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Formula and preparation process of alcohol group nanometer composite and surface modified dry powder mold paint

A nano-composite and surface modification technology, used in casting molding equipment, casting molds, casting mold components, etc., can solve problems such as reducing the refractoriness of coatings, fluctuations in the performance of paste coatings, and limiting the scope of use of coatings, and achieve high dispersion. , good dispersion, good suspension stability

Inactive Publication Date: 2010-02-10
深圳市景鼎现代科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Chinese patent CN86105456A discloses a lithium-based bentonite zircon powder powder casting coating. The raw materials such as lithium-based bentonite, zircon powder, resin and titanium dioxide are mixed and milled to make a powder coating, which is directly diluted with ethanol when used. Slurry coating, but because the suspending agent lithium-based bentonite has not caused swelling, the suspension of the mixed slurry coating is poor, resulting in very poor field usability
Chinese patent CN1022173C discloses a method for preparing alcohol-based dry powder coatings. The suspending agent lithium soil is subjected to denaturation treatment, and then mixed with refractory powder, binder and other additives to form alcohol-based dry powder coatings. The preparation process requires very high requirements. If the control is slightly improper, it will affect the performance of the coating, and this process is only suitable for the preparation of low-density refractory powder coatings such as quartz powder and graphite powder. For the zircon powder and chromite powder commonly used in casting coatings , Corundum powder and other high-density refractory powder dry powder coatings, still cannot guarantee its good suspension stability and other process properties
Chinese patent CN100377811C discloses a production method of alcohol-based attapulgite casting coating powder, using sodium-modified attapulgite clay as a suspending agent, and the prepared coating powder can reach a higher suspension rate in ethanol, but the coating The percentage of modified attapulgite clay in the powder is 55% to 85%, and the refractory powder (high alumina + graphite) is only 10% to 45%. The amount of suspending agent is much higher than that of refractory powder, although it makes The obtained slurry paint has good suspension stability, but at the cost of reducing the refractoriness of the paint, so the scope of use of the paint is limited, and it cannot be used in the production of steel castings and large iron castings
However, since the refractory powder is an inorganic material, the suspending agent organoclay and the film-forming compound are both organic materials, the dry powder coating made by mixing is easy to form segregation (especially after long-distance transportation and long-term storage), resulting in dry powder coating composition Inhomogeneity, which makes the performance of the mixed slurry coating fluctuate, and it is difficult to control when using

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Coating ratio: zircon powder 100kg, γ-glycidyl etheroxypropyl trimethoxysilane 0.5kg, stearic acid 0.5kg, organic montmorillonite 1.3kg, organic attapulgite 1.4kg, nano-SiO 2 1.3kg, phenolic resin 4.0kg, polyvinyl butyral 0.2kg.

[0021] Preparation process: Add γ-glycidyl etheroxypropyltrimethoxysilane to zircon powder, mix in a kneader for 0.5h, add stearic acid to mix and disperse for 4h, and place for 24h; the modified refractory powder Placed in a tumble mixer, adding organic montmorillonite, organic attapulgite and nano-SiO 2 Mix for 4 hours, and finally add phenolic resin and polyvinyl butyral and mix for 4 hours to obtain a finished dry powder casting coating.

Embodiment 2

[0023] Coating ratio: zircon powder 70kg, mullite powder 30kg, γ-aminopropyltriethoxysilane 0.6kg, calcium stearate 1.0kg, organic montmorillonite 1.7kg, organic attapulgite 1.7kg, nano-SiO 2 1.6kg, rosin modified phenolic resin 5.0kg, polyvinyl butyral 0.1kg.

[0024] Preparation process: Add γ-aminopropyltriethoxysilane to zircon powder and mullite powder, mix in a kneader for 0.5h, add calcium stearate to mix and disperse for 5h, and place for 24h; the modified The refractory powder is placed in a drum mixer, and organic montmorillonite, organic attapulgite and nano-SiO are added 2Mix for 4 hours, and finally add rosin-modified phenolic resin and polyvinyl butyral and mix for 3 hours to obtain a finished dry powder casting coating.

Embodiment 3

[0026] Coating ratio: kyanite powder 60kg, bauxite powder 40kg, γ-glycidyl etheroxypropyl trimethoxysilane 0.7kg, zinc stearate 1.5kg, organic montmorillonite 2.0kg, organic attapulgite 2.0kg , nano-SiO 2 2.0kg, phenolic resin 6.0kg.

[0027] Preparation process: Add γ-glycidyl etheroxypropyltrimethoxysilane to kyanite powder and bauxite powder, mix in a kneader for 0.5h, add zinc stearate to mix and disperse for 6h, and place for 24h; The cured refractory powder is placed in a tumble mixer, and organic montmorillonite, organic attapulgite and nano-SiO are added 2 Mix for 4 hours, and finally add phenolic resin and mix for 2 hours to obtain the finished dry powder casting coating.

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Abstract

The invention relates to an auxiliary material for casting and moulding, in particular to a formula of alcohol group dry powder mold paint for sand mold casting. The dry powder mold paint comprises surface modifier, suspending agent, binder and refractory powder, wherein the surface modifier is 0.6-4.2wt% of refractory powder, the suspending agent is 4.0-8.0wt% of refractory powder and the binderis 4.0-6.2wt% of refractory powder. The alcohol group nanometer composite and surface modified dry powder mold paint of the invention adopts nanometer layered clay and nano-SiO2 to form composite suspending agent so that the controllability of operation technological parameters of the alcohol group dry powder mold paint is good and the process performance and operating performance of the obtainedpulp-type paint can both meet the demand of the casting factory.

Description

Technical field: [0001] The invention relates to an auxiliary material for casting molding, in particular to an alcohol-based dry powder casting coating formula for sand casting and a preparation process thereof. Background technique: [0002] Mold coating is the most effective measure to solve the sand sticking on the surface of castings and improve the surface quality of castings. Among them, the alcohol-based coating is widely used in casting production plants due to its characteristics of ignition drying, good strength and high efficiency. At present, the vast majority of commercialized casting coatings are supplied in the form of paste, and the carrier liquid of alcohol-based coatings is mainly composed of ethanol, methanol, isopropanol, etc., which are flammable and dangerous goods, which inevitably makes Coatings are subject to many constraints in terms of packaging, transportation, storage, etc., especially the long transportation period and high cost; in addition, ...

Claims

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Application Information

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IPC IPC(8): B22C3/00
Inventor 孙鲁洪胡昊民
Owner 深圳市景鼎现代科技有限公司
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