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1387 results about "Hydrophobic monomer" patented technology

The effective transportation of monomer from monomer droplets through the water phase into particles is a crucial step in the emulsion polymerization of hydrophobic monomers with very low water solubility, such as VeoVa™ 10 monomer (vinyl ester of neodecanoic acid) or isodecyl methacrylate (IDMA).

Temperature-resistant salt-resistant efficient gel, and preparation and use thereof

The invention discloses a temperature resistant salt tolerant high efficiency gel and a preparation method and application thereof. The preparation method is characterized in that the preparation method comprises the following steps: preparing a comb-shaped associated copolymer PAH containing macromonomers and functional hydrophobic monomers into an aqueous solution having the concentration of 0.1 to 4g/L, the crosslinking agent concentration of 0.01 to 1.0g/L, the surfactant concentration of 0.01 to 8mmol/L and the sodium sulfite thermal stabilizer concentration of 0.005 to 1.0g/L; adding the aqueous solution into a mixing container with a stirring device; stirring the aqueous solution evenly at the room temperature; regulating the pH value of the solution to be equal to between 4 and 11, and obtaining a temperature resistant salt tolerant high efficiency gel polymer solution system used for tertiary oil recovery and scavenge, displacement modification, profile modification or water shutoff. The polymer solution system has micro-crosslinking to form the gel during the flowage inside the oil reservoir. The gel has good elasticity, not easy dehydration, stable gelling performance, and excellent tackification, temperature resistance, salt tolerance, shearing resistance and ageing resistance.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY

Harsh oil deposit reversed-phase microemulsion profile-control flooding system and preparation method thereof

The invention relates to a harsh oil deposit reversed-phase microemulsion profile-control flooding system and a preparation method thereof. The problems in the prior art that the initial particle size of the product is improper and polymeric microspheres are poor in expansibility under high-temperature high-salt conditions are mainly solved. The harsh oil deposit reversed-phase microemulsion profile-control flooding system disclosed by the invention comprises the following components in parts by weight of microemulsion: 20-70 parts of an oil-soluble solvent, 5-20 parts of an emulsifier and a co-emulsifier, 20-70 parts of a polymer aqueous phase containing acrylamide and other temperature-resistant salt-resistant comonomers. According to the technical scheme, a semi-continuous reaction method is adopted, the aqueous phase containing acrylamide and other temperature-resistant salt-resistant comonomers is added into an oil phase containing the emulsifiers in batches, and a hydrophobic monomer is added, so that the problems are solved, the prepared polyacrylamide reversed-phase microemulsion is directly compounded or is compounded with other oil field chemicals to be applied to such field applications for improving oil recovery as depth profile control, water plugging and displacement in tertiary oil recovery of a harsh oil deposit.
Owner:CHINA PETROLEUM & CHEM CORP +1

Hydrophobically-associating polyacrylamide fracturing fluid thickener, preparation method and applications thereof

The present invention relates to a hydrophobically-associating polyacrylamide fracturing fluid thickener, a preparation method and applications thereof. In the prior art, the polyacrylamide polymer fracturing fluid thickener has disadvantages of insufficient temperature resistance, incomplete gel breaking and instability at high temperature and high shearing. A purpose of the present invention is mainly to solve the problems in the prior art. The hydrophobically-associating polyacrylamide fracturing fluid thickener is prepared by carrying out a reaction on a reaction system comprising components of 15-50 parts by weight of acrylamide, 1-50 parts by weight of a cationic monomer or anionic monomer, 1-20 parts by weight of a nonionic monomer, 0.01-0.5 part by weight of a hydrophobic monomer, 0.001-0.005 part by weight of a molecular weight regulator, 0.0001-0.0005 part by weight of a composite initiator, and 30-80 parts by weight of water. With the technical scheme, the problems in the prior art are well solved. According to the present invention, the hydrophobically-associating polyacrylamide fracturing fluid thickener can be separately applied in the oil and gas field fracturing process, or can be compounded with other auxiliary agents so as to be adopted as the fracturing fluid thickener applied in the oil and gas field fracturing process.
Owner:CHINA PETROLEUM & CHEM CORP +1

Non-linear associating water-soluble quadripolymer, and preparation and use thereof

The invention discloses a non-linear associated water soluble quadripolymer as well as a preparation method and use thereof, comprising: adding 20 parts of acrylamide, 1-20 parts of nionic monomer or/and cationic monomer, 0.1-15 parts of macromonomer, 0.05-10 parts of hydrophobic monomer, 0.1-50 parts of surfactant and 60-1000 parts of deionized water to a three-necked reaction flask, adjusting the pH to be 3-9, adding 0.002-1 part of initiator (persulphate) at 30-75 DEG C after introducing N2 for 30min, reacting for 8-36h to obtain the quadripolymer PACH, diluting with water, and obtaining concentrated PACH solution. The macromonomer with a long chain and the hydrophobic monomer with a molecular association function are simultaneously introduced in a copolymer PACH, which can obtain the best synergistic viscosifying between rigid conformation of a molecular chain and molecular association and salt resistance. The non-linear associated water soluble quadripolymer is obtained. The copolymer is prepared into aqueous solution with the mass concentration of 0.2-3g/l and the surfactant concentration of 0.01-2mmol/l, added to a mixing vessel with a stirring device and evenly stirred at the room temperature to obtain a viscosified, salt-resistant and shear-resistant polymer oil displacement agent. The PACH has dual functions of a viscosifier and a high molecular surfactant; minute amount of a low molecular surfactant is added to the PACH solution, thus improving the apparent viscosity of the solution, reducing the surface tension of solution and the water-oil interfacial tension, and being beneficial to improving the crude oil recovery ratio. A copolymer PABE is prepared into the aqueous solution with the mass concentration of 0.05-7% to obtain high molecular surfactant with excellent surface activity, and the high molecular surfactant is used as an emulsifier, a demulsifier, a solubilizer and a wetting agent.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY
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