This invention discloses a method for preparing a high-adhesion flake-shaped
zinc powder pigment, belonging to the field of functional
pigment preparation technology. The preparation steps are as follows: spherical
zinc powder is ball-milled using prismatic irregular
grinding media to obtain micro-serrated flake-shaped
zinc powder; purified
phosphate coupling agent,
methyl methacrylate, high-purity
citric acid, and a self-made high-acid-value
copolymer dispersant are mixed in proportion, and ultrasonically dispersed with
ethanol to prepare a composite modification liquid; the flake-shaped zinc powder is added to the modification liquid according to the liquid-
solid ratio, and after gradient heating reaction,
centrifugation, gradient
ethanol washing, and
vacuum drying, modified zinc powder is obtained; after classification, fine, medium, and
coarse particle sizes are mixed in proportion to obtain the target
pigment. The high-acid-value dispersant in this invention inhibits agglomeration through strong adsorption and steric hindrance, synergistically with the
coupling agent and monomers to construct an active graft layer, and combined with the serrated structure to strengthen physical anchoring and chemical bonding. It exhibits stable dispersion and excellent mechanical properties, meeting the
high adhesion and high
corrosion resistance requirements of industrial coatings.