719 results about "Molybdenum oxide" patented technology

Provided herein are methods of depositing molybdenum (Mo) films. The methods involve depositing a thin layer of a molybdenum (Mo)-containing film such a molybdenum oxide, a molybdenum nitride, or a molybdenum oxynitride. The Mo-containing film is then converted to an elemental Mo film. A bulk Mo film may then be deposited on the elemental Mo film. In some embodiments, the process is performed at relatively low temperatures.

Systems and methods are provided for etching molybdenum in a wet ALE process. The methods disclosed herein use a wide variety of techniques and wet etch chemistries to oxidize a molybdenum surface and form a self-limiting, molybdenum oxide passivation layer in a surface modification step of the wet ALE process. For example, the methods use: (a) ultra-violet (UV) photolysis of peroxide oxidizers to create oxidizing radicals, which limit oxidation of the molybdenum surface and provide quasi-self-limiting oxidation behavior, (b) steric hinderance of oxidizers having large reactant molecules to achieve better self-limiting oxidation behavior, and / or (c) ligand-assisted oxidation to change the surface chemistry of the molybdenum oxide passivation layer and ensure self-limiting oxidation behavior. After forming the molybdenum oxide passivation layer using one or more of the oxidation techniques disclosed herein, the passivation layer is selectively removed in a dissolution step of the wet ALE process to etch the molybdenum surface.

The invention belongs to the technical field of catalysts, and particularly relates to a supported Co-based catalyst with a nano molybdenum carbide auxiliary as well as a preparation method and application of the supported Co-based catalyst. The preparation method comprises the following steps: depositing molybdenum oxide on the surface of a carrier material by adopting an atomic layer deposition method, then carrying out carburizing treatment to obtain a molybdenum carbide catalyst, depositing cobalt oxide on the surface of the molybdenum carbide catalyst by adopting the atomic layer deposition method, and then carrying out reduction treatment to obtain the supported cobalt-based catalyst with the nano molybdenum carbide assistant. According to the preparation method provided by the invention, the size of molybdenum carbide and the dispersity and valence state of cobalt are controlled by regulating and controlling the deposition times of molybdenum oxide, and the prepared catalyst has excellent catalytic activity and stability in the hydroformylation reaction of long-chain olefin with the carbon atom number being greater than or equal to 5.

The invention discloses a coating type high-molecular flame-retardant material. The composite material is prepared from the following components: organic silicon modified epoxy resin, a bio-based castor oil derivative, hydroxyapatite, carbon nanofibers, expanded graphite, ammonium polyphosphate, zinc borate, nano silicon dioxide, molybdenum oxide, microencapsulated red phosphorus, magnesium hydroxide, melamine cyanurate, aluminum diethylphosphinate, pentaerythritol, trihydroxymethyl phosphine oxide and a silane coupling agent. The coating is prepared from a titanate coupling agent, stearic acid, polyethylene glycol, 2, 6-butylated hydroxytoluene, triphenyl phosphite, 2, 4-dihydroxybenzophenone, sebacic diester, polytetrafluoroethylene micro powder, a modified polydimethylsiloxane flatting agent, organic montmorillonite, a polyether modified silicon defoaming agent and a solvent. The invention has the beneficial effects of high flame retardant efficiency, environmental friendliness, excellent comprehensive performance and excellent processability.

The invention discloses a supported iron-molybdenum catalyst for formaldehyde production and a preparation method and application thereof, and belongs to the field of catalysts.The catalyst comprises a core-shell structure, the core of the catalyst is a carrier, molybdenum trioxide is supported on the carrier, and the shell of the catalyst is iron molybdate. The carrier is selected from at least one of silicon dioxide, aluminum oxide, titanium oxide, magnesium oxide, magnesium silicate, a molecular sieve, white carbon black and hydroxyapatite; the preparation method comprises the following steps: firstly, loading molybdenum trioxide on a carrier, then dispersing the carrier in deionized water, dropwise adding a molybdenum source solution and an iron source solution in a parallel flow manner under stirring to perform deposition loading of iron molybdate, and performing aging, drying, forming and calcining to obtain the catalyst. The catalyst is used for preparing formaldehyde by oxidizing methanol, dimethyl ether and methylal; according to the catalyst disclosed by the invention, the raw material cost and the pollutant treatment capacity are obviously reduced due to the reduction of the dosage of molybdenum and iron components, and the catalyst has relatively good activity and stability.

The invention relates to the technical field of lubricating oil, in particular to anti-wear and anti-attrition composite lubricating oil and a preparation method and application thereof. The anti-wear and anti-attrition composite lubricating oil is prepared from the following raw materials: base oil, an anti-wear reagent at extreme pressure, a preservative, an antioxidant, a viscosity index improver and a dispersing agent, the extreme pressure anti-wear agent is obtained by modifying layered molybdenum oxide with metal micelles formed by dodecylamine and wet and then carrying out hydrothermal treatment and vulcanization. The prepared anti-wear and anti-attrition composite lubricating oil has excellent anti-wear and anti-attrition effects and extreme pressure properties, is suitable for the lubrication requirements under high load and harsh conditions, and has a wide application prospect.

The application provides a method for grading diesel deep hydrodesulfurization catalysts, which comprises the following steps: loading catalysts containing AlPO4-5 phosphorus aluminum molecular sieves and catalysts containing ETS-10 titanium silicon molecular sieves in the upper and lower parts of a fixed bed hydrogenation reactor respectively according to a loading mass ratio of 1:3-3:1, so that diesel is subjected to hydrodesulfurization reaction through catalysts containing AlPO4-5 phosphorus aluminum molecular sieves first and then through catalysts containing ETS-10 titanium silicon molecular sieves; the carrier of the catalysts containing AlPO4-5 phosphorus aluminum molecular sieves comprises AlPO4-5 phosphorus aluminum molecular sieves and aluminum oxide powder, the carrier of the catalysts containing ETS-10 titanium silicon molecular sieves comprises ETS-10 titanium silicon molecular sieves and aluminum oxide powder, and the active components of the two kinds of catalysts respectively comprise a combination of two or three of nickel oxide, molybdenum oxide and cobalt oxide. The sulfur content of the hydrogenated diesel obtained through the method can be as low as 10 μg / g or below.

The invention provides a beneficiation and enrichment method for high-molybdenum oxide ore, which comprises the following steps of: performing fraction magnetic separation on a product after ore grinding, regrinding magnetic separation coarse particle tailings, mixing the reground product with magnetic separation fine fraction tailings to perform low-potential sulphide ore flotation, performing oxidized ore flotation on sulphide ore flotation tailings, and the like. And finally, the molybdenum concentrate with the high recovery rate and grade is obtained, the molybdenum ore separation and enrichment effect is achieved, and the fine disseminated-particle-size refractory molybdenum oxide ore resources in the high-oxidation-type molybdenum ore are effectively and comprehensively recycled. In order to quickly optimize and obtain the optimal condition of oxidized ore flotation, the flotation inhibitor with the good inhibition effect is determined through the pure ore flotation test, the flotation collecting agent with the high selectivity is selected through the molecular simulation calculation method, and the flotation efficiency and selectivity are improved. The method provided by the invention can be widely applied to the fields of development of high-oxidation molybdenum ore mines and recycling of fine-fraction refractory molybdenum oxide ore resources in tailings after sulfuration flotation.

The present invention relates to a process for producing molybdenum dioxide dichloride, which is a very efficient process that does not use hazardous chlorine gas and high reaction temperatures and enables the production of molybdenum dioxide dichloride in high yield without solvent.

The invention discloses a preparation method of a high-strength molybdenum alloy wire and the high-strength molybdenum alloy wire. The technical problem that in the prior art, a molybdenum alloy wire is small in tensile strength is solved. The preparation method of the high-strength molybdenum alloy wire comprises the following steps that molybdenum oxide, rhenium oxide, ruthenium oxide and tungsten oxide are subjected to ball milling and mixing; adding a mixed solution containing cerium ions, yttrium ions and lanthanum ions into the ball-milled and mixed slurry, and continuing ball-milling and mixing; carrying out spray drying on the slurry to obtain composite powder; performing high-temperature hydrogen reduction treatment to obtain multi-component doped molybdenum powder; and the high-strength molybdenum alloy wire is obtained through compression molding treatment, high-temperature sintering treatment, high-temperature rotary swaging and wire drawing treatment.

The invention relates to superfine molybdenum powder and a converter reduction preparation method thereof, belongs to the technical field of rare metal powder metallurgy, and solves the problems that the existing molybdenum powder preparation process is easy to cause hardening and agglomeration, the appearance granularity of the molybdenum powder cannot be controlled, the reduction process is complicated, the efficiency is low, the energy consumption is high and the cost is high. The method comprises the following steps: (1) preparing molybdenum oxide powder; (2) adding the molybdenum oxide into a converter, and introducing hydrogen for reduction; wherein the molybdenum oxide powder is nanoscale molybdenum oxide. The contact area between the adopted nanoscale molybdenum oxide powder raw material and the reducing gas is large, the converter rotates to drive the raw material powder to flow, full contact between the raw material powder and the reducing gas is promoted, hardening and agglomeration are inhibited, the reduction efficiency is improved, one-step reduction is achieved, the morphology is easy to control, and no waste gas is generated; compared with a traditional static pusher furnace, the closed dynamic converter has the advantages that reduction hydrogen escape is greatly reduced, safety is improved, energy consumption is reduced, and the use amount of hydrogen is greatly reduced.

The invention provides a perovskite solar cell and a preparation method thereof, the perovskite solar cell comprises a substrate, a conductive anode, a hole transport layer, a perovskite light absorption layer, an electron tunneling protection layer, a hole barrier layer and a conductive cathode which are stacked in sequence, and the material of the electron tunneling protection layer comprises aluminum oxide and / or molybdenum oxide; the hole blocking layer is made of tin oxide and / or IZO. According to the invention, the electron tunneling protection layer is arranged between the perovskite light absorption layer and the hole blocking layer, so that the damage to perovskite in the process of depositing the buffer layer of the hole blocking layer is blocked, and the stability of the cell is greatly improved; and tin oxide and / or IZO can be directly deposited without using C60, so that the manufacturing cost is greatly reduced, and a device with higher stability is obtained.

The invention discloses a method for purifying electronic grade molybdenum dioxide dichloride, which comprises the following steps of: removing low-boiling-point substances by adopting a sublimation method, collecting sublimation gas of which the main component is a target product by adopting sublimation in a fixed temperature interval, then removing substances with different chemical properties and polarities by adopting a complexing and decomplexing method, and finally further removing impurities by sublimation to obtain the electronic grade molybdenum dioxide dichloride. And finally obtaining the electronic grade molybdenum dioxide dichloride with the purity not lower than 7N grade. The method has the characteristics of good purification effect, multi-method comprehensive impurity removal, industrial large-scale application, stable quality, high yield and simple and easy-to-separate impurity components.

The invention discloses a defect passivation perovskite solar cell and a preparation method thereof, and belongs to the technical field of solar cell preparation. The preparation method comprises the following steps: mixing a SnO2 aqueous solution and an organic hydrochloride solution, and carrying out ultrasonic treatment to obtain an organic hydrochloride doped SnO2 precursor solution; preparing a halogen-containing compound solution and an organic salt solution as a perovskite precursor solution; the preparation method comprises the following steps: uniformly mixing Fk209, tBP, Li-TFSI, Spiro-OMeTAD and chlorobenzene or tBP, Li-TFSI, P3HT and chlorobenzene to obtain a hole transport layer precursor solution; the preparation method comprises the following steps: preparing a SnO2 electron transport layer, a perovskite absorption layer and a hole transport layer on a substrate material in sequence, and finally preparing a molybdenum oxide layer and a silver electrode on the hole transport layer. The problem that a large number of defects exist in existing perovskite solar cell preparation is solved, and the carrier transmission capacity and the photoelectric conversion efficiency are improved.

The invention relates to the technical field of alloy processing, and discloses a high-performance corrosion-resistant nickel-based alloy plate and a preparation method thereof, and the method comprises the following steps: raw material preparation, smelting treatment, casting treatment, hot rolling treatment, solution treatment, aging treatment and surface passivation treatment. According to the invention, when a composite acid system is adopted for passivation treatment, the concentration of chromium / molybdenum atoms in a passivation film is optimized and balanced due to the specific ratio of nitric acid to chromic acid, a chromium oxide provides a compact passivation barrier, and a molybdenum oxide endows the film layer with a self-repairing characteristic to synergistically inhibit pitting nucleation; meanwhile, nano titanium dioxide particles pretreated by silane are embedded into the passivation film in situ under the action of ultrasonic oscillation, organic pollutants adsorbed on a film layer can be decomposed by the photocatalytic characteristic of the nano titanium dioxide particles, the local corrosion effect of a battery caused by dirt coverage is avoided, and the performance of the battery is improved through double upgrading of components and the structure of the passivation film. And the alloy plate has excellent pitting corrosion resistance and fouling resistance in a chloride ion-containing medium.

The invention provides a preparation method of high-purity molybdenum trioxide, which belongs to the technical field of molybdenum trioxide production and comprises the following steps: S1, crushing, grinding and roasting molybdenum ore sand to obtain crude molybdenum oxide, adding the crude molybdenum oxide into a sodium hydroxide solution, heating, stirring and filtering to obtain a crude sodium molybdate solution; s2, adjusting the pH value of the crude sodium molybdate solution to 5.5-7.0, introducing the crude sodium molybdate solution into an exchange column of macroporous cation exchange resin, then adjusting the pH value of the solution to 7.0-8.5, and introducing the crude sodium molybdate solution into an exchange column filled with anion exchange resin to obtain a high-purity sodium molybdate solution; s3, excessive ammonia water is added into the high-purity sodium molybdate solution, ammonium molybdate is separated out, washing and drying are conducted, and high-purity ammonium molybdate is obtained; and S4, the high-purity ammonium molybdate is put into a rotary calcining furnace, rare earth oxide is sprayed on the inner wall of a furnace tube, and the high-purity molybdenum trioxide is prepared by adopting a calcining mode of firstly heating, then cooling and then heating. According to the invention, the purpose of producing high-purity molybdenum trioxide is realized.

The present invention relates to the technical field of heavy oil hydrodesulfurization, and discloses a hydrodesulfurization catalyst preparation process, which comprises: adding deionized water, a nickel source, a molybdenum source and a dispersant into a reaction container, stirring to obtain a metal solution, pouring into a container filled with gamma-Al2O3, impregnating, drying, and roasting to obtain the hydrodesulfurization catalyst. The dispersing agent contains a large number of nitrogen atoms and a plurality of carboxyl groups and hydroxyl groups, has very strong coordination chelation performance on nickel and molybdenum, improves the dispersity of nickel and molybdenum precursors, enables the nickel and molybdenum precursors to be uniformly impregnated into a gamma-Al2O3 carrier, and nickel oxide and molybdenum oxide are uniformly distributed in the gamma-Al2O3 carrier after calcination, so that the nickel and molybdenum oxide-modified gamma-Al2O3 composite material is prepared. The obtained hydrodesulfurization catalyst can expose more nickel-molybdenum catalytic active centers, effectively catalyzes and removes sulfur-containing substances such as thiophenes in straight-run diesel oil, shows a higher desulfurization rate, and improves the quality of oil products.

The invention provides a molybdenum mineral content measuring method, and belongs to the field of process mineralogy, and the method comprises the following steps: carrying out ore grinding, ore washing and desliming treatment on a to-be-measured sample to obtain slurry and ore washing concentrate; the ore washing concentrate is subjected to gravity separation, and gravity separation concentrate and gravity separation tailings are obtained through separation; mixing the slime and the gravity concentrate to obtain a mixed sample, and performing molybdenum phase analysis to obtain the content of molybdenum oxide; an automatic mineralogical analysis sample of the mixed sample and an automatic mineralogical analysis sample of the gravity separation tailings are prepared respectively, automatic mineralogical analysis is carried out, and a molybdenite content correction coefficient and a molybdenum oxide content correction coefficient are calculated; and calculating the content of various molybdenum minerals in the to-be-detected sample in combination with the correction coefficient and the mineral content data. By optimizing the sample preparation process, molybdenite oxidation is reduced, and the mineral recognition accuracy is improved. Molybdenum oxide and molybdenum sulfide are treated separately, different correction processes are adopted, and the accuracy of ore molybdenum mineral measurement is improved in a targeted mode.

The invention discloses a Mo-Bi-based catalyst and a preparation method and application thereof.The catalyst comprises active components, the active components comprise spherical particles and molybdenum oxide nanorods attached to the surfaces of the spherical particles, and the spherical particles contain molybdenum and / or molybdenum oxide and bismuth and / or bismuth oxide. When the catalyst is applied to propylene oxidation synthesis of acrolein, the catalyst has the technical effect of high acrolein selectivity.

The invention relates to the technical field of nano powder material preparation, in particular to a method for preparing molybdenum powder based on a spray granulation precursor and the molybdenum powder. The method for preparing the molybdenum powder comprises the steps that ammonium molybdate and a pore forming agent are dissolved in ultrapure water at the room temperature, and mixed slurry is obtained; carrying out spray granulation treatment on the mixed slurry to obtain composite powder particles containing the pore-forming agent and ammonium molybdate; the composite powder particles are placed in an oxygen-containing atmosphere to be roasted, and superfine nano molybdenum trioxide is obtained; placing the superfine nano molybdenum trioxide in a hydrogen atmosphere for primary reduction treatment to obtain superfine molybdenum dioxide powder; and the superfine molybdenum dioxide powder is subjected to second-stage reduction treatment, the superfine molybdenum powder is obtained, and the reduction conditions of the first-stage reduction treatment and the second-stage reduction treatment are different. According to the preparation method, the superfine molybdenum powder with good uniformity and dispersity can be prepared.

The invention relates to the technical field of superfine molybdenum powder preparation, in particular to a preparation device and method for low-oxygen superfine molybdenum powder. The specific preparation device comprises a sublimation bin, a reaction area and a gas-solid separation bin which are sequentially connected, the reaction zone comprises a preheating zone, a reduction zone and a conversion zone; a part of the hydrogen pipeline and a part of the carbon monoxide pipeline are arranged in the preheating area; one end of the hydrogen pipeline extends to the reduction area and is used for providing preheated hydrogen and carrying out gas-phase reduction reaction on the preheated hydrogen and the gas-phase MoO3 subjected to heat preservation; one end of the carbon monoxide pipeline extends to the conversion area and is used for providing preheated carbon monoxide and reacting with water vapor to complete primary water vapor conversion; meanwhile, partial carbon monoxide is subjected to a disproportionation reaction to generate micro carbon powder, and the micro carbon powder and water vapor are subjected to a water gas reaction to complete secondary water vapor conversion. The problem that the oxygen content of existing superfine molybdenum powder prepared through gas-phase molybdenum trioxide reduction is too high is solved.

The invention provides a preparation method of a molybdenum phosphide / titanium nitride composite material and a battery positive electrode material and a lithium-carbon dioxide battery, and belongs to the technical field of new energy materials. And then a titanium nitride conductor layer is deposited on the molybdenum phosphide by using an atomic layer deposition technology to prepare the molybdenum phosphide / titanium nitride, the molybdenum phosphide is combined as a transition metal phosphide to have stable catalytic performance, and the titanium nitride is used as a conductor to have excellent conductivity. The lithium-carbon dioxide battery positive electrode catalyst with high catalytic activity, high conductivity and excellent stability is obtained through the synergistic effect of the two materials, and when the lithium-carbon dioxide battery positive electrode catalyst is applied to a lithium battery, higher energy density, longer cycle life and better rate capability are shown, so that the overall performance of the battery is improved, and the application prospect is wide. The requirements on high-performance batteries in the fields of electric automobiles, energy storage systems and the like are met.

The invention relates to the technical field of catalyst preparation, in particular to a deep hydrodenitrogenation and desulfurization catalyst and a preparation method thereof. According to the preparation method, a novel hydrodenitrogenation and desulfurization catalyst is obtained by redesigning raw materials of the catalyst and a preparation process of the catalyst. The raw material is a pseudo-boehmite product, and the active components comprise 18-25% of molybdenum oxide, 3.3-5.5% of nickel oxide and 1-3% of silicon oxide. The catalyst not only solves the problem of easy coking, but also prolongs the service life of the product to 2-3 years, can effectively reduce the use amount of the hydrodenitrogenation and desulfurization catalyst, reduces the use cost of the hydrodenitrogenation and desulfurization catalyst, and improves the hydrodenitrogenation and desulfurization effect of a reactor.

The invention discloses a preparation method of carbonyl fluoride, which comprises the following steps: with hexafluoropropylene and oxygen as raw materials, introducing gas into a reactor filled with a catalyst for reaction at high temperature; the catalyst is one of palladium oxide, ruthenium oxide, platinum oxide and molybdenum oxide. According to the scheme, the cost is low, the raw material utilization rate is high, and compared with other carbonyl fluoride synthesis methods, the reaction does not involve phosgene, fluorine and other dangerous chemicals, and reaction by-products are few. In addition, according to the method, the toxicity of raw materials is small, hexafluoropropylene can be completely reacted under the condition of excessive oxygen, the reaction process is environment-friendly and simple, and basically no three wastes are generated. According to the method, hexafluoropropylene and oxygen are adopted as raw materials which are common chemical raw materials and are cheap and easy to obtain, and the method is simple in reaction process, mild in reaction, easy to operate and suitable for industrial production.

The invention relates to the technical field of nano powder material preparation, in particular to a method for preparing molybdenum powder with controllable granularity and the molybdenum powder. The method for preparing the molybdenum powder with the controllable granularity comprises the steps that molybdenum salt and a pore forming agent are dissolved in water at the room temperature, and a mixed solution is obtained; drying the mixed solution to obtain a nano mixture of molybdenum salt coated with a pore-forming agent; roasting the nano mixture in an oxygen-containing atmosphere to obtain superfine molybdenum trioxide powder; the molybdenum trioxide powder is subjected to first-stage hydrogen reduction treatment, and superfine molybdenum dioxide powder without preferred orientation is obtained by adjusting the hydrogen dew point and the temperature field in the reduction process; and carrying out two-stage hydrogen reduction treatment on the superfine molybdenum dioxide powder to obtain molybdenum powder, and grinding and dispersing the molybdenum powder to obtain the superfine molybdenum powder. According to the preparation method, the superfine molybdenum powder with good uniformity and dispersity and controllable granularity can be prepared.

The present invention provides a carbon-coated iron-molybdenum catalyst and a preparation method and application thereof, belonging to the technical field of catalysts. The present invention first prepares iron-molybdenum oxide, then mixes the iron-molybdenum oxide with a carbon source solution, so that the carbon source can be evenly attached to the surface of the iron-molybdenum oxide, and forms a carbon-coated iron-molybdenum catalyst through pyrolysis. The graphene carbon layer generated on the surface of the metal iron-molybdenum catalyst can effectively protect the internal metal catalyst, prevent it from oxidation, agglomeration and loss, and extend the service life. At the same time, this graphene carbon layer can also have a positive effect on the adsorption mode of reactant molecules on the active sites of the catalyst, optimize the catalytic reaction process, and improve the conversion rate of formaldehyde and the service life of the catalyst; the addition of a surfactant can effectively disperse the metal iron-molybdenum catalyst particles, prevent them from agglomerating and precipitating, improve the effective utilization rate of the active metal, and also facilitate the carbon layer to be evenly coated on the catalyst surface.

The invention discloses a molybdenum oxide nanorod material, a preparation method of the molybdenum oxide nanorod material and application of the molybdenum oxide nanorod material to improvement of corn nutrient utilization, growth promotion and lodging resistance, and belongs to the technical field of corn nutrient utilization and agricultural nano material application. The morphology and dispersity of the nanorod are optimized by combining molecular composition characteristics of key enzymes (such as nitrate reductase and glutamine synthetase) in a corn nutrient utilization process, and finally the functional nanorod with targeting property and biocompatibility is obtained and can be widely applied to nutrient regulation and control scenes of corn water culture and field planting. After the material is applied, the activity of nitrate reductase and glutamine synthetase of a corn root system can be activated in a targeted manner, the nutrient utilization efficiency is accurately improved, and sufficient nutrition support is provided for plant growth. After the fertilizer is applied to plants, the root system is promoted to be developed, the stalks are thick and strong, the lodging resistance is remarkably enhanced, the protein content of the plants and grains can be increased, and the synergistic effects of efficient nutrient utilization, robust plant growth, lodging resistance and yield increase are achieved.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an efficient flame-retardant low-toxic-gas-release silicone rubber composite material and a preparation method thereof. The high-efficiency flame-retardant low-toxic-gas-release silicone rubber composite material comprises the following components in parts by weight: 100 parts of methyl vinyl silicone rubber; 10 to 20 parts of ZIF-67 modified by polysiloxane; 5-10 parts of modified nano molybdenum oxide; 5 to 10 parts of melamine cyanurate; 40 to 50 parts of mesoporous SiO2 aerogel; 1-3 parts of hydroxyl silicone oil; 0.5 to 1.5 parts of a vulcanizing agent; and 0-5 parts of an auxiliary agent. The flame-retardant and smoke-suppression performance of the silicone rubber composite material is remarkably improved through material technology innovation, and meanwhile, the mechanical property and the high temperature resistance are improved.

The invention provides a Ni-molybdenum oxide / Nb2O5 nano composite catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalysts. The catalyst precursor is prepared by adopting an excessive impregnation method, then the Ni-molybdenum oxide / Nb2O5 nano-composite catalyst is prepared by adopting a hydrogen reduction treatment method, active components in the catalyst are uniformly loaded, and the catalyst has excellent self-hydrogen hydrothermal catalytic performance. The Ni-molybdenum oxide / Nb2O5 nano composite catalyst prepared by the invention can minimize the dissociation energy of a C-O bond, promote the breakage of the C-O bond, enable the reaction to be carried out in a forward direction, and realize high-value conversion of guaiacol to catechol under mild reaction conditions without exogenous hydrogen.

The invention provides a waste molybdenum-based catalyst regeneration method which comprises the following steps: crushing and grinding a waste molybdenum-based catalyst to obtain catalyst powder; adding a liquid caustic soda solution into the obtained catalyst powder, and placing in a reaction kettle for hydrothermal reaction to obtain molybdenum hydroxide and sodium sulfate; the obtained molybdenum hydroxide is sequentially subjected to drying treatment, forming treatment and calcining treatment, and the regenerated catalyst is obtained. According to the present invention, the poisoning catalyst is regenerated by mainly using the hydrothermal reaction principle, such that the catalyst cost can be reduced, and the operation cost caused by other waste catalyst recovery methods can be avoided, such that the regeneration of the catalyst active component is achieved through the multi-stage staged treatment so as to significantly improve the regeneration efficiency and the regeneration frequency; and a new technical path is provided for resource utilization of the waste molybdenum-based catalyst.