The invention provides a power battery and a lithium ion electrolyte thereof. The lithium ion electrolyte comprises a non-aqueous organic solvent, lithium salt and an additive, wherein the additive comprises a first additive and a second additive, and the first additive comprises silane sulfate; the first additive accounts for 0.05 to 10% of the total weight of the electrolyte, and the second additive is an auxiliary additive and comprises one or more of vinylene carbonate, propane sultone, fluoroethylene carbonate, vinyl ethylene carbonate, ethylene sulfite, adiponitrile, and succinic anhydride in any proportion; the second additive accounts for 0.1-5wt% of the total weight of the electrolyte, and the non-aqueous organic solvent is a carbonic ester solvent, a carboxylic ester solvent, an ether solvent or a ketone solvent; and the lithium salt comprises primary lithium salt and secondary lithium salt.