The invention relates to the technical field of
alumina functional material preparation, in particular to an
alumina refractory material gradient
sintering process based on critical
temperature control, which comprises the following steps: mixing various additives such as alpha-Al2O3
powder, nano ZrO2, Yb2O3 and the like to prepare a suspension, and carrying out
spray granulation and isostatic compaction; organic matters are removed through a low-temperature section,
solid solution is promoted through a medium-temperature section, a strengthening
phase reaction is initiated through a high-temperature section, and
sintering is performed at different heating rates in a segmented manner; hCl gas is introduced into the high-temperature section,
ultrasonic vibration is applied, CO2 is introduced during gradient cooling, and pressure is applied; and finally, through segmented
nitriding treatment, a gradient structure from the
surface layer to the interior is formed, and the material performance is improved. According to the process, a gradient structure is formed in the material through multi-stage
temperature control, additive compounding, ultrasonic treatment and other treatments; the
corrosion resistance, the
thermal shock resistance and the
mechanical property of the
refractory material can be remarkably improved, the high-temperature industrial requirement is met, the application prospect is wide, and the benefit is high.