The invention relates to a method for processing polymer emulsion of a photo anode in a dye sensitization battery, which belongs to the field of dye sensitization solar batteries. The method comprises utilizing emulsion to scatter metallic oxide particles, firstly, achieving the even scattering of nanometer particles through the self-assembling of nanometer particles and emulsion particles to prevent birdnesting, increasing specific surface area of an electrode after film forming, increasing dye adsorbance and light absorption efficiency, and improving photoelectric transformation efficiency of a solar energy battery, secondly, forming a three-dimensional bicontinuous structure whose size can be controlled through the self assembling, providing a transmission channel between an electric charge and a positive hole, improving drift velocity of electric charges, and increasing electric charge collection efficiency and photocurrent, thirdly, leading the operation of emulsion preparation to be simple and convenient, and forming stable scattering, preparing emulsion to be transmitted in packaging after nanometer particles are produced, and preventing metallic oxide nanometer particles from birdnesting in the process of storing. The photoelectric transformation efficiency of a battery can be improved at least 20% through utilizing an emulsion scattering method to prepare electrodes. Colloids which can be suitable for different film forming techniques can be got through modulating an emulsion formula.