The invention provides a composite positive
electrode material and a preparation method and application thereof, the composite positive
electrode material comprises a matrix and a
carbon coating layer on the surface of the matrix, and the matrix comprises a porous LMFP material; the porous LMFP material comprises doped
metal elements, and holes of the porous LMFP material comprise a
lithium supplement agent.
Doping elements in the composite positive
electrode material can improve the stability of a
crystal structure and reduce high-temperature storage and cyclic gas production, and the
lithium supplement agent in the porous LMFP material can prolong the cycle life of the material and can be decomposed to form pores again after first-time charging, so that an
electrolyte can enter the interior of material particles, and the service life of the material is prolonged. And the
carbon coating layer can improve the
conductivity of the material and reduce the
polarization impedance of the material, and meanwhile, the
processing problems that residual alkali on the surface of the
lithium supplementing agent reacts with a glue solution, so that
slurry is gelled and the like can be avoided.