712 results about "Polymer modified" patented technology

The invention discloses high-toughness ultra-high performance concrete and a preparation method thereof, and relates to the technical field of polymer modified materials thereof. The concrete is composed of a cementitious material composite system, a fiber-reinforced system and a polymer modifier, the cementitious material comprises Portland cement, nano-silica, a rice hull ash-based auxiliary cementitious material and gradient grading quartz powder, and the fiber system adopts steel fiber / basalt fiber / polypropylene fiber multi-scale composite reinforcement. And a polyurethane emulsion interface modifier is matched. During preparation, a dry mixing-fiber dispersion-wet mixing three-stage process is combined with a microfluidization emulsification and segmented polymerization technology, so that uniform dispersion of fibers and matrix-fiber interface reinforcement are realized. The scheme has high strength, high toughness and industrial feasibility, and is suitable for harsh engineering scenes such as bridge joints and explosion-proof structures.

The invention discloses a high-toughness impervious polymer modified cement-based grouting material and a preparation method thereof, and belongs to the technical field of building repair materials. The component A is prepared from a cementing material, an admixture, a fine aggregate, a composite expanding agent, a polymer for concrete modification, fibers, an early strength agent, a water reducing agent, a composite retarder, a defoaming agent, an air entraining agent, a nano material and a functional component. The system solves the technical contradiction of toughness-strength-impermeability in the polymer modified cement-based material, and the material has excellent comprehensive performance: the initial fluidity is greater than or equal to 330 mm, the 28d compressive strength is greater than or equal to 82 MPa, the breaking strength is greater than or equal to 16.8 MPa, the bending-compression ratio is greater than or equal to 0.19, the impermeability pressure value is greater than or equal to 2.6 MPa, and the material is suitable for the fields of prefabricated buildings, tunnel engineering and the like.

The invention discloses a low-carbon polymer modified all-solid waste premixed fluid-state soil, which is prepared from the following components in parts by weight: 10-30 parts of low-carbon polymer modified all-solid waste premixed fluid-state soil, the concrete is prepared from the following components in parts by weight: 5-10 parts of a modifier, 5-10 parts of an exciting agent, 1-5 parts of an additive, 1-5 parts of a retarder, 10-20 parts of coal gangue powder, 10-20 parts of carbide slag, 10-20 parts of bentonite, 35-40 parts of fly ash, 35-40 parts of slag powder, 100 parts of clay powder, 145 parts of machine-made medium sand and 150 parts of water. According to the invention, the polymer polyacrylamide is added into the fluid soil, so that the compressive strength of the fluid soil stone body is improved; when the polyacrylamide is mixed with the fluid soil, active components in the polymer emulsion and components in the fluid soil are subjected to a cross-linking reaction to form a more complex network structure, so that a dispersion system of the slurry can be remarkably improved, the repulsive potential energy among particles in a multiphase dispersion is reduced, and the integrity and the stability of the slurry are enhanced; the slurry is not easy to separate when being injected into underground rock strata or fractures, and good uniformity and flowability are maintained.

The invention discloses a heavy metal chelating agent for industrial wastewater and a preparation method of the heavy metal chelating agent, and belongs to the technical field of sewage treatment.The preparation method comprises the steps that 2-hydroxyphenylboronic acid is subjected to graft modification through acrylic acid and polymerized on the surface of activated biomass porous carbon powder with acrylic acid, boron-containing polymer modified porous carbon is obtained, and then ferric chloride hexahydrate serves as an iron source; a boron-containing polymer modified porous carbon surface and aminated magnetic adsorption nanospheres are obtained, B-N coordination is formed between the aminated magnetic adsorption nanospheres and the boron-containing polymer modified porous carbon surface, boron element fixation is achieved through modified copolymerization, loss caused by long-time use of the boron element is avoided, lasting and stable chelation is guaranteed, activated biomass porous carbon serves as a carrier, and macromolecular resin serves as a coating layer. The environment-friendly biochar has the advantages of favorable degradability, greenness, degradability, safety and high efficiency, and avoids the problem of secondary pollution caused by the use of a chelating agent.

The invention relates to the technical field of asphalt modifiers, and particularly discloses an asphalt regenerant as well as a preparation method and application thereof. The asphalt modifier comprises an oil phase, a polymer phase, a nano reinforced phase and a functional additive phase, wherein the oil phase comprises petrochemical oil and vegetable oil; the polymer phase comprises four-arm radiation star-shaped SBS and a rubber powder lysis solution; the nano reinforced phase comprises silane coupling agent modified nano montmorillonite and graphene; the functional additive phase comprises maleic anhydride grafted polyethylene and sucrose ester. The asphalt regenerant provided by the invention is suitable for various types of aged asphalt, in particular to aged polymer modified asphalt, each failure phase of the aged polymer modified asphalt is accurately repaired through a multi-phase synergistic mechanism, full-dimension regeneration of the aged polymer modified asphalt from a molecular scale to macroscopic performance is realized, and the asphalt regenerant has a wide application prospect. Excellent applicability and reliability are shown in regeneration of various types of aged asphalt, and a powerful guarantee is provided for high-quality implementation of road engineering.

The invention relates to the technical field of asphalt performance analysis, in particular to a method for detecting and analyzing physical properties of polymer modified asphalt. According to the invention, the collected asphalt sample is subjected to pretreatment means of vacuum degassing, multi-angle image bubble monitoring and constant-speed stirring, the uniformity of the asphalt sample is judged according to physical state parameters at different positions, the reliability of subsequent detection data is further improved, and a plurality of uniformly-divided target asphalt samples are respectively placed in the constant-temperature containers; the method comprises the following steps: recording the heat conduction temperature of each target asphalt sample at different monitoring points in a constant-temperature water bath in real time, carrying out penetration detection on each target asphalt sample after the sample reaches heat balance, carrying out penetration index analysis according to the incidence relation between the temperature and the penetration, and evaluating the physical properties of the polymer modified asphalt based on the penetration index. The penetration data under different temperature gradients can be accurately obtained, the physical properties of the polymer modified asphalt can be comprehensively and accurately evaluated, and a reliable basis is provided for engineering quality control.

The invention discloses a lithium ion battery anti-cracking agent and a preparation method and application thereof.The preparation method is carried out under nitrogen protection and comprises the steps that a first polymer, a second polymer and a modifier are dissolved in a first solvent, and under the action of a catalyst, a reaction is carried out for 4-48 h at the temperature of 60-100 DEG C; and after the reaction is finished, cooling to below 40 DEG C, adding an amine compound, and reacting for 0.5-8 hours to obtain the anti-cracking agent for the lithium ion battery. The first polymer is polyvinyl butyral, and the hydroxyl content of the polyvinyl butyral is 18-21%; the second polymer is a triblock polymer as shown in a structural formula I, and the content of methyl methacrylate in the second polymer is 8-65%; the modifier is maleic anhydride or a maleic anhydride derivative; the catalyst is one of p-toluenesulfonic acid, hydrochloric acid and sulfuric acid. According to the anti-cracking agent, the battery pole piece can be intact and does not crack at high surface density under the condition of relatively low addition amount.

The invention relates to a high-utilization-rate RAP asphalt regenerant and a preparation method thereof. The regenerant comprises the following components in percentage by mass: 30%-50% of a petroleum-based softener, 10%-20% of biomass oil, 5%-15% of a polymer modifier, 1%-5% of a surfactant, 0.5%-2% of an antioxidant and 2%-10% of a functional additive. All the components have a synergistic effect, so that the asphalt modifier can effectively permeate aged asphalt, supplement light oil, reduce viscosity, recover flexibility and remarkably improve high-temperature rut resistance and low-temperature crack resistance of regenerated asphalt. By reasonably selecting the raw materials and proportioning, the production cost is reduced, the RAP utilization rate is improved, and the environment-friendly raw materials are adopted, so that the requirements of environmental regulations are met. The result of the embodiment shows that after the regenerant is added, the performance recovery of the aged asphalt is good, the viscosity of the regenerated asphalt mixture is moderate, the needle penetration recovery rate is high, the softening point is high, the ductility is large, the comprehensive performance is excellent, and the regenerant is superior to commercially available products.

The present disclosure pertains to methods for enhancing the properties of conventional Li / Al-LDH by integrating polymers to provide compositions comprising a Li / Al-LDH material and a polymer. The present disclosure further pertains to methods of using such polymer-modified-LDH to improve lithium adsorption and extraction performance. The disclosed methods can comprise incorporating the polymer during the precipitation reaction or by mixing the Li / Al-LDH product with a polymer solution under specific conditions. During the lithium extraction process, the disclosed compositions comprising a Li / Al-LDH material and a polymer can be used as an excellent lithium adsorbent to capture lithium ions from low-concentration lithium resources due to its improved physicochemical properties. The disclosed compositions comprising a Li / Al-LDH material and a polymer provides compositions for lithium extraction from low concentration resources, as well as expands the scope of lithium adsorbent material development.

The invention belongs to the field of polymer modification and processing, and particularly relates to a nano photocatalytic self-cleaning composite material, a fresh-keeping cover and a preparation method of the fresh-keeping cover. The composite material comprises aliphatic nylon, a maleic anhydride grafted copolymer, nano titanium dioxide, carbon nanotubes, boron nitride, a coupling agent, a release agent and an antioxidant. The nano photocatalytic self-cleaning composite material is prepared by taking nano titanium dioxide as an antibacterial active agent and adding a certain amount of carbon nanotubes and boron nitride powder. The carbon nanotubes can conduct electrons, have high surface area and high adsorption capacity, and are good dopants and carriers for titanium dioxide as photocatalysts. Hexagonal boron nitride can effectively improve separation and transfer of photo-induced electron-hole pairs of the material, so that the visible light response photocatalytic activity is enhanced. And by adding the carbon nanotubes and boron nitride, the dispersing performance of nano titanium dioxide can be physically improved, titanium dioxide agglomeration is prevented, and the photocatalytic self-cleaning performance of the nano titanium dioxide is improved.

The invention discloses a self-adhesive polymer modified asphalt composite root-resistant waterproof coiled material and a preparation method thereof, and relates to the field of waterproof coiled materials, the self-adhesive polymer modified asphalt composite root-resistant waterproof coiled material comprises an isolating membrane layer, a polymer modified asphalt layer, a tire base layer, a polymer modified asphalt layer and an isolating membrane layer which are sequentially arranged from top to bottom; the physical root resistance effect of the base layer and the chemical root resistance effect of the polymer modified asphalt layer synergistically improve the root resistance performance of the waterproof coiled material. The polymer modified asphalt layer is prepared from petroleum asphalt, aromatic hydrocarbon oil, SBS, modified styrene butadiene rubber, polyisobutene, modified microcapsules and other raw materials; the modified microcapsule is obtained by grafting nano montmorillonite, hindered phenol, thioether group and the like into a wall material urea-formaldehyde resin of an epoxy resin microcapsule, and the modified styrene-butadiene rubber is obtained by grafting DOPO and sorbate group into styrene-butadiene rubber through epoxidized emulsion polymerized styrene-butadiene rubber participating in a reaction. The waterproof coiled material disclosed by the invention has excellent self-repairing capability, flame retardance and antibacterial property, and is worthy of popularization.

The invention relates to the technical field of high polymer material and polymer modification, in particular to modified asphalt based on nano material reinforcement and a preparation method, the modified asphalt comprises matrix asphalt subjected to molecular cutting and compounding, a nano titanium dioxide-graphene-carbon nano tube ternary composite material, zwitter-ion and silane synergistically modified nano montmorillonite, the rubber powder subjected to special treatment, the bio-based and traditional compound plasticizer and the 2-mercaptobenzimidazole and sulfur compound stabilizer are synergistically modified. The modified asphalt has the advantages of excellent performance, high-temperature stability, low-temperature crack resistance, strong aging resistance, efficient and environment-friendly preparation process, low energy consumption, short period and good nanometer material dispersion, and adopts the bio-based plasticizer to promote the green development of the asphalt industry.

The invention discloses a waterproof, anti-crack and moisture-proof self-healing material for a concrete structure and a preparation method thereof, relates to the technical field of concrete, and aims to solve the problems that the mixing degree is poor and the waterproof and moisture-proof effects are reduced due to the fact that various aggregates for improving the strength are added to an existing concrete structure in order to improve the anti-crack strength. The concrete is prepared from the following raw materials by weight: 30%-50% of cement; 5%-30% of sand; 5%-30% of stones; 5%-20% of a reinforcing material; 5%-10% of polymer modified asphalt; 1%-5% of a water reducing agent; 1%-5% of an additive; 1%-5% of a chemical self-healing agent; 1%-5% of a foaming agent; the additive is one or more of a concrete expansive agent, a rapid hardening agent, a plasticizer, a polyurethane type flexible agent and a concrete retarder, and the reinforcing material is one or more of microfibers, slag, fly ash, silane ash and a cellulose material. The cellulose material is one or more of wood, hemp, polypropylene fiber and polyester fiber.

The present disclosure relates to a fluoride-free binder material for a positive electrode, and a preparation method therefor and the use thereof. Provided are a fluoride-free binder material for a positive electrode and a preparation method therefor. A copolymer of acrylonitrile and an acrylate is used as a main body structure, an ionic monomer is introduced, and a polyfunctional olefin monomer is introduced during polymerization to increase the branching degree of a polymer, thereby preparing a highly-branched acrylonitrile polymer modified via copolymerization, which polymer is used as a fluorine-free binder material for a positive electrode. The modified binder can provide more sites for contact between active materials and between a current collector and the active materials so as to further enhance the bonding ability, thereby increasing the overall cohesive force and improving the adhesion to the current collector; and the binder can effectively inhibit the fracture and delamination of an electrode sheet during processing, ensures the compactness of a positive electrode material even in the case of a low use amount, and retains structural integrity and cycling stability during cycling.

The invention belongs to the technical field of building materials, and discloses an early-strength polymer modified cement-based grouting material and a preparation method thereof. The grouting material disclosed by the invention is prepared from the following raw materials in parts by weight: 100 to 115 parts of a cementing material, 100 to 115 parts of river sand, 20 to 23 parts of water, 2 to 2.5 parts of a water reducing agent, 0.02 to 0.04 part of an expanding agent, 0.22 to 1.76 parts of an acrylic emulsion and 0.04 to 0.08 part of a de-foaming agent, wherein the cementing material comprises 71-81 parts of Portland cement, 9-19 parts of sulphoaluminate cement, 6-8 parts of silica fume and 11-15 parts of fly ash microbeads. The early-strength, high-strength and high-fluidity cement-based grouting material can be obtained under the conventional curing condition by adopting the combined action of the acrylic emulsion polymer, the Portland cement and the sulphoaluminate cement, the plastic expanding agent, the polycarboxylate superplasticizer and the defoaming agent, and has good economic benefits and practical values.

The invention relates to the technical field of waterproof materials, and particularly discloses a self-adhesive polymer modified asphalt waterproof material as well as a preparation method and application thereof. The self-adhesive polymer modified asphalt waterproof material is prepared from the following raw materials in parts by mass: 45 to 55 parts of asphalt, 8 to 12 parts of softening oil, 10 to 15 parts of modifier, 8 to 12 parts of desulfurized rubber and 10 to 15 parts of filler, the modifier comprises the following raw materials: an ethylene-octylene copolymer, butadiene styrene rubber, coumarone resin and a functional modified material; the functional modified material is prepared from illite and phthalic acid ester. Through the design of the modifier and the proportion design of the raw material components, the synergistic interaction effect of the raw materials is fully played, the comprehensive performance of the waterproof material is improved, and the self-adhesive polymer modified asphalt waterproof coiled material prepared from the waterproof material has excellent high and low temperature properties, persistent adhesivity, peel strength, aging resistance and water resistance.

The invention relates to the technical field of road construction and maintenance, and discloses a multi-polymer modified emulsified asphalt in-situ cold recycling mixture and a preparation process thereof, the multi-polymer modified emulsified asphalt in-situ cold recycling mixture comprises the following components by weight: 600-680 parts of nano hybrid emulsified asphalt; 250 to 350 parts of plasma activated recycled aggregate; 15 to 30 parts of a microcapsule phase change catalyst; 5 to 10 parts of bio-based interface reinforcing fiber; and 3-8 parts of a rare earth doped curing accelerator. According to the invention, through multi-technology cross-scale fusion of a quaternary polymer rigid-flexible synergistic system, a gradient emulsification-vacuum self-assembly process, double-shell intelligent catalytic release and rare earth gradient distribution-magnetic field induced fiber arrangement, the bottlenecks of unbalanced high and low temperature performance, easy interface stripping, poor aging resistance, extensive process regulation and control and the like of a traditional asphalt material are overcome; and the strength and toughness-durability-self-adaption performance synergistic jump is realized.

The invention provides a dredging and blocking combined salinized soil roadbed novel composite liner separation layer and a roadbed structure. The composite liner separation layer comprises a first layer of non-woven geotextile, an upper layer of three-dimensional geotextile drainage network, a second layer of non-woven geotextile, a polymer modified bentonite particle layer, a third layer of non-woven geotextile, a lower layer of three-dimensional geotextile drainage network and a fourth layer of non-woven geotextile which are sequentially arranged from top to bottom; the roadbed structure comprises a pavement structure layer, a roadbed, a composite liner partition layer and an embankment which are sequentially laid from top to bottom, and slope protection ways and drainage ditches are arranged on the two sides of the roadbed structure. Through the bentonite particle impermeable layer in the composite liner separation layer, infiltration of surface water can be prevented, and rising of capillary water and migration of water and salt under the action of temperature gradient can also be blocked; slope protection and drainage ditches are designed on the two sides of the roadbed, smooth salt and water drainage of the roadbed is guaranteed, and the risk of roadbed settlement caused by migration and uneven distribution of water and salt in the salinized soil roadbed is reduced.

The invention relates to the technical field of soil improvement materials, and provides a soil heavy metal pollution repairing agent based on biomass power plant ash, which mainly comprises surface modified porous biomass power plant ash, polymer modified bentonite, a soil modified repairing agent and clay minerals. The surface modified porous biomass power plant ash is obtained through gamma-aminopropyltriethoxysilane and humic acid modified porous biomass power plant ash clustering, and the polymer modified bentonite is bentonite modified by acrylic acid and sodium carboxymethyl cellulose through a polymerization reaction. The preparation method comprises the steps of pretreatment of biomass power plant ash, liquid nitrogen freezing, freeze drying, porous structure formation, surface modification and the like. The components are mixed, granulated and molded, so that the obtained remediation agent can effectively reduce the bio-availability of heavy metals in soil, reduce the heavy metal absorption of crops and improve the soil environment quality.

Some embodiments of the present disclosure relate to a method comprising mixing at least one compatibilizer precursor with at least one polymer, so as to result in a polymer concentrate and mixing the polymer concentrate with asphalt, so as to result in a polymer modified asphalt (“PMA”). Some embodiments of the present disclosure relate to formulations comprising a compatibilizer precursor, a polymer concentrate, PMA, or any combination thereof.

The invention discloses a high-temperature-resistant high-performance neodymium-iron-boron permanent magnet material and a preparation method thereof, and belongs to the technical field of neodymium-iron-boron permanent magnet materials. The material is prepared from neodymium iron boron magnetic powder, auxiliary metal, hyperbranched polyimide polymer modified nano zirconium oxide and a silane coupling agent through mixing, smelting, crushing, sintering, tempering, coating and curing. The hyperbranched polyimide polymer modified nano-zirconia is introduced into the components, so that the permanent magnet material has excellent thermal stability, the permanent magnet material can still keep stable magnetic performance and mechanical performance at high temperature, the attenuation resistance is good, the thermal demagnetization is low, and the interface bonding strength is improved after the nano-zirconia is modified by hyperbranched polyimide. The interfacial compatibility between the nano zirconium oxide and the polyimide is enhanced through click chemical reaction, and the interfacial bonding strength of the nano zirconium oxide on a neodymium iron boron matrix is improved. The three-dimensional branched structure of the hyperbranched polyimide can form physical crosslinking points in the material, so that the mechanical strength of the material is enhanced.

The invention relates to the technical field of self-leveling mortar, in particular to tailing gravel paste-based self-leveling mortar and a preparation method thereof. The tailing sand paste-based self-leveling mortar is prepared from the following raw materials in parts by weight: 60 to 70 parts of tailing sand, 30 to 40 parts of fly ash, 30 to 50 parts of cementing material, 18 to 25 parts of water, 1 to 10 parts of polymer modifier, 0.1 to 1 part of anti-crack fiber, 0.5 to 1.5 parts of binder and 0 to 0.18 part of water-retaining agent. The method is simple to operate, and the tailing sand is efficiently utilized, so that the problem of waste of tailing sand resources is solved.

The invention discloses a preparation process and application of a modified anti-segregation admixture for machine-made sand, and relates to the technical field of polymer modified materials. Modified polyoxyethylene ether and vinyltrimethoxysilane are adopted to construct a steric hindrance effect, styrene-acrylate emulsion is introduced to form an interpenetrating network structure, and nano silicon dioxide and bentonite are cooperated to construct a multi-scale enhancement system. Silane coupling agent hydrolysis and nano grafting reaction are realized through gradient heating, and the particle size distribution D90 of the emulsion is less than or equal to 5 microns by combining an ultrasonic-mechanical synergistic emulsification process. A three-dimensional network is formed by the composite thickening agent and anhydrous sodium sulfate, and after in-situ curing at 25 DEG C with RH greater than or equal to 80%, 0.1-0.5% of the additive is added, so that the slump retention value of the machine-made sand concrete is greater than 315mm (1h), the pressure bleeding rate is less than or equal to 9.7%, the 28d compressive strength is improved by 24.5-72.6 MPa, and the segregation resistance coefficient is reduced to 0.08-0.11. The technology breaks through the limitation of insufficient adaptability of traditional admixtures to machine-made sand, and is particularly suitable for long-distance pumping construction of high-stone-powder-content machine-made sand concrete.

Filtration apparatus comprising Graphene Oxide (GO) membranes modified by incorporation of polymeric components are described herein. The GO membranes include graphene oxide sheets covalently coupled to one or more polymeric components. Incorporation of polymeric components may increase d-spacing of the graphene oxide sheets resulting in improved filtration apparatus performance with respect to prior art membranes (e.g., high flux and rejection rate). In some embodiments the polymeric components may comprise branched polymers with primary amine functionalities which can act as efficient handles for covalent attachment to graphene oxide, resulting in the formation of new, robust amide bonds. The filtration apparatus described herein can exhibit improved performance in applications such as pulp and paper processing, which facilitates achieving permeate quality targets.

The invention relates to the technical field of special functional coating materials for lost foam casting, and particularly discloses a special coating for a large machine tool casting lost foam as well as application and a use method of the special coating. According to the invention, the full-temperature-range functional composite material and the composite aggregate are used for synergistic reinforcement, and mullite is used for high-temperature reinforcement; the temperature-sensitive polymer modified graphite can realize intelligent temperature response of graphite performance; spodumene is used as a thermal expansion adaptive fluxing agent, so that medium-temperature healing and thermal expansion adjustment of a coating system are facilitated; the composite reinforced fibers are reinforced and toughened aiming at large thermal stress of thick and large parts; as an ultralow-temperature glazing agent, the boron-containing glazing agent can form an initial liquid phase at about 450 DEG C to seal the surface of the coating and purify a ventilation channel; the rare earth oxide serving as a high-temperature phase stabilizer can be dissolved in mullite crystal lattices, so that the high-temperature phase stability is improved, and ceramic nodes are refined. Through raw material design, on the premise of ensuring moderate air permeability, the ultrahigh strength and crack resistance of a coating system at extremely high temperature are improved.

The invention relates to the technical field of bamboo winding composite material pipelines, and discloses a bionic bamboo joint connector of a bamboo winding pressure pipeline and a processing technology of the bionic bamboo joint connector, the bionic bamboo joint connector is arranged at the connecting part of two sections of axially aligned bamboo winding pipelines, and the bionic bamboo joint connector sequentially comprises an inner lining layer and an outer lining layer from inside to outside, the embedded steel bar reinforcing layer consists of a reinforcing material and embedded steel bar glue; the film covering restraint layer is composed of fiber reinforced cloth and impregnating resin; the socket fastening layer is composed of a metal fastening piece which is connected with the two pipes in a bridging mode. A protective layer is poured, and the whole connector is wrapped with polymer modified cement mortar; the invention further provides a processing technology of the bionic bamboo joint connector. The processing technology comprises the following six steps of pretreatment, lining welding, embedded steel bar reinforcement, film covering constraint, socket fastening and pouring protection. Through the composite structure of crossed truss type embedded steel bars, polymer modified mortar pouring and socket fastening, the connector obtains high connection strength, excellent anti-drawing performance and long-term durability.

The present invention belongs to the technical field of polymer modified materials, and specifically relates to an aging-resistant, flame-retardant polypropylene composite material, and a preparation method and application thereof. The aging-resistant, flame-retardant polypropylene composite material of the present invention comprises the following raw materials in parts by weight: 20 to 60 parts of polypropylene resin; 1 to 10 parts of compatibilizer; 5 to 25 parts of EPDM rubber recycled material; 5 to 30 parts of smoke suppression flame retardant; 0.1 to 2 parts of light stabilizer; 0.1 to 2 parts of antioxidant; 10 to 40 parts of glass fiber. The aging-resistant, flame-retardant polypropylene composite material of the present invention has excellent mechanical properties, as well as light and heat aging resistance; tensile strength>85MPa, bending modulus>6000MPa, cantilever beam notched impact strength>165J / m, and strength is higher than that of wood. The injection-molded building formwork will not break when it falls vertically from a height of 3m, and can reach the B2 level of combustion performance of building materials and their products.

The invention discloses a bioprosthetic valve modifier, a polymer-modified bioprosthetic valve and a preparation method, and belongs to the technical field of preparation of medical materials and medical instruments. The bioprosthetic valve modifier is formed by polymerizing a diclofenac monomer containing a thioketal group, a hydrophilic monomer, a cross-linking agent, an active ester monomer and an initiator. The preparation method of the polymer-modified bioprosthetic valve comprises the following steps: sequentially soaking a bioprosthetic valve material in a glutaraldehyde solution, an amino cationic polymer solution and a nanogel solution, and finally soaking the bioprosthetic valve twice with an active ester compound solution to obtain the polymer-modified bioprosthetic valve. According to the polymer-modified bioprosthetic valve prepared by the invention, the nanogel is modified on the surface of the valve in a covalent bond manner, so that the polymer-modified bioprosthetic valve has good stability and long-term effect, has good biocompatibility and anti-inflammatory, anti-coagulation and anti-calcification effects, and has a good medical application prospect.

The invention belongs to the technical field of building materials, and provides a cement-based composite material with an organic-inorganic interpenetrating structure and a preparation method of the cement-based composite material. According to the preparation method disclosed by the invention, the monomer and the polymer containing the active group are introduced, the in-situ polymer formed by the monomer through in-situ polymerization and the polymer containing the active group form a double-network polymer, a single-network structure is refined, and the single-network structure and a cement hydration reaction product which is synchronously performed form an organic-inorganic interpenetrating structure; the interaction between double networks and the cement-based material is enhanced, meanwhile, the microstructure is optimized, the mechanical property of the single polymer modified cement-based material can be improved, the compressive strength is improved, and the breaking strength is further enhanced; the prepared cement-based composite material with the organic-inorganic interpenetrating structure has excellent breaking strength and compressive strength.

The invention discloses a retarder for delaying cement setting time and a preparation method thereof, and belongs to the field of cement admixtures. The retarder is anionic polymer modified chitosan, and the preparation method comprises the following steps: (1) fully dissolving chitosan in a weak acid solution to obtain a chitosan solution; (2) fully dissolving an anionic polymer in a solvent to obtain an anionic polymer solution; and (3) adding the anionic polymer solution into the chitosan solution, fully stirring, carrying out electrostatic adsorption reaction, and centrifuging, washing, drying and crushing after the electrostatic adsorption reaction is finished to obtain the anionic polymer modified chitosan. Chitosan is modified through electrostatic adsorption of an anionic polymer to form a compound, the compound is added into cement, and the coagulation time of the cement is prolonged by utilizing the complexing action of functional groups of the compound on calcium ions and the surface adsorption action on cement particles, so that the construction operability is favorably improved; and the preparation process is simple, and the cost is low.