The invention provides a multi-element
lithium supplement agent and a preparation method thereof, a positive
pole piece and a
lithium ion battery, the multi-element
lithium supplement agent comprises an inner core, a first
coating layer and a second
coating layer, the inner core comprises lithium-rich lithium aluminum ferrite, the first
coating layer comprises lithium-rich lithium
manganate, and the second coating layer comprises lithium-rich lithium nickelate; the chemical general formula of the multi-element lithium supplement agent is LixFeaAlbMncNidOy, 0.1 < = d / (a + b) < = 0.9, 0.62 < = a < = 0.96, 0.04 < = b < = 0.38, 0.005 < = c / (a + b) < = 0.02, 5a + 5b + 2c + 2d < = x < = 5.5 a + 5.5 b + 2.1 c + 2.1 d, and y = (x + 3a + 3b + 4c + 2d) / 2. Iron and aluminum are adopted as main elements, and lithium-rich lithium
manganate and lithium-rich lithium nickelate are coated at the same time, so that the stability of the lithium supplementing agent can be improved, gas production can be reduced, the
ionic conductivity can be improved, and the capacity
exertion of the lithium supplementing agent can be promoted.