7801 results about "Polyolefin" patented technology

The invention relates to the field of electric heating materials, and provides a graphene-based heating coating and a preparation method thereof. The coating is prepared from functionalized graphene, a surface modified bismuth telluride nanobelt, polyaniline, bisphenol A epoxy acrylate, polyurethane acrylate, a dispersing agent, a flatting agent, a silane coupling agent, a defoaming agent and a propylene glycol methyl ether acetate / N-methyl pyrrolidone mixed solvent. The functionalized graphene is obtained by modifying a hyperbranched polyolefin-acryloyl-POSS copolymer, and carrying out ultrasonic stripping, centrifugal separation, gradient washing and vacuum drying; the surface-modified bismuth telluride nanobelt is modified by an amino silane coupling agent, so that the interfacial compatibility is improved. The preparation method comprises the steps of solvent premixing, nanofiller dispersion, ultrasonic homogenization, coupling agent modification, ultraviolet curing and thermocuring. The heating coating provided by the invention has high conductivity, excellent thermal stability and adhesive force, and can be widely applied to heating electric appliances and intelligent temperature control equipment.

The invention belongs to the technical field of gel materials, and particularly relates to aerogel powder for polyolefin modification and a preparation method and application thereof. The preparation method of the aerogel powder comprises the following steps: (1) preparing aramid nanofiber dispersion liquid; (2) preparing a polypyrrole coated aramid nanofiber dispersion liquid; (3) mixing polyamide acid and the polypyrrole coated aramid nanofiber dispersion liquid, and then carrying out partial imidization and solvent exchange to prepare hydrogel; and (4) carrying out freeze drying, thermal imidization and crushing to obtain the aerogel powder for polyolefin modification. The aerogel powder is a porous solid material formed by forming one-dimensional composite fibers from aramid nanofibers and polypyrrole and combining the one-dimensional composite fibers with polyimide resin. The aerogel powder and polyolefin resin are compounded to obtain the polyolefin resin composite material with high strength and antistatic property, and the polyolefin resin composite material can be widely applied to the fields of pipes, plates, grouting equipment parts, grouting bags and the like.

The invention belongs to the technical field of fiber materials, and particularly relates to a modified aramid nanofiber as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) preparing an aramid nanofiber dispersion liquid; (2) modifying the aramid nanofiber by using POSS; and (3) carrying out in-situ polymerization on polypyrrole on the surface of the aramid nanofiber. POSS (polyhedral oligomeric silsesquioxane) has a relatively large volume exclusion effect, the template effect of long-chain alkyl quaternary ammonium salt can be influenced by scattered adhesion of POSS on the surface of aramid nanofiber, uneven polymerization of pyrrole monomers is caused, and formation of a rough structure on the surface of the fiber is facilitated. According to the invention, the polypyrrole-coated aramid nanofiber with a coarse structure is used as a polyolefin modified material, so that the problem of low interfacial force existing in a common filler is solved, and the polyolefin resin composite material with high strength and antistatic property is obtained and can be widely applied to the fields of pipes, plates, grouting equipment parts, grouting bags and the like.

The application pertains to an artificial turf monofilament comprising a sheath comprising a virgin polyolefin polymer, a core comprising recycled polyolefin polymer obtained from recycled artificial turf. Furthermore, the application pertains to an artificial turf comprising said monofilament as well as a process for manufacturing said monofilament.

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The invention relates to the technical field of automation, in particular to a polyolefin production parameter optimization method and device, equipment and a storage medium, and aims to improve the optimization efficiency of polyolefin production parameters. According to the method, for historical production parameter sets corresponding to a plurality of historical polyolefin categories, historical product prediction models are respectively constructed, and parameter optimization processing is iteratively executed on a to-be-optimized parameter set of a target polyolefin category through the historical product prediction models until the to-be-optimized parameter set meets a target category production condition, so that a target production parameter set is obtained. And in each iterative training, performing prediction comparison processing on the to-be-optimized parameter set through each historical product prediction model to obtain a similarity weight of each historical product prediction model, determining a recommended production parameter of the target polyolefin category according to each obtained similarity weight, updating the to-be-optimized parameter set according to the recommended production parameter, and obtaining the target polyolefin category. And executing the next parameter optimization processing.

The invention provides a solid electrolyte slurry, an electrode slurry, a solid electrolyte sheet, an electrode sheet, a solid battery monomer, a battery device and a power utilization device.The solid electrolyte slurry comprises a sulfide solid electrolyte material, a solvent and a binder dissolved in the solvent, and the solvent is a non-polar solvent, a weak-polar solvent or a mixed solvent of the non-polar solvent and the weak-polar solvent; the binding agent comprises a polyacrylate binding agent and a non-polar polyolefin binding agent. The slurry disclosed by the invention has high dispersity, high suspension property and good cohesiveness, and can enable the solid-state battery monomer to have high initial coulombic efficiency when being used in the solid-state battery monomer.

The invention provides a polyolefin coated diaphragm with ion selectivity, a preparation method and application. The polyolefin coated diaphragm is composed of a porous polyolefin supporting layer, and a first ion selective skin layer and a second ion selective skin layer which are positioned on two surfaces of the porous polyolefin supporting layer, the first ion selective skin layer and the second ion selective skin layer are both composed of an intrinsic microporous polymer PIM or a modified intrinsic microporous polymer PIM; the PIM material has a high specific surface area, a rich microporous structure and good electrolyte affinity; therefore, the polyolefin coated diaphragm has good wettability and lithium ion permeability, the overall mechanical property and heat resistance of the diaphragm are effectively improved, and light weight is kept; meanwhile, the diffusion coefficient of the diaphragm to metal ions such as Mn, Ni and Fe is greatly reduced, the situation that in a lithium ion battery positive electrode material using an existing diaphragm, the metal ions such as Mn, Ni and Fe are dissolved out during battery operation and then pollute a negative electrode of the battery is effectively avoided, and the service life of the battery can be effectively prolonged.

An absorbent article comprising a hotmelt adhesive comprising a styrene-block-copolymer (SBC), an amorphous polyolefin and optionally a tackifier. The SBC is preferably selected from the group of SEBS, SEPS and SEP polymers, and the amorphous polyolefin is preferably a propylene-based copolymer (PbP) having a weight-average molecular weight Mw of less than 10 000 g / mol. The hotmelt adhesive bonds two components of the article, for example SAP particles on the core wrap.

The invention belongs to the technical field of waterproofing of constructional engineering, and provides a high-strength puncture-resistant railway tunnel waterproof and drainage board and a preparation method thereof.The high-strength puncture-resistant railway tunnel waterproof and drainage board is prepared from, by mass, 30-35 wt% of polyolefin elastomer POE, 40-45 wt% of high-density polyethylene and 20-30 wt% of antioxidant enhanced master batch; the antioxidant enhanced master batch is prepared from the following components in parts by weight: 6 to 8 parts of nano SiO2, 20 to 28 parts of EPDM-g-MS, 60 to 70 parts of linear low-density polyethylene, 1 to 3 parts of an antioxidant and 1 to 3 parts of an anti-ultraviolet agent. The waterproof and drainage board for the railway tunnel, provided by the invention, not only meets all properties specified in Q / CR562.3-2018, but also has more excellent tensile property and puncture resistance.

The invention relates to polyurethane resin, synthetic leather and a preparation method and application thereof, and relates to the technical field of polyurethane, the polyurethane resin is prepared from the following raw materials: bio-based polyester polyol, polyolefin polyol, isocyanate, a chain extender, a pore-forming agent and a solvent; the bio-based polyester polyol is prepared from the following raw materials: bio-based dihydric alcohol, bio-based dibasic acid and micromolecular branched chain-containing dihydric alcohol. The polyurethane resin provided by the invention is high in bio-based content, micromolecular branched chain-containing dihydric alcohol is introduced into bio-based polyester polyol, a branched chain structure provides scratch resistance for the synthetic leather taking the polyurethane resin as a coating layer, the crystallinity of the polyurethane resin is reduced by compounding the polyolefin polyol, the synthetic leather is endowed with soft hand feeling, and the synthetic leather has the advantages that the synthetic leather is not prone to being scratched, and the service life of the synthetic leather is prolonged. Due to the addition of the chain extender and the pore-forming agent, the polyurethane has excellent foaming performance, the synthetic leather has excellent water absorption, and the hand feeling of the synthetic leather is further improved.

The invention relates to the technical field of intelligent materials, in particular to low-temperature-resistant magnetorheological fluid and a preparation method thereof.The low-temperature-resistant magnetorheological fluid is prepared from, by weight, 60-75 parts of magnetic particles; 3 to 15 parts of modified magnetic particles; 10-25 parts of low-temperature-based carrier liquid, which comprises 40-60% of silicone oil and / or mineral oil, 20-30% of synthetic ester and 10-20% of poly-alpha-olefin; 0.1 to 1.0 part of a dispersant; 0.5 to 2.0 parts of an anticoagulant; wherein the modified magnetic particles are prepared by coating magnetic particles with SiO2 aerogel and grafting the coated magnetic particles with fluorine-containing silane; the preparation method comprises the steps that magnetic particles are sequentially subjected to silane coupling agent treatment, aerogel deposition and fluorine-containing silane gas-phase grafting, and modified magnetic particles are prepared; carrying out ultrasonic mixing on the base carrier liquid and an anticoagulant at 40-60 DEG C for 30 minutes; adding magnetic particles, modified magnetic particles and a dispersing agent, dispersing by adopting a micro-jet homogenizer, and then carrying out gradient cooling treatment. The low-temperature-resistant magnetorheological fluid has the effect of improving the low-temperature-resistant performance of the magnetorheological fluid.

The invention discloses a polyethylene cable with flexibility and fire resistance and a preparation method of the polyethylene cable, and relates to the technical field of polyethylene cables, the polyethylene cable comprises a cable core and a polyethylene protective sleeve, the polyethylene protective sleeve comprises the following components, the plastic is prepared from the following components in parts by mass: 50 to 70 parts of low-density polyethylene, 20 to 30 parts of modified polyolefin elastomer, 10 to 25 parts of lignin modified copolymer, 0.5 to 1 part of antioxidant, 0.6 to 1.2 parts of zinc oxide and 1 to 2 parts of talcum powder. The modified polyolefin elastomer is prepared from POE-g-MAH (Polyolefin Elastomer-g-MAH) and a DOPO Schiff base derivative; the lignin modified copolymer is prepared from lauryl methacrylate, isobornyl methacrylate and a lignin macroinitiator.

The invention relates to the technical field of blocking medicine bottles, and particularly discloses a blocking medicine bottle and a preparation method thereof, aiming at the problems that the upper limit of the blocking performance of the existing blocking medicine bottle is low and the blocking performance is difficult to break through due to the fact that the blocking performance of the existing blocking medicine bottle is mostly realized through structural design. A bottle body of the blocking medicine bottle comprises an inner layer, a secondary inner layer, a middle layer, a secondary outer layer and an outer layer which are sequentially arranged in a covering mode. The inner layer comprises polyethylene; the secondary inner layer comprises an ethylene-methyl acrylate copolymer; the middle layer comprises an ethylene-vinyl alcohol copolymer, cyclic polyolefin and modified montmorillonite; the secondary outer layer comprises an ethylene-methyl acrylate copolymer; the outer layer comprises polyethylene, cyclic polyolefin and modified montmorillonite. The barrier medicine bottle is formed by compositing five layers of materials, the oxygen and water transmittance is low, the barrier property is high, and the barrier medicine bottle has great application value in packaging of medicine or food and the like.

The present application discloses a composite separator, a preparation method therefor and a use thereof. The composite separator comprises a polyolefin separator, an adhesive layer coated on one or both sides of the polyolefin separator, and a cellulose film covering the surface of the adhesive layer, wherein the pore diameter of the cellulose film is greater than that of the polyolefin separator. According to the composite separator, the strength and thermal stability of a traditional separator can be improved, and the requirements of liquid absorption and retention are met, so that the performance and the cycle life of an energy storage device are improved.

The invention discloses a composite current collector, a preparation method thereof, an electrode plate containing the composite current collector, and a secondary battery. The composite current collector sequentially comprises a first conducting layer, a first bonding layer, an insulating layer, a second bonding layer and a second conducting layer, and the first conducting layer and the second conducting layer are both copper layers; binders of the first bonding layer and the second bonding layer are respectively and independently selected from any one of epoxy resin, polyolefin, polyester and polyurethane. The composite current collector prepared by the invention has good structural stability, has low requirements on an insulating layer, is high in safety when being applied to a battery, and is beneficial to improving the energy density of the battery.

The invention relates to the technical field of power cables, in particular to a heat-aging-resistant crosslinked polyethylene insulated power cable and a preparation method thereof. The cable comprises conductor wire cores, an insulating layer, a filling layer, a composite function layer, a steel tape armoring layer and a sheath layer from inside to outside. The insulating layer is composed of semi-conductive crosslinked polyethylene, silicone resin, nano montmorillonite and an HALS light stabilizer; the filling layer is composed of plasticized glass fabric, polyphenylene sulfide and rare earth oxide; the composite functional layer sequentially comprises a heat-conducting inner layer, a flame-retardant middle layer and an anti-UV outer layer from inside to outside; the sheath layer is composed of polyolefin, white carbon black, ceramic silicone rubber, a flame retardant, polyethylene wax and an initiator. According to the cable, cross-linked polyethylene and silicone resin are preferably selected as heat-resistant materials, heat conduction / flame retardance / UV resistance / armored multi-layer synergistic protection is achieved, the mechanical barrier performance is improved, meanwhile, damage of thermal stress to internal materials is reduced, comprehensive improvement of thermal aging resistance is achieved, and the cable is suitable for high-temperature, high-humidity and frequent thermal cycle harsh environments.

In some embodiments, a cable can include an electrically conductive inner core. A first insulation layer can be disposed about the inner core. An electrically conductive layer can be disposed about the first insulation layer. A second insulation layer can be disposed about the electrically conductive layer. A first polymer jacket can be disposed about the second insulation layer. The first polymer jacket can include a first layer of armor strength members disposed therein. A second polymer jacket can be disposed about the first polymer jacket. The second polymer jacket can include a second layer of armor strength members disposed therein. An outer polymer jacket can be disposed about the second polymer jacket. At least one of the first polymer jacket, the second polymer jacket, and the outer polymer jacket can be formed from an aliphatic polyketone polymer, an ethylene-propylene copolymer, a polyolefin elastomer, a polypropylene, or a cross-linkable polyethylene.

The invention discloses a preparation method of a flame-retardant anti-aging polyolefin plastic, and belongs to the technical field of polyolefin material processing.The preparation method comprises the steps that a modified anti-aging agent is mixed with a DOPO-based flame retardant modified by introducing isocyanate and epoxy groups, the mixture is added into a polyolefin material, during combustion, carbon formation is promoted by the phosphorus element, and the flame-retardant anti-aging polyolefin plastic is obtained. The flame retardant and nitrogen element synergistically play a flame-retardant role, meanwhile, epoxy groups in the flame retardant and carboxyl of polypropylene are subjected to a ring-opening reaction, the crosslinking degree of the material is enhanced, the modified anti-aging agent can effectively capture free radicals and inhibit oxidative degradation, and the mechanical strength and flame-retardant effect of the material are improved. According to the modification method, the anti-aging, high-temperature-resistant and flame-retardant properties of the polyolefin plastic are remarkably improved, the stability of the polyolefin plastic in high-temperature and severe environments is enhanced, the service life is prolonged, and the mechanical property and the thermal stability of the polyolefin plastic are improved.

The invention relates to a polyethylene and silica gel mixed material, a preparation method thereof and application of the polyethylene and silica gel mixed material in a composite optical cable silicon core tube. The composite material comprises the following components in parts by weight: high-density polyethylene, an ethylene-siloxane copolymer elastomer, a maleic anhydride grafted polyolefin elastomer, hydroxylated nano silicon dioxide, liquid paraffin, a crystallization nucleating agent, an ultraviolet light absorber, an auxiliary stabilizer, a processing aid and color master batch. The liquid paraffin is formed by blending dual-molecular-weight paraffin with different carbon chain lengths, and part of the liquid paraffin is grafted and modified by polybutylene so as to enhance the anchoring capacity of the lubricating phase; in addition, nano cellulose crystals grafted by a PEG-PCL (Polyethylene Glycol-Polycaprolactone) block copolymer are introduced, so that the dimensional stability and the interface structure integrity of the material are synergistically enhanced. The composite material has excellent low friction, thermal oxidation stability, creep resistance and ultraviolet aging resistance, and is suitable for preparation of a high-performance composite optical cable silicon core tube.

The invention relates to the technical field of material processing, and discloses a silicon-containing composition for processing a chlorine-containing polyolefin material and a preparation method, which are used for solving the problems of processing and extrusion of the chlorine-containing polyolefin composite material. The invention relates to a silicon-containing composition for processing a chlorine-containing polyolefin material. The silicon-containing composition comprises 5-95 parts of modified polysiloxane, 5-95 parts of hydrocarbon wax, 5-95 parts of fatty acid amide, 5-95 parts of metallic soap and 1-5 parts of other auxiliaries. The silicon-containing composition for processing the chlorine-containing polyolefin material is applied to processing and extrusion of the chlorine-containing polyolefin composite material, modified polysiloxane not only contains a plastic-loving part but also contains a filler-loving part, and meanwhile, the whole molecular structure takes organic silicon as a main chain, so that the special performance of the organic silicon is achieved; according to the present invention, the chlorine-containing polyolefin composite material is compounded with other lubricants so as to achieve efficient internal and external lubrication, high cost performance and no precipitation, can effectively delay the decomposition time of the chlorine-containing polyolefin, can weaken the adhesion effect between the chlorine-containing polyolefin and the metal, can substantially prolong the screw cleaning time during the processing of the chlorine-containing polyolefin composite material, and can improve the production efficiency.

The invention relates to the technical field of cable materials, in particular to a thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material and a preparation method thereof. The modified thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material is prepared from the following components in parts by weight: 30 to 36 parts of polypropylene, 12 to 16 parts of toughening agent, 10 to 16 parts of POE (Polyolefin Elastomer) compatilizer, 88 to 102 parts of flame retardant, 0.5 to 0.9 part of antioxidant, 1 to 2 parts of lubricant and 3 to 6 parts of modified nano particles, the modified nano particles are prepared from nano silicon dioxide and methyl methacrylate through graft polymerization. By adding the modified nanoparticles, the performance of the cable material is remarkably improved, so that the cable material achieves better balance and effect in the aspects of mechanical property, flame retardant property, electrical property, aging property, low-temperature property and the like.

The invention relates to the technical field of electric wire materials, in particular to a preparation process of a high-strength halogen-free flame-retardant electric wire. According to the preparation method, the polyolefin flame-retardant microspheres are obtained by adding propenylated cyclotriphosphazene, propenylated phosphaphenanthrene, methyl methacrylate, lauroyl peroxide, polyvinyl alcohol and deionized water. The flame-retardant modified boron nitride nanosheet is prepared by the following steps: firstly, preparing a flame-retardant modified boron nitride nanosheet, and then adding hydroxylated boron nitride, gamma-glycidyl ether oxypropyl trimethoxy silane and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the flame-retardant modified boron nitride nanosheet. An ethylene-vinyl acetate copolymer, polyolefin flame-retardant microspheres, flame-retardant modified boron nitride nanosheets, an antioxidant and a lubricant are mixed and react, and the high-strength halogen-free flame-retardant protective sleeve is obtained. And wrapping the periphery of the copper core wire with the high-strength halogen-free flame-retardant protective sleeve to obtain a finished product. The finished product prepared by the invention has excellent flame retardant property and high strength, thereby having a wide application prospect in the technical field of electric wire materials.

The present invention addresses the problem of providing a method for producing olefins that can sufficiently remove polyamides from waste plastics. [Solution] The method for producing olefins according to the present invention includes a thermal decomposition step of thermally decomposing a waste plastic raw material containing polyolefins and polyamides to obtain a hydrocarbon stream, a separation step of separating a thermal decomposition product of the polyamides from the hydrocarbon stream that has undergone the thermal decomposition step, and a catalytic cracking step of catalytically cracking the hydrocarbon stream that has undergone the separation step in the presence of a catalyst containing zeolite to obtain olefins.

The preparation method of the high-temperature-resistant diaphragm for the lithium battery comprises the following steps: uniformly mixing water, a dispersing agent and an inorganic ceramic material in a mass ratio of (65-75): (0.5-0.8): (35-25), stirring and grinding to obtain a mixed solution; a modified acrylic polymer binder, a polyacrylamide polymer binder, a wetting agent and the mixed solution are mixed to be uniform, high-heat-resistance coating slurry is obtained, and the mass ratio of the modified acrylic polymer binder to the polyacrylamide polymer binder to the wetting agent to the inorganic ceramic material is (1.5-2.5): (1.5-2.5): (0.03-0.06): 100; and coating two opposite surfaces or any one surface of a polyolefin base membrane with the high-heat-resistance coating slurry to form a coating on the corresponding surface of the polyolefin base membrane, and drying to obtain the high-temperature-resistant diaphragm for the lithium battery.

The invention belongs to the field of olefin polymers, and relates to a reversible cross-linked polyolefin elastomer and a preparation method thereof. The reversible cross-linked polyolefin elastomer is a reversible cross-linked polyolefin elastomer in which a cross-linked network is formed through three non-covalent bonds, namely hydrogen bonds, ionic bonds and coordinate bonds, and the hydrogen bonds and the cross-linked bonds account for 0.1-85% by taking the sum of the three non-covalent bonds, namely the hydrogen bonds, the ionic bonds and the coordinate bonds as 100%; the ionic crosslinking bond accounts for 0.5-90%; and the coordination crosslinking bond accounts for 9-99%. Compared with a reversible cross-linked polyolefin elastomer in the prior art, the reversible cross-linked polyolefin elastomer prepared by the invention contains hydrogen bonds, ionic bonds and coordinate bonds at the same time, and a synergistic effect is generated through combination of reversible cross-linked interaction of the coordinate bonds, the hydrogen bonds and the ionic bonds; therefore, the material has excellent physical and mechanical properties and also has recoverability and self-repairability.

The invention discloses a silane cross-linked polyolefin halogen-free flame-retardant cable material and a low-energy-consumption preparation method thereof.The preparation method comprises the steps that EVA / EEA serves as a matrix, silane groups are covalently connected to a polyolefin molecular chain through a free radical grafting reaction, and a grafting material containing an active silane side group is prepared; meanwhile, vinyl isocyanate is adopted to chemically modify hydroxyl on the surface of magnesium hydroxide, vinyl is grafted to the surfaces of particles, the polarity of the particles is reduced, and the dispersity of the particles is enhanced; then carrying out melt blending on the grafted material and modified magnesium hydroxide, constructing an interface bridge by using an anhydride group, and shortening the two-phase distance; finally, through room-temperature natural cross-linking and warm water auxiliary cross-linking, silane groups are promoted to be hydrolyzed into silanol, the silanol is condensed to form a-Si-O-Si-three-dimensional network, meanwhile, vinyl on the surface of magnesium hydroxide and a polyolefin matrix are subjected to free radical copolymerization, and a covalent bond interface layer is formed between inorganic particles and an organic matrix. According to the method, the synergistic improvement of high crosslinking degree, strong stretchability and excellent flame retardance of the cable material is realized through molecular-level interface regulation and cross-linking network optimization.

The invention provides a secondary battery and an electronic device. The secondary battery comprises a positive electrode, a negative electrode, a diaphragm and an electrolyte, wherein the positive electrode comprises a current collector, and a positive electrode mixture layer and an organic matter insulating layer which are arranged in contact with the current collector; the organic matter insulating layer comprises an organic insulating material and an adhesive, the organic insulating material comprises polyolefin, and the electrolyte comprises lithium difluorophosphate and boron-containing lithium salt. The secondary battery has good low-temperature cycling performance, low-temperature voltage drop and good safety.

The invention belongs to the technical field of packaging adhesive films for photovoltaic modules, and particularly relates to a water-blocking and oxygen-blocking adhesive film for photovoltaic module packaging and a preparation method of the water-blocking and oxygen-blocking adhesive film for photovoltaic module packaging, and the water-blocking and oxygen-blocking adhesive film comprises a water-blocking layer and an oxygen-blocking layer which are adjacent to each other through co-extrusion; wherein the waterproof layer is prepared from the following materials in parts by mass: 100 parts of grafted polyolefin resin, 0.05 to 0.5 part of alkaline nano oxide and 0.1 to 1 part of antioxidant; the oxygen barrier layer is prepared from the following materials in parts by mass: 100 parts of oxygen barrier resin, 0.1-1 part of an oxygen absorbent, 0.1-1 part of a silane coupling agent and 0.05-0.5 part of a light conversion agent; the oxygen-resistant resin comprises any one or a combination of more of PS (polystyrene), PE (polyethylene), PET (polyethylene terephthalate), PB (polybutylene), PP (polypropylene), PVC (polyvinyl chloride), PVDC (polyvinyl dichloride), PA6 (polyamide 6) and EVOH (ethylene-vinyl alcohol).

A garden hose nozzle includes a hose nozzle, wherein the hose nozzle is made of injection molding and has a body part, one end of the body part is connected to a water spray part for spraying water, the other end of the body part is equipped with a water supply part used to supply water. The surfaces of the body part, the water spray part, and the water supply part are covered with at least one wrapping layer for protection and holding. The wrapping layer is composed of a thermoplastic polyolefin, a polyethylene, and a cork. The proportions of the thermoplastic polyolefin, the polyethylene, and the cork in the wrapping layer are 15%, 54%, and 30% respectively.