109results about "Fullerenes" patented technology

The invention provides embedded metal fullerene and a preparation method thereof. The preparation method comprises the following steps: mixing a metal source and graphite powder, and filling a hollow graphite rod with the mixture to prepare an anode; the electrode is installed at the anode end of an electric arc furnace, and on-line activation is conducted through anode and cathode short-circuit current under the inert atmosphere; then carrying out arc discharge under specific air pressure and current, and collecting generated carbon ash; performing ultrasonic extraction by using an organic solvent to obtain a fullerene crude extracting solution; and finally, performing multi-stage separation and purification by high performance liquid chromatography, and performing primary and fine separation by sequentially adopting preparative and semi-preparative chromatographic columns to obtain a high-purity product. According to the method, a complete technical path capable of efficiently and controllably preparing the ultra-high-purity embedded metal fullerene is formed through a synthesis process integrating online activation and accurate atmosphere regulation and control and a multi-stage gradient chromatography purification strategy, and a solid foundation is laid for application of atomic-scale accurate materials in the frontier fields of quantum devices and the like.

To provide a composite material using fullerene and a metal-organic framework, a method for producing the same, and a quartz crystal resonator sensor using the same.SOLUTION: The composite material of the present invention comprises fullerene nanotubes and a zeolitic imidazolate framework (ZIF) containing metal ions positioned on surfaces of the fullerene nanotubes. The method for producing the composite material of the present invention comprises acid-treating fullerene nanotubes, mixing and reacting the fullerene nanotubes, imidazole or a derivative of the same, and a salt of a metal element in a solvent, and washing and drying an obtained product.SELECTED DRAWING: Figure 1

To provide a method of forming highly spherical carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin) particles.SOLUTION: The method may comprise: mixing a mixture comprising (a) a carbon nanomaterial-graft-polyolefin (CNM-g-polyolefin), (b) a carrier fluid that is immiscible with the polyolefin of the CNM-g-polyolefin, optionally (c) a thermoplastic polymer not grafted to a CNM, and optionally (d) an emulsion stabilizer at a temperature higher than a melting point or softening temperature of the polyolefin of the CNM-g-polyolefin and the thermoplastic polymer, if included, and at a shear rate sufficiently high to disperse the CNM-g-polyolefin in the carrier fluid; cooling the mixture to below the melting point or softening temperature to form the CNM-g-polyolefin particles; and isolating the CNM-g-polyolefin particles from the carrier fluid.SELECTED DRAWING: Figure 1

The invention provides an anti-biofilm composition based on the synergistic effect of amino fullerene and vancomycin and application of the anti-biofilm composition. The mass ratio of the amino fullerene to the vancomycin is 10: 1. The amino fullerene derivative and vancomycin are combined to have a remarkable synergistic effect in the aspect of inhibiting the formation of the biological membrane for the first time, and the inhibition rate of the biological membrane reaches 93%, so that the amino fullerene derivative and vancomycin have a strong synergistic effect. The composition provided by the invention can effectively remove more than 40% of formed mature biological membranes (24-48-hour biological membranes), which is an effect which cannot be realized by independent use of vancomycin.

Embodiments of the present disclosure relate to methods and apparatus for producing carbon nanomaterial (CNM) products, which may include carbon nanotubes and various other allotropes of nanocarbon. The methods and apparatus use consumable carbon dioxide (CO2) and renewable carbonate electrolyte as reactants in an electrolysis reaction to make CNTs. In some embodiments of the present disclosure, the operating conditions of the electrolysis reaction may be varied to produce CNM products with even greater generation of a desired allotrope of nanocarbon or a desired combination of two or more allotropes.

The present disclosure provides a heating film, a manufacturing method thereof, a heating element, and a heating electrical device, the heating film comprising graphene and an auxiliary agent, the auxiliary agent comprising at least one of a reinforcing agent, a warming agent, and a spectral adjuster, the reinforcing agent comprising at least one of ammonia water, glucose, ethylene glycol, ethylenediamine, carboxymethylcellulose, polyvinyl alcohol, polyethylene glycol, and chitin, the warming agent comprising at least one of carbon nanotubes, fullerenes, carbon black, and graphene nanoplatelets, and the spectral adjuster comprising at least one of silicon carbide, boron nitride, and silicon nitride.

The invention discloses a carbon material rich in intrinsic defects as well as a preparation method and application thereof, and belongs to the technical field of catalysts, fullerene or fullerene derivative carbon cages adopted by the invention have a pi conjugated structure, so that relatively strong pi-pi interaction force exists among molecules. Fullerene or a fullerene derivative is used as a raw material, a macroscopic crystalline material, namely a fullerene condensed state precursor, is obtained through self-assembly based on intermolecular acting force, the fullerene condensed state precursor is subjected to pre-etching treatment through oxygen plasma, surface modification is conducted on the fullerene condensed state precursor, and the fullerene or fullerene derivative is obtained. The preparation method comprises the following steps: preparing a fullerene condensed state precursor, performing two-stage temperature programming heat treatment of low-temperature pre-etching treatment and high-temperature roasting in ZnCl2 molten salt, endowing the fullerene condensed state precursor with five-membered ring topological defects and carbon intrinsic defects of boundaries and curvatures, so as to obtain the carbon material rich in intrinsic defects, and endowing the carbon material with good electro-catalytic performance by the intrinsic defect sites.

To provide a production method of a carbonaceous material dispersion for removing moisture easily and quickly from a carbonaceous material dispersion without deterioration of stability of the dispersion.SOLUTION: There is provided a production method of a carbonaceous material dispersion in which carbonaceous material particles are dispersed in an organic dispersion medium, the method comprising: a step for adding the carbonaceous material particles into the organic dispersion medium and dispersing the particles for forming a carbonaceous material dispersion, then blowing a dry inert gas into the dispersion whose temperature is held to 20-120°C for bringing the dispersion into contact with the dry inert gas for evaporating moisture in the dispersion.SELECTED DRAWING: Figure 1

This fullerene derivative has a structure represented by formula (1) or formula (2) (wherein Ar represents a substituted or unsubstituted aromatic ring, * represents a carbon atom at a linkage point with respect to a fullerene core, X represents O, S, Se, or Te, and R represents an organic group).

The present disclosure relates to a carbon-based nanomaterial composition that may be formed from a gas mixture and a silicon powder. The gas mixture may include a carbon based gas, an oxygen gas, and a hydrogen gas. The carbon-based nanomaterial composition may include silicon doped nanospheres.

The invention belongs to the technical field of magnetic materials, and discloses a room-temperature molecular magnet and a preparation method and application thereof, the room-temperature molecular magnet is an organic eutectic, an acceptor in the organic eutectic is fullerene, and a donor in the organic eutectic is H2TPP, MgTPP, MnTPP, FeTPP, CoTPP, NiTPP, CuTPP or ZnTPP. The preparation method of the organic eutectic is simple, and the organic eutectic has good ferromagnetism at 300K, shows room-temperature magnetism and has good application prospects in magnetic semiconductors.

The invention discloses a synthesis method of a fullerene nano material with glycolipid metabolism regulation capability, and belongs to the technical field of material science and biomedical engineering. The fullerene and the metformin are combined through chemical bonds, the strong oxidation resistance of the fullerene and the hypoglycemic effect of the metformin are exerted at the same time, the synergistic treatment effect is formed, and the drug composition is superior to a single drug; active oxygen in cells can be efficiently removed, oxidative stress is effectively relieved, and the functions of pancreatic beta cells are protected; through structural modification, the problem of low bioavailability caused by hydrophobicity of fullerene and hydrophilicity of metformin is solved, and the solubility and absorption efficiency of the medicine are improved; in conclusion, through chemical combination of the fullerene and the metformin, a dual-mechanism synergistic effect of oxidation resistance and blood sugar reduction is achieved, the treatment effect is remarkably improved, meanwhile, good safety and biocompatibility are achieved, and important application value is achieved in the field of treatment of the type II diabetes mellitus.

A method of manufacturing a carbon nanostructure, such as a carbon foam material, is disclosed. The method comprises the steps of: (a) using a first laser beam to irradiate an encapsulated or sub-surface region of a carbon pre-cursor material below a surface of the material, to create carbon foam in that sub-surface region, and a disorganised, amorphous non-graphene material above the carbon foam, and then (b) using a second laser beam to remove or ablate the disorganised, amorphous non-graphene material sitting above the carbon foam, to expose at least some of the carbon foam. The resultant carbon foam material shows a significant D peak; the 2D peak is significantly less than the G peak; and the peak D:peak G ratio is significantly above zero. In appearance and Raman signature, it appears similar to a carbon nano-onion material. It can be used in biosensors, supercapacitors and pseudo-capacitors.

A nanostructure includes a plurality of substantially spherically curved carbon layers having diameters in a range of 1 nanometer to 1000 nanometers and a plurality of nitrogen atoms attached to an outer convex side of the carbon layers. A composition of matter includes a liquid fuel and an additive including at least one liquid and a plurality of carbon nano-onions. A method of fabricating an additive for liquid fuel includes creating a carbon based material using a plasma in an environment including at least one hydrocarbon gas and / or at least one liquid containing hydrocarbons, organometallic metal-complex, and / or element-organic compounds, evaporating organic material from the carbon-based material, nitrating the carbon-based material, and extracting carbon nano-onions from the nitrated carbon-based material.

To provide fullerene-coated boron nitride particles capable of improving voltage-resistant performance with no loss of heat radiation performance when applied to a heat radiation member of a semiconductor device, that are easily manufacturable at low cost; and to provide a resin composition using the same, a resin sheet, a semiconductor device and a manufacturing method of the fullerene-coated boron nitride particles thereof.SOLUTION: Fullerene-coated boron nitride particles comprise hexagonal boron nitride particles, and fullerene covering at least part of a surface made of the hexagonal boron nitride particles.SELECTED DRAWING: Figure 1

The invention discloses a preparation method and a preparation device of fullerene, and relates to the technical field of fullerene. The preparation method of the fullerene comprises the following steps: S1, carrying out gasification treatment on an organic substrate under first vacuum pressure to obtain a gasified product; s2, under second vacuum pressure, inert gas is used for carrying the gasification product into a pyrolysis chamber, and after pyrolysis treatment, a pyrolysis product is obtained; and S3, cooling the pyrolysis product to obtain carbon ash containing fullerene, so that the yield and purity of the fullerene can be improved.

Embodiments of the present disclosure generally relate to methods of producing carbon-nitrogen allotrope nanomaterials. More specifically, the methods of the present disclosure utilize nitrogen-containing compounds as a feedstock for nitrogen doped carbon nanomaterial production. In some embodiments, a method for forming carbon-nitrogen nanomaterials includes mixing a nitrogen-rich feedstock, carbon-based feedstock, and a catalyst to form a feed solution. The method further includes injecting the feed solution into a carrier gas stream and into a heated reaction vessel. The heated reaction vessel includes a first zone and a second zone. The method further includes heating the feed solution within the first zone at a first temperature. The method further includes heating the feed solution within the second zone at a second temperature to form the carbon-nitrogen nanomaterials. The method further includes removing the carbon-nitrogen nanomaterials from the heated reaction vessel.

To provide industrially useful fullerene derivative solutions, etc. [Solution] The fullerene derivative solution comprises a fullerene derivative, one or more first solvents, and one or more second solvents, wherein the boiling point of the first solvent is 200°C or lower. The boiling point of the second solvent is 100°C or lower. Among the Hansen solubility parameters of the first solvent, when the dispersion force term is δD1, the polarity term is δP1, and the hydrogen bonding term is δH1, the following conditions are satisfied: 17.8 ≤ δD1 ≤ 18.9, 4.4 ≤ δP1 ≤ 4.7, and 4.8 ≤ δH1 ≤ 6.9. The volume ratio of one or more first solvents to the total volume of one or more first solvents and one or more second solvents is greater than the volume ratio of one or more second solvents to the total volume.

The invention discloses two-dimensional fullerene and an alkali metal intercalation stripping method and application thereof, and belongs to the technical field of two-dimensional fullerene preparation.The stripping method comprises the steps that a fullerene superlattice material and molten alkali metal are mixed and subjected to an intercalation reaction, and an alkali metal intercalation compound is obtained; and dispersing the alkali metal intercalation compound in a solvent containing an electron quencher, and stripping to obtain the two-dimensional fullerene. By means of the mild intercalation and electron quenching solvation stripping technology, efficient stripping is achieved within a short time, and high quality and high yield of the material are guaranteed. Compared with an organic cation intercalation layer, the stripping speed is high, the stripping efficiency is high, alkali metal and a solvent containing an electron quencher are easy to remove, almost no residue exists, and the conductivity, the thermal stability and the catalytic activity of the product are all improved. Compared with an electrochemical stripping method, the method does not need an external electric field, avoids bubble-mechanical disturbance, and is high in stripping speed and efficiency, less in residual ions and higher in skeleton integrity.

The invention discloses a preparation method of a fullerene-containing metal wear self-repairing material for a transmission lubricating system, and relates to the technical field of lubricating materials. Comprising the following steps: (1) pretreating raw materials, and preparing artificially synthesized nano hydroxyl magnesium silicate, fullerene-nano indium composite powder and micro-nano composite hydroxyl magnesium silicate powder; (2) preparing a fullerene-indium-copper-lithium quaternary composite dispersion liquid; (3) mixing the micro-nano composite hydroxyl magnesium silicate powder and the composite dispersion liquid in the modified base oil in a gradient manner, and adding an antioxidant and an anti-settling agent; and (4) regulating the particle size to D50 = 500-800nm and the viscosity to 150-200mm / s at 40 DEG C, and carrying out vacuum degassing and packaging to obtain a finished product. According to the method, shutdown-free in-situ repair of the worn surface of the transmission system is achieved, the friction coefficient is reduced to 0.02-0.06, the hardness of the metal surface is improved by 1-2 times, and the service life of equipment is prolonged by one time or above.

A method of preparing graphene from coal can include thermally processing raw coal and, after the coal has been at least partially cooled from thermal processing, forming reduced graphene oxide from the coal.

The present CIP builds upon and extends the work presented in the parent invention by broadening the scope of functionalized fullerene technology. While the parent application focused on enhancing the safety and efficacy of ophthalmic and other medical solutions through the selective removal of preservatives, this CIP adapts those core functionalization strategies and filtration technology for the extraction of lithium ions from brine and other solutions (e.g., earthen source circulates). The functionalization techniques described herein demonstrate the versatility and scalability of fullerene-based systems for diverse applications, ranging from biomedical solutions to critical industrial processes such as lithium recovery. Together, these innovations illustrate the significant potential of functionalized fullerenes to address pressing challenges across multiple fields, unifying the parent and CIP in their commitment to efficient, selective and sustainable solutions.

The invention belongs to the technical field of nano materials, and relates to fullerol with moderate hydroxylation degree and a preparation method and application thereof. Fullerol with the chemical formula of C60 (OH) n.mH2O is obtained by controlling the mass ratio of fullerene to an alkaline reagent and adopting the processes of grinding, dissolving, concentration, alcohol precipitation and drying, n is 10-15, preferably 12, m is 10-15, preferably 12.5, and the product is a needle-like crystal and forms a stable dispersion liquid in water. Thermogravimetric analysis shows that the fullerol has controllable hydroxyl number and relatively high water solubility, has better ABTS < + > and. OH removal capability compared with low-hydroxylated and high-hydroxylated fullerol, can reduce the ROS level in cells and improve the cell survival rate and migration capability, can be used as an active component of an antioxidant and a cell repair preparation, and has a broad application prospect. The composition is used for skin barrier repair and oxidative stress related disease prevention and treatment.

The invention relates to the technical field of nano material preparation, in particular to a method for preparing a fullerene tube through catalytic chemical vapor deposition. A catalytic chemical vapor deposition method is utilized, carbon is orderly assembled at a certain temperature by means of a catalyst, reaction conditions influencing catalyst-carbon interface bonding are further controlled, and direct preparation of the fullerene tube from bottom to top is achieved. The fullerene tube is in a molecular form and is composed of hemispherical fullerene cap ends at the two ends and a carbon nano tube tubular structure in the middle section, the length-diameter ratio is larger than 1, the length is within or below the range of short carbon nano tubes, and the diameter is 0.4-3 nm. According to the method, the design of the catalyst and the control of the dynamic process of catalytic growth of the nano carbon material are taken as the core, the direct preparation of the quasi-one-dimensional fullerene tube is finally realized, the bottleneck that the controllable preparation method of the fullerene tube at the present stage is few and the existing method has more byproducts is broken through, and the method has the characteristics of good controllability, simple process, low cost, suitability for large-scale preparation and the like; and a new way is provided for realizing efficient and controllable preparation of the fullerene tube.

To provide a porous carbon material carrying metal particles, a production method therefor, and a catalyst prepared using the same.SOLUTION: The porous carbon composite material of the present invention contains a porous carbon nanotube based on a fullerene nanotube and a porous carbon structure based on a zeolitic imidazolate framework (ZIF) positioned on the surface of the porous carbon nanotube and containing metal particles, wherein a ratio of an atomic percentage of metal particles (M) to carbon (C) constituting the porous carbon nanotube and the porous carbon structure is 0.015 or more and 0.03 or less.SELECTED DRAWING: Figure 1

The present disclosure provides a heating film, a manufacturing method thereof, a heating element, and a heating electrical device, the heating film comprising graphene and an auxiliary agent, the auxiliary agent comprising at least one of a reinforcing agent, a warming agent, and a spectral adjuster, the reinforcing agent comprising at least one of ammonia water, glucose, ethylene glycol, ethylenediamine, carboxymethylcellulose, polyvinyl alcohol, polyethylene glycol, and chitin, the warming agent comprising at least one of carbon nanotubes, fullerenes, carbon black, and graphene nanoplatelets, and the spectral adjuster comprising at least one of silicon carbide, boron nitride, and silicon nitride.

The present application relates to a method for extracting fullerene from acetylene black conductive agent waste coke. The method for extracting fullerene from acetylene black conductive agent waste coke comprises the following steps: heat treating the acetylene black conductive agent waste coke to obtain pretreated acetylene black conductive agent waste coke; under ultrasonic conditions, using an imidazole ionic liquid as an extractant to perform ultrasonic extraction treatment on the pretreated acetylene black conductive agent waste coke, separating, and obtaining an ionic liquid extract liquid rich in fullerene and a solid residue; performing gradient cooling crystallization treatment on the ionic liquid extract liquid rich in fullerene to obtain C 70 fullerene and C 60 fullerene. The present application realizes the recycling and utilization of acetylene black conductive agent waste coke, solves the problems of safety hazards and environmental pollution existing in the prior art of extracting fullerene, and solves the problems of complicated separation and purification steps, high energy consumption and long production cycle existing in the prior art of extracting fullerene.

This invention belongs to the field of electrocatalytic materials technology, specifically relating to fullerene-modified cobalt-based transition metal oxide nanocomposites, their preparation methods, and applications. The fullerene-modified cobalt-based nanocomposites prepared by combining fullerenes with cobalt-based materials not only significantly improve the catalytic activity and selectivity of the chloride evolution reaction (CER), but also effectively inhibit material corrosion and deactivation under strong oxidizing environments. Their performance is significantly superior to traditional cobalt-based materials and cobalt-based materials modified with carbon black or graphene. This breakthrough provides a novel solution to address the inherent defects of cobalt-based catalysts, demonstrating significant application prospects in highly corrosive electrochemical reactions such as CER. It can be used for efficient electrochlorination treatment of recalcitrant organic pollutants in various water bodies, including groundwater, surface water, and industrial wastewater.

The present disclosure relates to a carbon-based nanomaterial composition that may be formed from a gas mixture and a sodium powder. The gas mixture may include a carbon based gas, an oxygen gas, and a hydrogen gas. The carbon-based nanomaterial composition may include sodium doped nanospheres.