The invention belongs to the technical field of
sodium ion battery negative
electrode materials, and discloses an
asphalt-based hard carbon material for a
sodium ion battery and a preparation method of the
asphalt-based hard carbon material. The 3, 4, 9, 10-
perylenetetracarboxylic dianhydride is adopted as the cross-linking agent, the
doping amount of the 3, 4, 9, 10-
perylenetetracarboxylic dianhydride is only 10-30% of the
mass of the
asphalt, and the reversible
sodium storage capacity of the asphalt can be remarkably improved under the condition limited by the invention. In an
oxygen atmosphere, an anhydride group of 3, 4, 9, 10-
perylenetetracarboxylic dianhydride and an
oxygen-containing functional group in asphalt are subjected to a cross-linking reaction, and a formed cross-linking structure effectively inhibits melting rearrangement in an asphalt
carbonization process, so that the electrochemical performance of the sodium-
ion battery hard carbon negative
electrode material is remarkably improved. According to the prepared asphalt-based hard carbon negative
electrode material, 1 mol / L NaPF6-EC / DEC is used as an
electrolyte, and under the
current density of 20 mA / g, the initial coulombic efficiency reaches 75.64%, and the reversible capacity is 319.76 mAh / g; and under the
current density of 200mA / g, the reversible capacity can still reach 189.14 mAh / g.