The invention relates to a composite modified hydration
heat regulation material.
Starch is firstly reacted with an acid catalyst and a crosslinking agent, and then a product is reacted with alkenyl
succinic anhydride to obtain the composite modified hydration
heat regulation material, wherein the amount of the acid catalyst is 5 to 25 % of the
mass of the
starch, the amount of the crosslinking agent is 1 to 5% of the
mass of the
starch, and the amount of the alkenyl
succinic anhydride is 10 to 30% of the
mass of the
starch. The invention also provides a preparation method and application of the hydration
heat regulation material. The regulation material is prepared by a starch crosslinking reaction, and has a
spatial network structure, and
high resistance to acid and alkali and high
shear resistance, the
peak value of the hydration heat release rate can be effectively reduced, and the
compressive strength of concrete is improved; meanwhile, by introducing a polar acetyl functional group, the polarity characteristic of the hydration heat regulation material is improved, the number of intermolecular
hydrogen bonds is reduced, and the freeze-thaw property of the material is improved; and the modified hydration heat regulation material has the advantages of reducing the
surface tension of a
cement pore solution, generating independent closed bubbles, also playing an air entraining role of a three-dimensional
network structure, improving the freeze-thaw property of concrete, and being favorable for the practical application of the hydration heat regulation material.