-temperature high-conductivity composite solid-state electrolyte membrane and a preparation method and application thereof, and relates to the technical field of solid-state lithium battery materials, the low-temperature high-conductivity composite solid-state electrolyte membrane comprises: a polymer matrix composed of poly (1, 3-dioxolame) and a polyvinylidene fluoride-hexafluoropropylene copolymer; the ion conduction network is composed of a metal organic framework filler with the surface modified with-SO3Li groups and sulfonic acid lithiated carbon nanotubes arranged in the axial direction of the polymer matrix; a first anti-freezing interface layer and a second anti-freezing interface layer are arranged on the surfaces of the two opposite sides of the polymer matrix, and the first anti-freezing interface layer and the second anti-freezing interface layer are butanedinitrile-glutaronitrile eutectic plastic crystal layers composed of butanedinitrile, glutaronitrile, lithium salt and a nano reinforcing agent respectively. The solid electrolyte is suitable for polar scientific investigation equipment, spacecrafts and other low-temperature environments, and solves the industrial problems of sharp increase of low-temperature grain boundary impedance and interface contact failure of the traditional solid electrolyte.

The invention discloses lithium ion diaphragm coating slurry and a preparation method and application thereof.The lithium ion battery diaphragm comprises a base membrane and a coating on the base membrane, the coating comprises a dispersing agent, potassium carboxymethyl cellulose and side-chain modified polyvinylidene fluoride, and the method for preparing the side-chain modified polyvinylidene fluoride comprises the steps that vinylidene fluoride, hexafluoropropylene, (S)-4-pentene-1, 2, 4-triazole-1, 2, 4-triazole-1, 2, 4-triazole-1, 2, 4-triazole-1, 2, 4-triazole-1, 2, 4-triazole-1, 3-triazole-1, 3-triazole-1, 2-triazole-1, the preparation method comprises the following steps: uniformly mixing 1, 2-diol, (S)-3-(trifluoromethyl) adipyl dichloride, an initiator, an auxiliary agent and a solvent, and reacting for 9-12 hours in an inert gas atmosphere at 75-80 DEG C under a stirring condition to obtain a reaction solution; and carrying out spray drying on the reaction liquid to obtain the side chain modified polyvinylidene fluoride. The coating slurry provided by the invention can realize firm bonding between the diaphragm and a pole piece at room temperature, improves the stability and safety of a battery structure, and remarkably reduces the internal resistance of the battery diaphragm at the same time.

The application relates to the technical field of batteries, in particular to a composite solid electrolyte membrane and a preparation method and application thereof. The composite solid electrolyte membrane comprises the following layers which are sequentially stacked: a first membrane layer comprising a polymer, a solid electrolyte and a lithium salt; a second membrane layer comprising a polymer, a solid electrolyte and a lithium salt; and a third membrane layer which is an interface layer; wherein the solid electrolyte and the lithium salt content of the second membrane layer are higher than those of the first membrane layer, and the polymer is formed by polymerization of raw materials comprising triacetyl cellulose (TCA) and polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP). The composite solid electrolyte membrane has improved high-temperature resistance and good ion transmission performance.

The invention relates to a preparation process of a fluorination liquid, in particular to a preparation method and device of perfluorohexane, and the preparation method comprises the following steps: mixing hexafluoropropylene and fluorine-containing gas for reaction to obtain crude perfluorohexane; the method comprises the following steps of: performing primary alkali washing and secondary alkali washing on a crude product of perfluorohexane, removing moisture, and finally performing primary condensation and secondary condensation to obtain the product of perfluorohexane by primary condensation and recover hexafluoropropylene for circular reaction by secondary condensation. The preparation device comprises a reaction tower, a buffer tank, a primary alkaline washing tower, a secondary alkaline washing tower, a drying tower, a first cold trap and a second cold trap which are communicated in sequence. The method is simple in production process, high in hexafluoropropylene conversion rate, high in product purity and low in comprehensive cost, and has good economic benefits and application prospects.

The invention provides a green and efficient production method of hexafluoropropylene oxide, and belongs to the technical field of synthesis of organic fluorine compounds. The method comprises the following steps: carrying out a continuous oxidation reaction on hexafluoropropylene, oxygen and a perfluoro solvent in an immersed supergravity reactor to generate HFPO and byproducts carbonyl fluoride and trifluoroacetyl fluoride, removing the solvent from the reacted liquid, feeding the liquid into an acyl fluoride rectifying tower, separating low-boiling-point acyl fluoride from the tower top, enriching HFPO, unreacted HFP and a small amount of acyl fluoride from the tower bottom, and carrying out a continuous oxidation reaction on the HFPO and the byproducts carbonyl fluoride and trifluoroacetyl fluoride. Converting acyl fluoride into anhydrous trifluoroacetic acid from a high-boiling-point substance at the bottom of the tower through a hydrolysis tower, carrying out alkali washing on the synthesis gas to obtain an HFPO crude product, and further carrying out drying and extractive distillation to obtain an HFPO product; acyl fluoride rectified by an acyl fluoride rectifying tower is directly used for producing PAVE, and long-chain perfluoroacyl fluoride accumulated in a solvent of oxidation reaction is hydrolyzed to synthesize a non-PFOA emulsifier. The method has the advantages of high HFPO selectivity, short reaction time and high safety; the method realizes resource comprehensive utilization of byproducts, and is environment-friendly and economical.

The invention discloses an ultrathin battery diaphragm with high cohesiveness and safety as well as a preparation method and application of the ultrathin battery diaphragm. The battery diaphragm comprises a polyolefin base material and polyvinylidene fluoride coatings arranged on the two sides of the polyolefin base material, wherein each polyvinylidene fluoride coating comprises aluminum oxide particles, a first polyvinylidene fluoride copolymer and a second polyvinylidene fluoride copolymer; the particle size of the aluminum oxide particles is below 0.4 micron; both the first polyvinylidene fluoride copolymer and the second polyvinylidene fluoride copolymer contain vinylidene fluoride and hexafluoropropylene monomer units, and the molar percentage of the hexafluoropropylene monomer unit in the first polyvinylidene fluoride copolymer is lower than that of the hexafluoropropylene monomer unit in the second polyvinylidene fluoride copolymer. The battery diaphragm has ultra-thin thickness, has high binding power with a metal electrode plate, and is high in battery safety when being used for a battery.

The invention relates to a preparation method of a solid electrolyte, which comprises the following steps: preparing a filler: adding reactants 2, 5-dihydroxy terephthalaldehyde and triaminoguanidine hydrochloride into a solvent, mixing, and stirring to react to obtain a reaction product; adding the reaction product into a saturated sodium fluoride aqueous solution, and stirring to obtain a product; washing and drying the product to obtain a filler; the preparation method comprises the following steps: mixing lithium bis (trifluoromethylsulfonyl) imide, vinylene carbonate, a polyvinylidene fluoride-hexafluoropropylene copolymer, a filler and an organic solvent, and then adding an initiator azodiisobutyronitrile to obtain mixed slurry; and drying the mixed slurry to obtain the solid electrolyte. The invention also provides the composite solid electrolyte, a battery and an electric device. The solid electrolyte integrates the characteristics of the polymer electrolyte and the filler, and has better mechanical properties while improving the ionic conductivity.