1769results about "Liquid solutions solvent extraction" patented technology

A method comprises planarizing a substrate material with a functionalized chemical planarization pad. The functionalized chemical planarization pad includes a plurality of functional groups bonded to a material of the pad. The functional groups are configured to chemically react with the substrate material such that a portion of substrate material bonds to the functional groups. The pad is regenerated by applying a regeneration solution configured to break bonds between the functional groups and substrate material bonded to the functional groups to form removed material. The removed material is complexed in a dissolved complexing agent to form dissolved material in an effluent phase.

The invention relates to the technical field of liquid-liquid homogeneous microextraction, in particular to a method for microextraction analysis of perfluorooctanoic acid by using a switchable eutectic solvent. Comprising the following steps: step 1, mixing a hydrogen bond acceptor and a hydrogen bond donor according to a set proportion value, and stirring and mixing at a set temperature value to obtain a eutectic solvent; step 2, filtering the water sample through a water-based filter membrane, then adding a set amount of deep eutectic solvent, dropwise adding an alkaline solution, carrying out full vortex mixing through a mixer, and then adding an acidic solution to form an emulsion; according to the method, the high selectivity of the green solvent with a specific structure on perfluorooctanoic acid and the characteristic that the solvent is switched between hydrophilic and hydrophobic forms are utilized, so that the microextraction time is shortened, and the impurity removal and enrichment effects are enhanced. The method is simple and convenient to operate, green, environment-friendly, low in cost and good in effect, has the advantage of efficiently and rapidly pretreating the batch small-size complex matrix sample, and has a relatively good application prospect.

To provide a method for recovering oil from an oil-containing waste liquid, enabling efficient separation and recovery of oil from the oil-containing waste liquid through a solvent extraction method.SOLUTION: The method for recovering oil from an oil-containing waste liquid includes: an extraction step for extracting an oil-containing waste liquid using a solvent, thereby transferring oil in the oil-containing waste liquid to the solvent; a separation step for separating the solvent including the extracted oil and the waste liquid from each other; and an oil recovery step for separating and recovering the oil from the separated solvent-containing oil. In the method for recovering oil, the solvent is n-hexane, an oil concentration in the oil-containing waste liquid supplied to the extraction step is 1,000-5,000 mg / L, a volume ratio (solvent / waste liquid ratio) of the solvent to the oil-containing waste liquid is 0.01-0.05, and the oil concentration in the solvent containing the oil separated in the separation step is 4 mass% or more.SELECTED DRAWING: Figure 1

The invention relates to the field of ginsenoside extraction, in particular to a device and method for removing a plasticizer in a ginsenoside extract, and the device comprises a roll-over stand, a removal cabin and the like. According to the equipment and the method for removing the plasticizer in the ginsenoside extract, the filtering assembly and the adsorption resin blocks are distributed in the removal cabin in the vertical direction, so that fine filtering treatment and adsorption removal treatment of a ginsenoside extract solution are completed in sequence; and in addition, the filter assembly and the plurality of adsorption resin blocks can be subjected to backwashing treatment in a mutually separated state, so that the overall treatment process steps of the backwashing treatment work are reduced on the basis of ensuring that efficient backwashing treatment is synchronously performed on the filter assembly and all the adsorption resin blocks. The defects that multiple treatment devices need to be used in multiple filtering treatment and ion adsorption treatment processes of the ginsenoside extract solution, the plasticizer removal treatment efficiency is affected, and the plasticizer removal treatment period is delayed are overcome.

To provide an extractant for selectively extracting lithium salt, a method for recovering lithium salt, and a method for producing lithium salt.SOLUTION: A lithium salt extractant comprises at least one selected from a group consisting of a compound represented by a general formula (1) and a compound represented by the general formula (2) (where X1, X2, X3 and X4 independently represent an oxygen atom, a sulfur atom, a sulfinyl group, a sulfonyl group, a carbonyl group, or an imino group).SELECTED DRAWING: None

The invention discloses a method for separating iron and lithium in a lithium iron phosphate iron salt leaching solution and recycling iron phosphate, and belongs to the technical field of waste lithium battery recycling. The method comprises the following steps: constructing a bis (2-ethylhexyl) phosphate and trioctyl decyl tertiary amine mixed extraction system for selective extraction of Fe < 3 + >, adopting phosphoric acid for reverse extraction, recycling phosphoric acid reverse extraction liquid, preparing iron phosphate and the like. According to the method, efficient enrichment of Fe < 3 + > and efficient elution of Fe < 3 + > from a loaded organic phase are realized. The purity of the raffinate Li solution is relatively high, so that the subsequent preparation of battery-grade lithium carbonate is facilitated. The strip liquor can be recycled for multiple times, an iron intermediate is precipitated through pH adjustment, and the FePO4 product can be finally prepared through washing, aging and high-temperature calcination. The method is high in extraction selectivity, recyclable in process and mild in operation condition, has good separation effect and resource utilization efficiency, and is suitable for popularization and application of a Fe / Li separation process in lithium battery recovery.

The invention discloses an extraction tower, which comprises a tower body, a main shaft, a reciprocating lifting member, an autorotation member, a motor and a movable sieve plate group, the main shaft is rotatably arranged in the tower body, the main shaft and the tower body are coaxially arranged, the reciprocating lifting member is fixedly installed on the top of the main shaft, the reciprocating lifting member is used for enabling the main shaft to do reciprocating lifting motion, and the autorotation member is used for rotating the main shaft. The top and the bottom of the rotation part are fixedly connected with the main shaft and the bottom inner wall of the tower body respectively, the rotation part is used for enabling the main shaft to rotate, and the multiple movable sieve plate sets are evenly distributed outside the main shaft. The device not only can oscillate and scatter a liquid material in the vertical direction, but also can stir and scatter the liquid material in the horizontal direction, double multi-stage dispersion operation is achieved, the solvent liquid material mixing and contacting effect is improved, and the solvent liquid material contacting degree is guaranteed.

The invention aims to provide a device and method for extracting iron from red mud and preparing iron oxide red, and belongs to the technical field of resource utilization, hydrochloric acid is adopted to leach iron element in the red mud, and a ferric chloride solution is separated from leachate through an extraction process. And then, carrying out alkali precipitation, washing and firing to prepare the high-purity iron oxide red. By using the method disclosed by the invention, the iron resource in the red mud can be recycled, so that the dual purposes of resource utilization and environment-friendly treatment are achieved.

The utility model provides a wet-process phosphoric acid extraction device. A liquid outlet hole, a first mounting hole and a second mounting hole formed in an extraction tank of the wet-process phosphoric acid extraction device are all communicated with an extraction cavity, the liquid outlet hole is arranged close to the top of the extraction tank, and an extraction agent inlet pipe and a to-be-extracted liquid inlet pipe are both communicated with the extraction cavity; a first driving part of the first stirring assembly is arranged at the bottom of the extraction tank, and the driving end of the first driving part is connected to a first shearing stirring net through a first mounting hole; a second driving part of the second stirring assembly is arranged at the top of the extraction tank, the driving end of the second driving part is connected to a second shearing and stirring net through a second mounting hole, the second shearing and stirring net is located above the first shearing and stirring net, and the rotating speed of the first driving part is larger than that of the second driving part. According to the wet-process phosphoric acid extraction device, by arranging the first shearing and stirring net and the second shearing and stirring net, emulsification and demulsification of a mixed solution of a to-be-extracted solution and an extraction agent are achieved, and therefore the wet-process phosphoric acid extraction efficiency and effect are improved.

The invention provides a large-scale fluid extraction and separation intelligent control method based on a mixing tank structure, and relates to the technical field of intelligent control, and the method comprises the steps: collecting parameter information in a mixing tank through double-cycle sampling, dividing flow field partitions based on three-dimensional numerical characteristics, collecting concentration gradient information of a target object, and building a digital twinborn model; executing a partition self-adaptive control strategy to dynamically adjust stirring parameters, controlling extraction agent supplement, adjusting the opening degree of a partition plate, and monitoring and updating the control strategy in real time. According to the method, precise zone control is realized, the extraction efficiency is improved, the energy consumption is reduced, and the method adapts to complex working condition changes.

This disclosure relates to an annular centrifugal extractor with Solid Separation Part to Separate Solid Particles Present in Solvent Extraction Fluid. In order to remove solid particles from the solution, a solid separation part / rotating bowl is attached to rotating bowl in such a way that solid particles settle inside the solid separation part. This solid separating centrifugal extractor contains two parts: (I) upper part which acts as a liquid-liquid separator to separate aqueous and organic solution used in solvent extraction operation and (II) bottom part which acts as a solid separator to separate solid particle present in solvent extraction liquids. The bottom rotating rotor is coupled with upper rotating rotor by threading arrangement. Both the rotating rotors are confined within a stationary cylinder. Dispersion with solid particles entering inside the rotating bowl is deflected towards the wall of the rotating cylinder by deflecting baffle by centrifugal sedimentation.

The invention discloses an egg yolk lecithin separation and extraction device and a technology thereof, and relates to the technical field of separation and extraction, the egg yolk lecithin separation and extraction device comprises: a stirring barrel, the stirring barrel is arranged on the ground; the feeding hole is fixedly formed in the top of the stirring barrel; the solvent tank is fixedly mounted at the top of the stirring barrel, and a chloroform solution is arranged in the solvent tank; the separating funnel is fixedly mounted at the bottom of the stirring barrel, and the separating funnel is used for separating an egg phosphorus solvent from a water phase; the motor is fixedly mounted at the top of the stirring barrel; the stirring rod is fixedly mounted at the output end of the motor, and a reciprocating spiral groove is formed in the surface of the stirring rod; the stirring plate is fixedly mounted at the bottom of the stirring rod; the elastic telescopic rod enables egg yolk and chloroform on the sliding plate to be mixed more sufficiently through up-down movement of the sliding plate.

The present invention addresses the problem of how to effectively and efficiently extract, separate, and recover high-concentration PFAS contained in water regardless of the type of PFAS. An organic fluorine compound is converted to a chemical species having a negative charge on the basis of ionization by acid dissociation of the organic fluorine compound, molecularization of protonation-type hydrophobic cations, or both of these items, the distribution of the organic fluorine compound to an aqueous phase is promoted, and the organic fluorine compound is recovered.

The invention belongs to the technical field of organic matter extraction, and particularly relates to a green directional extraction and purification method for haematococcus astaxanthin, which comprises the following steps: (1) mixing dried haematococcus powder and a composite pretreatment agent according to a mass ratio of 1: (8-15), and stirring to obtain a pretreated algae solution; (2) treating the pretreated algae liquid through ultrahigh-pressure microjet equipment to obtain wall-broken slurry; (3) mixing the wall-broken slurry and a composite extraction agent according to a volume ratio of 1: 3-1: 5, and performing extraction separation to obtain an astaxanthin extraction phase; (4) carrying out selective adsorption on the astaxanthin extraction phase through an adsorption column filled with a molecular imprinting adsorbent; (5) collecting eluent by adopting a gradient elution method; and (6) performing vacuum concentration on the eluent, and performing spray drying to obtain an astaxanthin product. According to the method, the astaxanthin extraction efficiency and the product purity are remarkably improved, meanwhile, the energy consumption is reduced to the maximum extent, toxic solvent residues are avoided, and the stability of the astaxanthin is effectively protected.

The invention discloses a method for preparing a battery-grade lithium compound. The method comprises the following steps: S1, carrying out sulfuric acid acidification reaction on a lithium-containing raw material or roasting by adding sulfate, and carrying out water leaching to obtain leached slurry; the lithium-containing raw material is a lithium mineral or a waste lithium battery material; s2, calcium oxide or calcium hydroxide is added into the leaching slurry, filtering is performed after full reaction, filtrate A and filter residues A are obtained, the main component of the filtrate A is lithium hydroxide, and the filtrate A further comprises soluble impurities formed after water leaching; s3, adding a substance for removing calcium ions into the filtrate A, fully reacting, and filtering to obtain filtrate B and filter residues B; s4, fully contacting the filtrate B with an extracting agent for extraction, and then separating to obtain a loaded organic phase and raffinate; s5, reversely extracting the loaded organic phase to obtain a lithium solution and a blank organic phase; and S6, further treating the lithium solution to obtain the battery-grade lithium compound. Sodium ions are basically not introduced, the energy consumption is low, the process is simplified, the product quality is high, the production cost is low, the lithium yield is high, and byproducts are convenient to treat.

Targetry coupled separation refers to enhancing the production of a predetermined radiation product through the selection of a target (including selection of the target material and the material's physical structure) and separation chemistry in order to optimize the recovery of the predetermined radiation product. This disclosure describes systems and methods for creating (through irradiation) and removing one or more desired radioisotopes from a target and further describes systems and methods that allow the same target to undergo multiple irradiations and separation operations without damage to the target. In contrast with the prior art that requires complete dissolution or destruction of a target before recovery of any irradiation products, the repeated reuse of the same physical target allowed by targetry coupled separation represents a significant increase in efficiency and decrease in cost over the prior art.

The invention discloses an immersed rotating packed bed combined coil device and method for reactive extraction, and the combined coil device comprises a shell, a liquid inlet, a sealing assembly, a liquid premixing pipe, a packing assembly, a heat exchange jacket, a liquid emptying port, a liquid outlet and a spiral coil assembly; according to the device, a reactor cavity is completely filled with liquid, so that an immersed reaction environment is formed; and a strong shearing effect is generated by utilizing the supergravity silk screen filler, so that rapid heterogeneous mixing is realized, and the reaction selectivity is improved. Meanwhile, a supergravity reaction area and a coil flow area are combined into a whole, the spiral coil can repeatedly change the flow direction and form vortex to realize continuous flow of the material and maintain the dispersion state of liquid drops, and the retention time of the material is flexibly regulated and controlled by adjusting the length of the coil, so that the reaction conversion rate is remarkably improved.

The invention discloses an application of an ionic liquid in extraction of trioxymethylene, in the process of generating trioxymethylene by acid-catalyzed condensation of a formaldehyde aqueous solution, the ionic liquid is added as an extraction agent to extract and separate the trioxymethylene generated by reaction, and the ionic liquid is methyl tributyl phosphonium bis (trifluoromethanesulfonyl) imide salt; when the ionic liquid is used for extracting trioxymethylene, a ternary azeotropic system of trioxymethylene, water and methylene glycol can be broken, the ionic liquid and trioxymethylene are subjected to nonpolar Van der Waals' force interaction so as to realize extraction, and methylene glycol and water are left in a water phase through hydrogen-bond interaction, so that high-purity trioxymethylene with the purity of more than or equal to 99.5 wt.% is obtained.

The invention discloses equipment and a process for efficiently and continuously extracting astaxanthin by a low-frequency microwave-assisted eutectic solvent method, and belongs to the technical field of bioactive substance extraction. The method for extracting astaxanthin by the low-frequency microwave-assisted eutectic solvent method comprises the following steps: performing low-frequency microwave pretreatment on a eutectic solvent to obtain a high-temperature pretreated eutectic solvent; cooling the pretreated eutectic solvent, then mixing the pretreated eutectic solvent with crustacean byproducts, performing eutectic solvent extraction treatment, performing ultrasonic-assisted extraction in the process, and then performing solid-liquid separation to obtain filtrate; mixing the filtrate with an extraction solvent, and extracting to obtain an extraction solvent phase containing astaxanthin and a eutectic solvent phase; and removing the extraction solvent in the extraction solvent phase containing the astaxanthin to obtain an astaxanthin product.

The invention relates to a method for efficiently extracting high-specification battery-grade lithium carbonate, and belongs to the technical field of lithium carbonate preparation. The method comprises the following steps: pretreatment: mixing a lithium-containing solution raw material with liquid caustic soda; extraction: fully mixing the lithium-containing solution with a no-load extraction agent, and performing phase splitting; reverse extraction: conveying sulfuric acid with a certain concentration and a lithium-containing load oil phase through a centrifugal pump respectively, fully mixing in an extraction tank, and splitting phases; calcium and magnesium are removed from the strip liquor, specifically, the strip liquor is adsorbed through resin, calcium and magnesium in the strip liquor are adsorbed and removed, and the resin is recycled through acid-base regeneration and water washing after adsorption saturation; wastewater treatment: firstly recycling an organic extracting agent in a non-dissolved state from the water-phase raffinate in the extraction procedure through an oil separator, and then treating and regenerating through a macroporous resin adsorption tank; precipitating lithium: placing the prepared sodium carbonate solution in a beaker, stirring and heating, slowly dropwise adding the lithium sulfate solution, continuously reacting, and filtering; and washing and drying: filtering, and drying the lithium carbonate obtained after filtering.

The invention belongs to the technical field of extraction separation, and relates to a silver-based eutectic solvent which is composed of silver salt serving as a hydrogen bond acceptor and an organic compound serving as a hydrogen bond donor. Wherein the organic compound serving as the hydrogen bond donor is a carbonyl organic compound or an alcohol organic compound. The silver-based deep-eutectic solvent provided by the invention is easy to prepare, the structure is easy to regulate and control, and the silver-based deep-eutectic solvent has the advantages of good thermal stability, reproducibility and the like, and has high unsaturated hydrocarbon absorption capacity and excellent separation performance for unsaturated hydrocarbon mixtures.

The invention discloses a method for efficiently extracting phenol from coal tar and primarily separating crude phenol oil, and relates to the technical field of chemical separation. Carrying out multi-stage cross-flow or counter-flow extraction on the extracting agent and the coal tar to obtain a raffinate phase and a high-concentration extraction phase; and mixing the raffinate with condensate at the top of the regeneration device and supplemented fresh water, and recovering residual organic amine through a reverse extraction device to obtain a dephenolized oil product and backwashing water. Mixing and diluting the extract phase with backwashing water, and standing for phase splitting to obtain a high-grade crude phenol oil phase and a low-concentration extract phase; the low-concentration extraction phase absorbs CO2 in the industrial tail gas for acidification to obtain a low-grade crude phenol oil phase and an amine salt aqueous solution; and desorbing the amine salt aqueous solution to obtain a regenerated extraction agent (circularly used for extraction), tower top condensate (circularly used for reverse extraction) and water-containing industrial-grade CO2 gas (recycled or sealed after drying). According to the method, high-efficiency extraction of the phenolic compounds in the coal tar and primary separation of crude carbolic oil are realized by utilizing the extraction performance differences of extraction capacities, selectivity and the like of the extraction agents with different concentrations on the phenolic compounds, and the production economy is improved.

This disclosure provides an optimized, energy-efficient, and sustainable solution for continuous in situ bio-based chemical recovery by integrating high pressure reverse osmosis with extraction processes. These systems achieve higher recovery efficiency while reducing production costs and environmental impact.

The invention relates to an olefin hydroformylation homogeneous catalysis continuous reaction process and system. The process comprises the following steps: mixing raw materials olefin, synthesis gas and a metal catalyst, and then carrying out hydroformylation reaction; removing a light component containing the product aldehyde from the hydroformylation reaction liquid to obtain a heavy component containing the metal catalyst; uniformly mixing the heavy component with a first extraction agent, and performing phase splitting to obtain a first heavy component phase and a first extraction agent phase; a metal catalyst and a second extraction agent are separated from the first extraction agent phase, the metal catalyst is circularly used for the hydroformylation reaction, and the second extraction agent is used as the first extraction agent mixed with the heavy components. Based on the characteristics of solubility difference and specific gravity difference between the metal catalyst and other substances in the heavy components under specific conditions, the heavy components in a reaction system are reacted at a lower temperature on the premise of not additionally adding a reagent which can influence the activity of the catalyst, and the activity of the catalyst can be well maintained within a longer reaction time.

The enhanced extraction and separation system comprises a liquid membrane extraction device, a preliminary sedimentation device and an enhanced phase separation device which are connected in sequence, the liquid membrane extraction device is provided with a fermentation liquor inlet and an extraction agent inlet, and the liquid membrane extraction device is used for enabling a mixed material of the fermentation liquor and an extraction agent to continuously form a liquid membrane, liquid filaments and liquid drops; the liquid membrane extraction effect is achieved; the primary sedimentation device is used for carrying out pre-sedimentation treatment on the mixed liquid discharged from the liquid membrane extraction device; the reinforced phase separation device comprises an extraction liquid reinforced phase separator and a raffinate reinforced phase separator, and the extraction liquid reinforced phase separator is connected with an extraction liquid outlet of the preliminary sedimentation device and used for rapidly separating raffinate carried in the extraction liquid; and the raffinate reinforced phase separator is connected with the raffinate outlet of the primary sedimentation device and is used for quickly separating the extract contained in the raffinate. According to the invention, the liquid membrane extraction and reinforced phase separator technology is reasonably applied to the working condition of the bio-based fermentation liquor, and good extraction and separation effects are achieved.

The utility model discloses a biotechnology solution extraction and separation device which comprises a base, a mixed extraction and separation structure and a driving structure, the mixed extraction and separation structure is arranged on the base, and the driving structure is arranged on the base. The mixed extraction separation structure comprises a support frame, a shaft seat, a rotating shaft, a fixed ring seat, a mixed extraction separation tank, a sealing cover, a thin pipe, a valve, a mixed screen plate and a belt pulley I, the support frame is arranged on the base, the shaft seat is fixedly arranged on the support frame, the rotating shaft is rotationally arranged on the shaft seat, and the fixed ring seat is fixedly arranged on the rotating shaft. The utility model belongs to the technical field of biotechnology equipment, particularly relates to a biotechnology solution extraction and separation device, and effectively solves the problems that most of biotechnology solution extraction and separation devices need to perform oscillation extraction firstly and then transfer into a separation device, and liquid is easy to scatter in the static separation and oscillation transfer process, so that waste is caused, and the cost is high. And the extraction efficiency is influenced.

The utility model discloses Chinese herbal medicine plant juice low-temperature extraction equipment which comprises a tank body, two positioning frames are fixedly connected to the interior of the tank body, an extraction tank is fixedly installed between the two positioning frames, a filter screen plate is fixedly connected to the bottom of the inner side of the extraction tank, a butt joint groove is formed in the bottom of the extraction tank, and the butt joint groove is fixedly connected with the filter screen plate. And the top of the butt joint groove extends to the bottom of the filter screen plate. According to the solid-liquid separation device, the movable liquid discharging mechanism is started to move downwards, at the moment, the butt joint groove is opened, liquid in the extraction tank penetrates through the filter screen plate to be discharged, is discharged through the liquid discharging channel and is discharged into the material receiving box through the annular guide-out pipe, crystals are filtered by the filter screen plate to achieve solid-liquid separation, and the stirring mechanism is closed in the liquid discharging process; and therefore, the device has the advantages that the crystals are effectively prevented from being broken, the separation effect is better during solid-liquid separation, the purity of discharged liquid is improved, and subsequent purification is facilitated.

Devices, systems, and techniques can be provided for processing an oil-containing material with an alcohol-based solvent to extract oil from the material. In some examples, a system includes a pretreatment dehydration vessel that removes water from the oil-containing material prior to processing the oil-containing material in an extractor to extract oil from the material. An alcohol-based solvent may also be supplied to the dehydration vessel to remove water from the oil-containing material, thereby generating a dehydrated material that can be extracted in a downstream extractor.

The invention discloses a metal ion extraction and separation device and a use method thereof.The device comprises a separation bin and a mixing chamber, a defoaming module is arranged at the inner top of the separation bin, and the inner bottom of the separation bin is divided into a clarifying chamber and a purifying chamber through a partition plate arranged in the middle. Low-speed, high-shear and multi-chamber mixing is achieved, the mixing effect is ensured, then an emulsion layer is preliminarily eliminated through the defoaming module, fluid kinetic energy consumption is achieved through a slow flow frame, a flow channel extension plate, a pore plate and a T-shaped plate which are sequentially designed in the clarifying chamber, and the natural layering efficiency is improved; the monitoring module is used for controlling and sucking an emulsion layer between the two phases to enter the centrifugal chamber for centrifugal separation, and the indirect flow bin is used for realizing rapid and effective separation and recovery of other phases in the target phase, so that the emerald green effect in the whole ion extraction process is improved, the purity of the separated two phases is improved, and meanwhile, the problem that the emulsion layer is difficult to separate is solved.

Targetry coupled separation refers to enhancing the production of a predetermined radiation product through the selection of a target (including selection of the target material and the material's physical structure) and separation chemistry in order to optimize the recovery of the predetermined radiation product. This disclosure describes systems and methods for creating (through irradiation) and removing one or more desired radioisotopes from a target and further describes systems and methods that allow the same target to undergo multiple irradiations and separation operations without damage to the target. In contrast with the prior art that requires complete dissolution or destruction of a target before recovery of any irradiation products, the repeated reuse of the same physical target allowed by targetry coupled separation represents a significant increase in efficiency and decrease in cost over the prior art.