2913 results about "Sorbent" patented technology

A direct air capture (DAC) of CO2 system includes a reaction reactor having a solid, amine-functionalized sorbent configured to sequester CO2 from air; an in-situ dual-function device configured as a CO2 conversion reactor and an exchange fluid regeneration device; and the exchange fluid, recirculating between the reaction reactor and the dual-function device, configured to capture the sequestered CO2 from the solid sorbent in the reaction reactor and release the captured CO2 in the conversion reactor, the exchange fluid including one or more amino acids.

An atmospheric CO2 capture system includes a compartment housing a solid CO2 sorbent, an exchange fluid including a chemical component with selectivity towards CO2, and an electrochemical cell or mineralization reactor in fluid communication with the compartment, the system having a cycle including a first state of sorbing CO2 from incoming air onto the solid CO2 sorbent until a saturation point is reached; a second state of regenerating the sorbent by flooding the compartment with the exchange fluid to detach CO2 from the saturated sorbent and bind the detached CO2 to the chemical component; and a third state of regenerating the chemical component and utilizing the CO2 in the electrochemical cell or mineralization reactor.

The invention discloses a production method and a production device of an energy-saving sustainable aviation fuel, and the production method comprises the following steps: S1, adsorbing carbon dioxide in air by using an adsorbent, desorbing through high-temperature carrier gas, and cooling and compressing the desorbed carbon dioxide; s2, carbon dioxide and deionized water are preheated and then electrolyzed, and synthesis gas and oxygen are generated; s3, after the synthesis gas is compressed, performing Fischer-Tropsch reaction to generate a mixture of Fischer-Tropsch oil wax, light hydrocarbon and water, cooling and separating, and returning the Fischer-Tropsch reaction heat to preheat the synthesis gas; s4, pressurizing the Fischer-Tropsch oil wax, mixing the Fischer-Tropsch oil wax with hydrogen, carrying out hydrofining reaction to generate a gas-liquid isomerous oil-gas mixture, cooling and separating, and recycling heat energy of a product to And S5, after gas-liquid separation, preheating a liquid phase, carrying out rectification operation, separating and cooling to obtain a sustainable aviation fuel product. By recovering the heat in each link, the heat is efficiently utilized, and the energy-saving performance of production is improved.

The invention relates to the technical field of drying equipment, in particular to a low-consumption constant-temperature dehumidification device and a control method, and achieves an efficient and energy-saving constant-temperature dehumidification effect. The heat recovery module recovers heat in the condensation and regeneration process, the collaborative optimization module coordinates operation of all the modules, the energy utilization efficiency is remarkably improved, and energy consumption is reduced. The control system module dynamically adjusts the state of each module according to the real-time data of the temperature and humidity sensor, ensures the stability of the environment temperature and humidity, and further improves the control precision by adopting a dynamic decoupling control strategy. The regeneration module utilizes recovered heat energy to efficiently regenerate adsorbents and cooperates with novel composite adsorbents, the service life of the adsorbents is prolonged, and the dehumidification performance is improved. The air circulation module forms uniform airflow, and local temperature and humidity unevenness is avoided. A user can set parameters through the interaction unit, the system is controlled to automatically adjust the operation strategy, intelligent operation is achieved, and the system performance is optimized.

An atmospheric CO2 capture system includes a compartment housing a solid CO2 sorbent, an exchange fluid including a chemical component with selectivity towards CO2, and an electrochemical cell or mineralization reactor in fluid communication with the compartment, the system having a cycle including a first state of sorbing CO2 from incoming air onto the solid CO2 sorbent until a saturation point is reached; a second state of regenerating the sorbent by flooding the compartment with the exchange fluid to detach CO2 from the saturated sorbent and bind the detached CO2 to the chemical component; and a third state of regenerating the chemical component and utilizing the CO2 in the electrochemical cell or mineralization reactor.

The invention provides a method for selecting a high-concentration VOCs adsorbent at different temperatures and application, and belongs to the technical field of waste gas governing. According to the method, through testing pore structure parameters of a model adsorption material with concentrated pore size distribution, a static adsorption isotherm and a dynamic penetration curve for VOCs at different temperatures, a high-concentration VOCs adsorbent is obtained; a linear relation equation of the critical aperture and the critical pressure is established through linear fitting, then a correlation equation of the critical aperture, the temperature and the partial pressure is established, and the appropriate aperture distribution range and the model selection standard of the high-concentration VOCs adsorbent at different temperatures are determined by combining dynamic adsorption results. According to the method, the ternary matching relation equation of the VOCs partial pressure, the temperature and the critical aperture is constructed, accurate type selection of the high-concentration VOCs adsorbent at different temperatures is achieved, the pore volume utilization rate and the adsorption capacity can be improved, meanwhile, desorption energy consumption and the VOCs pyrolysis risk are reduced, and a theoretical basis is provided for adsorbent type selection and technical optimization.

A gas-liquid contactor for capturing carbon dioxide from atmospheric air includes at least one inlet; at least one outlet spaced apart from the at least one inlet; a gas-sorbent interface disposed between the at least one inlet and the at least one outlet; a liquid distribution system configured to flow a CO2 capture solution along the gas-sorbent interface; at least one gas-circulating device configured to flow atmospheric air along a flow path to contact the atmospheric air with the CO2 capture solution and absorb CO2 from the atmospheric air into the CO2 capture solution to form a CO2-lean gas stream flowable through the at least one outlet, wherein the CO2-lean gas stream is deflected from a downward direction to an upward direction causing at least a portion of aerosolized particles in the CO2-lean gas stream to exit said CO2-lean gas stream upstream of the at least one outlet.

The invention provides an activated carbon adsorption and desorption system and an activated carbon adsorption and desorption method. Performing bed layer heat storage compensation on the standard temperature in the desorption link according to the temperature fluctuation characteristic of the adsorption bed layer in the adsorption link and the environment temperature of the adsorption bed layer to obtain the heat storage compensation temperature of each desorption stage in the desorption link; performing stage desorption on the activated carbon adsorbent based on the desorption duration of each desorption stage in the desorption link and all the heat storage compensation temperatures, and extracting the desorption residual quantity of pollutants in the activated carbon adsorbent from the pollutant concentration information of a stage desorption outlet; the effective desorption rate of the activated carbon adsorbent is determined according to the desorption residual quantity and the current adsorption capacity, and the critical adsorption capacity of the activated carbon adsorbent in the next cycle is cyclically updated based on the effective desorption rate. Based on the scheme, bed layer heat storage compensation in activated carbon critical adsorption capacity updating can be achieved.

A system for capture of atmospheric CO2 includes a reaction reactor having a solid sorbent; and a mineralization reactor downstream from the reaction reactor, the system having three states including in the reaction reactor, a first state of sequestering CO2 from air into the solid sorbent; in the reaction reactor, a second state of releasing the sequestered CO2 from the sorbent by contacting the CO2-enriched sorbent with an exchange fluid having one or more amino acids and forming a CO2-enriched exchange fluid; and in the mineralization reactor, a third state of reacting the sequestered CO2 from the CO2-enriched exchange fluid with an alkaline feedstock to form a carbonate while regenerating the exchange fluid.

The invention relates to the technical field of gas separation and purification, in particular to a method and system for recycling hydrogen in mixed gas through pressure swing adsorption. The method comprises the following steps: performing multi-layer adsorption impurity removal on mixed gas containing 20-25% of silane, 10-15% of disilane and 60-70% of hydrogen, and cooling to 22-28 DEG C; the mixed gas subjected to primary impurity removal enters a pressure swing adsorption device, and an adsorbent in the adsorption device is modified activated carbon. The system comprises a mixed gas cylinder, a pretreatment unit, a pressure swing adsorption unit and a hydrogen collection unit which are connected in sequence. By adopting the pressure swing adsorption method, the hydrogen recovery rate is remarkably increased and can reach 93%, the purity can reach 99.2% or above, and the strict requirement of high-end industrial production for high-purity hydrogen can be met.

The utility model discloses a bitter apricot kernel wastewater treatment device which comprises an equipment shell, a water inlet pipe and a water outlet pipe are respectively arranged on the equipment shell, and a wastewater treatment assembly communicated with the water inlet pipe and the water outlet pipe is arranged in the equipment shell; the wastewater treatment assembly comprises a plurality of groups of apricot shell adsorption tanks which are connected in series, apricot shells are filled in the apricot shell adsorption tanks and are used as adsorbents, the apricot shells adsorbing hydrocyanic acid are subjected to carbonization treatment, and the hydrocyanic acid is destroyed in the carbonization treatment process and forms a part of pyroligneous liquor; the hydrofluoric acid on-line detector is arranged at the downstream of the apricot shell adsorption tank and is used for detecting the content of hydrofluoric acid in the treated wastewater; the control valve group is connected to the water inlet pipelines and the water outlet pipelines of the apricot shell adsorption tanks and is used for controlling the working states of the multiple groups of apricot shell adsorption tanks. The device is efficient in use, easy to operate, low in maintenance cost, safe and reliable, hydrofluoric acid is eliminated in the carbonization process, waste water is recycled, and water resources are saved.

The present application belongs to the technical field of gaseous arsenic adsorption, and particularly relates to a sulfur-tolerant gaseous arsenic adsorption material, a preparation method and application thereof. Manganese oxide and an iron source are mixed and placed in a ball mill jar, then the ball mill jar is sealed, argon is filled into the jar, and the iron-modified manganese oxide adsorption material is obtained by ball milling. The addition of iron improves the sulfur tolerance of manganese oxide, so that the adsorbent still has high gaseous arsenic adsorption capacity under high-concentration SO2 conditions, and is suitable for the removal of gaseous arsenic in typical high-SO2 flue gas, i.e. non-ferrous smelting flue gas. The preparation method is simple, the cost is low, the gaseous arsenic adsorption capacity is large, and the present application has a wide application prospect.

The application discloses a porous aluminum-based carrier and a preparation method thereof, a CO2 adsorbent and application thereof. The preparation of the porous aluminum-based carrier comprises the following steps: segmental aging: a solution containing pseudo-boehmite is subjected to two-stage aging, the first stage is stirring aging, and the second stage is standing aging, the two kinds of aging modes are combined to improve the crystallinity of the pseudo-boehmite; organic solvent washing and pore expansion: the pseudo-boehmite is filtered out, and is subjected to water washing first and then organic solvent washing; segmental drying: low-temperature air blowing drying and vacuum drying are combined, the drying mode, the drying temperature and the solvent evaporation rate during drying are adjusted to avoid pore shrinkage or collapse caused by excessively high drying temperature and excessively fast solvent evaporation speed. The preparation of the porous aluminum-based carrier is simple in operation and low in energy consumption, and the CO2 adsorbent prepared from the porous aluminum-based carrier and an organic amine has excellent adsorption performance such as high adsorption capacity, fast adsorption rate and high stability.

The invention relates to the technical field of glass cleaning agents, in particular to an environment-friendly cover plate glass cleaning agent and a preparation method thereof. The environment-friendly cover plate glass cleaning agent comprises the following raw materials in percentage by weight: 12-20% of inorganic base, 8-12% of a surfactant, 5-8% of a chelating agent, 3-5% of a humectant, 1-3% of an adsorbent, 1-3% of a dispersing agent, 0.3-1% of a buffering agent and the balance of deionized water, the surfactant is dodecyl glucoside and dodecyl ethyoxyl sulphobetaine, and the weight range ratio of the dodecyl glucoside to the dodecyl ethyoxyl sulphobetaine is (3-1): 1; the chelating agent is one or more of sodium gluconate, sodium polyaspartate and sodium polyepoxysuccinate. According to the present invention, the degradable surfactant and the degradable chelating agent are adopted, and the dispersant is added to modify the nanometer titanium dioxide, such that the low pollution property is achieved while the high decontamination efficiency and the anti-fingerprint ability are considered.

The invention discloses a gas purification real-time monitoring method, system and device and a medium, and belongs to the technical field of gas purification. The method comprises the following steps: a data acquisition stage: acquiring inlet gas flow and outlet component data; in the adsorbent state monitoring stage, the adsorbent state is monitored in real time through the monitoring point position in the adsorption barrel; in the adsorption capacity calculation stage, the residual adsorption capacity is predicted through an impurity penetration curve model on the basis of inlet flow and outlet component data, and bidirectional verification and correction are carried out on the residual adsorption capacity and an internal monitoring state; in the regeneration time prediction stage, the optimal regeneration time is dynamically predicted according to discharged gas component analysis and residual adsorption capacity; in the real-time regulation and control stage, parameters of the purifier and the regenerative heater are adjusted in real time according to the prediction result. Accurate evaluation of the state of the adsorption cylinder and intelligent optimization of the regeneration process are achieved, the utilization rate of the adsorption cylinder is remarkably increased, and the total energy consumption of regeneration is reduced.

The invention discloses surface hydroxylation modified mesoporous SiO2, a preparation method of the surface hydroxylation modified mesoporous SiO2 and a SiO2-based solid amine adsorbent. The preparation method comprises the following steps: dispersing waste glass powder into a first alkali solution, and reacting under a heating condition to obtain a sodium silicate solution; the concentration of the first alkali solution is 20-30 g / L; introducing carbon dioxide into the sodium silicate solution to obtain mesoporous SiO2; dispersing the mesoporous SiO2 into a second alkali solution, and carrying out heating treatment, so as to obtain surface hydroxylation modified mesoporous SiO2; and the concentration of the second alkali solution is 0.2-3 g / L. The glass powder is subjected to silicon extraction in an alkali dissolution mode to obtain the Na2SiO3 solution, the silicon recovery rate of 92% can be achieved, the prepared surface hydroxylation modified mesoporous SiO2 can be used as a carrier, PEI is loaded through a physical dipping method, the SiO2-based solid amine CO2 adsorbent is prepared, and on the basis of maintaining the high CO2 adsorption capacity, the CO2 adsorption capacity is greatly improved. The long-term stability of the solid amine adsorbent in an O2-containing environment can be maintained, and the service life and the long-term cyclic adsorption performance of the solid amine adsorbent are greatly improved.

The invention relates to a continuous production method of high-purity tetraethoxysilane, and belongs to the technical field of tetraethoxysilane preparation. The method comprises a raw material pretreatment stage and a purification and rectification stage: in the pretreatment stage, silicon tetrachloride and ethanol are subjected to an esterification reaction in a molar ratio of 1: (3-4) under the protection of nitrogen, the pH is adjusted to be neutral through triethylamine, and triethylamine hydrochloride is removed through reduced pressure distillation; then, a cerium oxide-molecular sieve composite adsorbent with the specific surface area larger than or equal to 800 m / g and the pore diameter of 2-5 nm is adopted for dehydration under the pressure of 0.8-1.2 MPa till the water content is smaller than or equal to 5 ppm, and volatile impurities are removed through high-purity nitrogen purging; in the purification stage, metal ions and Cl are synergistically removed through a titanate modified resin layer and a nano TiOtube layer, and then step-by-step separation is performed through a four-stage differential pressure rectifying tower. Through collaborative optimization of structural design of the composite adsorbent, construction of an organic-inorganic hybrid interface of the resin layer and pressure gradient rectification, 72-hour continuous production is achieved, the single-pass yield of the product is 92%, and the total amount of metal impurities is smaller than or equal to 5 ppb.

The invention relates to a gas nanometer purification method and a purifier, and the method comprises the following steps: gas to be cleaned enters a gas-water separator for gas-liquid separation and coarse filtration, liquid impurities and large-particle solid impurities in the gas are removed, and preliminarily purified gas is obtained; on the basis of switching logic, the preliminarily purified gas is alternately conveyed to two adsorption unit groups for deep adsorption purification, adsorbent dehydration treatment and fine dust interception treatment are sequentially completed in the adsorption units, and clean gas is obtained; one part of the clean gas is conveyed to the gas storage bin to be stored, and the other part of the clean gas is conveyed to the regeneration gas bin to be pre-stored for regeneration cycle of the subsequent adsorption unit. Through the integrated method design of continuous adsorption working conditions, online regeneration cycle and automatic pressure equalizing switching, seamless connection of adsorption and regeneration and uninterrupted gas supply in the whole process are achieved, gas supply interruption and severe gas pressure fluctuation are effectively avoided, and the strict use requirements of precise manufacturing, automatic production lines and continuous production scenes for stable gas sources can be met.

The invention discloses a micropore-rich carbon adsorbent and application thereof in separation of mixed gas of sulfur hexafluoride and nitrogen, and the micropore-rich carbon adsorbent is prepared by taking cellulose acetate as a precursor, performing low-temperature pre-carbonization treatment in an inert atmosphere, mixing with KOH, performing high-temperature activation in the inert atmosphere, and finally washing and drying. The carbon adsorbent prepared by a unique two-step method of low-temperature pre-carbonization and high-temperature activation has an extremely high specific surface area (1100-1700m < 2 > / g) and a pore channel structure mainly comprising micropores (the pore diameter is concentrated in 0.5-0.8 nm). The adsorbent shows ultrahigh adsorption capacity (the adsorption capacity can reach 2.83 mmol / g at the temperature of 25 DEG C and the pressure of 0.1 bar) on SF6. The carbon adsorbent disclosed by the invention is simple in preparation method, low in raw material cost and environment-friendly, and has a wide application prospect in the field of SF6 recovery and purification.

The utility model discloses an adsorption cylinder for catalytic adsorption and purification of gas, which is cylindrical and is characterized in that a plurality of purification flow channels with inwards gradually reduced cross sections are uniformly distributed on the peripheral wall of the adsorption cylinder, and a layer of catalytic adsorption material is arranged on the inner wall of each purification flow channel. The utility model further discloses an adsorption bed structure adopting the adsorption cylinder. According to the adsorption cylinder and the adsorption bed structure thereof disclosed by the utility model, adsorption is realized on the basis of the arc-shaped reducing purification runner, the adsorption treatment and purification efficiency can be better improved, the adsorption rate and the adsorption material consumption rate at each position can be matched so as to improve the utilization efficiency of an adsorbent material, and the regeneration treatment of the adsorbent material is facilitated.

An exchange fluid having one or more amino acid for removing carbon dioxide from a solid sorbent and systems containing the same are disclosed. The exchange fluid may further include a neutralizing base for neutralizing the amino acid. The system may further employ an electrochemical cell to regenerate the exchange fluid by removing carbon dioxide from the exchange fluid without employing degrading temperatures and pressures.

The invention provides a device and a method for detecting antibiotics in aquaculture water, and belongs to the technical field of environmental pollutant detection. According to the device disclosed by the invention, a Fe3O4 (at) GO magnetic nano adsorption material is packaged in a micro-fluidic chip reaction chamber, and a magnetic sticker is innovatively adopted to realize immobilization and replaceable design of an adsorbent; the integrated electromagnetic oscillation module drives the adsorbent to vibrate in the microchannel, and the mass transfer capture efficiency of antibiotics such as sulfonamides, quinolones and tetracyclines is remarkably improved. According to the method, an adsorption-elution-detection integrated process is initiated for the first time, the pretreatment time is shortened to be within 10 minutes from the hour level, synchronous detection of 0.01-5 [mu] g / L ultra-trace multi-component antibiotics in 5-10 [mu] L of a water sample is achieved, compared with a traditional method, the detection precision is remarkably improved, the matrix interference resistance is high, and the method is suitable for large-scale popularization and application. The method is suitable for real-time online monitoring of multiple antibiotic residues in the aquaculture environment.

The invention belongs to the technical field of organic matter extraction, and particularly relates to a green directional extraction and purification method for haematococcus astaxanthin, which comprises the following steps: (1) mixing dried haematococcus powder and a composite pretreatment agent according to a mass ratio of 1: (8-15), and stirring to obtain a pretreated algae solution; (2) treating the pretreated algae liquid through ultrahigh-pressure microjet equipment to obtain wall-broken slurry; (3) mixing the wall-broken slurry and a composite extraction agent according to a volume ratio of 1: 3-1: 5, and performing extraction separation to obtain an astaxanthin extraction phase; (4) carrying out selective adsorption on the astaxanthin extraction phase through an adsorption column filled with a molecular imprinting adsorbent; (5) collecting eluent by adopting a gradient elution method; and (6) performing vacuum concentration on the eluent, and performing spray drying to obtain an astaxanthin product. According to the method, the astaxanthin extraction efficiency and the product purity are remarkably improved, meanwhile, the energy consumption is reduced to the maximum extent, toxic solvent residues are avoided, and the stability of the astaxanthin is effectively protected.

The invention discloses a composite adsorbent for removing tetracycline in wastewater and a preparation method thereof, and relates to the field of wastewater treatment.The preparation method comprises the following steps that gasified slag and corn roots are pretreated and then mixed and pyrolyzed to prepare a magnetic biochar substrate, the magnetic biochar substrate is dispersed in a solvent, copper salt and organic ligands are added, and the magnetic biochar substrate is obtained; and collecting products through an external magnetic field to obtain the composite adsorbent for removing tetracycline in wastewater. A copper-based metal organic framework material grows in situ on a gasified slag / corn root biochar substrate, and the specific surface area of the material is increased by using a highly ordered porous structure of MOF; through the combined action of various mechanisms, the adsorbent shows extremely high adsorption capacity and good selectivity on tetracycline molecules.

The invention discloses a composite hydrogel adsorbent and a preparation method and application thereof, and belongs to the technical field of wastewater treatment.The preparation method comprises the specific steps that S1, neutralized acrylic acid, acrylamide and a cross-linking agent are added into deionized water and stirred to be uniform, and a precursor solution is obtained; s2, adding alkali-activated fly ash into the precursor solution, uniformly mixing, sequentially adding alkali liquor and an initiator, and fully stirring for reaction to obtain a mixed solution; and S3, curing the obtained mixed solution in a mold, washing with water, and drying to obtain the composite hydrogel adsorbent. According to the invention, the reaction system is optimized, so that the super-fast polymerization curing of the hydrogel is realized; the prepared composite hydrogel has excellent mechanical property and metal ion adsorption property; the whole preparation process is simple to operate, high in gel forming speed, free of light / heat initiation, mild in condition and low in cost, and can be applied to adsorption of heavy metal ions in wastewater.

Sorbent materials for the adsorption of hydrocarbons and methods for manufacturing them are described. The sorbents include a slurry of activated carbon and a porous sheet layer permeable to hydrocarbons configured to remove emissions from air intakes. The methods for manufacturing the sorbent materials include providing both a hydrocarbon permeable layer and a slurry that includes the sorbent material, drying the slurry, and affixing the dried slurry layer to the surface of the hydrocarbon permeable layer.

A system for gas separation includes a first housing, a first reactor section that includes first adsorbent beds that are disposed within the first housing, a second housing, and a second reactor section that includes a second adsorbent bed disposed within the second housing. The first adsorbent beds (i) include respective solid sorbents configured to adsorb target molecules from a fluid stream that is subject to the gas separation and (ii) are arranged in parallel with respect to each other and relative to a flow direction of the fluid stream. The second adsorbent bed (i) includes a respective solid sorbent configured to adsorb the target molecules from the fluid stream and (ii) is staged in series relative to the first adsorbent beds and the flow direction. Each of the first adsorbent beds has a volume that is different from a volume of the second adsorbent bed.

The invention provides a high-concentration volatile organic compound shallow cooling adsorption and desorption method based on filling type adsorption, and belongs to the technical field of waste gas treatment. According to the method, the pore structure parameters of a model adsorption material with concentrated pore size distribution and the static adsorption isotherm and dynamic penetration curve of VOCs at different temperatures are tested; a linear relation equation of critical aperture and critical pressure is established through fitting, a correlation equation of the critical aperture, temperature and partial pressure is constructed, dynamic adsorption capacity is calculated, and the low-temperature strengthening method suitable for dynamic adsorption is determined by combining a shallow cold adsorption and desorption strategy. According to the method, a ternary matching relation equation among VOCs partial pressure, adsorbent aperture and adsorption temperature is constructed, the critical aperture under a specific adsorption condition is calculated, a low-temperature enhanced VOCs shallow cold adsorption and desorption technology is developed, the desorption difficulty is reduced while the pore volume utilization rate and the adsorption capacity are improved, and a support is provided for adsorbent type selection and adsorption technology optimization.

The invention relates to a renewable industrial flue gas carbon dioxide adsorbent and a preparation method thereof. The method comprises the following steps: S1, mixing alkali metal, an aluminum oxide precursor, silicon oxide and a first solvent, or mixing an alkali metal solution, the aluminum oxide precursor, the silicon oxide and an optional second solvent, and then molding the mixed material to obtain microsphere particles; s2, mixing the microsphere particles and organic amine, and carrying out first loading treatment and drying treatment to obtain an organic amine loaded material; s3, roasting the organic amine-loaded material, mixing the obtained roasted material with a carrier material, and carrying out second loading treatment, so as to obtain the carbon dioxide adsorbent, the carrier material is selected from at least one of polystyrene-polyacrylic acid-polyethylene oxide, polymethyl methacrylate-b-polystyrene, zirconium oxide and a porous ceramic material. The carbon dioxide adsorbent is relatively high in adsorption capacity and relatively good in selectivity, reproducibility and stability; and large-scale industrial production and application are facilitated.

The invention discloses a liquid treatment agent for red mud harmless treatment and a preparation method thereof.The liquid treatment agent comprises a treatment agent A and a treatment agent B. The treatment agent A is formed by mixing hydrochloric acid and sulfuric acid, and the treatment agent B is prepared from malic acid, acetic acid, phthalic acid monoester, a solvent and an adsorbent, the mass fraction of the malic acid is 20%-40%, the mass fraction of the acetic acid is 20%-40%, the mass fraction of the phthalic acid monoester is 15%-25%, the mass fraction of the solvent is 5%-15%, and the mass fraction of the adsorbent is 5%-15%. The red mud is subjected to primary treatment by using the liquid treatment agent A, and then the red mud subjected to primary treatment is treated again by using the liquid treatment agent B, so that the alkalinity of the red mud can be effectively reduced, and various heavy metals, fluorides, radioactive elements and trace toxic elements in the red mud can be effectively removed; the environment pollution caused by the loss of the harmful substances is avoided, so that the innocent treatment of the red mud is realized.