753results about "Iron compounds" patented technology

A lithium manganese iron phosphate cathode material, including a first lithium manganese iron phosphate particle and a second lithium manganese iron phosphate particle. A molar ratio of Mn to Fe in the first lithium manganese iron phosphate particle is greater than or equal to 1. A molar ratio of Mn to Fe in the second lithium manganese iron phosphate particle is smaller than or equal to the molar ratio of Mn to Fe in the first lithium manganese iron phosphate particle. A particle size of the first lithium manganese iron phosphate particle is smaller than or equal to a particle size of the second lithium manganese iron phosphate particle. A preparation method of the lithium manganese iron phosphate cathode material and an application thereof are provided. The first precursor, having a manganese content greater than or equal to that of iron, inhibits crystal growth during sintering, resulting in a smaller particle size. The second precursor, having a manganese to iron ratio smaller than or equal to the ratio in the first precursor, promotes crystal growth during sintering, resulting in a larger particle size. This results in a particle size grading between large particles and small particles, improves the spatial utilization of particle packing, and enhances the compaction density and volumetric capacity of the lithium manganese iron phosphate cathode material.

The application discloses a MnFe2O4 / GO wave-absorbing aerogel with a directional aperture structure and a preparation method thereof, belongs to the technical field of wave-absorbing material preparation, and is characterized in that manganese ferrite (MnFe2O4) magnetic particles are uniformly loaded on the surface of graphene to obtain a graphene aerogel with a three-dimensional loose porous structure and magnetic particle assembly; the MnFe2O4 is prepared by using a low-temperature co-precipitation method, and the MnFe2O4 / GO wave-absorbing aerogel is prepared by combining directional freezing and heat treatment, and the method is mild and simple. The application improves the impedance mismatch problem of the graphene material, enhances the magnetic loss of the material, and obtains a novel porous aerogel wave-absorbing material which has both dielectric loss and magnetic loss by introducing the manganese ferrite.

The invention discloses an oxide-coated ion-doped sodium ferric sulfate positive electrode material as well as a preparation method and application thereof. The positive electrode material is formed by compounding a sodium ferric sulfate bulk phase material doped with various valence metal cations and anions and coated with carbon similar to a positive temperature coefficient thermosensitive metal oxide. Wherein the metal cations with various valence states are doped on Na or Na / Fe ion sites of the sodium ferric sulfate, the doped anions occupy part of three-dimensional S-O tetrahedron positions, the inorganic carbon in the carbon compound is uniformly distributed in the sodium ferric sulfate bulk phase material, and the organic carbon is uniformly distributed outside the sodium ferric sulfate bulk phase material. The positive electrode plate assembled battery prepared from the positive electrode material has the advantages of high reversible charge-discharge capacity, excellent cycle performance and rate capability and high electron and ion migration rate in a low-temperature environment. The method is low in raw material cost, simple in synthesis method, short in production period and suitable for large-scale continuous production.

The present application relates to the technical field of sodium‑ion batteries, and provides a sodium iron sulfate-based composite positive electrode material, and a preparation method therefor and a use thereof. The sodium iron sulfate-based composite positive electrode material has a porosity of 0.1%-10% and a compacted density of 2.1-3 g / cm3; in addition, the sodium iron sulfate-based composite positive electrode material has a specific surface area of 5-12 m2 / g, and a sodium-rich impurity phase in the sodium iron sulfate-based composite positive electrode material has a mass percentage content of 0.1%-1%. The present application helps to improve the performance of batteries, such as the charge / discharge capacity and the initial coulombic efficiency.

The invention belongs to the technical field of electrochemistry, and particularly provides a lanthanum-cerium double-doped sodium ferric sulfate positive electrode material and a preparation method thereof. The material is composed of a matrix and a carbon coating layer coating the matrix, the matrix has a chemical expression of Na6Fe4-x-yLaxCey (SO4) 7, x is greater than or equal to 0.01 and less than or equal to 0.1, and y is greater than or equal to 0.01 and less than or equal to 0.1. The material is prepared through spray drying and high-temperature sintering treatment in sequence, the particle morphology is regular, and the particle size distribution is uniform; the electronic conductivity and Na < + > diffusion rate of the material are remarkably improved by rare earth doping, so that the material has more excellent low-temperature cycle performance, sodium storage performance and the like.

The invention discloses a lithium supplement agent which comprises a lithium supplement inner core and a carbon coating layer coating the surface of the lithium supplement inner core, and the lithium supplement inner core is doped with an Al element; the lithium supplementing agent meets the condition that A / I is larger than or equal to 0.3 and smaller than or equal to 4, A is the mass ratio of the Al element in the lithium supplementing agent, and I is the ID / IG value of the lithium supplementing agent in a Raman spectrogram. By regulating and controlling the A / I ratio of the Al doping amount to the carbon coating layer structure, the lithium supplementing capacity, the conductivity and the air stability are improved, and meanwhile, the gas production phenomenon in the lithium removal process is effectively inhibited.

A method for preparing a positive electrode material and an energy storage battery are provided. The method includes: preparing an Fe-MOF, including: dispersing a first iron source in a solvent, adding the cyanamide organic ligands into the solvent to perform reflux reaction to obtain a reaction solution, and performing cooling, filtering, and cleaning on the reaction solution to obtain the Fe-MOF; grinding and blending the Fe-MOF with a second iron source, a lithium source, and a phosphorus source to obtain a premix; and performing a sintering treatment on the premix under an atmosphere of an inert gas to obtain a composite lithium iron phosphate positive electrode material. The composite lithium iron phosphate positive electrode material includes lithium iron phosphate particles and carbon nanotubes, the lithium iron phosphate particles are attached to a surface of the carbon nanotubes, and there is iron wrapped by each of the carbon nanotubes.

The invention discloses a method for preparing a NaFeO2 material and leaching copper, zinc and molybdenum from copper slag, and relates to the technical field of metallurgical solid waste resource utilization. The method comprises the following steps: grinding the copper slag, mixing the ground copper slag with a sodium salt, roasting the mixture in a muffle furnace at a proper temperature, and finally carrying out ultrasonic washing and filtering on the roasted product to obtain filter residues and filtrate; and drying filter residues to obtain a high-purity NaFeO2 material, and recovering valuable metals such as copper, zinc and molybdenum from filtrate. In the washing process, valuable metal elements copper, zinc and molybdenum in the copper slag are efficiently leached into the solution, the leaching rate reaches 96% or above, and synchronous recovery of the valuable elements is achieved; according to the method, the industrial waste residue copper slag is successfully converted into the NaFeO2 product with the high additional value, meanwhile, valuable metal is efficiently extracted, the method has the advantages of being simple in process, low in cost, high in recycling degree and environmentally friendly, a new way is opened up for high-value utilization of the copper slag, and the method has good industrial application prospects.

The invention provides a multi-component composite metal oxide nanosheet gradient coating polypropylene diaphragm and a preparation method and application thereof, and the multi-component composite metal oxide nanosheet gradient coating polypropylene diaphragm comprises a polypropylene substrate and a Ti-Fe-Zr ternary composite oxide nanosheet gradient coating coated on the surface of the substrate, the thickness of the coating is 1-2.5 [mu] m, a gradient structure in which the concentration of nanosheets decreases progressively is formed from the surface to a substrate, the thickness of a surface compact layer accounts for 30-40%, and the interlayer spacing is 1.0-2.0 nm. The diaphragm disclosed by the invention has excellent electrolyte affinity, ionic conductivity and thermal stability, and can effectively inhibit the growth of lithium dendrites and prolong the cycle life of the battery.

The invention discloses a preparation method of a non-stoichiometric lithium supplement additive, a low-ratio non-stoichiometric base material is used as a core, an outer shell is a carbon-coated metal oxide layer, and the preparation method comprises the following steps: uniformly mixing iron oxide powder and a mixed lithium source, and carrying out uniform stirring to obtain a mixture; sintering, crushing and sieving the obtained blended powder in an inert gas atmosphere to obtain a lithium supplement additive base material A; and sufficiently and uniformly mixing the base material A and the carbon-coated improved oxide powder, and sintering to obtain a final product. The non-stoichiometric iron-based lithium supplement agent is synthesized, the intrinsic lithium preparation amount is greatly reduced, and part of low-cost lithium salt is mixed, so that the cost is effectively reduced, the residual alkali can be reduced, and the battery processing performance is improved; in addition, by adopting the carbon-coated metal oxide MxOy (at) C, conductivity improvement and an oxygen adsorption module are organically combined, the conductivity of the lithium supplementing agent is improved, the oxygen release amount is reduced, and the comprehensive performance of the lithium supplementing agent is obviously improved.

The invention relates to the technical field of battery sodium supplementation agents, in particular to a sodium supplementation agent with a core-shell structure, a preparation method and a positive pole piece. The preparation method comprises the following steps: providing a core material containing sodium salt; a first coating process: providing a first coating material containing organic fluorine, mixing the core material containing the sodium salt with the first coating material, and performing first sintering to obtain a primary coating coated with a first coating layer; and a second coating process: providing a second coating material containing a carbon source, mixing the second coating material with the primary coating, and carrying out second sintering to obtain the sodium supplement which is coated with a first coating layer and a second coating layer and has the core-shell structure. The invention provides the sodium supplementing agent with the core-shell structure, the preparation method and the positive pole piece, so that the problem of poor sodium supplementing performance of the sodium supplementing agent in the related technology is solved.

The invention relates to the technical field of sodium ion battery positive electrode materials, in particular to a composite sodium ferric sulfate positive electrode material, a sodium ion battery and a preparation method. The preparation method comprises the following steps: preparing a group IIIA metal doped composite sodium ferric sulfate precursor; mixing with a solution containing a sodium source, an iron source and a phosphorus source; and performing staged heat treatment under a protective atmosphere to form a pyrophosphate ferric phosphate sodium coating layer. The particle size D50 of the composite sodium ferric sulfate positive electrode material is 3-5 [mu] m, and the composite sodium ferric sulfate positive electrode material can inhibit iron dissolution and enhance structural stability through bulk phase doping and surface coating cooperation, can prolong the cycle life of a battery and reduce gas production, and is suitable for a high-performance sodium ion battery.

Provided is a MnZn-based ferrite having excellent characteristics of maximum magnetic flux density (Bm) even in a high-temperature environment. The MnZn ferrite according to one embodiment of the present invention contains Fe2O3, ZnO, and MnO as main components, in 100 mol% of the main components, the content of Fe2O3 is 56.0 to 59.0 mol%, the content of ZnO is 2.5 to 7.0 mol%, and the remainder is MnO, and the MnZn ferrite contains 0.010 to 0.050 mass% of SiO2, 0.020 to 0.060 mass% of CaO, and 0.150 to 0.350 mass% of Co2O3 as auxiliary components relative to 100 mass% of the main components.

The invention discloses a preparation method of a lanthanum ferrite / zinc oxide composite material, which comprises the following steps: preparing lanthanum ferrite LFO, ultrasonically stirring ferric nitrate nonahydrate, lanthanum nitrate hexahydrate and a dispersing agent in a hydrothermal solvent to obtain a mixed solution, preparing an LFO / ZnO composite material, dispersing the LFO prepared in the step S1 and zinc acetate in ethanol, performing ultrasonic treatment, heating and stirring, and condensing and refluxing to obtain the LFO / ZnO composite material. Cooling, and continuously stirring in an ice-water bath; dropwise adding a NaOH ethanol solution at the temperature of 0 DEG C, and stirring for 2 hours; adding deionized water, stirring, centrifuging to remove the supernatant, dispersing the precipitate powder in ethanol, and carrying out hydrothermal reaction; after the hydrothermal reaction is finished, centrifuging the solution, and after centrifugation is finished, pouring out the solution to obtain a precipitate; washing with deionized water and an ethanol solution, drying the precipitate, and calcining the dried powder in a muffle furnace to obtain a p-n type LFO / ZnO composite material; according to the method, the size of lanthanum ferrite can be accurately regulated and controlled through a cooperative regulation strategy of the solvent proportion and the ligand size, and different types of gases can be accurately distinguished.

The invention discloses a preparation method of an iron-doped cerium-based perovskite type high-selectivity Cu ion capture stabilizing agent and application of the stabilizing agent in heavy metal pollution remediation, and the stabilizing agent is prepared through a sol-gel method and comprises the steps that cerous nitrate and citric acid are dissolved in water, and the mixture is heated and stirred to be gel-shaped; standing the gel solution in a drying oven at a constant temperature to obtain a Fe-Ce-PVSK precursor; grinding the precursor into powder, putting the powder into a quartz boat, and calcining in an air atmosphere through a horizontal tube furnace to obtain a product; and finally, washing to be neutral to obtain the iron-doped cerium-based perovskite stabilizing agent. Due to the high oxygen vacancy concentration and rich active sites, the stabilizing agent has high selectivity and high adsorption capacity and has specific capturing capacity on Cu < 2 + >. The preparation method has mild reaction conditions. The stabilizing agent can effectively reduce the bio-availability of heavy metals in a polluted matrix, promote healthy growth of plants, and realize pollution restoration and ecological function recovery at the same time.

The invention provides rare earth based hexaaluminate, a preparation method thereof and a methane combustion catalyst. The general formula of the rare earth based hexaaluminate is AByAl12-yO19, A is a rare earth element and / or an alkaline earth metal element, B is a transition metal element, and y is more than 0 and less than 12. By introducing the rare earth element and / or alkaline earth metal, the stability of a hexaaluminate skeleton is enhanced, and the high temperature resistance of the hexaaluminate skeleton is further improved; and meanwhile, the transition metal is used for partially replacing Al < 3 + >, so that the catalyst has better high-temperature catalytic activity when being applied to catalytic methane combustion, and the methane catalytic combustion reaction temperature can be obviously reduced.

The invention provides a multi-element lithium supplement agent and a preparation method thereof, a positive pole piece and a lithium ion battery, the multi-element lithium supplement agent comprises an inner core, a first coating layer and a second coating layer, the inner core comprises lithium-rich lithium aluminum ferrite, the first coating layer comprises lithium-rich lithium manganate, and the second coating layer comprises lithium-rich lithium nickelate; the chemical general formula of the multi-element lithium supplement agent is LixFeaAlbMncNidOy, 0.1 < = d / (a + b) < = 0.9, 0.62 < = a < = 0.96, 0.04 < = b < = 0.38, 0.005 < = c / (a + b) < = 0.02, 5a + 5b + 2c + 2d < = x < = 5.5 a + 5.5 b + 2.1 c + 2.1 d, and y = (x + 3a + 3b + 4c + 2d) / 2. Iron and aluminum are adopted as main elements, and lithium-rich lithium manganate and lithium-rich lithium nickelate are coated at the same time, so that the stability of the lithium supplementing agent can be improved, gas production can be reduced, the ionic conductivity can be improved, and the capacity exertion of the lithium supplementing agent can be promoted.

This disclosure provides lithium supplement materials, including Li5Fe1-xMxO4 and a cladding layer disposed on a surface of Li5Fe1-xMxO4. In Li5Fe1-xMxO4, where M is at least one of Ni, Mn, Ru, Cr, Cu, Nb, Al, Mg, Ca, Ga, Ti, and Mo, and 0≤x≤0.2. The cladding layer includes M′-doped zinc oxide or M′-doped composite oxide based on zinc oxide, and M′is an ion capable of forming a substitutional solid solution with zinc oxide or composite oxide based on zinc oxide.

The invention discloses a preparation method of manganese-based hydrotalcite and application of the manganese-based hydrotalcite in removing thallium pollution. According to the invention, the manganese-based hydrotalcite is prepared by adopting a nucleation crystallization method by accurately regulating and controlling the hydrotalcite laminate element composition, the interlayer ion species and the atomic proportion. The prepared manganese-based hydrotalcite realizes high-selectivity specific adsorption of thallium pollutants through surface hydroxyl complexing, interlayer anion exchange, electrostatic interaction and oxidation-reduction reaction. Even in a complex adsorption environment, such as interference of different pH values, various common metal cations and organic matters, the manganese-based hydrotalcite can still keep the adsorption efficiency higher than 95%, and in a natural water environment, thallium pollutants can be effectively reduced to be lower than the national surface water discharge standard (0.1 microgram / L).

The invention provides a positive electrode material and a preparation method thereof, a battery monomer, a battery device and a power utilization device. The positive electrode material comprises a sodium transition metal oxide and a silicate material located on the surface of the sodium transition metal oxide, the positive electrode material has the following chemical formula: NaxMyNzO2 / (aNa2O.nSiO2-XrOt.SiO2) b, M comprises one or more of Fe, In, Co, Mn, Ni and Cr, N comprises one or more of Cu, Li, Ti, Zr, K, Sb, Nb, Mg, Ca, Mo, Zn, W, Bi, Sr, Sn, Ga and Al, and X comprises one or more of Na, Li, K, Mg, Ca, Zn, Al, Cr, Sr, Sn and Sb; 0.58 < = x < = 1.05, 0 < y < = 1, 0 < = z < = 1, 0 < y + z < = 1, 1 / 3 < = r / t < = 2, 1 < = n / a, and 0 < b < = 0.2. The positive electrode material provided by the invention can improve the rate capability and the processability of the battery monomer.

A lithium manganese iron phosphate cathode material, including a first lithium manganese iron phosphate particle and a second lithium manganese iron phosphate particle. A molar ratio of Mn to Fe in the first lithium manganese iron phosphate particle is greater than or equal to 1. A molar ratio of Mn to Fe in the second lithium manganese iron phosphate particle is smaller than or equal to the molar ratio of Mn to Fe in the first lithium manganese iron phosphate particle. A particle size of the first lithium manganese iron phosphate particle is smaller than or equal to a particle size of the second lithium manganese iron phosphate particle. A preparation method of the lithium manganese iron phosphate cathode material and an application thereof are provided.

To provide a ferrite powder having excellent temporal stability of a magnetic permeability while maintaining a high filling property, and a high magnetic permeability and a low loss at a high frequency. The ferrite powder contains: 56.0 mass% or more and 63.0 mass% or less of iron (Fe); 7.0 mass% or more and 13.0 mass% or less of manganese (Mn); and 1.0 mass% or more and 3.0 mass% or less of zinc (Zn).

A carbon-coated cathode material (3) and a preparation method thereof. The carbon-coated cathode material (3) includes a lithium metal phosphate particle (P) and a carbon coating layer (C). The carbon coating layer (C) is coated on the lithium metal phosphate particle (P). The carbon coating layer (C) is formed by a first heat treatment and a second heat treatment. A first carbon source is added in the first heat treatment, and a second carbon source is added in the second heat treatment. The first carbon source has a first weight percentage relative to the lithium metal phosphate particle (P). The second carbon source has a second weight percentage relative to the lithium metal phosphate particle (P). The first weight percentage of the first carbon source is equal to or less than the second weight percentage of the second carbon source.

The application discloses a doped sodium iron fluorosulfate compound, a positive electrode material and a preparation method thereof and a sodium ion battery. y M z (SO4)2F, wherein y+z=1, 0 The doped sodium iron fluorosulfate compound of the application not only reduces the gas production, but also has relatively high gram capacity performance and cycle performance.

The invention relates to an iron-containing gadolinium-doped cerium oxide electrode material, a solid oxide battery and a preparation method, the chemical formula of the iron-containing gadolinium-doped cerium oxide electrode material is FexGd0. 1Ce0. 9-xO2-delta, x is more than or equal to 0.025 and less than or equal to 0.2, and delta is more than or equal to 0.05 and less than or equal to 0.2. The preparation method comprises the following steps: adding a gadolinium source, a cerium source and an iron source into deionized water according to a stoichiometric ratio, uniformly mixing to obtain a mixed solution, sequentially adding a complexing agent and a pH regulator into the mixed solution, and heating and stirring for reaction to obtain precursor gel; drying and crushing the precursor gel to obtain precursor powder; and calcining the precursor powder to obtain the iron-containing gadolinium-doped cerium oxide electrode material. The electrode material disclosed by the invention is relatively simple and uniform in component; when being used as a fuel electrode to be applied to a solid oxide electrolytic cell for CO2 electrolysis, the composite material shows excellent electrochemical performance, and can still keep a stable structure and good durability after long-term operation in a high-temperature CO2 atmosphere.

The application discloses a preparation method and application of a fluoride sodium ion battery positive electrode material, and belongs to the technical field of sodium ion battery positive electrode material preparation, and comprises the following steps: (1) dissolving an iron salt in deionized water to obtain an A solution; uniformly mixing sodium fluoride and an inorganic acid in water to obtain a B solution; (2) dropping the A and B solutions into a co-precipitation reaction kettle at the same flow rate, and reacting under heating and stirring, and monitoring the pH value of the reaction system in real time; and washing and drying to obtain a precursor Na3FeF6; (3) mixing the precursor with a carbon source, and sintering under an inert atmosphere to obtain a sodium ion battery positive electrode material NaFeF3@C coated with a carbon layer; the application effectively solves the capacity attenuation and cycle stability problems of the sodium ion battery positive electrode material, and provides a solution with high performance, low cost and environmental friendliness for development of the sodium ion battery positive electrode material.

A positive electrode active material for secondary batteries includes a lithium metal composite oxide having a crystal structure that can be attributed to the space group Fm-3m. The lithium metal composite oxide contains at least Li, Mn, Ti, and M. The M is a positive element different from Li, Mn, and Ti. The crystallite size of the lithium metal composite oxide is in a range of 1 nm to 100 nm, or in an X-ray diffraction (XRD) profile using CuKα radiation of the lithium metal composite oxide, the half-value width of a diffraction peak attributed to the (200) plane is in a range of 0.1° to 1.8°, based on 2θ.

A rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material includes a rhombohedral zinc orthosilicate (Zn2SiO4) phase, a cubic zinc ferrite (ZnFe2O4) phase, and a hexagonal silicon dioxide (SiO2) phase. The rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material exhibits a morphology including spherical microscale particles with an average diameter ranging from 0.8 micrometer (μm) to 1.8 μm and irregular nanoscale aggregates with an average diameter ranging from 50 nanometer (nm) to 110 nm. The rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material has an adsorption capacity for basic fuchsin dye of greater than or equal to 140 milligrams per gram (mg / g). Furthermore, a method for producing the rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material includes calcination of metal precursors.

The application provides an inverse perovskite material, a preparation method thereof, a positive electrode material and a sodium ion battery, and belongs to the technical field of electrode materials. The inverse perovskite material has an inverse perovskite structure phase, and a chemical expression formula of the inverse perovskite material is Na x Li y TM z Ch m O n ; wherein 1.5 >= x >= 0.4, 1.6 >= y >= 0.5, 0.8 <= z <= 1.2, 0.8 <= m <= 1.2, and 0.8 <= n <= 1.2; TM is selected from transition metal elements, and Ch is selected from chalcogen elements. The application can improve the first circle discharge specific capacity and the cycle performance of a sodium ion battery prepared by using the inverse perovskite material as a positive electrode material by selecting Na elements, Li elements, transition metal elements, chalcogen elements and oxygen elements and regulating the ratio of the elements.

The present application discloses a lithium-supplementing additive, and a preparation method therefor and an application thereof. The lithium-supplementing additive comprises a granular lithium-supplementing material and also comprises lithium fluoride; moreover, the lithium fluoride is at least bonded to the surface of the lithium-supplementing material, and the lithium fluoride is generated by the reaction between an organic fluorine source and residual alkali contained in the lithium-supplementing material. The lithium-supplementing additive is high in purity, and a lithium fluoride coating layer at least bonded in situ to the surface of the lithium-supplementing material effectively achieves the effect of isolation and protection, so that it is ensured that the lithium-supplementing material is high in lithium-supplementing effect, storage performance and processing performance; moreover, the lithium fluoride improves the lithium-ion intercalation and deintercalation performance and the lithium-ion conductivity. In addition, the preparation method for a lithium-supplementing additive can ensure that a prepared lithium-supplementing additive is stable in structure and electrochemical performance, the efficiency is high, and the production cost is saved.