1927 results about "Interfacial bonding" patented technology

The invention discloses fiber-reinforced anti-crack concrete and a preparation method thereof, and relates to the technical field of building materials, the fiber-reinforced anti-crack concrete comprises the following raw material components: 310-450 parts of cement, 150-190 parts of water, 930-1200 parts of coarse aggregate, 630-800 parts of fine aggregate, 80-180 parts of mineral active admixture, 1.2-18 parts of multi-element composite fiber, 1.8-4.5 parts of polycarboxylic acid water reducer, and 20-35 parts of anti-crack synergistic system. Through a quaternary fiber system, a three-dimensional interlocking net-shaped crack-resistant framework is formed in concrete slurry, the problems that the single fiber reinforcement effect is limited, and the interface bonding force with a concrete matrix is insufficient are solved, and the crack resistance and the mechanical property of the concrete are improved.

The invention relates to the technical field of metal surface protection, and discloses a corrosion-resistant self-repairing metal fastener and a preparation method thereof.The corrosion-resistant self-repairing metal fastener comprises a zinc alloy matrix, a nanometer passivation layer, a slow-release corrosion-resistant layer and a self-repairing functional layer, and the nanometer passivation layer, the slow-release corrosion-resistant layer and the self-repairing functional layer sequentially wrap the zinc alloy matrix; the zinc alloy matrix consists of Al, Cu, Mg, Ce and Zn; the nano passivation layer adopts zinc phosphate / silane composite sol to construct a Si-O-P covalent bond network, and plasma is combined to graft epoxy groups to enhance the interface bonding strength; the slow-release anti-corrosion layer is used for loading a pH response type benzotriazole derivative through gradient aperture mesoporous silica, so that the dynamic controlled release of a corrosion inhibitor is realized; the self-repairing functional layer adopts a synergistic effect of a mechanical triggering type sulfydryl siloxane microcapsule and a pH triggering type EDTA chelating agent microcapsule to form a physical plugging-chemical passivation dual-mode repairing mechanism. Through four-stage cooperation of matrix modification, interface strengthening, slow-release regulation and control and intelligent repair, the corrosion resistance of the corrosion-resistant self-repairing metal fastener in a complex environment is remarkably enhanced.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention discloses a preparation method of an interface-modified flame-retardant polypropylene-based bamboo-plastic composite material. According to the method, a modification solution composed of a polyphenol component and a boron-containing component is adopted, bamboo powder is treated under the normal-temperature stirring condition, and the interface modified bamboo powder is successfully prepared. The mechanism is that polyphenol and a boron-containing component are subjected to a coordination reaction on the surface of bamboo powder, and a reversible borate dynamic covalent bond is constructed. The dynamic bond has a temperature response characteristic: reversible dissociation is realized during high-temperature processing, so that the melt viscosity of a composite system is reduced, and the processing fluidity is improved; the interface bonding force between the bamboo powder and the polypropylene matrix and the mechanical strength of the composite material are remarkably enhanced. In addition, the introduced boron element is used as an efficient flame-retardant component and promotes generation of a compact protective carbon layer during combustion, so that the flame-retardant property of the composite material is comprehensively improved.

The invention discloses a method for preparing a copper-aluminum layered composite board by introducing laser into an intermediate layer, which comprises the following steps: introducing laser into the intermediate layer (Al-Cu-Mg-Si-Zr-Sc series alloy), so that on one hand, copper and aluminum to be compounded are in a heating state to be subjected to rolling compounding by utilizing the heat conduction effect of the heated intermediate layer; the rolling reduction rate and the rolling mill capacity requirement are obviously reduced; and on the other hand, the added middle layer has excellent obdurability, so that the cooperative deformation capacity between the to-be-compounded dissimilar materials can be improved, and the interface bonding performance of the composite material is improved. And a mode of'introducing laser into the middle layer and carrying out short-time online annealing treatment 'is adopted to replace'large down pressure and long-time diffusion annealing' adopted by a traditional copper-aluminum composite material, so that the processing and forming efficiency of the copper / aluminum composite material is remarkably improved, and the method has the characteristic of short process.

The invention relates to a degradable filter element and a preparation method thereof, and belongs to the technical field of PLA filter elements. The degradable filter element is arranged between an atomizing element shell and a metal heating wire, a plurality of capillary holes are formed in the degradable filter element and used for being filled with tobacco tar, and the degradable filter element is prepared from a degradable composite material through melt spinning. The degradable composite material comprises the following components: polylactic acid and modified silicon dioxide, wherein the modified silicon dioxide is prepared by taking nano silicon dioxide, a silane coupling agent, ferulic acid, amino acid and copper chloride as raw materials, the silicon dioxide is organically modified, so that the dispersity of the silicon dioxide in a polylactic acid system is improved, the interface binding force of the silicon dioxide is improved, and the mechanical property of a polylactic acid material is improved; various antibacterial components are introduced, so that the antibacterial property of the polylactic acid material can be effectively improved.

Low-carbon, carbon-neutral, and carbon-negative asphalt composites are disclosed. The composites comprise an asphalt binder and a functionalized biochar incorporated as a partial replacement for the binder and / or mineral filler. The biochar is physically, chemically, or mineralogically modified to enhance dispersion, interfacial bonding, mechanical performance, and carbon sequestration. The invention further includes methods for producing such composites, biochar-based additive compositions, and kits for practical implementation. Applications include asphalt pavements, waterproofing membranes, crack sealants, conductive deicing systems, and VOC-reducing asphalt mixtures. The resulting materials demonstrate improved durability, thermal and electrical properties, and significant reductions in greenhouse gas emissions.

The invention provides an activated carbon fiber capable of efficiently removing formaldehyde and a preparation method thereof, the activated carbon fiber is of a composite material fiber structure of porous TiO2 derived from activated carbon and a metal organic framework (MOF), and the preparation method of the composite material comprises pretreatment of activated carbon, preparation of a Ti-MOF precursor and preparation of TiO2 / activated carbon fiber. According to the invention, the MOF-derived porous TiO2 / activated carbon composite fiber structure is constructed, physical adsorption and photocatalytic degradation functions are cooperated, and the limitation of single adsorption capacity is broken through; the interface bonding problem of the MOF derivative and the activated carbon is solved, and high-dispersion loading and stable and firm compounding of the active components are realized; a process path capable of realizing large-scale preparation is provided, and continuous production of the composite fiber is realized through an electrostatic spinning technology.

The invention discloses a polyethylene composite material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The polyethylene composite material comprises the following components in parts by weight: 100 parts of high-density polyethylene, 6-20 parts of a high-density polyethylene reclaimed material, 3-16 parts of ultra-high molecular weight polyethylene, 1-6 parts of a compatilizer, 1-2 parts of an inorganic filler and 1-2 parts of a flow modifier, 2-3 parts of color master batch; wherein the viscosity average relative molecular weight of the ultra-high molecular weight polyethylene is 1,000,000-2,000,000, and the test standard is ASTM (American Society for Testing Material) D4020. According to the polyethylene composite material disclosed by the invention, part of the high-density polyethylene recycled material is doped, and the interface bonding force between the new high-density polyethylene material and the high-density polyethylene recycled material is improved through the synergistic effect of the ultra-high molecular weight polyethylene, the compatilizer and the inorganic filler; the mechanical property and the wear-resisting property of the polyethylene composite material doped with the high-density polyethylene reclaimed material are improved.

The invention relates to the cross technical field of building materials and microorganism mineralization, and discloses a hollow fiber mediated biological concrete carbon fixation fiber, a preparation method and concrete.The carbon fixation fiber comprises a fiber carrier providing a transportation path and a diffusion channel for CO2 and carbon fixation microorganisms loaded on the fiber carrier, and the solid carbon fibers are applied to concrete as reinforcing fibers. According to the invention, carbon-fixing microorganisms are loaded on the surface of a fiber carrier with a hollow structure, so that carbon-fixing fibers with a stable microorganism-carrier composite system are formed; the carbon fixation fiber is applied to concrete, a transportation path and a diffusion channel are provided for CO2 in a concrete matrix through hollow mediation, and through directional mineralization of carbon fixation microorganisms on an interface where the reinforced fiber and the concrete are replaced, the carbon fixation amount is increased, meanwhile, the interface bonding force is enhanced, and the low-carbon concrete with the high CO2 storage capacity and the excellent mechanical property is prepared. And a new material and a new process are provided for a carbon neutralization target in the building industry.

The invention discloses a multi-layer gradient composite polyethylene lining hose and a microwave triggering repairing method thereof, the multi-layer gradient composite polyethylene lining hose comprises a self-repairing functional layer, a reinforcing framework layer, an interface bonding layer and an outer protective layer which are sequentially compounded from inside to outside, and the invention relates to the technical field of pipeline repairing. According to the multi-layer gradient composite polyethylene lining hose and the microwave triggering repairing method thereof, through combination of a multi-layer gradient composite structure (a self-repairing layer, a reinforcing framework and a gradient interface) and a microwave triggering repairing technology, three major breakthroughs are achieved: 1) the service life of a pipeline is prolonged to 50 years (the self-repairing efficiency is greater than or equal to 85%); (2) the repairing efficiency is improved by 3 times (DN1000 pipe is less than or equal to 8 hours), (3) the energy consumption is reduced by 70% (microwave directional curing), an intelligent monitoring system (optical fiber sensing and AI analysis) ensures the construction precision (the gap is less than or equal to 2 mm), high strength (the ring stiffness is SN12 grade), low emission (the carbon emission is reduced by 65%) and wide applicability (DN300-DN3000) are achieved, and a traditional pipeline repairing mode is thoroughly innovated.

The invention discloses a glue solution for a copper-clad plate and a preparation method of the glue solution, and relates to the technical field of copper-clad plates. According to the prepared glue solution for the copper-clad plate, the composite epoxy resin, the curing agent, the accelerant, the solvent, the flexibilizer and the inorganic filler, the composite epoxy resin comprises bisphenol A epoxy resin, epoxy phenyl polysiloxane, itaconic acid polyaryletherketone and hydroxyl-terminated fluorine-containing vinyl polysiloxane, so that the interface bonding force with the copper plate is enhanced; the dielectric constant and the dielectric loss are effectively reduced, the peel strength and the toughness of the material are also remarkably improved, and the toughening agent is modified polyether sulfone microspheres; the modified polyethersulfone microspheres are prepared by coating polyethersulfone microspheres with hexamethylenediamine tetrapropionamide diamine, the hexamethylenediamine tetrapropionamide diamine is prepared by carrying out acylation condensation reaction on hexamethylenediamine tetramethyl propionate and ethylenediamine, and the polyethersulfone microspheres are prepared by carrying out electrostatic spinning on a spinning solution of polyethersulfone and vinylpyridine, so that the peel strength of the glue solution is remarkably improved.

The invention belongs to the technical field of concrete, and particularly relates to a preparation method and application of coal gangue-based ultra-high performance concrete UHPC for wet joints. Through composite gradient activation of calcination and ball milling and alkali-lithium salt synergistic excitation, efficient dissolution of active components of the coal gangue is achieved, the 3d compressive strength of the UHPC material is larger than or equal to 120 MPa, the 28d compressive strength of the UHPC material is larger than or equal to 150 MPa, and the UHPC material is improved compared with a traditional coal gangue-based material; meanwhile, through the synergistic effect of nano SiO2 / graphene oxide multi-scale reinforcement and steel fiber toughening, the interface bonding strength reaches 12-14 MPa, the chloride ion diffusion coefficient is smaller than 1.5 * 10 <-12 > m < 2 > / s, and the problems of wet joint interface debonding and durability degradation are solved.

The invention discloses a carbon fiber / polypropylene composite material as well as a preparation method and application thereof, and belongs to the technical field of composite materials. The invention aims to regulate and control the interface structure and the adhesive property of the carbon fiber / polypropylene composite material. The preparation method comprises the following steps: firstly preparing a polyethyleneimine solution to soak carbon fibers, then preparing a suspension of a modified material to treat the carbon fibers, and carrying out temperature-controlled crystallization to prepare the carbon fiber / polypropylene composite material. The polyethyleneimine solution treatment is the key for the modified material to be adhered to the surface of the carbon fiber, the interface structure of the carbon fiber / polypropylene composite material can be effectively regulated and controlled by selecting the appropriate suspension concentration of the modified material, the interface bonding strength and the mechanical property of the composite material are improved, and the industrial application requirements are better met.

The invention discloses a carbon fiber reinforced modified resin material and a preparation method thereof, and belongs to the technical field of high-molecular compound composition.The preparation method comprises the steps that 40-60 parts of acidified carbon fibers, 8-12 parts of silane coupling agent modified graphene oxide, 10-20 parts of polyethylene glycol and 3-8 parts of alkylphenol polyoxyethylene ether are ultrasonically mixed to be uniform with acetone as a solvent, and a mixture I is obtained; mixing 100 parts of epoxy resin and 30-50 parts of a curing agent, heating and stirring until the mixture is melted to obtain a mixture II; the mixture I and the mixture II are placed in a vacuum drying oven to be mixed and stirred, the obtained product is placed at the room temperature and then subjected to heating curing treatment, and the carbon fiber reinforced modified resin material is obtained, so that the interface bonding strength of the composite material is remarkably improved by optimizing the formula, and the composite material has excellent mechanical properties; the composite material has a wide application prospect in the fields of aerospace, automobile manufacturing, electronics and other high-performance composite material requirements.

The invention discloses an interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material and a method. The interface covalently bonded core-shell structure boron nitride polypropylene composite dielectric material comprises a maleic anhydride grafted polypropylene matrix and a core-shell structure filler dispersed in the maleic anhydride grafted polypropylene matrix, the core-shell structure filler comprises hydroxylated boron nitride nanoparticles covalently grafted on a polymer shell layer on the surface of the core-shell structure filler; the polymer shell layer is polyglycidyl methacrylate; the epoxy group of the polymer shell layer reacts with the anhydride group of the maleic anhydride grafted polypropylene matrix to form a covalent bond. The invention has the characteristics of strong interface bonding force, uniform filler dispersion, and excellent comprehensive electrical properties and processability.

The invention belongs to the technical field of high-performance cutter coatings, and relates to a cross-scale bionic gradient coating design method based on a multi-principal-element high-entropy system, which comprises the following steps: sequentially forming a high-entropy alloy plastic layer, a high-entropy alloy / high-entropy ceramic tough layer and a nanocrystalline high-entropy ceramic superhard layer on the surface of a cutter matrix, and constructing a gradient transition structure; the method comprises the following steps: matching a high-entropy alloy plastic layer with a tool matrix binding phase, optimizing a high-entropy alloy / high-entropy ceramic tough layer material, improving interface binding force, optimizing gradient transition design by adopting thermal-mechanical coupling calculation, constructing an atomic model, simulating and optimizing a microstructure based on molecular dynamics, and establishing a finite element model to simulate thermal cycle and mechanical load. The interface performance is optimized, a mathematical model is constructed through a BP neural network and a particle swarm optimization algorithm, and gradual transition design of the tool base body and the coating is achieved. The problems that the tool coating interface is high in brittleness, insufficient in adhesiveness, limited in thermal stability and the like are solved, and the bonding performance of the coating interface and the stability and durability of the coated tool are improved.

The invention relates to the technical field of material detection, in particular to a silver coating adhesive force detection method based on multi-frequency impedance imaging, which comprises the following steps: applying a dual-mode multi-frequency excitation signal to the surface of a silver coating through an attached microelectrode array, synchronously acquiring voltage-current response data, and generating a dual-mode multi-frequency impedance original data set; performing time-varying impedance phase-locked separation on the dual-mode multi-frequency impedance original data set, extracting a dynamic impedance component of a coating-matrix interface region, and reconstructing a three-dimensional sub-interface impedance distribution diagram; and outputting an adhesive force quantized value through an oscillation frequency-adhesive force conversion model according to the spatial oscillation frequency characteristics of the impedance phase in the three-dimensional sub-interface impedance distribution diagram. According to the invention, a double-phase-locked loop system is adopted to realize the time-varying component demodulation of the impedance response of the silver coating-matrix interface, the low-frequency dynamic impedance signal modulated by silver ion migration is effectively extracted, and the weak change of the interface bonding state is sensitively reflected.

The invention discloses a series of inorganic polymeric adhesives and repair application thereof, the inorganic polymeric adhesives are oligomer structures formed by reaction of inorganic cation precursors and inorganic anions in the presence of capping agents, and the oligomer structures can be cured to form an inorganic polymeric network. The formula of the adhesive can be subjected to ion level regulation and control according to the specific composition of a to-be-repaired inorganic material product, ionic bond reconstruction between the adhesive and a base material is achieved in the heat treatment process, an inorganic interface bonding layer which is compact in structure, matched in crystal form and coordinated in thermal expansion is formed, and the adhesive has the advantages of being high in continuity, free of weak bonding areas, free of obvious pores and the like. The problems of thermal aging, falling, chromatic aberration and the like of a traditional binder can be effectively avoided, the service life of a repaired structure is prolonged, and the environmental stability is improved. The method has popularization and application potentials in the fields of aerospace, weaponry, advanced manufacturing, consumer electronics, medical health, cultural relic repair, jade repair, decorative art and the like.

The invention discloses a nano-microporous composite aerogel material and a preparation process thereof, and belongs to the technical field of aerogel materials, the composite aerogel material comprises modified PTFE dispersion liquid, SiO2 sol, a magnetic hydrophobic modifier, self-repairing microcapsules, reinforced fibers and a surface modifier. The double-shell structure of the self-repairing microcapsule provides excellent mechanical strength and chemical stability, and the self-repairing microcapsule can crack and release the siloxane prepolymer core material during microcrack propagation. The PTFE dispersion liquid is pretreated through plasma-initiated graft polymerization, so that the interface bonding force between the reinforced fiber and the composite aerogel is remarkably improved. According to the treatment method, a chemical bonding layer is formed on the surface of the fiber, and the mechanical interlocking and chemical bonding force of an interface are enhanced, so that the layering phenomenon is avoided, and the stability of the material in a repeated impact environment is further improved.

The invention relates to the field of concrete, and provides high-cracking-resistance concrete and a preparation method thereof.The concrete comprises a surface modified rubber fiber composition, surface modified end-hooked steel fibers, Portland cement, fly ash, silica fume, a superplasticizer, mineral powder, coarse aggregate, fine aggregate and water. The surface modified rubber fiber composition is composed of millimeter-sized and micron-sized rubber fibers, and is subjected to alkali treatment, oxidative sulfonation and amination modification, so that the cement compatibility and interface bonding force of the fibers are improved; the surface modified end-hooked steel fiber is subjected to dopamine hydrochloride auto-polymerization deposition and drying curing treatment, and the reinforcing effect is improved. The preparation method comprises the steps of fiber pretreatment, admixture mixing, aggregate dry mixing, slurry preparation, fiber uniform dispersion and concrete forming maintenance, and material uniformity and performance stability are ensured. By optimizing fiber modification and component proportion, the cracking resistance and durability of the concrete are improved, and the concrete is suitable for high-performance building structures and engineering application.

The invention relates to the technical field of flame-retardant materials, in particular to a halogen-free flame-retardant glass fiber modified polypropylene material and a preparation method thereof. The material comprises the following components in parts by mass: 60-80 parts of polypropylene, 15-30 parts of long glass fiber, 8-15 parts of a halogen-free intumescent flame retardant, 2-5 parts of a synergist, 3-8 parts of a compatilizer, 2-3 parts of an interface modifier, 2-4 parts of a dynamic cross-linking agent and 1-3 parts of a functional additive. According to the halogen-free flame-retardant glass fiber modified polypropylene material and the preparation method thereof, an intumescent halogen-free flame retardant melamine polyphosphate is compounded with organic montmorillonite, nano zinc borate and MXene, so that the flame-retardant efficiency is improved through a synergistic effect, and the release of smoke and toxic gas in a combustion process is inhibited; the halogen-free flame-retardant glass fiber modified polypropylene material has a good flame-retardant effect by introducing the halogen-free flame-retardant glass fiber, and maleic anhydride grafted polypropylene is introduced as a compatilizer to modify the surface of the long glass fiber and enhance the interface bonding force between the long glass fiber and a matrix.

According to the caisson wharf and the construction method thereof, a layered structure of a steel slag-rubber particle composite lower layer and a regenerated resin-basalt fiber composite upper layer is adopted for a base, and interface bonding is enhanced in combination with a silane coupling agent; the foundation bed is assembled by precast concrete modules and is poured by nano mortar; the caisson main body is provided with a positioning plate which is inserted into the guide groove, the caisson main body is filled with multi-graded steel slag fragments, and an independent airbag cavity is pre-buried in a bottom plate; the buoyancy control system dynamically adjusts the water injection rate based on multi-sensor data; the ecological permeable pipeline network adopts a diatomite-zeolite coating; the prestressed steel strand towing system is regulated and controlled in real time through the friction damper. The caisson wharf and the construction method thereof have the remarkable advantages in the aspects of structural stability, ecological friendliness, construction efficiency, intelligence and automation, the problems existing in a traditional caisson wharf can be effectively solved, and the requirements of modern port construction are met.

The invention provides a solid-state battery and a preparation method thereof, and particularly relates to the technical field of solid-state batteries. The solid-state battery is composed of a plurality of laminated units, the laminated unit comprises a positive pole piece, an all-solid-state electrolyte membrane and a negative pole piece which are sequentially stacked according to a sandwich structure; among the positive pole piece, the all-solid-state electrolyte membrane and the negative pole piece, convex structures and concave structures which are uniformly arranged are distributed on any two mutually contacted surfaces of the positive pole piece, the all-solid-state electrolyte membrane and the negative pole piece. When the components of the solid-state battery are overlapped, the convex structures and the concave structures on the surfaces of the solid-state battery can be mutually engaged to form a stable micro-embedded structure, the interface bonding strength between the positive electrode and the electrolyte and between the negative electrode and the electrolyte is greatly enhanced through physical embedding, and the problem of unstable bonding in the prior art is solved. Meanwhile, the uniform concave-convex structure ensures the controllability and consistency of the interface contact area, effectively reduces and stabilizes the interface impedance, improves the performance consistency of the pole piece, and further improves the production yield and the overall performance stability of the battery.

The invention discloses fiber reinforced concrete for bridge deck pavement and a preparation method thereof, and belongs to the technical field of concrete. The fiber reinforced concrete is prepared from the following raw materials: Portland cement, modified basalt fiber, a slow-release mineralizer, a stress-oriented dispersing aid and the like. The modified basalt fiber is a basalt fiber which is subjected to amino silanization through a silane coupling agent KH-550 and then is catalytically grafted with ethylenediamine tetraacetic acid and hydroxyethyl methylacrylate through DCC (dicyclohexylcarbodiimide); the slow-release mineralizer comprises calcium sulphoaluminate and silicon-based coated nano calcium sulfate; the silicon-based coated nano calcium sulfate is core-shell structure powder formed by coating a nano calcium sulfate core material with a silicon dioxide shell layer; the concrete is strong in interface bonding, excellent in dynamic fatigue resistance, good in durability and stable in volume, and the problem that the mechanical property, the durability and the dynamic anti-interference capability of the concrete cannot be considered at the same time is solved.

The invention relates to the technical field of coating compositions, and particularly discloses an ardealite-based heat-insulation fireproof coating and a preparation method thereof.The ardealite-based heat-insulation fireproof coating is prepared from titanium dioxide modified ardealite, hollow glass beads, styrene-acrylic emulsion, modified composite flame-retardant fibers, calcium sulfate whiskers, microencapsulated red phosphorus, redispersible latex powder, deionized water, a dispersing agent and a defoaming agent; the preparation method comprises the following steps: firstly, preparing titanium dioxide modified phosphogypsum, secondly, modifying the composite flame-retardant fiber, and finally, mixing and stirring all the components. Through the synergistic effect of the titanium dioxide modified phosphogypsum and the composite flame-retardant fiber and in combination with an ultrasonic-assisted preparation process, a double heat-insulating barrier and a synergistic flame-retardant mechanism is formed; and calcium sulfate whiskers are matched for toughening, so that the fireproof heat-insulating performance and the structural stability of the coating are improved, and the problem that the coating is easy to crack is solved.

The invention discloses a high-strength hoop and a processing method thereof in the technical field of mechanical connection fasteners. The high-strength hoop comprises the following raw materials: modified carbon fibers, a modified epoxy resin matrix, chopped glass fibers, an antioxidant and an aluminate coupling agent. Cleaning the modified carbon fibers with acetone to remove oil stains, oxidizing the modified carbon fibers with concentrated nitric acid at 80-85 DEG C to generate polar functional groups containing hydroxyl and carboxyl, washing the modified carbon fibers with water until the modified carbon fibers are neutral, drying the modified carbon fibers, immersing the modified carbon fibers into an absolute ethyl alcohol solution of an aluminate coupling agent for ultrasonic dispersion, and curing the modified carbon fibers at 100-105 DEG C; the modified epoxy resin matrix is prepared by heating and melting epoxy resin, adding nano montmorillonite, stirring and dispersing, adding polyamide, an accelerant and a flexibilizer, and carrying out vacuum defoaming at 100-105 DEG C. The hoop has the advantages of high strength, weather resistance and the like by modifying and enhancing interface bonding and matrix toughness, and is suitable for connection under complex working conditions.

The invention discloses an anode material for adipic acid monoester electrolysis and a preparation method of the anode material, the electrode solves the key problems that a platinum layer is easy to fall off, the catalytic activity is low, the organic matter poisoning resistance is poor and the like of a traditional titanium platinum-plated electrode through multi-scale interface strengthening and nano structure regulation and control; the preparation method comprises the following core steps: constructing a porous ZrO2-TiO2 composite oxide layer on the surface of a titanium substrate by adopting a micro-arc oxidation-hydrothermal composite process, and generating platinum nanoparticles in situ to pre-fill pores, so that the anchoring effect of a platinum layer is remarkably enhanced; depositing a platinum / carbon nano tube (Pt / CNT) composite catalyst layer on the surface of the oxide layer through a pulse-ultrasonic synergistic electroplating technology, wherein the carbon nano tube is used as a conductive framework to inhibit platinum agglomeration; through vacuum annealing and electrochemical activation treatment, the interface bonding force and active site exposure are further optimized; the electrode shows excellent performance in an adipic acid monoester electrolysis system, and efficient electrocatalytic conversion from adipic acid monomethyl ester to dimethyl sebacate is achieved.

The present invention relates to the technical field of concrete. Disclosed is a toughening design method for fiber-reinforced concrete. The method of the present invention changes the passive control characteristics of fibers on a concrete crack propagation process in conventional fiber-reinforced concrete. Starting from the origin of composite material design, firstly, an ultrahigh-ductility composite cementitious matrix is designed; and secondly, an aggregate is incorporated. On the basis of a specific combination of matrix and aggregate parameters, a composite material develops meso-scale multiple cracking and strain-hardening behaviors between aggregate particles during external loading. The fiber-reinforced concrete prepared by this method actively disperses brittle damage and failure within the material, and avoids unstable crack propagation caused by weak interfacial bonding between the aggregate and the matrix. Compared to conventional fiber-reinforced concrete design methods, the present invention more accurately establishes relationships between material compositions, microstructures and macroscopic mechanical response, and more efficiently enhances the toughness of the material.

The invention relates to the technical field of capacitor films. The invention discloses a preparation process of a high-performance polypropylene capacitor film. The preparation process comprises the following steps: A1, preparing a polypropylene capacitor film; a2, carrying out surface cleaning and activation pretreatment on the polypropylene capacitance film; a3, evaporating a gradient modified layer on the surface of the pretreated polypropylene capacitance film; a4, carrying out laser plasma synergistic treatment and crystallinity regulation and control on the modified polypropylene capacitor film; and A5, coating the outer layer of the modified polypropylene capacitance film with a functional layer, and carrying out annealing post-treatment to prepare the high-performance polypropylene capacitance film. The mechanical strength and the electrical stability are improved through nano filler dispersion, two-way stretching and crystallinity regulation and control; through the collaborative design of surface cleaning and activation and a gradient functional layer, excellent interface bonding force and environmental adaptability are given; and by means of technologies such as multi-source evaporation and laser plasma co-processing, precise regulation and control and diversified expansion of the performance are achieved, the method is suitable for various scenes, and the process repeatability is good.