1053 results about "Vinyl ether" patented technology

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro (propyl vinyl ether) unit of 4.3 to 6.0% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 0.7 to 1.4 g / 10 min, and the number of functional groups of 20 or less per 106 main-chain carbon atoms.

Provided is a copolymer comprising tetrafluoroethylene unit and perfluoro(ethyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(ethyl vinyl ether) unit of 4.5 to 6.2% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 0.8 to 4.0 g / 10 min, and the number of functional groups of 20 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro (propyl vinyl ether) unit of 5.6 to 6.38 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 17.1 to 23.0 g / 10 min, and the number of functional groups of 50 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 5.5 to 6.5% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 36.1 to 49.9 g / 10 min, and the number of functional groups of 50 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 4.4 to 5.28 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 11.0 to 16.0 g / 10 min, and the number of functional groups of 50 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 6.2 to 7.1% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 28.0 to 35.9 g / 10 min, and the number of functional groups of 20 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 3.7 to 4.4% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 28.0 to 34.0 g / 10 min, and the number of functional groups of 20 or less per 106 main-chain carbon atoms.

There is provided a powder coating material, comprising a copolymer comprising tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 5.0 to 6.2% by mass with respect to the whole of the monomer units, the copolymer has a melt flow rate at 372° C. of 20.0 to 35.0 g / 10 min, and the copolymer has the number of functional groups of 100 or less per 106 main-chain carbon atoms.

There is provided a copolymer containing tetrafluoroethylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of perfluoro(propyl vinyl ether) unit of 2.4 to 3.48 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 0.8 to 1.4 g / 10 min, and the number of functional groups of 20 or less per 106 main-chain carbon atoms.

A fluoroelastomer production method including a step in which monomers A comprising a compound represented by CX1X2=CX3-L-Z, a cyano-group-containing monomer, and at least one compound selected from the group consisting of tetrafluoroethylene, fluorine-containing vinyl ethers, and fluorine-containing allyl ethers are polymerized in an aqueous medium under conditions that substantially no fluorine-atom-containing emulsifier is present.

The invention provides a perfluoroether rubber sealing element and a preparation method thereof, and the preparation method comprises the following steps: taking tetrafluoroethylene and perfluoroalkyl vinyl ether as comonomers, and carrying out emulsion polymerization under the condition of a vulcanization point monomer and a chain transfer agent to obtain raw perfluoroether rubber; the preparation method comprises the following steps: mixing the raw perfluoroether rubber, the carboxyl fluorinated modified carbon nanotubes, a filler, a vulcanizing agent and an accelerant, and performing first-stage vulcanization and second-stage vulcanization to obtain the perfluoroether rubber sealing element. According to the perfluoroether rubber sealing element and the preparation method thereof provided by the invention, the compressive deformation resistance of the perfluoroether rubber sealing element is improved by adding the carboxyl fluorinated modified carbon nanotubes, so that the sealing element is ensured to meet the sealing requirement of semiconductor equipment.

The invention discloses a preparation method of high-efficiency fusible polytetrafluoroethylene (PFA), and relates to the technical field of fluorine-containing polymers. The preparation method comprises the following specific steps: adding high-purity water into a polymerization kettle, starting stirring, adding a surfactant, a dispersing aid, a chain transfer agent and a perfluoroalkyl vinyl ether monomer, controlling the temperature and pressure of the polymerization kettle, adding an initiator solution into the reaction kettle, and initiating a copolymerization reaction; the preparation method comprises the following steps: continuously adding a gas mixture of tetrafluoroethylene and perfluoroalkyl vinyl ether into a polymerization kettle after a polymerization reaction is started, continuously adding an initiator solution into a reaction kettle at a constant speed at the same time, and recovering unreacted monomers in the polymerization kettle after the reaction is finished to obtain a fusible polytetrafluoroethylene (PFA) resin emulsion. The method overcomes the problem of low polymerization efficiency caused by low filling coefficient and long solvent recovery period of the original solvent phase PFA polymerization reaction, and improves the utilization rate of raw materials.

To provide a coated seed capable of contributing to dispersion of work periods by advancing a sowing period to autumn or winter from a conventional cultivation system of sowing in spring.SOLUTION: There is provided a coated seed that makes it possible to suppress germination until an appropriate time while maintaining seed viability by coating the seed with a coating material that can inhibit water absorption, which triggers seed germination, until a temperature is suitable for germination and can be peeled off from the seed at a temperature that allows for growth (for example, a hydrophobic coating material containing a vinyl ether copolymer consisting of repeating units of the following formula (1), where R1 represents an alkyl group having 3 to 10 carbon atoms, and R2 represents a cyclic hydrocarbon group whose basic skeleton is an alicyclic group having 10 to 15 carbon atoms).SELECTED DRAWING: None

The present invention relates to a coating composition for forming a UV light conversion coating for a photovoltaic cell, a UV light conversion coating prepared using the same, a method for preparing the UV light conversion coating, and a photovoltaic cell and a photovoltaic module comprising the coating. The composition comprises the following components in parts by mass: (A) 100 parts of first epoxy resin which is in a liquid state at room temperature, wherein each molecule of the first epoxy resin contains at least two glycidyl ether groups on average; (B) 33-66 parts of a second epoxy resin in a liquid state at room temperature, wherein the second epoxy resin is an alicyclic epoxy resin of which each molecule contains at least two epoxy cycloalkyl groups on average; (C) 33-66 parts of vinyl ether monomer in a liquid state at room temperature; (D) 6-16 parts of a cationic initiator; (E) 3-15 parts of a UV light conversion agent; and (F) 0-200 parts of an inert diluent. When the light conversion coating prepared from the coating composition is used in a photovoltaic cell or a photovoltaic module, the light transmittance of a UV wave band can be reduced, the visible light wavelength transmittance can be improved, the light conversion efficiency can be improved, and the light conversion coating has excellent adhesive force and ageing resistance.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 9.4 to 10.1% by mass with respect to the whole of the monomer units, a content of perfluoro (propyl vinyl ether) unit of 0.8 to 1.78 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 4.5 to 8.5 g / 10 min, and a total number of a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 90 or less.

The invention discloses a UV-curable battery core insulating paint and a preparation method thereof, and belongs to the technical field of photocureable paints. The UV-curable battery core insulating paint comprises urethane acrylate, self-made vinyl ether modified urethane acrylate, epoxy acrylate, an acrylate monomer, mercaptan, a coupling agent, color paste, a photoinitiator and a leveling agent. The preparation method comprises the following steps: mixing the polyurethane acrylate, the epoxy acrylate, the acrylate monomer and the mercaptan, stirring at normal temperature for 60-120 minutes, adding the coupling agent, the color paste and the flatting agent, stirring at a high speed for 1-3 hours, adding the photoinitiator in a dark place, and stirring for 20-60 minutes to obtain the UV battery core insulating paint. The diluting capacity and the chemical resistance are considered, and the insufficient performance of matrix resin is supplemented; the combination of a photo-initiation system ensures efficient and rapid curing, adaptability to each light source and effective resistance to oxygen inhibition.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 8.5 to 9.5% by mass with respect to the whole of the monomer units, a content of perfluoro (propyl vinyl ether) unit of 1.2 to 1.88 by mass with respect to the whole of the monomer units, a melt flow rate at 372°° C. of 9.0 to 15.0 g / 10 min, and a total number of a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 100 or less.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 9.4 to 11.4% by mass with respect to the whole of the monomer units, a content of perfluoro (propyl vinyl ether) unit of 1.2 to 2.38 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 17.0 to 24.0 g / 10 min, and a total number of a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 120 or less.

The invention relates to the technical field of composite materials, in particular to a corrosion-resistant PEEK sealing material for a sealing check ring and a preparation method of the corrosion-resistant PEEK sealing material. The preparation method specifically comprises the following steps: step 1, initiating polymerization of PEEK resin containing double bonds, PTFE micro powder and sodium allysulfonate by ultraviolet radiation to obtain modified PTFE resin; 2, grafting the oxidized carbon fibers with a silane coupling agent to obtain modified carbon fibers; and 3, adding PEEK resin, modified PTFE resin, modified carbon fibers, a methyl vinyl ether-maleic anhydride copolymer, carbon fibers and a lubricant into a double-screw extruder, uniformly mixing, extruding and granulating to obtain the corrosion-resistant PEEK sealing material for the sealing retainer ring. The PEEK sealing material has the advantages of excellent corrosion resistance, excellent wear resistance and good processability, and can be used for preparing a sealing check ring with better sealing performance.

The invention discloses a high-safety temperature-responsive electrolyte, a lithium ion battery and a sodium ion battery, the high-safety temperature-responsive electrolyte comprises a thermal response solvent, a cosolvent and an electrolyte salt, the thermal response solvent is a thermal response polymer monomer, the thermal response polymer monomer has at least one of the structures of vinyl ether, divinyl ether, dialkenyl amide and dialkenyl butanediimine, the thermal response polymer monomer can quickly form a polymer solid electrolyte under the catalysis of an initiator salt in electrolyte salt under a high-temperature condition, and the fixation of the solid electrolyte enables a diaphragm in a battery not to collapse, so that the battery diaphragm can be used as a lithium ion battery diaphragm. Therefore, short circuit caused by thermal shrinkage and fusion of the diaphragm is avoided, and thermal runaway is avoided. The electrolyte can be used for preparing the lithium-ion and sodium-ion battery, and the lithium-ion and sodium-ion battery can keep a relatively high capacity retention rate while giving consideration to the safety performance.

The invention relates to a fluorine-containing binder for a sulfide all-solid-state battery and a preparation method and application thereof.The binder is formed by copolymerizing isoprene and lithium perfluorovinyl ether sulfonate, specifically, the lithium perfluorovinyl ether sulfonate, a chelating agent, an emulsifying agent, ferrous sulfate, a reducing agent and an acid-base buffering agent are dissolved in water, cooling is conducted in the inert atmosphere, and the fluorine-containing binder for the sulfide all-solid-state battery is obtained. And adding isoprene, an initiator and a molecular weight regulator, and carrying out polymerization reaction to obtain the fluorine-containing binder. The isoprene can enhance the solubility of the lithium perfluorovinyl ether sulfonate fragment in the non-polar solvent, so that the whole polymer is dissolved in the non-polar solvent; the perfluorovinyl ether lithium sulfonate has a large space proportion of fluorocarbon groups, and has a shielding effect on hydrocarbon groups on isoprene, so that the stability of the whole polymer can be improved. The fluorine-containing binder prepared by the preparation method disclosed by the invention is a binder with high elasticity, high ionic conductivity and high stability.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 11.5 to 12.5% by mass with respect to the whole of the monomer units, a content of perfluoro(propyl vinyl ether) unit of 0.3 to 0.8% by mass with respect to the whole of the monomer units, and a melt flow rate at 372° C. of 0.9 to 5.8 g / 10 min.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit, and a fluoro (alkyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 11.2 to 13.2% by mass with respect to the whole of the monomer units, a content of the fluoro (alkyl vinyl ether) unit of 0 to 0.4% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 10.0 to 17.0 g / 10 min, and a total number of —CF2H, a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 90 or less.

The invention relates to the technical field of architectural glass coatings, and discloses a functional coating for architectural glass and a preparation method of the functional coating. Comprising the following raw materials in parts by weight: 40-60 parts of water-based acrylic resin emulsion, 0.4-0.6 part of a defoaming agent, 5-15 parts of modified nano zinc oxide, 0.3-0.5 part of a flatting agent, 1.5-2.5 parts of a coalescing agent, 3-5 parts of a curing agent, 2-4 parts of a dispersing agent, 30-45 parts of deionized water and 3-5 parts of a thickening agent. An alternating structure formed by copolymerization of alkenyl ether (ester) and fluorine-containing ethylene is grafted on the surface of nano-zinc oxide, so that the surface of the nano-zinc oxide has fluorine-containing chain segments, and the excellent hydrophobic property of the chain segments and the antistatic capacity of the nano-zinc oxide cooperate with each other, so that the coating has super-hydrophobic property and self-cleaning capacity; the compatibility of the modified nano-zinc oxide and the coating is remarkably improved, and meanwhile, the nano-zinc oxide has a shielding effect on ultraviolet rays in long and medium wave bands, so that a coating film formed by curing the coating has excellent anti-ultraviolet performance.

The invention discloses a high-strength moisture-proof gypsum board and a preparation method thereof, and relates to the technical field of gypsum board preparation. The high-strength moisture-proof gypsum board is prepared by dipping the surface paper in the composite dipping liquid and then pouring the surface paper and the gypsum core with the waterproof agent, the composite dipping liquid comprises the methoxy vinyl ether copolymer and the epoxy polyoxymethylene dimethyl ether, and the methoxy vinyl ether copolymer is 2, 3, 5-trimethyl-1, 3-pentanediol monoisobutyrate. According to the present invention, epoxy polyoxymethylene dimethyl ether is prepared by reacting 2, 4-dimethoxymethoxyphenylacetic acid with 2-hydroxyethyl vinyl ether, and the epoxy polyoxymethylene dimethyl ether is prepared by terminating polyoxymethylene dimethyl ether with allyl and then reacting with phthalimide hexperoxy acid, such that the waterproofness and the mechanical property of the gypsum board are improved; the waterproof agent is prepared by reacting hydrogen-containing silicone oil and fluorine-containing hyperbranched amide polyurea urethane, so that the moisture resistance and bonding strength of the gypsum board surface paper are enhanced, and additional mechanical support is provided for the gypsum board.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 8.0 to 9.4% by mass with respect to the whole of the monomer units, a content of perfluoro (propyl vinyl ether) unit of 0.6 to 1.5% by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 6.8 to 9.9 g / 10 min, and a total number of a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 90 or less.

The invention relates to the technical field of polymer composite materials, and discloses a nano-ceramic-based composite insulating coating and a preparation method thereof, and the coating is prepared from a composite resin matrix, a composite functional ceramic filler, a double-reactivity organosilicon linker and an initiator. Wherein the composite resin matrix is composed of vinyl-terminated polydimethylsiloxane and a vinyl ether functionalized fluorocarbon copolymer, and a soft and rigid interpenetrating network structure is formed. The composite functional ceramic filler is prepared from needle-shaped silicon nitride, flaky hexagonal boron nitride, nano silicon dioxide, nano cerium oxide and nano barium titanate. According to the invention, a chemical bonding interface is constructed between the inorganic filler and the organic resin, and the synergistic effect of the composite matrix and the multifunctional filler is optimized, so that the coating has excellent adhesive force, flexibility and thermal shock resistance, obtains high volume resistivity and breakdown strength, and meets the insulation protection requirements under harsh working conditions.

The invention provides a PFA composite material laminated plate and a preparation method thereof, and belongs to the technical field of perfluororesin.The method comprises the steps that CNT, tetrafluoroethylene monomers and perfluoroalkyl vinyl ether monomers are polymerized to obtain CNT-containing PFA emulsion, and the CNT-containing PFA emulsion is dried and devolatilized to obtain CNT-containing PFA micro powder; coating the PFA micro powder on the surface of the spread yarn carbon fiber, and drying to obtain a prepreg; melting, extruding, granulating and casting the PFA micro powder to obtain a PFA cast film; a PFA cast film and the spread yarn carbon fiber prepreg are stacked according to different film forming directions, vacuum exhausting and compression molding are carried out, and a laminated plate is obtained; and the laminated plates are sequentially stacked, vacuum exhaust and compression molding are conducted, and the PFA composite material laminated plate is obtained. By means of the treatment scheme, the tensile strength of the PFA composite material laminated plate in the x-y direction and the z-axis direction is improved, and the method can be applied to the semiconductor manufacturing process in the high-temperature and strong-oxidizing-property solvent environment.

The invention discloses a step-by-step polymerization preparation method of fluorinated ethylene propylene, and relates to the technical field of fluorine-containing polymers. According to the method adopted by the invention, ternary polymerization and ternary polymerization are divided into two steps, the first step is copolymerization of tetrafluoroethylene (TFE) and a perfluorovinyl ether monomer, the reaction can be carried out under lower pressure, the concentration of the TFE monomer is lower at the moment, and the polymerization reaction can be carried out according to a preset proportion only by a small amount of the perfluorovinyl ether monomer; the polymer emulsion with very small particle size is obtained. And 2, adding a certain amount of hexafluoropropylene (HFP) into the polymer emulsion, and continuously carrying out polymerization reaction to obtain the final fluorinated ethylene-propylene emulsion. A step-by-step polymerization process is adopted, so that the loss of a perfluorovinyl ether monomer in a fluorinated ethylene propylene ternary polymerization process is reduced, and the production cost is effectively reduced; the step-by-step polymerization can shorten the time of the second-step polymerization reaction and improve the production efficiency.

There is provided a fluorine-containing copolymer comprising tetrafluoroethylene unit, hexafluoropropylene unit and perfluoro (propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 11.4 to 12.2% by mass with respect to the whole of the monomer units, a content of perfluoro (propyl vinyl ether) unit of 0.9 to 1.78 by mass with respect to the whole of the monomer units, a melt flow rate at 372° C. of 4.0 to 13.0 g / 10 min, and a total number of a carbonyl group-containing terminal group, —CF═CF2 and —CH2OH per 106 main-chain carbon atoms of 90 or less.