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Phenyl organic silicon modified polyurethane resin, preparation method and application thereof

The invention discloses a phenyl organic silicon modified polyurethane resin, a preparation method and application thereof, and belongs to the field of polyurethane resin. The structural formula of the phenyl organic silicon modified polyurethane resin is as shown in the description; the preparation method of the phenyl organic silicon modified polyurethane resin comprises the following steps: dissolving phenylsilanediol into an organic solvent, taking a reaction with chlorosilane (R<2>SiCH3Cl2) to prepare hydroxyl-terminated methyphenyl polysiloxane, under the action of a catalyst, mixing the hydroxyl-terminated methyphenyl polysiloxane with a silane compound to obtain amino or imino terminated methyphenyl polysiloxane, then in the atmosphere of argon, mixing diisocyanate, amino or imino terminated methyphenyl polysiloxane, polyethylene glycol or polyol with a mixed solvent, and taking a reaction to obtain the phenyl organic silicon modified polyurethane resin. The phenyl organic silicon modified polyurethane resin has the advantages of being capable of reducing the water absorption, improving the hydrophobicity, and improving the compatibility of organic silicon and polyurethane, and can be prepared to thin film with good properties; the preparation method is simple and feasible.
Owner:WUHAN UNIV
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