The invention discloses an environmental-protection anti-corrosive heat-dissipation powder paint, and a preparation method and application thereof. The environmental-protection anti-corrosive heat-dissipation powder paint comprises the following raw materials in parts by weight: 40-90 parts of matrix resin, 2-40 parts of curing agent, 0.5-10 parts of carbon nanotube, 0.5-2 parts of additive, 0-4.5 parts of hexagonal boron nitride, 0-15 parts of aluminum nitride, 0-10 parts of magnesium nitride, 0-10 parts of silicon carbide and 5-30 parts of pigment and filler. The composition and proportioning of the raw materials of the powder paint disclosed by the invention are scientific and reasonable. The experimental result indicates that the powder paint has the advantages of favorable heat-dissipation effect, high efficacy enhancement rate (higher than 60%) and favorable cooling effect (more than 20 DEG C), and can effectively solve the problem of poor heat-dissipation effect in the high-power electronic product, thereby prolonging the service life of the electronic product. The powder paint disclosed by the invention is free of organic solvent, and is environment-friendly and safe; the powder paint disclosed by the invention also has favorable comprehensive properties, such as flexibility, hardness, adhesive force and the like, and stable chemical properties; and the coating formed by the powder paint has the advantages of high corrosion resistance and shock resistance, favorable insulation property and wide application range.