1458 results about "Interfacial bonding" patented technology

The invention discloses fiber-reinforced anti-crack concrete and a preparation method thereof, and relates to the technical field of building materials, the fiber-reinforced anti-crack concrete comprises the following raw material components: 310-450 parts of cement, 150-190 parts of water, 930-1200 parts of coarse aggregate, 630-800 parts of fine aggregate, 80-180 parts of mineral active admixture, 1.2-18 parts of multi-element composite fiber, 1.8-4.5 parts of polycarboxylic acid water reducer, and 20-35 parts of anti-crack synergistic system. Through a quaternary fiber system, a three-dimensional interlocking net-shaped crack-resistant framework is formed in concrete slurry, the problems that the single fiber reinforcement effect is limited, and the interface bonding force with a concrete matrix is insufficient are solved, and the crack resistance and the mechanical property of the concrete are improved.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention discloses a preparation method of an interface-modified flame-retardant polypropylene-based bamboo-plastic composite material. According to the method, a modification solution composed of a polyphenol component and a boron-containing component is adopted, bamboo powder is treated under the normal-temperature stirring condition, and the interface modified bamboo powder is successfully prepared. The mechanism is that polyphenol and a boron-containing component are subjected to a coordination reaction on the surface of bamboo powder, and a reversible borate dynamic covalent bond is constructed. The dynamic bond has a temperature response characteristic: reversible dissociation is realized during high-temperature processing, so that the melt viscosity of a composite system is reduced, and the processing fluidity is improved; the interface bonding force between the bamboo powder and the polypropylene matrix and the mechanical strength of the composite material are remarkably enhanced. In addition, the introduced boron element is used as an efficient flame-retardant component and promotes generation of a compact protective carbon layer during combustion, so that the flame-retardant property of the composite material is comprehensively improved.

Low-carbon, carbon-neutral, and carbon-negative asphalt composites are disclosed. The composites comprise an asphalt binder and a functionalized biochar incorporated as a partial replacement for the binder and / or mineral filler. The biochar is physically, chemically, or mineralogically modified to enhance dispersion, interfacial bonding, mechanical performance, and carbon sequestration. The invention further includes methods for producing such composites, biochar-based additive compositions, and kits for practical implementation. Applications include asphalt pavements, waterproofing membranes, crack sealants, conductive deicing systems, and VOC-reducing asphalt mixtures. The resulting materials demonstrate improved durability, thermal and electrical properties, and significant reductions in greenhouse gas emissions.

The invention relates to the cross technical field of building materials and microorganism mineralization, and discloses a hollow fiber mediated biological concrete carbon fixation fiber, a preparation method and concrete.The carbon fixation fiber comprises a fiber carrier providing a transportation path and a diffusion channel for CO2 and carbon fixation microorganisms loaded on the fiber carrier, and the solid carbon fibers are applied to concrete as reinforcing fibers. According to the invention, carbon-fixing microorganisms are loaded on the surface of a fiber carrier with a hollow structure, so that carbon-fixing fibers with a stable microorganism-carrier composite system are formed; the carbon fixation fiber is applied to concrete, a transportation path and a diffusion channel are provided for CO2 in a concrete matrix through hollow mediation, and through directional mineralization of carbon fixation microorganisms on an interface where the reinforced fiber and the concrete are replaced, the carbon fixation amount is increased, meanwhile, the interface bonding force is enhanced, and the low-carbon concrete with the high CO2 storage capacity and the excellent mechanical property is prepared. And a new material and a new process are provided for a carbon neutralization target in the building industry.

The invention discloses an interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material and a method. The interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material comprises a maleic anhydride grafted polypropylene matrix and a core-shell structure filler dispersed in the maleic anhydride grafted polypropylene matrix, the core-shell structure filler comprises hydroxylated boron nitride nanoparticles covalently grafted on a polymer shell layer on the surface of the core-shell structure filler; the polymer shell layer is polyglycidyl methacrylate; the epoxy group of the polymer shell layer reacts with the anhydride group of the maleic anhydride grafted polypropylene matrix to form a covalent bond. The invention has the characteristics of strong interface bonding force, uniform filler dispersion, and excellent comprehensive electrical properties and processability.

The invention relates to the technical field of material detection, in particular to a silver coating adhesive force detection method based on multi-frequency impedance imaging, which comprises the following steps: applying a dual-mode multi-frequency excitation signal to the surface of a silver coating through an attached microelectrode array, synchronously acquiring voltage-current response data, and generating a dual-mode multi-frequency impedance original data set; performing time-varying impedance phase-locked separation on the dual-mode multi-frequency impedance original data set, extracting a dynamic impedance component of a coating-matrix interface region, and reconstructing a three-dimensional sub-interface impedance distribution diagram; and outputting an adhesive force quantized value through an oscillation frequency-adhesive force conversion model according to the spatial oscillation frequency characteristics of the impedance phase in the three-dimensional sub-interface impedance distribution diagram. According to the invention, a double-phase-locked loop system is adopted to realize the time-varying component demodulation of the impedance response of the silver coating-matrix interface, the low-frequency dynamic impedance signal modulated by silver ion migration is effectively extracted, and the weak change of the interface bonding state is sensitively reflected.

The invention provides a solid-state battery and a preparation method thereof, and particularly relates to the technical field of solid-state batteries. The solid-state battery is composed of a plurality of laminated units, the laminated unit comprises a positive pole piece, an all-solid-state electrolyte membrane and a negative pole piece which are sequentially stacked according to a sandwich structure; among the positive pole piece, the all-solid-state electrolyte membrane and the negative pole piece, convex structures and concave structures which are uniformly arranged are distributed on any two mutually contacted surfaces of the positive pole piece, the all-solid-state electrolyte membrane and the negative pole piece. When the components of the solid-state battery are overlapped, the convex structures and the concave structures on the surfaces of the solid-state battery can be mutually engaged to form a stable micro-embedded structure, the interface bonding strength between the positive electrode and the electrolyte and between the negative electrode and the electrolyte is greatly enhanced through physical embedding, and the problem of unstable bonding in the prior art is solved. Meanwhile, the uniform concave-convex structure ensures the controllability and consistency of the interface contact area, effectively reduces and stabilizes the interface impedance, improves the performance consistency of the pole piece, and further improves the production yield and the overall performance stability of the battery.

The invention discloses fiber reinforced concrete for bridge deck pavement and a preparation method thereof, and belongs to the technical field of concrete. The fiber reinforced concrete is prepared from the following raw materials: Portland cement, modified basalt fiber, a slow-release mineralizer, a stress-oriented dispersing aid and the like. The modified basalt fiber is a basalt fiber which is subjected to amino silanization through a silane coupling agent KH-550 and then is catalytically grafted with ethylenediamine tetraacetic acid and hydroxyethyl methylacrylate through DCC (dicyclohexylcarbodiimide); the slow-release mineralizer comprises calcium sulphoaluminate and silicon-based coated nano calcium sulfate; the silicon-based coated nano calcium sulfate is core-shell structure powder formed by coating a nano calcium sulfate core material with a silicon dioxide shell layer; the concrete is strong in interface bonding, excellent in dynamic fatigue resistance, good in durability and stable in volume, and the problem that the mechanical property, the durability and the dynamic anti-interference capability of the concrete cannot be considered at the same time is solved.

The invention discloses a high-strength hoop and a processing method thereof in the technical field of mechanical connection fasteners. The high-strength hoop comprises the following raw materials: modified carbon fibers, a modified epoxy resin matrix, chopped glass fibers, an antioxidant and an aluminate coupling agent. Cleaning the modified carbon fibers with acetone to remove oil stains, oxidizing the modified carbon fibers with concentrated nitric acid at 80-85 DEG C to generate polar functional groups containing hydroxyl and carboxyl, washing the modified carbon fibers with water until the modified carbon fibers are neutral, drying the modified carbon fibers, immersing the modified carbon fibers into an absolute ethyl alcohol solution of an aluminate coupling agent for ultrasonic dispersion, and curing the modified carbon fibers at 100-105 DEG C; the modified epoxy resin matrix is prepared by heating and melting epoxy resin, adding nano montmorillonite, stirring and dispersing, adding polyamide, an accelerant and a flexibilizer, and carrying out vacuum defoaming at 100-105 DEG C. The hoop has the advantages of high strength, weather resistance and the like by modifying and enhancing interface bonding and matrix toughness, and is suitable for connection under complex working conditions.

The present invention relates to the technical field of concrete. Disclosed is a toughening design method for fiber-reinforced concrete. The method of the present invention changes the passive control characteristics of fibers on a concrete crack propagation process in conventional fiber-reinforced concrete. Starting from the origin of composite material design, firstly, an ultrahigh-ductility composite cementitious matrix is designed; and secondly, an aggregate is incorporated. On the basis of a specific combination of matrix and aggregate parameters, a composite material develops meso-scale multiple cracking and strain-hardening behaviors between aggregate particles during external loading. The fiber-reinforced concrete prepared by this method actively disperses brittle damage and failure within the material, and avoids unstable crack propagation caused by weak interfacial bonding between the aggregate and the matrix. Compared to conventional fiber-reinforced concrete design methods, the present invention more accurately establishes relationships between material compositions, microstructures and macroscopic mechanical response, and more efficiently enhances the toughness of the material.

The invention relates to the technical field of capacitor films. The invention discloses a preparation process of a high-performance polypropylene capacitor film. The preparation process comprises the following steps: A1, preparing a polypropylene capacitor film; a2, carrying out surface cleaning and activation pretreatment on the polypropylene capacitance film; a3, evaporating a gradient modified layer on the surface of the pretreated polypropylene capacitance film; a4, carrying out laser plasma synergistic treatment and crystallinity regulation and control on the modified polypropylene capacitor film; and A5, coating the outer layer of the modified polypropylene capacitance film with a functional layer, and carrying out annealing post-treatment to prepare the high-performance polypropylene capacitance film. The mechanical strength and the electrical stability are improved through nano filler dispersion, two-way stretching and crystallinity regulation and control; through the collaborative design of surface cleaning and activation and a gradient functional layer, excellent interface bonding force and environmental adaptability are given; and by means of technologies such as multi-source evaporation and laser plasma co-processing, precise regulation and control and diversified expansion of the performance are achieved, the method is suitable for various scenes, and the process repeatability is good.

The invention discloses a rare earth metal ceramic and a preparation method thereof, and belongs to the technical field of metal ceramic preparation, the rare earth metal ceramic comprises, by mass, 45-65% of a ceramic phase, 30-50% of a metal binding phase and 3-8% of a rare earth additive, the ceramic phase is composed of one of TiC and WC and one of Al2O3 and ZrO2, the metal binding phase is composed of a Ni-Co alloy and Mo or Cr, and the rare earth additive is composed of one of Al2O3 and ZrO2. The rare earth additive is composed of mixed rare earth oxide and nano rare earth fluoride. The invention further provides a preparation method of the rare earth additive. Through the synergistic effect of oxide grain boundary purification and fluoride liquid phase sintering in a two-phase rare earth system, the problem that traditional single rare earth is difficult to add and disperse is solved, through staged hot pressing sintering, dual optimization of grain refinement and density improvement is achieved, and the high-temperature oxidation resistance and interface bonding strength of metal ceramic are enhanced.

The invention relates to the technical field of composite materials, in particular to a high-strength epoxy resin composite material and a preparation method thereof, and the high-strength epoxy resin composite material comprises the following raw materials in parts by weight: 50-80 parts of a base material, 10-20 parts of a curing agent, 5-10 parts of modified carbon nanotubes, 3-10 parts of a reinforcing sheet, 3-6 parts of a reinforcing material and 1-3 parts of a flame retardant. In the preparation method, the modified carbon nanotubes are in chemical bond connection with the base material through surface modification, the interface bonding force is enhanced, stress is effectively transmitted, the unique layered structure and surface modification treatment of the enhanced sheet are enhanced, the enhanced sheet is firmly combined with the resin matrix, and a three-dimensional enhanced network is formed through the synergistic effect of mechanical interlocking and stress dispersion. The vermiculite sheet layer prevents crack propagation, and the modified carbon nanotubes and the reinforcing material effectively transfer stress, so that the tensile strength and bending strength of the composite material are greatly improved, and the high-strength application requirement is met.

This invention relates to the field of cable technology and discloses a torsion-resistant cross-linked polyethylene (XLPE) insulated cable suitable for scenarios involving intermittent winding and static cycles, such as cable logistics warehousing and mobile emergency equipment. Existing technologies, designed for continuous winding, cannot address the residual stress generated by the rigidity of cross-linked polyethylene in intermittent scenarios, nor the aging and crack propagation problems caused by the coupling of residual stress with the environment. This invention incorporates a gradient porous stress-relieving layer outside the conductor, releasing residual stress and strengthening interfacial bonding through modulus transition and chemical adhesion; the XLPE insulation layer is modified with EVA to reduce rigidity and reinforced with nano-silica; and a self-healing layer containing directional microcapsules and carbon nanotubes is incorporated outside the insulation layer to achieve precise crack repair and anti-aging, reducing insulation cracks, conductor breakage, and shielding failure during intermittent winding and static cycles, ensuring the cable's reliability in the target scenarios.

The invention relates to the technical field of functional composite probe material preparation, in particular to a three-core spinning technology-based bio-compatible gel probe and a preparation method thereof, and the three-core spinning technology-based bio-compatible gel probe comprises a composite skin layer and three functional core layers; the composite skin layer is composed of a sodium alginate-polydopamine-chitosan grafted copolymer in a mass ratio of 2: 1: 0.5, and contains # imgabs 0 # chondroitin sulfate and # imgabs 1 # polyoxyethylene; the three core layers are respectively a carbon nanotube-polyaniline # imgabs2 # hybrid material, a graphene-polypyrrole-boron nitride hybrid material and a # imgabs3 # polythiophene-hydroxyapatite hybrid material, and the mass ratio of the carbon material to the conductive polymer to the newly added nano material in each core layer is 1: 2: 0.3; and the diameter ratio of the skin layer to the three core layers is 1: 0.28: 0.22: 0.17. According to the invention, multichannel signal transmission is realized, the impedance is reduced by the hybrid material, and the conductivity is improved; the composite skin layer is matched with soft tissue mechanical properties, and interface bonding is stable; and the biocompatible component reduces inflammation, is suitable for acquiring nerve electrophysiological signals, and is easy for large-scale production.

The invention belongs to the field of composite ink coatings, and particularly discloses a high-thermal-conductivity and high-adhesiveness copper foil coating ink coating as well as a preparation method and application thereof. The ink coating is prepared from the following components in parts by weight: 15 to 25 parts of epoxy resin, 10 to 20 parts of polyurethane resin, 5 to 12 parts of modified cellulose, 30 to 45 parts of heat-conducting filler, 8 to 15 parts of aliphatic polyisocyanate curing agent, 20 to 35 parts of solvent, 2 to 5 parts of silane coupling agent and 0.5 to 3 parts of pigment. The modified cellulose is prepared by modifying halogen-free betaine hydroxide, and can cooperate with the double-resin matrix to enhance the interface bonding force and construct a three-dimensional heat-conducting network. After the surface of an electrolytic or rolled copper foil is coated with the ink coating, the heat conductivity coefficient of the coating is larger than 0.4 W / (m.K), the dyne value is larger than 38, the cross-cut test is larger than or equal to 4B, alcohol wiping resistance is achieved, falling is avoided, the color difference delta E is smaller than 1, and the ink coating is suitable for a high-frequency circuit substrate and a lithium battery current collector.

The invention relates to a PVB (polyvinyl butyral) composite film as well as a preparation method and application thereof. The PVB composite film is prepared from the following raw materials in parts by weight: 100 parts of PVB resin, 1-10 parts of nano praseodymium oxide, 1-10 parts of a dispersing agent, 0.01-1 part of a coupling agent and 20-50 parts of a plasticizer. The nano praseodymium oxide is added into the PVB resin, and the infrared absorption band of the PVB composite film is optimized by utilizing the infrared absorption performance, chemical stability and heat-resistant stability of the nano praseodymium oxide, so that infrared radiation can be efficiently blocked, and the excellent heat insulation effect and long-term use stability of the PVB composite film are realized. Furthermore, the nano praseodymium oxide is modified by a coupling agent, so that the dispersion uniformity of the nano praseodymium oxide in the PVB resin and the interface bonding force of the nano praseodymium oxide and the PVB resin are improved, the light transmittance loss of the PVB composite film is reduced, and the mechanical property and the heat insulation property of the composite film are improved.

The invention discloses a high-temperature-resistant high-performance neodymium-iron-boron permanent magnet material and a preparation method thereof, and belongs to the technical field of neodymium-iron-boron permanent magnet materials. The material is prepared from neodymium iron boron magnetic powder, auxiliary metal, hyperbranched polyimide polymer modified nano zirconium oxide and a silane coupling agent through mixing, smelting, crushing, sintering, tempering, coating and curing. The hyperbranched polyimide polymer modified nano-zirconia is introduced into the components, so that the permanent magnet material has excellent thermal stability, the permanent magnet material can still keep stable magnetic performance and mechanical performance at high temperature, the attenuation resistance is good, the thermal demagnetization is low, and the interface bonding strength is improved after the nano-zirconia is modified by hyperbranched polyimide. The interfacial compatibility between the nano zirconium oxide and the polyimide is enhanced through click chemical reaction, and the interfacial bonding strength of the nano zirconium oxide on a neodymium iron boron matrix is improved. The three-dimensional branched structure of the hyperbranched polyimide can form physical crosslinking points in the material, so that the mechanical strength of the material is enhanced.

The invention relates to the field of optical display and material engineering, in particular to a silica gel integrated optical film with a 3D light splitting function and a manufacturing method of the silica gel integrated optical film. A silica gel integrated optical film with a 3D light splitting function comprises a transparent optical base material and a microstructure layer, and the microstructure layer is combined on the surface of the transparent optical base material in an integrated forming mode. And the microstructure layer is an anhydrous silica gel-resin composite material obtained by combining organic silica gel with low refractive index and resin with high refractive index through an anhydrous chemical reaction system. The optical film obtained in the invention has excellent interface bonding stability and long-term reliability, the overall thickness of the optical film is small, the optical loss is reduced, the light transmittance is higher, and the overall transmittance can reach 93% or above. And the manufacturing process integration degree and the mold repeated utilization rate are high, the industrial batch production requirement can be met, and the excellent industrial application prospect is achieved.

The invention relates to an automobile scratch-resistant protective film and a preparation method thereof, and belongs to the technical field of automobile protective materials. The material is prepared from modified nano aluminum oxide, modified polyurethane acrylate, polyurethane acrylate, a photoinitiator, a flatting agent, an antioxidant and a solvent, the modified nano aluminum oxide is prepared through an esterification reaction of nano alpha-Al2O3 and stearic acid, and the hardness and wear resistance of a coating are enhanced; and the modified polyurethane acrylate is prepared by reacting a polyurethane prepolymer with a hydroxyl compound, so that the interface bonding force with the nano particles and the flexibility of the coating are improved. The preparation method comprises the following steps: dispersing modified nano aluminum oxide into a solvent, sequentially adding other components, and uniformly mixing to obtain functional coating slurry; the surface of a PET base material is coated with the slurry, and ultraviolet curing molding is performed after pre-drying. The prepared protective material has the characteristics of high hardness, scratch resistance, strong adhesive force with automobile paint and excellent weather resistance, and is suitable for automobile surface protection.

The invention provides a method for optimizing the proportion of industrial waste residues and a microbial composite curing agent, and belongs to the technical field of building materials.The method comprises the steps that the industrial waste residues are ground into superfine powder with the specific surface area of 350-450 m < 2 > / kg, meanwhile, bacillus is cultured at the temperature of 30-35 DEG C until the concentration of bacillus is 108-109 / mL, and a mixture is obtained; a pH meter and a dissolved oxygen meter are adopted to monitor the state of a microbial solution in real time, the aeration intensity and nutrient solution supplement are automatically adjusted according to critical value judgment, a composite curing agent is prepared according to the calculation proportion, the interface bonding strength and compressive strength are tested, and the curing effect is evaluated through a strength development equation and a durability prediction equation. According to the comprehensive performance indexes, the matching parameters are dynamically adjusted, the testing and adjusting process is repeated until the results are stabilized in the target performance interval for five continuous times, the final matching is determined, and the technical problem that the matching of the industrial waste residues and the microbial composite curing agent is difficult to accurately optimize is solved.

The invention relates to the technical field of chip welding, and discloses a continuous vacuum welding device for an IGBT (Insulated Gate Bipolar Translator) chip, which comprises a working channel formed by connecting a plurality of working furnaces in series, vacuum gate valves used for sealing the space are installed at an inlet and an outlet of the working channel and the butt joint position of every two adjacent working furnaces, and the conveying mechanism is used for conveying product carriers, is installed in the working furnaces and comprises two conveying assemblies symmetrically distributed on the two sides of the axis of the working channel; the two ends of the product carrier are erected on the conveying parts of the two conveying assemblies correspondingly. The preheating furnace, the welding furnace and the cooling furnace are connected in series to form the working channel, and the vacuum gate valves are mounted at the inlets and the outlets of the cavities, so that the adjacent cavities are independently sealed, the oxygen content of each cavity is controlled in an extremely low range, the ceramic copper-clad plate is prevented from being oxidized, the welding void rate is reduced, and the interface bonding strength is improved.

The invention discloses light building corrosion-resistant fiber concrete and a production method thereof, the light building corrosion-resistant fiber concrete comprises the following raw materials by mass: 300-400 parts of high belite sulphoaluminate cement, 10-20 parts of modified corrosion-resistant fiber, 50-80 parts of a mineral admixture, 800-1000 parts of a coarse aggregate, 600-700 parts of a fine aggregate, 5-10 parts of a composite admixture, and 120-150 parts of water; wherein the mineral composition of the high belite sulphoaluminate cement is as follows: 18 to 25 percent of C4AF, 15 to 20 percent of anhydrous calcium sulphoaluminate (C4A3S), 45 to 55 percent of belite (C2S) and less than or equal to 10 percent of other minerals. By optimizing the ratio of C4AF to anhydrous calcium sulphoaluminate in the high belite sulphoaluminate cement and combining with a special calcining process, the contradiction of low early strength caused by increase of the content of C4AF is solved, and meanwhile, a foundation is laid for long-term corrosion resistance; and by adopting a silane coupling agent-nano silicon dioxide composite modification technology, the limitation of limited single modification effect is solved, and the synchronous improvement of the corrosion resistance of the fiber and the interface bonding strength is realized.

The invention relates to the technical field of building solid waste resource utilization, and discloses a bamboo-based biochar and cement-based waste-based artificial aggregate preparation method, which comprises: using cement-based waste powder as a main raw material, and using ordinary Portland cement and bamboo-based biochar as auxiliary materials, firstly carrying out alkali modification or ultrasonic modification treatment on the bamboo-based biochar, and then carrying out drying to obtain the artificial aggregate based on the bamboo-based biochar and the cement-based waste. The surface property is improved; then mixing the materials, and preparing a regular and uniform aggregate blank by adopting a disc granulation method and accurately controlling the inclination angle and the rotating speed in combination with a reserved dry powder rolling and sticking process; finally, the blank is cured, particularly carbonization curing is adopted, and carbon dioxide and cement hydration products react to generate calcium carbonate to fill internal pores. According to the invention, interface bonding is enhanced through the modified charcoal, the porosity is reduced through carbonization curing, the prepared artificial aggregate has the advantages of high compressive strength and low water absorption, and high-proportion utilization of cement-based wastes is realized.

The invention is suitable for the technical field of composite materials, and provides a laminated composite material toughening intermediate layer and a preparation method thereof, and the preparation method comprises the following steps: obtaining an aramid short fiber wet-laid non-woven felt by using a processing method of a wet non-woven material; then the aramid fiber surface is activated through hydrofluoric acid etching; the preparation method comprises the following steps: grafting soluble polyether-ether-ketone resin with an active end group on the surface of the aramid fiber, and impregnating the aramid fiber at the same time; and the polyetheretherketone resin grafted on the surface of the aramid fiber is re-endowed with crystallinity through acidification reduction reaction of the polyetheretherketone resin grafted on the surface of the aramid fiber. According to the invention, the interface bonding performance of the aramid fiber toughening middle layer in the laminated composite material is regulated and controlled, the interlayer toughness of the carbon fiber reinforced polyether-ether-ketone composite material laminated board can be effectively improved while the original crystallinity of the polyether-ether-ketone resin is maintained, the possibility of interlayer cracking can be obviously reduced, a brand new scheme is provided for interlayer toughening of such materials, and the application prospect is broad. The material has potential application prospects in the fields of aerospace special materials and the like.

The invention discloses a preparation method of a transformer insulating material, belongs to the technical field of transformer insulating materials, and aims to solve the technical problems of large interlayer insulation conduction temperature rise and low coil space filling rate of an existing epoxy pouring dry-type transformer. Epoxy resin and a curing agent are stirred under the vacuum negative pressure condition to form a basic resin mixture; dividing the mixture into two components, and respectively preparing heat-conducting reinforced resin containing nanometer aluminum oxide particles and anti-cracking reinforced resin containing polyester film fragments; coating the surface of the insulation paper with heat-conducting resin, then laying epoxy glass fiber gridding cloth, and injecting anti-cracking resin to fill gaps; carrying out hot press molding to obtain an interlayer insulating plate, and treating and drying the interlayer insulating plate with a silane coupling agent; and finally compounding with a polyester film to form the insulating material. The material is used for coil interlayer and turn-to-turn insulation of an epoxy pouring dry-type transformer, and the longitudinal insulation performance improvement and temperature rise control of a winding are realized by optimizing the thermal conductivity, the filling rate and the interface bonding force of the resin.

The invention discloses a composite material hollow plate and a preparation method, and belongs to the technical field of composite material plate preparation. The composite material hollow plate comprises an outer plate and an inner plate, a plurality of corrugated supporting structures are connected between the outer plate and the inner plate, and a cavity is formed between every two adjacent corrugated supporting structures. A wear-resistant reinforcing agent is added into an outer plate material to improve the surface wear resistance, an epoxy-amine dual-core double-wall microcapsule is introduced into an inner plate material to enhance the crack repairing capacity, and a shape memory reinforcing agent is added into a corrugated supporting structure material to endow the material with the shape memory characteristic. The invention solves the technical problems of difficulty in consideration of strength and toughness, short service life, poor buffer performance, insufficient interface bonding strength and the like of the existing composite material hollow plate, and is particularly suitable for steel coil packaging and other application scenes requiring repeated use and high reliability.

The application relates to the technical field of composite materials, and particularly discloses a carbon fiber / epoxy electromagnetic shielding composite material with strong interface bonding and a preparation method thereof, which comprises the following steps: hydrothermal reaction of oxidized carbon fibers O-CF, an organic ligand and an iron source in a solvent, washing and drying of the fibers to obtain MIL-loaded carbon fibers, carbonization treatment to obtain iron-based oxide-loaded carbon fibers dF@CF, vacuum-assisted introduction of epoxy resin into the multilayer carbon fibers dF@CF, and curing to obtain the carbon fiber / epoxy electromagnetic shielding composite material. The organic ligand and trivalent iron ions are used to synthesize a large number of rhombic MILs on the active sites on the surface of the carbon fibers, the MILs are reduced into iron-based oxide nanoparticles after carbonization, the iron-based oxide nanoparticles are closely loaded on the surface of the carbon fibers, the interface bonding performance is improved, the electromagnetic shielding efficiency is increased, and the carbon fiber / epoxy composite material with both the interface and the electromagnetic shielding efficiency is realized.

The invention discloses a carbon fiber modified sizing agent as well as a preparation method and application thereof. The preparation method of the carbon fiber modified sizing agent comprises the following steps: (1) reacting 5-norbornene-2-methylamine with monofunctional epoxy resin to obtain slurry; and (2) dissolving the slurry prepared in the step (1) in an organic solvent to prepare the modified sizing agent. And then obtaining the modified carbon fiber through a dipping and sizing process. The method is simple in process, and the interface bonding strength of the carbon fibers and the polydicyclopentadiene can be greatly improved.