4132 results about "Sorbent" patented technology

Described herein are sorbents functionalized with polyamines having oxygen-containing units selected from carbonyl units, hydroxyl units, and combinations thereof, methods of making same, and methods of using same.

A gas-liquid contactor for capturing carbon dioxide (CO2) from atmospheric air includes an inlet; an outlet; a gas-sorbent interface disposed between the inlet and the outlet; a liquid distribution system configured to flow a CO2 capture solution along the gas-sorbent interface; a fan configured to flow the atmospheric air along a flow path from: the inlet, along the gas-sorbent interface, and to the outlet, to contact the atmospheric air with the CO2 capture solution and absorb CO2 from the atmospheric air into the CO2 capture solution to form a CO2-lean gas stream; and an electrostatic drift eliminator within the flow path downstream of the gas-sorbent interface and upstream of the outlet. The CO2-lean gas stream includes aerosols of the CO2 capture solution. The electrostatic drift eliminator is configured to ionize at least some of the aerosols of the CO2 capture solution to form ionized aerosols and collect the ionized aerosols.

The invention relates to the technical field of adsorbents, and particularly discloses an aluminum oxide type adsorbent and a preparation method thereof.The preparation method comprises the following steps that lanthanum salt, cerium salt and a polyethylene glycol aqueous solution are mixed to be uniform, then the mixture is mixed with gamma-Al2O3 to be uniform, pH is adjusted, standing is conducted, solid-liquid separation is conducted, drying and roasting are conducted, and a double-doped carrier is obtained; dispersing the double-doped carrier in a mixed solution containing 2-methylimidazole, ferric salt and zinc salt, adjusting the pH value, carrying out heating reaction, solid-liquid separation and drying in an inert atmosphere, grinding to obtain powder, and carrying out molding treatment on the powder to obtain a composite carrier; uniformly mixing the Ag modified molecular sieve with silica sol, coating the surface of the composite carrier with the mixture, and drying to obtain an adsorbent precursor; dipping an adsorbent precursor in the dispersion liquid, and after dipping, solid-liquid separation and drying, reactivating to obtain the aluminum oxide type adsorbent; the prepared adsorbent can synergistically and efficiently remove multiple impurities and is excellent in corrosion resistance.

A direct air capture (DAC) of CO2 system includes a reaction reactor having a solid, amine-functionalized sorbent configured to sequester CO2 from air; an in-situ dual-function device configured as a CO2 conversion reactor and an exchange fluid regeneration device; and the exchange fluid, recirculating between the reaction reactor and the dual-function device, configured to capture the sequestered CO2 from the solid sorbent in the reaction reactor and release the captured CO2 in the conversion reactor, the exchange fluid including one or more amino acids.

An atmospheric CO2 capture system includes a compartment housing a solid CO2 sorbent, an exchange fluid including a chemical component with selectivity towards CO2, and an electrochemical cell or mineralization reactor in fluid communication with the compartment, the system having a cycle including a first state of sorbing CO2 from incoming air onto the solid CO2 sorbent until a saturation point is reached; a second state of regenerating the sorbent by flooding the compartment with the exchange fluid to detach CO2 from the saturated sorbent and bind the detached CO2 to the chemical component; and a third state of regenerating the chemical component and utilizing the CO2 in the electrochemical cell or mineralization reactor.

The invention discloses a production method and a production device of an energy-saving sustainable aviation fuel, and the production method comprises the following steps: S1, adsorbing carbon dioxide in air by using an adsorbent, desorbing through high-temperature carrier gas, and cooling and compressing the desorbed carbon dioxide; s2, carbon dioxide and deionized water are preheated and then electrolyzed, and synthesis gas and oxygen are generated; s3, after the synthesis gas is compressed, performing Fischer-Tropsch reaction to generate a mixture of Fischer-Tropsch oil wax, light hydrocarbon and water, cooling and separating, and returning the Fischer-Tropsch reaction heat to preheat the synthesis gas; s4, pressurizing the Fischer-Tropsch oil wax, mixing the Fischer-Tropsch oil wax with hydrogen, carrying out hydrofining reaction to generate a gas-liquid isomerous oil-gas mixture, cooling and separating, and recycling heat energy of a product to And S5, after gas-liquid separation, preheating a liquid phase, carrying out rectification operation, separating and cooling to obtain a sustainable aviation fuel product. By recovering the heat in each link, the heat is efficiently utilized, and the energy-saving performance of production is improved.

The invention relates to the technical field of drying equipment, in particular to a low-consumption constant-temperature dehumidification device and a control method, and achieves an efficient and energy-saving constant-temperature dehumidification effect. The heat recovery module recovers heat in the condensation and regeneration process, the collaborative optimization module coordinates operation of all the modules, the energy utilization efficiency is remarkably improved, and energy consumption is reduced. The control system module dynamically adjusts the state of each module according to the real-time data of the temperature and humidity sensor, ensures the stability of the environment temperature and humidity, and further improves the control precision by adopting a dynamic decoupling control strategy. The regeneration module utilizes recovered heat energy to efficiently regenerate adsorbents and cooperates with novel composite adsorbents, the service life of the adsorbents is prolonged, and the dehumidification performance is improved. The air circulation module forms uniform airflow, and local temperature and humidity unevenness is avoided. A user can set parameters through the interaction unit, the system is controlled to automatically adjust the operation strategy, intelligent operation is achieved, and the system performance is optimized.

An atmospheric CO2 capture system includes a compartment housing a solid CO2 sorbent, an exchange fluid including a chemical component with selectivity towards CO2, and an electrochemical cell or mineralization reactor in fluid communication with the compartment, the system having a cycle including a first state of sorbing CO2 from incoming air onto the solid CO2 sorbent until a saturation point is reached; a second state of regenerating the sorbent by flooding the compartment with the exchange fluid to detach CO2 from the saturated sorbent and bind the detached CO2 to the chemical component; and a third state of regenerating the chemical component and utilizing the CO2 in the electrochemical cell or mineralization reactor.

The invention provides a method for selecting a high-concentration VOCs adsorbent at different temperatures and application, and belongs to the technical field of waste gas governing. According to the method, through testing pore structure parameters of a model adsorption material with concentrated pore size distribution, a static adsorption isotherm and a dynamic penetration curve for VOCs at different temperatures, a high-concentration VOCs adsorbent is obtained; a linear relation equation of the critical aperture and the critical pressure is established through linear fitting, then a correlation equation of the critical aperture, the temperature and the partial pressure is established, and the appropriate aperture distribution range and the model selection standard of the high-concentration VOCs adsorbent at different temperatures are determined by combining dynamic adsorption results. According to the method, the ternary matching relation equation of the VOCs partial pressure, the temperature and the critical aperture is constructed, accurate type selection of the high-concentration VOCs adsorbent at different temperatures is achieved, the pore volume utilization rate and the adsorption capacity can be improved, meanwhile, desorption energy consumption and the VOCs pyrolysis risk are reduced, and a theoretical basis is provided for adsorbent type selection and technical optimization.

A gas-liquid contactor for capturing carbon dioxide from atmospheric air includes at least one inlet; at least one outlet spaced apart from the at least one inlet; a gas-sorbent interface disposed between the at least one inlet and the at least one outlet; a liquid distribution system configured to flow a CO2 capture solution along the gas-sorbent interface; at least one gas-circulating device configured to flow atmospheric air along a flow path to contact the atmospheric air with the CO2 capture solution and absorb CO2 from the atmospheric air into the CO2 capture solution to form a CO2-lean gas stream flowable through the at least one outlet, wherein the CO2-lean gas stream is deflected from a downward direction to an upward direction causing at least a portion of aerosolized particles in the CO2-lean gas stream to exit said CO2-lean gas stream upstream of the at least one outlet.

An article for joule heating is described, including a three-dimensional substrate on and / or in which a pyrolyzate of a phenolic resin or polymer forms an electrically conductive carbon network. Such articles may be incorporated in structured materials applications, which may include support, sorbent, and or catalyst components. Also described are methods of fabricating such articles and structured materials, and apparatus comprising same, and methods of use of such articles and structured materials and apparatus for conducting material transformation processes requiring input of heat for their performance, such as CO2 adsorption, methane pyrolysis for hydrogen and carbon production, hydrogen-assisted conversion of CO2 to hydrocarbons, including catalytic conversion of CO2 to olefins, catalytic conversion of CO2 to propane (liquefied petroleum gas), and catalytic conversion of CO2 to renewable natural gas, reverse water gas shift reaction, steam ethane cracking, propane cracking, steam methane reforming, and dry methane reforming.

The invention relates to the technical field of wastewater treatment, and provides a pretreatment device and method for wastewater containing heavy metal ions, and the pretreatment device comprises a water inlet unit, a multi-stage reaction unit, a solid-liquid separation unit, a deep adsorption unit and an intelligent control unit; the water inlet unit comprises a wastewater storage pool and a pH adjusting pool, and the pH adjusting pool is provided with a pH sensor and a dosing device; the multi-stage reaction unit consists of three rotational flow reaction tanks which are connected in series, and spiral guide plates are arranged in the tanks to enhance mixing; the solid-liquid separation unit comprises an inclined plate sedimentation tank and a centrifugal filter; a sludge return pipe is arranged at the bottom of the inclined plate sedimentation tank and extends to the reaction tank; the deep adsorption unit is filled with a modified zeolite-activated carbon composite adsorbent, and a heavy metal ion concentration online monitor is arranged at the rear end; the intelligent control unit dynamically adjusts the dosage and the reaction time based on pH and concentration data. The device has the beneficial effects that the mixing efficiency of wastewater treatment is enhanced, the pH application range of wastewater treatment is widened, and the cost is reduced.

The invention relates to the technical field of adsorbent preparation, in particular to an ammonia modified porous carbon adsorbent and a preparation method thereof. The preparation method of the ammonia modified porous carbon adsorbent comprises the following steps: carrying out hydrothermal acid leaching on gasified fine residues and an acid solution to obtain acid leaching residues; stirring the acid leaching residues in an alkali solution, washing and drying to obtain a porous carbon material; and dipping the porous carbon material in a tetraethylenepentamine solution, and then drying to obtain the ammonia modified porous carbon adsorbent. The ammonia modified porous carbon adsorbent is successfully constructed by taking a porous carbon material derived from coal gasification fine slag as a substrate and further adopting a surface ammonia functionalization modification strategy. The preparation method is simple, the raw materials are easy to obtain, and the prepared ammonia modified porous carbon adsorbent has a good adsorption effect on methylene blue and hexavalent chromium. According to the method, high-added-value resource utilization of the coal gasification solid waste is achieved, and a solution is provided for treatment of the dye wastewater and the heavy metal wastewater.

The invention provides an activated carbon adsorption and desorption system and an activated carbon adsorption and desorption method. Performing bed layer heat storage compensation on the standard temperature in the desorption link according to the temperature fluctuation characteristic of the adsorption bed layer in the adsorption link and the environment temperature of the adsorption bed layer to obtain the heat storage compensation temperature of each desorption stage in the desorption link; performing stage desorption on the activated carbon adsorbent based on the desorption duration of each desorption stage in the desorption link and all the heat storage compensation temperatures, and extracting the desorption residual quantity of pollutants in the activated carbon adsorbent from the pollutant concentration information of a stage desorption outlet; the effective desorption rate of the activated carbon adsorbent is determined according to the desorption residual quantity and the current adsorption capacity, and the critical adsorption capacity of the activated carbon adsorbent in the next cycle is cyclically updated based on the effective desorption rate. Based on the scheme, bed layer heat storage compensation in activated carbon critical adsorption capacity updating can be achieved.

The invention provides a material for removing sodium ions in saline-alkali soil and a preparation method, and relates to the field of sodium ion adsorbents, the preparation method comprises the following steps: (1) lignin modification: under a water bath condition, dissolving sulfate lignin in a mixed solution of analytically pure acetic acid and 30% hydrogen peroxide, then adding ferric chloride, reacting for 1.5-2.5 hours, diluting with distilled water by 7-8 times, centrifuging and washing to obtain modified lignin; drying to obtain oxidized lignin; (2) hydrogel synthesis: mixing and stirring the oxidized lignin and analytically pure acrylic acid, adding a cross-linking agent and an initiator, and reacting in a drying oven at 65-75 DEG C for 1.5-2.5 hours to form a sodium ion adsorption material with a porous interpenetrating network structure; by modifying the lignin, particularly introducing more hydroxyl and carboxyl groups, the performance of the lignin in the application of adsorbing ions, preparing hydrogel and the like can be improved.

The invention relates to the technical field of adsorbents, and discloses a moisture-resistant carbon dioxide trapping adsorbent, and a preparation method thereof comprises the following steps: S1, blending oxalic acid or oxalate or squaric acid and a zinc source in a reaction system to obtain a mixture I; s2, dissolving an organic ligand in a solvent to obtain a mixture II; s3, the mixture I and the mixture II are subjected to a reaction and post-treatment, and the adsorbent is obtained. According to the prepared adsorbent, a pore structure is formed in situ in the preparation process, the specific surface area is large, the porosity is large, the structure can be kept stable in the presence of water and steam, and the adsorbent is stable to wet acid gas.

A system for capture of atmospheric CO2 includes a reaction reactor having a solid sorbent; and a mineralization reactor downstream from the reaction reactor, the system having three states including in the reaction reactor, a first state of sequestering CO2 from air into the solid sorbent; in the reaction reactor, a second state of releasing the sequestered CO2 from the sorbent by contacting the CO2-enriched sorbent with an exchange fluid having one or more amino acids and forming a CO2-enriched exchange fluid; and in the mineralization reactor, a third state of reacting the sequestered CO2 from the CO2-enriched exchange fluid with an alkaline feedstock to form a carbonate while regenerating the exchange fluid.

The invention relates to the technical field of solid waste resource utilization, and particularly discloses a waste incineration fly ash resource treatment method which comprises the following steps: firstly, efficiently removing dioxin in fly ash in a manner of adding a vanadium-cerium-loaded charcoal catalyst and co-pyrolyzing with fluidized bed combustion ash; the method comprises the following steps: preparing fly ash from fly ash, washing the fly ash with micro-nano bubble water containing carbon dioxide for dechlorination, adding an iron-manganese-silicon biochar adsorbent after dechlorination to adsorb heavy metals in the fly ash, sintering the fly ash after adsorption and fly ash under an alkaline condition to further stabilize residual soluble chlorine and heavy metals in the fly ash, and finally, recycling the residual soluble chlorine and heavy metals in the fly ash. And the treated fly ash and cement are processed into cement building blocks with good mechanical properties, so that resource utilization of the waste incineration fly ash is realized.

The invention discloses an adsorption-extraction combined heavy metal polluted water remediation system and method, and belongs to the field of water pollution treatment. The system is provided with a sensing unit which collects data in real time through a heavy metal concentration sensor and the like; the model unit outputs key information such as adsorbent real-time saturation and the like based on the acquired data and an adsorbent saturation prediction model; the decision-making unit is used for calculating a dynamic threshold value according to the information, accurately judging regeneration time and optimizing regeneration parameters; the execution unit executes a regeneration operation according to the instruction. And the feedback unit feeds back the regenerated data to the model unit to realize dynamic optimization of the system. According to the method, closed-loop operation of data acquisition, processing, decision making and feedback is realized based on cooperation of all units of the system. According to the invention, the remediation efficiency of the heavy metal polluted water body is effectively improved, the regeneration of the adsorbent is accurately controlled, the operation energy consumption is reduced, the complex and changeable pollution working conditions can be better handled, and the effluent quality is guaranteed.

The invention discloses a process for preparing ultra-pure hydrogen by recovering and purifying hydrogen. The process comprises the following steps: nitrogen replacement: carrying out three times of pressurization-decompression circulation on an adsorption tower and a pipeline; pretreatment of raw materials: hydrogen-containing tail gas is treated by a buffer tank, a compressor, a desulfurization tower and a horizontal adsorption tower and then enters a PSA (Pressure Swing Adsorption) system; pSA purification: a 6-2-3 / P process is adopted, two towers in six adsorption towers perform adsorption at the same time, and hydrogen larger than or equal to 99.99% is produced; regeneration of the adsorbent is completed through three-stage pressure equalizing and reducing, clockwise / anticlockwise pressure reducing, product hydrogen flushing and three-stage pressure equalizing and boosting; refining by a membrane separation unit: carrying out membrane separation on PSA hydrogen to produce ultrapure hydrogen of which the purity is greater than or equal to 99.999%, and returning trapped gas to a compressor; and condensate water recovery: carrying out steam stripping and deoxygenization on the process condensate liquid, and then taking the process condensate liquid as boiler feed water. The process integrates PSA and membrane separation technologies, realizes efficient and energy-saving ultrapure hydrogen preparation, and is suitable for the fields of green hydrogen energy storage, electronic industry, high-end chemical industry and the like.

The invention relates to the technical field of gas separation and purification, in particular to a method and system for recycling hydrogen in mixed gas through pressure swing adsorption. The method comprises the following steps: performing multi-layer adsorption impurity removal on mixed gas containing 20-25% of silane, 10-15% of disilane and 60-70% of hydrogen, and cooling to 22-28 DEG C; the mixed gas subjected to primary impurity removal enters a pressure swing adsorption device, and an adsorbent in the adsorption device is modified activated carbon. The system comprises a mixed gas cylinder, a pretreatment unit, a pressure swing adsorption unit and a hydrogen collection unit which are connected in sequence. By adopting the pressure swing adsorption method, the hydrogen recovery rate is remarkably increased and can reach 93%, the purity can reach 99.2% or above, and the strict requirement of high-end industrial production for high-purity hydrogen can be met.

The utility model discloses a bitter apricot kernel wastewater treatment device which comprises an equipment shell, a water inlet pipe and a water outlet pipe are respectively arranged on the equipment shell, and a wastewater treatment assembly communicated with the water inlet pipe and the water outlet pipe is arranged in the equipment shell; the wastewater treatment assembly comprises a plurality of groups of apricot shell adsorption tanks which are connected in series, apricot shells are filled in the apricot shell adsorption tanks and are used as adsorbents, the apricot shells adsorbing hydrocyanic acid are subjected to carbonization treatment, and the hydrocyanic acid is destroyed in the carbonization treatment process and forms a part of pyroligneous liquor; the hydrofluoric acid on-line detector is arranged at the downstream of the apricot shell adsorption tank and is used for detecting the content of hydrofluoric acid in the treated wastewater; the control valve group is connected to the water inlet pipelines and the water outlet pipelines of the apricot shell adsorption tanks and is used for controlling the working states of the multiple groups of apricot shell adsorption tanks. The device is efficient in use, easy to operate, low in maintenance cost, safe and reliable, hydrofluoric acid is eliminated in the carbonization process, waste water is recycled, and water resources are saved.

The utility model relates to the technical field of waste gas treatment, in particular to a device for continuously and circularly adsorbing and desorbing VOCs waste gas in CEC tail gas. The device comprises a condensation separation unit and an adsorption and desorption unit which are sequentially communicated, the condensation separation unit comprises a condenser and a gas-liquid separator which are sequentially communicated through a pipeline; a discharge port of the condenser is connected to an upper feed port of the gas-liquid separator, and an upper gas outlet of the gas-liquid separator is connected to the adsorption and desorption unit; the adsorption and desorption unit comprises a fluidized bed adsorption tower and a desorption tower, and a discharge port in the bottom of the fluidized bed adsorption tower is connected to an adsorbent feed port in the bottom of the desorption tower; an adsorbent discharge port in the top of the desorption tower is connected to an upper feed port of the fluidized bed adsorption tower; and an upper gas outlet of the gas-liquid separator is connected to a gas inlet of the fluidized bed adsorption tower. According to the device disclosed by the utility model, the continuous cycle operation can be realized in the adsorption and desorption processes, the regeneration temperature and pressure of the adsorbent are adjustable and controllable, the adsorption efficiency is high, and the efficient removal of VOCs impurities can be ensured.

The invention discloses a comprehensive control system and method for carbon emission of a methanol dual-fuel power ship. The method comprises the following steps: analyzing carbon emission characteristics at different moments by collecting and acquiring sensor data in real time; solving based on the constructed carbon emission optimization model in combination with a particle swarm algorithm to obtain the optimal ship navigational speed, adsorbent circulation rate and methanol fuel injection pressure corresponding to the minimum carbon emission of the methanol dual-fuel power ship; cO2 in tail gas is captured in real time through the ship carbon capture unit, the circulation rate of an adsorbent is adjusted in time according to optimization information of the ship navigation optimization control unit, the circulation efficiency of the adsorbent is calculated according to the carbon emission amount, the adsorbent is updated or replaced in time, and the comprehensive control process of the ship carbon emission is comprehensively evaluated. And comprehensive control of ship carbon emission is realized according to the comprehensive evaluation result. The problem of poor carbon emission control effect caused by insufficient cooperative control of a methanol dual-fuel power ship carbon capture device and a power system is solved.

The invention belongs to the technical field of metallurgical industry gas resource utilization, and particularly relates to a method and system for preparing synthesis gas from blast furnace gas. The method comprises the steps that a CO2 adsorbent is heated to the first temperature to conduct CO2 adsorption on blast furnace gas, the adsorbent after CO2 adsorption is obtained, the CO2 adsorbent is CaO, and the first temperature is smaller than or equal to 650 DEG C; the adsorbent after CO2 adsorption is heated to a second temperature for CO2 desorption, obtained CO2 and H2 are catalyzed by a copper-based catalyst under the second temperature condition to be subjected to a reverse water-gas shift reaction, synthesis gas is obtained, and the second temperature is higher than or equal to 700 DEG C. The method provided by the invention realizes effective separation and conversion of carbon dioxide in blast furnace gas to obtain a synthesis gas product, thereby realizing closed cycle of carbon resources, remarkably improving the economical efficiency of blast furnace gas, and realizing efficient utilization of energy.

The invention relates to a bimolecular modified straw adsorbent as well as a preparation method and application thereof. The preparation method comprises the following steps: cleaning, drying and grinding straws, and sieving by a 100-mesh sieve; adding a polyethylene diamine solution, and carrying out stirring reaction at normal temperature; adding L-cysteine, adjusting the pH value to 4.5-5.5, and continuously stirring to react for 6-10 hours; and filtering, washing and drying to obtain the product. The preparation method has the advantages of simple steps, easily available raw materials and low requirements on equipment; the prepared bimolecular modified straw adsorbent has good removal effect and selectivity on Sb (III) and Sb (V), and is wide in pH value adaptation range. And a new technical means is provided for high-value conversion of straws and removal of antimony in water.

An integrated system for adsorbing carbon dioxide (CO2) in the air is described. The system includes: an adsorber that adsorbs the CO2 from the air using a sorbent; and a desorber, coupled to the adsorber, that desorbs the adsorbed CO2 from the sorbent (e.g., in an energy-efficient manner, such as without using steam) into an output of the system. In contrast with other approaches, the system may continuously move the sorbent, as an ensemble, through the system. Thus, the system may concurrently (and continuously) perform adsorption and desorption. Moreover, the sorbent may include a cost-effective and robust free-standing bulk solid. This may allow the sorbent to be used in multiple cycles or transits through the system. Furthermore, after the multiple cycles, the sorbent may be replaced while the system is operating, and the used sorbent may be recycled for subsequent reuse in the system.

The invention discloses a composite heavy metal adsorbent synthesized through mineral conversion and a preparation method of the composite heavy metal adsorbent, and belongs to the technical field of deep processing of natural nonmetallic minerals and preparation of heavy metal adsorption functional materials, and the main preparation method comprises the following steps: S1, crushing and crushing natural clay minerals, and sieving with a 80-mesh sieve to obtain mineral powder; s2, mixing the obtained mineral powder with a calcium compound, and carrying out ball milling; s3, adding a boron compound, and continuing ball milling; s4, adding water into a solid material obtained by ball milling according to a solid-to-liquid ratio of (1: 5)-(1: 20), putting into a microwave hydrothermal reaction kettle, adding an organic auxiliary agent, carrying out gradient heating to 100-200 DEG C, reacting for 30-120 minutes, then naturally cooling to room temperature, separating, drying and crushing; according to the invention, natural clay raw ore is taken as a raw material, and the borate-silicate composite adsorption material is prepared in a preparation mode of combining solid-phase reaction and microwave hydrothermal treatment, so that high-concentration and low-concentration heavy metal ions are efficiently removed.

The invention relates to a spherical hydrotalcite phase desulfurization adsorbent as well as a preparation method and application thereof, the preparation method comprises the following steps: mixing an iron source, a nickel source and organic carboxylate, and then carrying out hydrothermal carbonization reaction to obtain the spherical hydrotalcite phase desulfurization adsorbent. The nickel source and the iron source are selected as the raw materials, hydroxide radicals of laminates and carbonate ions between the laminates of the prepared hydrotalcite phase desulfurization adsorbent can increase the alkalinity of the surface of the desulfurization adsorbent and improve the adsorption capacity to hydrogen sulfide, and meanwhile, the hydrotalcite phase desulfurization adsorbent can react with hydrogen sulfide in a catalytic oxidation manner, so that the removal efficiency is improved. Organic carboxylate is selected as a hydrothermal auxiliary agent, carboxylate radicals can chelate metal ions through multidentate coordination to form a stable complex, so that the nucleation rate of hydrotalcite is delayed, the particle size uniformity is improved, meanwhile, a carbon coating layer is generated through hydrothermal carbonization, and pores in the carbon coating layer and pores in hydrotalcite can form hierarchical pore channels, so that the composite material is prepared. The mass transfer efficiency is synergistically improved, so that the adsorption capacity of the adsorbent is improved.

The present application belongs to the technical field of gaseous arsenic adsorption, and particularly relates to a sulfur-tolerant gaseous arsenic adsorption material, a preparation method and application thereof. Manganese oxide and an iron source are mixed and placed in a ball mill jar, then the ball mill jar is sealed, argon is filled into the jar, and the iron-modified manganese oxide adsorption material is obtained by ball milling. The addition of iron improves the sulfur tolerance of manganese oxide, so that the adsorbent still has high gaseous arsenic adsorption capacity under high-concentration SO2 conditions, and is suitable for the removal of gaseous arsenic in typical high-SO2 flue gas, i.e. non-ferrous smelting flue gas. The preparation method is simple, the cost is low, the gaseous arsenic adsorption capacity is large, and the present application has a wide application prospect.